Abstract: A process for reducing the residual content of free alkylating agent in aqueous solutions of amphoteric or zwitterionic surface-active agents by aftertreatment with ammonia, an amino acid containing 2 to 8 carbon atoms, or an oligopeptide.
Abstract: Combinations of fluoride or monofluorophosphate with phosvitin or soluble salts thereof provide superior protection against demineralization of tooth enamel when used in oral hygiene compositions such as toothpastes and mouthwashes.
Type:
Grant
Filed:
September 9, 1992
Date of Patent:
January 18, 1994
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Peter Wuelknitz, Hans Laska, Walter Ploeger
Abstract: A method of using resorbable waxes for coagulation of blood on endogenous hard tissue, especially bone, which waxes consist of waxy polyester-oligomers of hydroxybarboxylic acids which are viscous to solid at body temperature. On the basis of their structure, these waxes are degradable by endogenous metabolic mechanism, wherein the rate of degradation can be adjusted.
Abstract: The use of a fatty oil ex Helianthus annuus containing 78 to 92% by weight oleic acid and 2 to 10% by weight linoleic acid for the production of diperazelaic acid, with elimination of enrichment steps with respect to the oleic acid content, by fat splitting, distillation, oxidative ozonolysis of the fatty acid mixture obtained, and reaction of the azelaic acid thus obtained with hydrogen peroxide to form diperazelaic acid. The resulting diperazelaic acid has improved stability in storage and is obtained in high yields and in highly pure form.
Type:
Grant
Filed:
May 6, 1988
Date of Patent:
January 11, 1994
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Horst Eierdanz, Paul Schulz, Beatrix Kottwitz
Abstract: The invention relates to optionally solventless two-component polyurethane surfacers containing finely divided fillers in a high pigment volume concentration based on a polyfunctional isocyanate component (B) and a polyol component (A) which is liquid at room temperature and which consists of mixture components containing isocyanate-reactive hydroxyl groups with an at least predominant content of branched-chain polyols (A1) containing ester and ether groups, which contains at least a proportion of the finely divided fillers and, optionally, the additives and which, for application, is mixed with the isocyanate component (B) and applied as a mixture which can still be processed by shaping.
Type:
Grant
Filed:
March 27, 1992
Date of Patent:
January 11, 1994
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Bernhard Gruenewaelder, Bernhard Parent, Hermann Kluth, Juergen Wegner, Werner Haller
Abstract: The process of producing a stable polymer dispersion by aqueous emulsion polymerization of an ethylenically unsaturated monomer in the presence of a stabilizer selected from a polyester or polyamide containing a sulfate or sulfonate group.
Abstract: The invention describes a process for the partial or complete exchange of the free radical inhibitors (preparation inhibitor) from their admixtures with free radical-reactive--and especially polymerizable and/or cross-linkable--olefinically mono- and/or polyunsaturated compounds against free radical inhibitors or inhibitor systems (application inhibitor), the kind and amount of which are freely determinable.
Abstract: An ozonator power supply including a step-up transformer having one end of its primary winding connected to one side of an AC supply, its other end connected to the other side of the AC supply via a pair of switches connected in antiparallel, and a controller for providing switching pulses to said switches for making them conductive during variable portions of alternate half cycles of the AC voltage provided by said supply. An inductor is included in the circuit with the primary or secondary winding of the transformer that resonates with the capacitive impedance of an ozonator, for presenting a substantially non-reactive load to said AC supply.
Abstract: Fatty alcohol mixtures R.sub.mix --OH of natural and, in particular, purely vegetable origin and ethoxylates thereof showing improved low-temperature behavior and corresponding to the general formula R.sub.mix --O--(CH.sub.2 CH.sub.2 O).sub.x --H, in which x is a number of 2 to 10 and R.sub.mix represents selected mixtures of saturated and olefinically unsaturated fatty alcohol hydrocarbon radicals in the C 6-20 or C 12-20 ranges correspond to specification I for the chain length range R.sub.mix --=6-20 and to specification II for the chain length range R.sub.mix --=C 12-20:______________________________________ Specification I II structurally analogous to % by weight ______________________________________ C 6 caproic acid 0.1-0.6 -- C 8 caprylic acid 2.5-10 -- C 10 capric acid 2.5-14 -- C 12 lauric acid 37-52 39-69 C 14 myristic acid 10-20 10-27 C 16 palmitic acid 6-10 6-14 C 18 stearic acid 1-5 1-7 C 18' oleic acid 5-23 6-31 C 18" linoleic acid 1-4 1-6 C 18"' linolenic acid 0.1-1 0.1-2 C 20 arachic acid 0.
Type:
Grant
Filed:
October 23, 1992
Date of Patent:
January 4, 1994
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Karl-Heinz Schmid, Hans Peter Kubersky, Guenter Demmering, Alfred Meffert
Abstract: The invention relates to a process for the stereo-selective preparation of 8.alpha.,12-oxido-13,14,15,16-tetranorlabdane by dehydration of 8.alpha.,12-dihydroxy-13,14,15,16-tetranorlabdane with acid-charged aluminium oxides.
Abstract: 2,5-diacyloxy-2,5-dihydrofurans corresponding to formula (I) ##STR1## wherein R is a C.sub.1 -C.sub.8 alkyl radical or a phenyl radical are useful as activators for inorganic per compounds in oxidizing, cleaning or disinfecting solutions.
