Abstract: A process for producing an ultraviolet radiation stabilized polymeric, particularly polycarbonate, article comprising impregnation of the surface layers of said article with an ultraviolet radiation absorber by first applying onto the surface of said article an ultraviolet radiation stabilizing composition containing an ultraviolet radiation absorber and a nonaggressive liquid carrier, and then heating the article with the stabilizing composition on its surface to a temperature sufficient for said absorber to diffuse into the surface layers of said article but insufficient to deleteriously affect the properties of the polymer.
Abstract: Improved impact or shock resistant laminates comprising a plurality of lamina including a back polycarbonate lamina opposite the direction of impact or shock, such back polycarbonate lamina having a relatively hard and brittle overlying or exposed layer or coating opposite the direction of impact, are provided by interposing intermediate layer between said hard and brittle exposed layer and the polycarbonate lamina which intermediate layer is softer and less brittle than said exposed layer, such intermediate layer reducing failure and spalling of the polycarbonate surface opposite the impact or shock receiving surface.
Abstract: A process for producing an ultraviolet radiation stabilized polymeric, particularly polycarbonate, article comprising impregnation of the surface of said article with an ultraviolet radiation absorber by heating said polymeric article and applying onto the surface of said heated article an ultraviolet radiation stabilizing composition containing an ultraviolet radiation absorbing compound and a nonaggressive carrier.
Abstract: Amidines are one of the strongest organic bases and find application where this property is needed, such as in phase transfer catalysis in the form of their substituted derivatives. Their use, however, has been hampered by their expensive nature due to only mediocre yields in their preparation. The present invention provides a process for the preparation of substituted amidines in essentially quantitative yields.
Abstract: Ternary compositions are disclosed which comprise a mixture of a high molecular weight thermoplastic, aromatic polycarbonate, an acrylate copolymer, and thermoplastic polyester.
Abstract: An improved impact resistant double glazed structure comprising a back laminate positioned opposite the direction of impact, said back laminate comprising a plurality of laminae selected from polycarbonate, glass and solid resinous materials, and a front glass laminate positioned forward of said back laminate comprising a plurality of glass laminae, including a relatively thin front glass lamina facing the direction of impact having a thickness of from about 30 to about 220 mils, a relatively thin back glass lamina opposite the direction of impact having a thickness of from 30 to about 220 mils, and a relatively thicker glass core positioned intermediate said relatively thin back and front glass laminae.
Abstract: Thermally stable polycarbonate compositions are obtained by admixing with a high molecular weight aromatic polycarbonate resin a stabilizing amount of a bisphosphite.
Type:
Grant
Filed:
March 16, 1979
Date of Patent:
January 26, 1982
Assignee:
General Electric Company
Inventors:
Ronald L. Markezich, Gary L. Freimiller, Walter K. Olander, Robert J. Axelrod
Abstract: A shaped, non-opaque coated polycarbonate article having improved abrasion and chemical solvent resistance comprising a polycarbonate substrate having disposed on the surface thereof a non-opaque primer layer of controlled thickness comprised of a thermoset acrylic polymer and disposed on said primer layer a non-opaque top coat comprised of a thermoset organopolysiloxane.
Type:
Grant
Filed:
January 10, 1980
Date of Patent:
December 29, 1981
Assignee:
General Electric Company
Inventors:
Daniel R. Olson, Ona V. Orkin, Karen K. Webb
Abstract: Polycarbonate compositions having improved barrier properties; i.e., low water vapor transmission and low gas permeability, are obtained by employing selected mono- and di-alkyl substituted monomers.
Abstract: A non-opaque coated polycarbonate shaped article, and a process for producing the same, having improved abrasion and chemical solvent resistance comprising a polycarbonate substrate having thereon (i) a primer layer comprised of a thermoplastic acrylic polymer containing functional groups; and (ii) a top coat containing a thermoset organopolysiloxane on said primer layer.The process for producing said coated polycarbonate article comprises the steps of: (i) priming the surface of a polycarbonate substrate by forming a primer layer comprised of a thermoplastic acrylic polymer containing functional groups; (ii) applying a top coat composition containing a further curable organopolysiloxane onto the primed substrate; and (iii) curing the further curable organopolysiloxane to form a hard, abrasion and chemical solvent resistant top coat which is tenaciously and durably adhered to the polycarbonate substrate.
Type:
Grant
Filed:
August 17, 1979
Date of Patent:
November 3, 1981
Assignee:
General Electric Company
Inventors:
Siegfried H. Schroeter, Daniel R. Olson
Abstract: A process for preparing a thermoplastic, randomly branched aromatic polycarbonate is disclosed which comprises reacting a carbonate precursor, a dihydric phenol, and a dianhydride branching agent and maintaining the resultant reaction medium at a pH of from about 9 to about 12 to thereby produce a thermoplastic randomly branched aromatic polycarbonate.
Abstract: An interfacial polymerization process for preparing high molecular weight aromatic polycarbonates by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of certain cyclic di- or triamines or salts of cyclic di- or triamines.
Abstract: A plasticized polycarbonate composition comprising in admixture a high molecular weight aromatic carbonate polymer and a minor amount of an organosulfur plasticizer.
Abstract: Highly pure dihalodiphenols or predetermined, statistical mixtures of unreacted, monohalo- and dihalodiphenols are obtained reacting the diphenol, which is suspended or dissolved in a suitable solvent, with a halogen while concurrently purging the reaction with a gas that is inert to the reaction.
Abstract: An interfacial polymerization process for preparing high molecular weight aromatic polycarbonates by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of certain non-cyclic polyamines or salts of non-cyclic polyamines.
Abstract: A foamable thermoplastic injection moldable composition comprising in admixture (a) a polyester resin, (b) a filler selected from the group consisting of fibrous glass or a mineral or mixtures thereof in an amount of from about 5 to about 50 weight percent and (c) a minor amount of a foaming agent. The compositions can also include flame retardant additives.
Abstract: An interfacial polymerization process for preparing high molecular weight aromatic polycarbonates by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of a 5 to 8 membered heterocyclic compound which contains only carbon and nitrogen atoms in the ring and further characterized in that the ring contains at least two nitrogen atoms and at least one carbon atom, and in that the ring is aromatic in character and contains a maximum amount of olefinic unsaturation.
Abstract: An interfacial polymerization process for preparing a high molecular weight aromatic carbonate polymer by reacting a dihydric phenol with a carbonate precursor in the presence of a catalytic amount of a substituted pyridine or a salt of a substituted pyridine.
Type:
Grant
Filed:
December 28, 1979
Date of Patent:
August 25, 1981
Assignee:
General Electric Company
Inventors:
Donald B. G. Jaquiss, Victor Mark, Lawrence C. Mitchell