Abstract: A method for converting methane to higher molecular weight hydrocarbons wherein hot oxidative coupling reactor effluent is briefly contacted with a C.sub.2 to C.sub.20 alkane quench material to remove part of the heat contained in the raw reactor effluent, and is then further quenched by thermal quenching means to achieve a temperature which discourages retrograde reactions.
Type:
Grant
Filed:
July 6, 1989
Date of Patent:
May 14, 1991
Assignee:
Amoco Corporation
Inventors:
Robert H. Walker, Paul A. Willems, George A. Huff, Lewis E. Grimes, David F. Tatterson, Robert L. Mehlberg
Abstract: An early meltdown process of wax sweating is provided which enhances the efficiency, quality, product yield, and throughput of wax. In the early meltdown process, slack wax is crystallized. The crystallized was is then sweated while simultaneously draining the liquid drippings from the sweating oven. The congealing point of the liquid drippings are monitored. When the congealing point of the liquid drippings indicate that the melting temperature of the desired wax product has been obtained, sweating and drainage are stopped, and the remaining solid bed of wax in the sweating oven is rapidly melted and subsequently upgraded.
Abstract: Removal of the small amount of lower molecular weight olefins produced by certain isomerization catalysts during the catalytic isomerization of xylene results in reduced xylene loss. Such removal can be conveniently effected by use of a mild hydrogenation catalyst separate from the isomerization catalyst in the process.
Abstract: A process is disclosed for preparing a composition comprising a polybutyl ketone and a hydroxyester of an epoxidized polybutene wherein the epoxide groups of said epoxidized polybutene are at least 70% trisubstituted. Acid compounds are reacted with epoxidized polybutenes to obtain compositions of increased reactivity as compared with polybutyl ketone compounds. These compositions are useful as chemical intermediates to modify such materials as polyesters and polyurethenes, for applications such as coatings, foams, and sealants.
Abstract: A hydrotreating process if provided in which resid and resins are hydrotreated with hydrogen-rich gases in the presence of a hydrotreating catalyst in an ebullated bed reactor.
Type:
Grant
Filed:
July 18, 1989
Date of Patent:
May 7, 1991
Assignee:
Amoco Corportion
Inventors:
James F. Mosby, Lawrence B. Peck, James L. Taylor, William I. Beaton
Abstract: A method is disclosed for preparing overbased petroleum oxidates which comprises carbonating a petroleum oxidate in the presence of a base selected from the group consisting of alkali metal compounds and alkaline earth metal components. The petroleum oxidate is made by oxidizing petroleum oil in the presence of a base. The overbased petroleum oxidates are useful as rust inhibitors, dispersants, detergents, friction modifiers and as a substrate for overbased sulfonates, phenates, and salicylates. The overbased sulfonates, phenates and salicylates are easily overbased and have improved storage stability and improved rust inhibition.
Abstract: A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprises the product formed by (A) forming a solution of a magnesium-containing species from a magnesium carbonate or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing solution by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic ether; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor.
Type:
Grant
Filed:
November 9, 1989
Date of Patent:
May 7, 1991
Assignee:
Amoco Corporation
Inventors:
Gregory G. Arzoumanidis, Nicholas M. Karayannis, Habet M. Khelghatian, Sam S. Lee, Bryce V. Johnson
Abstract: A continuous process for production of maleic anhydride is disclosed wherein maleic anhydride is produced in high yield and catalyst productivity is in the range of from about 0.12 to about 0.18 pounds of maleic anyhdride produced per pound of catalyst per hour. The catalyst comprises vanadium-phosphorus-oxygen and a modifier, preferably molybdenum. The increased catalyst productivity substantially increases production rates without necessity for extensive equipment modification.
Abstract: Viscous, liquid polybutenes of at least 50 wt. % vinylidene content are disclosed together with a procedure for preparing the compounds using an aluminum chloride-organic nitro compound catalyst.
Abstract: Described are blends of a crystalline poly(aryl ether ketone) and a polyarylate and/or a liquid crystalline polyarylate. These blends exhibit improved mechanical properties and environmental stress rupture resistance.
Abstract: A method for preparing one or more dimethylnaphthalenes from one or more dimethyltetralins, and optionally for preparing one or more other specific dimethylnaphthalenes by isomerization of the aforesaid dimethylnaphthal-dimethylnaphthalene(s) is disclosed.
