Abstract: The adhesion and/or corrosion resistance of a autodeposited coating can be improved by rinsing the uncured coating with an aqueous treatment solution that has a pH between 7 and 11 and contains between 0.05 and 5 w/o of anions derived from multifunctional organic acids, preferably anions of 1-hydroxyethylidene-1,1-diphosphonic acid, citric acid, tartaric acid, and/or oxalic acid. The method is particularly useful on leaf springs and other metallic objects with surfaces of high carbon and/or shot blasted steel, and is particularly useful in conjunction with an autodeposition bath containing internally stabilized poly {vinylidene chloride} latex, hydrofluoric acid, ferric fluoride, and hydrogen peroxide.
Abstract: Mixtures of light colored bis(C.sub.8 -C.sub.22 fatty acid) alkylene diamides, C.sub.8 -C.sub.22 fatty acid esters, and, if desired, metal soaps of C.sub.8 -C.sub.22 fatty acids can be obtained if, in a melt containing fatty acids with 8 to 22 carbon atoms, a part of the fatty acids are condensed to the corresponding fatty acid diamides with diamines of the general formula NH.sub.2 --R--NH.sub.2, in which R is a straight chain, branched, or cyclic alkylene group with 2 to 12 carbon atoms; a part of the fatty acids are esterified with fatty alcohols with 8 to 22 carbon atoms and/or multifunctional alkanols with 2 to 15 carbon atoms and 2 to 6 hydroxyl groups; and, if desired, a part of the fatty acids are converted to the corresponding metal soaps with basic compounds of divalent metals. The condensation with the diamines is carried out before the esterification of the fatty acids with fatty alcohols and/or multifunctional alkanols. The mixtures so obtained can be used as additives in plastics.
Type:
Grant
Filed:
November 19, 1991
Date of Patent:
September 28, 1993
Assignee:
Neynaber Chemie GmbH
Inventors:
Kurt Worschech, Erwin Fleischer, Peter Wedl, Frido Loeffelholz
Abstract: A process for the production of sclareolide from sclareol comprising the steps ofA) oxidatively degrading sclareol to a reaction product which is one or both of the following compounds: ##STR1## using either a hypochlorite salt in the presence of a ruthenium salt or potassium permanganate, andB) oxidizing the above reaction product with a peracid or salt thereof to form sclareolide.The above process results in good yields and much shorter reaction times than prior art processes.
Abstract: 1,3-disubstitued nitrobenzenes of the general formula I: ##STR1## in which X is a hydroxyl group or an amino group and R.sup.1 is hydrogen or a C.sub.1-4 alkyl group and their salts are suitable for use as an oxidation dye precursor of the coupler type, together with prior art primary intermediate components, for the production of oxidation dyes, preferably for the production of hair colorants. With developers of the p-phenylenediamine, p-aminophenol, 2.5-diaminopyridine, and 2,4,5,6-tetraaminopyrimidine types, primarily brown hues with great light stability are formed.
Type:
Grant
Filed:
October 9, 1992
Date of Patent:
September 21, 1993
Assignee:
Henkel Kommanditgelsellschaft auf Aktien
Inventors:
David Rose, Edgar Lieske, Horst Hoeffkes
Abstract: Described is a process for the simplified sterilization, by heating to high temperatures, of semisolid to solid preparations based on oligomers of lower carboxylic acids or their salts, as well as their transformation products with molecular weight regulating components, the preparations also optionally including biocompatible minerals. According to the invention, the materials to be sterilized are subjected to the action of high frequency oscillations in the microwave range (microwaves).
Abstract: Ketone compounds are obtained by rearrangement of epoxides in the presence of iodide ions providing quaternary ammonium and phosphonium salts, optionally in admixture with alkali metal or alkaline earth metal iodides, are used as the rearrangement catalysts.
Abstract: Radiation curable compositions containing outstanding reactive diluents have been developed. The diluents are lower alkyl ether acrylates and methacrylates of particular alkoxylated and non-alkoxylated polyols.Examples are mono-methoxy trimethylolpropane diacrylate, mono-methoxy neopentyl glycol monoacrylate and mono-methoxy, ethoxylated neopentyl glycol monoacrylate having an average of about two moles of ethylene oxide.
Type:
Grant
Filed:
August 5, 1992
Date of Patent:
September 7, 1993
Assignee:
Diamond Shamrock Chemical Co.
Inventors:
Francis A. Hibie, Robert A. LieBerman, Ira M. Rose
Abstract: A process for forming a chromium/silica/phosphate protective conversion coating on a metal surface is improved by pretreating the surface with a composition comprising at least one of (i) H.sub.2 TiF.sub.6, (ii) H.sub.2 SiF.sub.6, and (iii) a derivative of poly{alkenylphenol} before applying the conversion coating. The process of the invention results in a protective base coating having superior adhesion to paint at a relatively high coating weight which is desirable for improved corrosion resistance. This process is especially useful in forming such protective conversion coatings on continuous cast aluminum surfaces.
Abstract: The invention is a composition of at least one anionic or amphoteric surfactant, water and a viscosity reducing effective amount at least one alkyl polyglycoside and at least one alkali metal chloride.
