Abstract: This invention concerns a stabilized packaging environment for a particulate vinyl lactam polymer, particularly polyvinylpyrrolidone particles, which comprises a sealed, oxygen-impervious receptacle containing said polymer particles and a separate air permeable package within the receptacle containing a water moistened oxygen scavenging agent, preferably iron powder, an iron (II) salt, ascorbic acid or a mixture of such agents.
Type:
Grant
Filed:
September 16, 1998
Date of Patent:
December 18, 2001
Assignee:
ISP Investments Inc.
Inventors:
Chi-San Wu, Laurence Senak, Donna Osborne, James F. Curry, Charles B. Schriver, Irwin B. Silverstein
Abstract: The present invention is directed towards compositions which contain a crosslinked absorbent polymer and a water soluble low molecular weight compound. The water soluble low molecular weight compound reduces the rate at which water evaporates from the crosslinked absorbent polymer. The crosslinked absorbent polymers of this invention have a water retention value greater than or equal to about 6. This invention also is directed towards methods for preparing the compositions of this invention.
Abstract: A polymer useful in oral care compositions which has a reactive group covalently bonded to a bactericide, flavorant and/or essential oil compound, said bond being hydrolyzable in aqueous solution to slowly release said compound into said composition.
Abstract: The hydroxybenzoate compounds of this invention are defined by the formula:
wherein Y is hydrogen, hydroxy, halo, a C1 to C6 alkyl or a C2 to C6 alkyl ether;
R is a C4 to C6 mono- or di-olefinically unsaturated hydrocarbon radical, a C4 to C7 mono- or di-acetylenically unsaturated hydrocarbon radical or a C2 to C3 acetylenically unsaturated hydrocarbon radical when at least one of X and Y is other than hydrogen and
X is hydrogen, hydroxy, halo, a C1 to C6 alkyl, a C2 to C6 alkyl ether or
in which A is selected from the group of X,
B is selected from the group of Y and
R1 is hydrogen, hydroxy, C1 to C6 alkyl, C1 to C6 alkoxy or —COOR2 in which R2 is C1 to C6 alkyl, a C2 to C6 olefinically unsaturated hydrocarbon radical or a C2 to C7 acetylenically unsaturated hydrocarbon radical.
Abstract: A cosmetic composition for rejuvenating the appearance of skin with reduced or minimal potential for skin irritation, in the form of a lotion, creme, solution or gel, or applied onto a carrier, includes about 0.5 to 50 wt. % in an aqueous, alcoholic or aqueous-alcoholic solution of a solvent-free, high molecular weight terpolymer of methyl vinyl ether-maleic anhydride-isobutylene, said composition having a pH of 1.5 to 5.
Abstract: A process of making a cosmetically or pharmaceutically-acceptable emulsion or gel composition which comprises: (a) heating a reaction mixture comprising, by weight, about 5-70% of a vinyl monomer in about 30-95% of an oil as solvent, wherein said oil is selected from the group consisting of a silicone oil, a mineral oil and a water-insoluble organic ester and a free radical initiator, optionally in the presence of a crosslinking agent and/or an oil soluble surfactant, with agitation, under an inert gas, at about 40-150° C., wherein the oil is present in an amount sufficient to keep the resultant vinyl polymer in a stirrable state until the end of the polymerization, (b) adding a surfactant, if a suitable surfactant was not present during polymerization, and, (c) then adding water to form an oil-in-water, a water-in-oil or a water-in-oil-in-water emulsion or gel, in a volume ratio of oil-in-water of 30:70 to 10:90, or water-in-oil of 90:10 to 30:70.
Type:
Grant
Filed:
March 13, 1999
Date of Patent:
October 9, 2001
Assignee:
ISP Investments Inc.
Inventors:
Krystyna Plochocka, Jui-Chang Chuang, Jenn S. Shih
Abstract: A method of inhibiting blood platelet aggregation in humans which comprises administering an extract blend of the fruit of the Emblica officinalis plant to control said aggregation, suitably in a dose amount of about 50-500 mg/day.
Type:
Grant
Filed:
September 21, 2000
Date of Patent:
September 18, 2001
Assignees:
Natreon Inc., Indian Herbs Research & Supply Company LTD
Abstract: A composition for preventing or retarding the formation of gas hydrates during the transport of a fluid comprising water and a hydrocarbon through a conduit. The composition is a copolymer of vinyl caprolactam and vinyl pyridine, and terpolymers thereof, with vinyl pyrrolidone, preferably including 70-97% by weight vinyl caprolactam. Suitably such polymers have a molecular weight in the range of 500 to 2500, and are made in a polymerization solvent, preferably a glycol ether, most preferably, 2-butoxyethanol; and also including a carrier solvent, preferably monoethylene glycol.
Type:
Grant
Filed:
October 12, 1999
Date of Patent:
August 28, 2001
Assignee:
ISP Investments Inc.
Inventors:
Kirill N. Bakeev, Jui-Chang Chuang, Thomas Winkler, Michael A. Drzewinski, David E. Graham
Abstract: This invention relates to stable, quaternized vinlypyridine carboxylate home-, co- and ter-polymers, useful as dye transfer inhibitors and polymers complexable with active agrochemical, pharmaceutical or cosmetic agents for controlled release thereof, and to a commercial process for the synthesis of said polymers in high yield and purity.
Type:
Grant
Filed:
September 22, 1999
Date of Patent:
August 7, 2001
Assignee:
ISP Investments Inc.