Type:
Grant
Filed:
February 27, 1989
Date of Patent:
April 30, 1991
Assignee:
Amoco Corporation
Inventors:
David L. Sikkenga, Ian C. Zaenger, Gregory S. Williams
Abstract: A process for the production of trimellitic anhydride with improved color properties disclosed. This process comprises treating trimellitic anhydride with an activated silicon compound followed by fractionation and at temperatures of about 200.degree. to about 300.degree. C. and a decreasing pressure of about 1 to about 25 mm Hg. Trimellitic anhydride is used in the manufacture of polyesters and polyamides-imides.
Abstract: Disclosed is an improved process for the hydrodemetallization, hydrodesulfurization, hydrodenitrogenation, and hydroconversion of a hydrocarbon feedstock containing asphaltenes, metals and Shell hot filtration solids precursors. The process utilizes a catalyst mixture wherein one component of the mixture is a relatively small pore catalyst and another component is a catalyst that possesses a relatively large amount of macropore volume.
Type:
Grant
Filed:
March 30, 1990
Date of Patent:
April 23, 1991
Assignee:
Amoco Corporation
Inventors:
Frederick T. Clark, Albert L. Hensley, Jr., David Lyzinski, Lawrence B. Peck
Abstract: A process of concurrently dedusting and upgrading particulate laden raw, whole retort oil is provided which comprises the steps of: retorting solid hydrocarbon-containing material such as oil shale to liberate an effluent stream of dust laden hydrocarbons; injecting the dust-laden retort effluent product stream into a catalytic hydrotreater; agitating the product stream in the hydrotreater to constantly maintain the particulates in suspension within the oil; catalytically hydrotreating the agitated product stream in the presence of a hydroprocessing gas at a pressure of from 500 to 3000 psi, a temperature of from 650.degree. to 850.degree. F. and a space velocity of from 0.1 to 6.0 hr.sup.-1, whereby the suspended particulates are agglomerated to facilitate solid-liquid separation and substantial amounts of sulfur and nitrogen contaminants are simultaneously removed from the resulting ungraded oil; and mechanically separating the agglomerated particulates from the upgraded whole oil.
Type:
Grant
Filed:
August 31, 1988
Date of Patent:
April 23, 1991
Assignee:
Amoco Corporation
Inventors:
Jeffrey T. Miller, Albert L. Hensley, Jr.
Abstract: A process is disclosed for preparing hydroxyethers of epoxidized polybutenes wherein the epoxide groups of said epoxidized polybutenes are about 70% trisubstituted and about 20% tetrasubstituted. Hydroxyl compounds are reacted with epoxidized polybutenes to obtain compounds of increased flexibility, water resistance, lubricity, and adhesion as compared with said hydroxyl compounds.
Type:
Grant
Filed:
January 31, 1989
Date of Patent:
April 16, 1991
Assignee:
Amoco Corporation
Inventors:
Wayne T. Riddick, Vincent F. Smith, Jr.
Abstract: A composite comprised of diamond particles embedded in a metal matrix is a highly satisfactory heat sink material for use with a semiconductor.
Abstract: A process is disclosed for preparing adhesives from polyethylene terephthalate which comprises reacting a trimellitic acid polyester ether with polyethylene terephthalate to prepare a nonlinear copolymer with crosslinking characteristics suitable for use as an adhesive either as a hot-melt adhesive or as a pressure-sensitive adhesive.
Abstract: A polypropylene composition which demonstrates good color stability and water carry-over properties comprises polypropylene containing a hindered amine light stabilizer and about 0.01 to about 0.5 wt. % of a fluoborate salt. Ammonium fluoborate, sodium fluoborate and potassium fluoborate are particularly useful.
Abstract: The filter system includes a plurality of porous metal filter tubes and is used in a method for extracting high purity solid para-xylene crystals from a mother liquor feed slurry of mixed xylenes in liquid and crystal form utilizing a separation unit which includes a crystallization stage where the mother liquor slurry is cooled in at least one crystallizer to crystallize liquid para-xylene into solid crystals, an isomerization stage where xylenes, such as ortho-xylene and meta-xylene, are reacted over a catalyst bed to convert these xylenes into para-xylene, and a distillation stage where the mixed xylenes are separated from the impurities from which byproducts are obtained.
Abstract: A process is disclosed for liquid phase oxidation of alkyl aromatic hydrocarbons to aromatic carboxylic acids in presence of a multivalent catalyst promoted by a source of bromine. The oxidation is conducted in at least two oxidation reactions. Exothermic heat of reaction is controlled by means of a liquid phase heat exchanger to control temperature and pressure. Oxygen partial pressure in each stage is at least 1.5 psia to minimize oxygen starvation and improve selectivity. Low reactor temperature, high reactor pressure and improved selectivity improve product yield and product quality.