Type:
Grant
Filed:
November 17, 1992
Date of Patent:
December 28, 1993
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Beatrix Kottwitz, Thomas Merz, Rudolf Lehmann
Abstract: A process for the production of a solid metal soap of the formulaM(R--COO)(R"--COO)in which M is at least one metal from the group of Ca, Mg, Cd, Ba, Zn, and Pb; and R and R' are C.sub.8 -C.sub.34 hydrocarbon radicals, by direct synthesis from at least one fatty acid with metal oxides and/or metal hydroxides which comprises maintaining a reaction zone containing a liquid phase comprising fatty acid under reduced pressure, passing a portion of the liquid phase to an external premixing zone, introducing a solid metal oxide and/or metal hydroxide into the liquid phase in the premixing zone, passing the mixture to the reaction zone through an intensive mixing zone, and continuously removing water of neutralization formed by the reaction.
Type:
Grant
Filed:
February 16, 1993
Date of Patent:
December 28, 1993
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Willi Wuest, Gottfried Duerr, Josef Wollmann, Harald Liebs, Hans Scheck
Abstract: The invention is a processing aid for thermoplastic polyesters which is a salt of a polycarboxylic acid or the salt of a polycarboxylic partial ester. The polycarboxylic acids are partial esters or sales of modified acids such as succinic acid, adipic acid, phthalic acid, citric acid, dicarboxylphenyl group and the like. The addition of the processing aid improves the slip and transparency.
Type:
Grant
Filed:
November 2, 1992
Date of Patent:
December 21, 1993
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Rainer Hoefer, Dieter Krampitz, Andreas Lippmann
Abstract: A bleaching liquid detergent composition containing(A) 3 to 9% by weight of a C.sub.12-18 alkyl sulfate in the form of the sodium or potassium salt,(B) 8 to 20% by weight, based on free fatty acid, of a saturated or unsaturated sodium or potassium soap,(C) 0.3 to 3% by weight of an alkyl glucoside corresponding to the formula RO(G).sub.x, wherein R is a C.sub.8-18 alkyl radical, G is a glucose unit and x is a number of 1 to 10,(D) 8 to 18% by weight of an ethoxylated C.sub.12-18 alcohol containing on average 5 to 9 moles ethylene oxide,(E) 2 to 10% by weight hydrogen peroxide,(F) 0.3 to 2% by weight citric acid present as Na or K citrate, and(G) the balance, a solvent mixture consisting of water and monohydric or polyhydric alcohols containing 2 to 6 carbon atoms.
Abstract: The invention relates to the use of a substantially clear and at least largely solventless, aqueous, one-component polyurethane dispersion based on the reaction products ofa polyol mixture consisting completely or partly of polypropylene glycol,a mixture of polyfunctional isocyanates consisting completely or partly of .alpha.,.alpha.,.alpha.',.alpha.'-tetramethyl xylene diisocyanate (TMXDI),a functional component capable of salt formation in aqueous solution andoptionally a chain-extending agentas a universal household adhesive and to a process for its production in the absence of inert solvents.
Type:
Grant
Filed:
October 9, 1992
Date of Patent:
December 14, 1993
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Wolfgang Klauck, Gerhard Gierenz, Wolfgang Maier, Rainer Hoefer, Roland Gruetzmacher
Abstract: Improved chromate conversion coating composition for forming non-cracking conversion coatings on aluminum or its alloys. Improvement is obtained by control of the total acid (TA) and free acid (FA) levels to a minimum of 6.0 and 3.5 respectively with a TA:FA ratio in the range of 1.5 to 2.5 by inclusion of aluminum nitrate in the composition.
Abstract: The invention relates to moldable, radically polymerizable multicomponent mixtures containingethylenically unsaturated, polymerizable compounds, if desired in admixture with soluble and/or insoluble fillers andan activator system initiatable by contact with oxygen,and is characterized in that these multicomponent mixtures contain an activator system based on the following principal components which can be initiated by contact with oxygen and water and, in particular, by contact with ambient air:N-alkyl-substituted tert-arylamines containing at least one aliphatic CH bond in the .alpha.-positionmetal compounds at least partly soluble in the system to accelerate the drying of unsaturated oils andcompounds of weakly acidic carboxylic acids having pK.sub.a values of no less than about 0.9 which can be hydrolyzed to the free carboxylic acid on contact with moisture.
Type:
Grant
Filed:
February 27, 1991
Date of Patent:
December 7, 1993
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Thomas Huver, Herbert Fischer, Winfried Emmerling
Abstract: A test unit for a monitoring device includes reference and measuring electrodes coupled to a preamplifier and a temperature compensating resistor for the preamplifier. The test unit has components corresponding to those of the monitoring device as well as a power supply and a voltmeter coupled to the output of its preamplifier. Cables are provided for substituting either or both electrodes of the monitoring device for the electrodes of the test device, and a switch is provided for substituting a temperature compensation resistor of the monitoring device for the temperature compensation resistor of the test device. A cable is adapted for connection to either preamplifier for supplying it with operating potentials derived from the power supply and for coupling the output of either preamplifier to the voltmeter.