Inventors:
Jenn S. Shih, Eduardo T. Yap, John C. Hornby, Bala Srinivas
Abstract: A non-aqueous, heterogeneous polymerization process comprises heating a reaction mixture of about 5-70%, preferably 10-30%, by weight, of a vinyl monomer in an oil as solvent, and a free radical initiator, optionally in the presence of a crosslinking agent and/or a surfactant, wherein the oil solvent is present in an amount sufficient to keep the resultant polymer in a stirrable state throughout the polymerization. The polymer reaction product is capable of forming a uniform emulsion or gel upon addition of water thereto.
Type:
Grant
Filed:
December 10, 1997
Date of Patent:
July 3, 2001
Assignee:
ISP Investments Inc.
Inventors:
Krystyna Plochocka, Jui-Chang Chuang, Jenn S. Shih
Abstract: This invention relates to a single phase emulsifiable concentrate composition comprising (a) between about 0.05 and about 25 wt. % of a biologically, fungicidally and/or herbicidally active aza compound; (b) between about 2 and about 40 wt. % of a lactam selected from the group of N-methyl pyrrolidone, N-methyl caprolactam, a C8 to C18 alkyl pyrrolidone, a C8 to C18 caprolactam and a mixture thereof; (c) between about 2 and about 20 wt. % of a moisture scavenging agent selected from the group consisting of a liquid molecularly hindered carbodiimide, a molecular sieve or a mixture thereof and (d) between about 10 and about 80 wt. % of a mixture of at least two non-ionic surfactants having an overall hydrophilic/lipophilic balance (HLB) above 7. The invention also relates to the stable oil-in-water (o/w) miniemulsions prepared from the above by dilution to between about 40 and about 99.99 wt. % water for a “pour on”, dip or spray solution useful in the treatment of animals or plants.
Type:
Grant
Filed:
October 9, 1998
Date of Patent:
July 3, 2001
Assignee:
ISP Investments Inc.
Inventors:
Domingo I. Jon, Donald I. Prettypaul, Matthew J. Benning, Kolazi S. Narayanan, Robert M. Ianniello
Abstract: A clear, one-phase, efficacious aqueous microemulsion of an agriculturally active pyrethroid insecticide for delivery at a high loading of active is provided herein which is free of nonylphenol ethoxylate.
Type:
Grant
Filed:
April 4, 2000
Date of Patent:
June 26, 2001
Assignee:
ISP Investments Inc.
Inventors:
Kolazi S. Narayanan, Domingo Jon, Robert M. Ianniello, Donald Prettypaul
Abstract: What is described is a high molecular weight homogeneous, branched copolymer of maleic anhydride and a C1-C5 alkyl vinyl ether monomer, in which a branching agent is present in an amount of less than 0.5 wt. % of the polymer. A solution process of making such polymer also is described.
Abstract: A composition for preventing or retarding the formation of gas hydrates during the transport of a fluid comprising water and a hydrocarbon through a conduit. The composition is a homopolymer of vinyl caprolactam, or copolymers thereof, having a low molecular weight in the range of 500 to 4000, which is made by polymerization of the monomer or monomers in a polymerization solvent which is a mixture of a glycol ether and water, preferably 2-butoxyethanol and water, at a pH of about 8-12.
Type:
Grant
Filed:
April 21, 2000
Date of Patent:
June 5, 2001
Assignee:
ISP Investments Inc.
Inventors:
Kirill N. Bakeev, Randall Myers, Jui-Chang Chuang, Thomas Winkler, Allen Krauss
Abstract: A method of protecting hair or wool against thermal degradation when heat treated at 100-180° C. which comprises applying a composition which includes methyl vinyl ether-maleic acid copolymer as an active constituent to said hair or wool.
Type:
Grant
Filed:
June 22, 1999
Date of Patent:
June 5, 2001
Assignee:
ISP Investments Inc.
Inventors:
Roger L. McMullen, Jr., Janusz Jachowicz
Abstract: This invention relates to a color stable pigment composition for coating hard mineral granules employed for weather surfacing asphalt roofing and siding shingles. The composition is a 40-60% aqueous slurry of pigment containing ferrosoferric oxide and a silicate/clay mixture which is suitable for coating the surface of the mineral granules. The invention also pertains to a process for the manufacture of the coated granules, to the dry coated mineral granule product containing ferrosoferric oxide bonded in a silicate/clay matrix which is suitable for surfacing asphaltic shingles, to the dried composition containing from about 5 to about 50 wt. % total pigment in a silicate/clay matrix in which the pigment contains Fe3O4 in a concentration of between about 2 and about 100% and to a Fe3O4 pigment mixture per se.
Abstract: A natural antioxidant blend in the form of an amphorous powder was obtained by extraction from Emblica officinalis fruit. In this process, the finely pulped fruit was treated with a dilute aqueous salt solution at hot water temperature to provide an extract-containing solution, which was filtered and dried to provide the desired antioxidant blend powder. A synergistically stabilized composition of ascorbic acid or its derivatives with the antioxidant composition of Emblica officinalis, is also described. Cosmetic, pharmaceutical and nutritional use formulations thereof also are described.
Abstract: A process of making a vinyl caprolactam (VCL)-based polymer which comprises suspension polymerizing the monomers in aqueous medium in the absence of an added protective colloid, wherein polymer formed at an early stage of the polymerization functions as a dispersing agent to maintain polymer particles suspended in water throughout the polymerization.
Type:
Grant
Filed:
July 1, 1999
Date of Patent:
May 1, 2001
Assignee:
ISP Investments Inc.
Inventors:
Jui-Chang Chuang, Michael A. Drzewinski
Abstract: A composition of St. John's Wort, in the form of a stable, free-flowing, powder, having effective antidepressant properties, characterized by having essentially no hypericin therein.
Type:
Grant
Filed:
August 31, 1999
Date of Patent:
May 1, 2001
Assignees:
Natreon Inc., Indian Herbs Research & Supply Company Ltd.