Abstract: In an industrial dishwasher a cleaning solution which is highly concentrated relative to the rinsing water is recirculated in a washing region over items to later be rinsed, whereby the cleaning solution is directed into a collector trough, where the level of the solution is maintained automatically through use of a metering tank juxtaposed to the collector trough, whereby the metering tank collects rinse water, and a non-return flap valve located between the collector trough and metering tank provides for rinse water to flow from the metering tank into the collector trough only at such times when the level of the cleaning solution in the collector trough is lower than the level of the rinse water in the metering tank at upper-most regions thereof.
Abstract: This invention is directed to a method for treating fibers by applying thereto a compound having the general formula ##STR1## wherein R.sub.1 is alkyl from 1 to 23 carbon atoms, R.sub.2 is alkyl from 1 to 23 carbon atoms, n is a number from 3 to 15, and X is --C.sub.2 H.sub.4 O-- or --C.sub.3 H.sub.6 O--, or a mixture of --C.sub.2 H.sub.4 O-- and --C.sub.3 H.sub.6 O--.
Abstract: In the process described, cyclic polyimino ethers with .DELTA..sup.2 -oxazoline or .DELTA..sup.2 -5,6-dihydro-4H-1,3-oxazine structure are applied, alone or together with cyclic monoimino ethers of the same type, or with lactones, plus cationic polymerization catalysts, to solid surfaces and polymerized by heating. The process gives smooth, glossy coatings with high adhesive strength, hardness, and elasticity.
Type:
Grant
Filed:
January 21, 1992
Date of Patent:
August 31, 1993
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Brigitte Hase, Ulrich Eicken, Wolfgang Gress, Norbert Stork
Abstract: A wet strength resin composition is comprised of an aminopolyamide-epichlorohydrin acid salt resin having a total organically bound chlorine of up to 0.7% by weight of the resin. The amount of total organically bound chlorine present is controlled by the process parameters.
Abstract: Textile treatment preparations based on the condensates of aliphatic monocarboxylic acids or amide-forming derivatives thereof with optionally hydroxyl-substituted polyamines and an addition of dispersion accelerators from the group of certain monosaccharides and hydrogenation products thereof, polyols and natural and synthetic hydrophilic polymers show particularly good dispersibility, even in cold water, if the amino groups unreacted during the condensation reaction are only partly neutralized with low molecular weight, optionally hydroxyl-substituted mono- or polycarboxylic acids.
Abstract: A process is disclosed for the hydrothermal production of potassium silicate solutions with high SiO.sub.2 :K.sub.2 O molar ratios, by the hydrothermal reaction of quartz sand with aqueous potassium hydroxide solutions at temperatures in the range of 150.degree. to 300.degree. C. at the pressures of saturated water vapor corresponding to these temperatures in a pressure reactor, which is characterized in that the potassium silicate solutions obtained thereby, which have SiO.sub.2 :K.sub.2 O molar ratios of less than 2.75:1, are then reacted with a quartz tempered at temperatures in the range of over 1100.degree. C. up to melting point, the temperatures and pressures also being maintained in the ranges named.
Type:
Grant
Filed:
May 26, 1992
Date of Patent:
August 24, 1993
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Rudolf Novotny, Alfred Hoff, Jost Schuertz
Abstract: The invention relates to a process for the removal of fillers from waste paper, after floatation of the printing ink, in the presence of at least partly water-soluble polymers and/or copolymers having number average molecular weights of 1,000 to 500,000 by flotation.
Type:
Grant
Filed:
February 28, 1992
Date of Patent:
August 24, 1993
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Konrad Engelskirchen, Herbert Fischer, Klaus Hornfeck, Doris Oberkobusch, Ludwig Schieferstein
Abstract: An improved resorbable body and tissue compatible wax useful for the mechanical coagulation of blood on bones is produced by the reaction of, for example, lactic or glycolic acids with glycerol. The reaction mixture is then purified by forming a solvent suspension and washing with isopropanol to produce a purified wax essentially free of the hydroxycarboxic acid impurity, say, less than 0.1%.
Abstract: Octyl ethers and octadienyl ethers of glucose, sucrose, are disclosed. Compositions comprised of a mixture of octyl ethers of glucose and sucrose and those containing octadienyl ethers of sugar acids are also disclosed.
Type:
Grant
Filed:
March 26, 1991
Date of Patent:
August 17, 1993
Assignees:
Henkel Research Corporation, Zucker-Aktiengesellschaft Uelzen-Braunschweig
Inventors:
Bert Gruber, Kenneth J. Weese, Hans-Peter Mueller, Karlheinz Hill, Arno Behr, James R. Tucker
Abstract: Alkoxylation products of at least one of ethylene oxide, propylene oxide, and butylene oxide and at least one C.sub.10-22 carboxylic acid mono-, di-, or tri-glyceride which is of natural origin or is obtained from natural origin wherein in the 9, 10 position, the 13, 14 position, or in both positions of the carboxylic acid the following unit is present ##STR1## in which R is a hydrogen atom, an OH group or an OR.sup.1 group,R.sup.1 is a C.sub.9-18 alkyl group, a C.sub.9-18 alkenyl group or a ##STR2## group, and R.sup.2 is a hydrogen atom, a C.sub.1-21 alkyl group or a C.sub.2-21 alkenyl group.The invention also relates to compositions containing the above alkoxylation products in place of alkoxylated castor oil normally present in the compositions, and to a process for preparing the alkoxylation products.