Abstract: Sulfur dioxide is removed from gas mixtures such as flue gas containing the same by contacting the gas mixture with a solid sorbent comprising a porous gamma-alumina base, about 2 to 20 percent by weight (based on alumina) of a coating of a refractory oxide such as titanium dioxide, zirconium dioxide, or silica, and an active material, such as copper oxide, which is capable of selective removal of sulfur oxides from a gas mixture.
Abstract: A method for separating organometallic compounds from liquid hydrocarbons containing the same wherein the liquid hydrocarbon is contacted with a contact material comprising: an adsorbent selected from the group consisting of alumina, silica-alumina and silica gel; cupric chloride impregnated on the adsorbent; and water. The presence of water in the contact material is essential to good separation performance. The contact material may also comprise an amine which may be present either as a reaction product or a complex.
Abstract: Flue gas is desulfurized by absorbing it onto a selective absorbent-catalytic material. The absorbed SO.sub.2 is recovered by contacting it in a desorption cycle with a reducing desorption gas. In one embodiment, multiple absorbent beds are employed and alternate absorption-desorption cycles are used in each of the multiple beds with the flue gas and the desorption gas used alternately. The sulfur oxide is recovered in concentrated form in the desorption gas stream and is then utilized as feed in a conventional sulfuric acid plant yielding concentrated sulfuric acid.
Type:
Grant
Filed:
July 23, 1973
Date of Patent:
November 2, 1976
Assignee:
Exxon Research and Engineering Company
Inventors:
David F. Greene, Robert J. Lang, Albert B. Welty, Jr.
Abstract: Process for preparing surface impregnated catalysts and sorbents, and flue gas desulfurization process using the same. The sorbent is produced by pre-soaking a porous solid particulate carrier material in a polar organic liquid such as a C.sub.5 -C.sub.10 alcohol, immersing the carrier without drying in an impregnating solution for a time sufficient to permit the impregnating solution to penetrate to a controlled depth without totally impregnating the carrier, and drying and calcining the impregnated carrier, whereby a contact material having an inner zone of substantially unimpregnated carrier and an outer zone of carrier impregnated with active material is produced. Sulfur dioxide is removed from flue gas by contacting the flue gas with a sorbent thus prepared. The preferred carrier for flue gas desulfurization is alumina and the preferred active material is copper oxide.
Type:
Grant
Filed:
September 25, 1972
Date of Patent:
October 12, 1976
Assignee:
Exxon Research and Engineering Company
Inventors:
Neville L. Cull, Lloyd A. Pine, Dale D. Maness
Abstract: Grease compositions comprising (1) a lithium soap derived from a fatty acid containing an epoxy group and/or ethylenic unsaturation, and (2) a dilithium soap derived from a straight chain dicarboxylic acid. In a preferred embodiment, the grease composition will also comprise a lithium salt derived from a hydroxy-substituted carboxylic acid. Greases comprising lithium salts derived from an epoxy substituted fatty acid in combination with other lithium salts and derived from an ethylenically unsaturated fatty acid, a dicarboxylic acid and a hydroxy-substituted aromatic acid are particularly effective.
Type:
Grant
Filed:
February 28, 1975
Date of Patent:
October 12, 1976
Assignee:
Exxon Research and Engineering Company
Inventors:
Ian D. Campbell, Terrance O. Brown, Donald W. Murray
Abstract: A coating composition useful in metal working processes comprises a major amount of a mineral oil having a viscosity of 100.degree.F of at least 100 SUS and (a) 1.0 to 20.0 parts by weight of a paraffin wax, (b) 0.1 to 10.0 parts by weight of a polymeric wax modifier and (c) 0.1 to 10.0 parts by weight of an extreme pressure agent. The compositions can also contain one or more rust inhibitors. Particularly preferred classes of extreme pressure agents for use in this comparison are sulfur containing agents and zinc salts of dialkyl dithiophosphates.
Abstract: Substantially sulfur-free combustible fuel gas under superatmospheric pressure is produced by partial combustion or gasification under superatmospheric pressure of a sulfur-containing solid, liquid or gaseous fuel. The gasification is effected within a fluidized bed of particles containing alkaline earth metal compounds (e.g. the oxides) which are capable of reacting with, and of fixing, the fuel sulfur as sulfides under reducing conditions. Sulfide-containing particles are exposed to an oxidizing atmosphere and the sulfides are thereby converted to oxides with the liberation of SO.sub.2 in useful concentrations, and with the liberation of heat. Particles containing regenerated oxides are re-used for fixing more sulfur during fuel gasification. Expedients are described by which it is ensured that the sulfur-fixing activity of the particles is substantially maintained and that the temperatures of the particles during sulfur-fixing and regeneration are maintained within predetermined ranges.
Abstract: A heat soaked polymer by-product from the production of gasoline using the 90.degree.-400.degree.F. steam cracker naphtha as feed is upgraded by first subjecting the same to a thermal polymerization and then subjecting the thermal polymerization product to a hydrotreating or hydrogenation step or both. Generally, the hydrotreatment is accomplished at relatively mild conditions so as to avoid any change in aromatic ring structure. Hydrogenation, on the other hand, is accomplished at more severe conditions so as to effect hydrogenation of the aromatic rings. In those cases where a mild hydrotreatment only is used, the products obtained are, generally, useful as aromatic oils of light color. Where more severe hydrogenation is used, on the other hand, the products are useful as naphthenic oils.
Abstract: Process and apparatus for reducing emissions from internal combustion engine exhaust gas. The exhaust gas treatment system includes a first stage converter containing an NO.sub.x reduction catalyst, a second stage converter containing a catalyst for oxidation of CO and hydrocarbons, and means for admitting secondary air to the inlet of the second stage. Reduced CO and hydrocarbon emissions are obtained by admitting air in an amount not greater than that required to achieve a stoichiometric mixture to the inlet of the first stage during cold (i.e., choked) engine operation, discontinuing the flow of air to the first stage inlet when the average air-fuel ratio reaches approximately its normal warm engine value, and thereafter continuing operation without adding an appreciable quantity of air to the inlet of the first stage. The engine is operated with a substantially net rich average air-fuel ratio during warmup and with a slightly net rich average air-fuel ratio thereafter.