Patents Represented by Attorney William H. Magidson
  • Patent number: 5015799
    Abstract: A method for converting methane to higher molecular weight hydrocarbons wherein hot oxidative coupling reactor effluent is briefly contacted with a C.sub.2 to C.sub.20 alkane quench material to remove part of the heat contained in the raw reactor effluent, and is then further quenched by thermal quenching means to achieve a temperature which discourages retrograde reactions.
    Type: Grant
    Filed: July 6, 1989
    Date of Patent: May 14, 1991
    Assignee: Amoco Corporation
    Inventors: Robert H. Walker, Paul A. Willems, George A. Huff, Lewis E. Grimes, David F. Tatterson, Robert L. Mehlberg
  • Patent number: 5015357
    Abstract: An early meltdown process of wax sweating is provided which enhances the efficiency, quality, product yield, and throughput of wax. In the early meltdown process, slack wax is crystallized. The crystallized was is then sweated while simultaneously draining the liquid drippings from the sweating oven. The congealing point of the liquid drippings are monitored. When the congealing point of the liquid drippings indicate that the melting temperature of the desired wax product has been obtained, sweating and drainage are stopped, and the remaining solid bed of wax in the sweating oven is rapidly melted and subsequently upgraded.
    Type: Grant
    Filed: March 7, 1989
    Date of Patent: May 14, 1991
    Assignee: Amoco Corporation
    Inventor: Roger M. Rueff
  • Patent number: 5015794
    Abstract: Removal of the small amount of lower molecular weight olefins produced by certain isomerization catalysts during the catalytic isomerization of xylene results in reduced xylene loss. Such removal can be conveniently effected by use of a mild hydrogenation catalyst separate from the isomerization catalyst in the process.
    Type: Grant
    Filed: September 21, 1989
    Date of Patent: May 14, 1991
    Assignee: Amoco Corporation
    Inventor: Mark G. Reichmann
  • Patent number: 5015697
    Abstract: A process is disclosed for preparing a composition comprising a polybutyl ketone and a hydroxyester of an epoxidized polybutene wherein the epoxide groups of said epoxidized polybutene are at least 70% trisubstituted. Acid compounds are reacted with epoxidized polybutenes to obtain compositions of increased reactivity as compared with polybutyl ketone compounds. These compositions are useful as chemical intermediates to modify such materials as polyesters and polyurethenes, for applications such as coatings, foams, and sealants.
    Type: Grant
    Filed: January 31, 1989
    Date of Patent: May 14, 1991
    Assignee: Amoco Corporation
    Inventor: Wayne T. Riddick
  • Patent number: 5013427
    Abstract: A hydrotreating process if provided in which resid and resins are hydrotreated with hydrogen-rich gases in the presence of a hydrotreating catalyst in an ebullated bed reactor.
    Type: Grant
    Filed: July 18, 1989
    Date of Patent: May 7, 1991
    Assignee: Amoco Corportion
    Inventors: James F. Mosby, Lawrence B. Peck, James L. Taylor, William I. Beaton
  • Patent number: 5013463
    Abstract: A method is disclosed for preparing overbased petroleum oxidates which comprises carbonating a petroleum oxidate in the presence of a base selected from the group consisting of alkali metal compounds and alkaline earth metal components. The petroleum oxidate is made by oxidizing petroleum oil in the presence of a base. The overbased petroleum oxidates are useful as rust inhibitors, dispersants, detergents, friction modifiers and as a substrate for overbased sulfonates, phenates, and salicylates. The overbased sulfonates, phenates and salicylates are easily overbased and have improved storage stability and improved rust inhibition.
    Type: Grant
    Filed: November 19, 1986
    Date of Patent: May 7, 1991
    Assignee: Amoco Corporation
    Inventor: Francis J. Slama
  • Patent number: 5013702
    Abstract: A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprises the product formed by (A) forming a solution of a magnesium-containing species from a magnesium carbonate or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing solution by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic ether; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor.
    Type: Grant
    Filed: November 9, 1989
    Date of Patent: May 7, 1991
    Assignee: Amoco Corporation
    Inventors: Gregory G. Arzoumanidis, Nicholas M. Karayannis, Habet M. Khelghatian, Sam S. Lee, Bryce V. Johnson
  • Patent number: 5011945
    Abstract: A continuous process for production of maleic anhydride is disclosed wherein maleic anhydride is produced in high yield and catalyst productivity is in the range of from about 0.12 to about 0.18 pounds of maleic anyhdride produced per pound of catalyst per hour. The catalyst comprises vanadium-phosphorus-oxygen and a modifier, preferably molybdenum. The increased catalyst productivity substantially increases production rates without necessity for extensive equipment modification.
    Type: Grant
    Filed: November 22, 1989
    Date of Patent: April 30, 1991
    Assignee: Amoco Corporation
    Inventor: Hassan Taheri
  • Patent number: 5012030
    Abstract: Viscous, liquid polybutenes of at least 50 wt. % vinylidene content are disclosed together with a procedure for preparing the compounds using an aluminum chloride-organic nitro compound catalyst.
    Type: Grant
    Filed: October 10, 1989
    Date of Patent: April 30, 1991
    Assignee: Amoco Corporation
    Inventors: Kelley R. Lane, Wayne P. Schammel
  • Patent number: 5011894
    Abstract: Described are blends of a crystalline poly(aryl ether ketone) and a polyarylate and/or a liquid crystalline polyarylate. These blends exhibit improved mechanical properties and environmental stress rupture resistance.
    Type: Grant
    Filed: August 22, 1989
    Date of Patent: April 30, 1991
    Assignee: Amoco Corporation
    Inventors: Lloyd M. Robeson, James E. Harris
  • Patent number: 5012024
    Abstract: A method for preparing one or more dimethylnaphthalenes from one or more dimethyltetralins, and optionally for preparing one or more other specific dimethylnaphthalenes by isomerization of the aforesaid dimethylnaphthal-dimethylnaphthalene(s) is disclosed.
    Type: Grant
    Filed: February 27, 1989
    Date of Patent: April 30, 1991
    Assignee: Amoco Corporation
    Inventors: David L. Sikkenga, Ian C. Zaenger, Gregory S. Williams
  • Patent number: 5010207
    Abstract: A process for the production of trimellitic anhydride with improved color properties disclosed. This process comprises treating trimellitic anhydride with an activated silicon compound followed by fractionation and at temperatures of about 200.degree. to about 300.degree. C. and a decreasing pressure of about 1 to about 25 mm Hg. Trimellitic anhydride is used in the manufacture of polyesters and polyamides-imides.
    Type: Grant
    Filed: January 10, 1990
    Date of Patent: April 23, 1991
    Assignee: Amoco Corporation
    Inventor: Chang M. Park
  • Patent number: 5009771
    Abstract: Disclosed is an improved process for the hydrodemetallization, hydrodesulfurization, hydrodenitrogenation, and hydroconversion of a hydrocarbon feedstock containing asphaltenes, metals and Shell hot filtration solids precursors. The process utilizes a catalyst mixture wherein one component of the mixture is a relatively small pore catalyst and another component is a catalyst that possesses a relatively large amount of macropore volume.
    Type: Grant
    Filed: March 30, 1990
    Date of Patent: April 23, 1991
    Assignee: Amoco Corporation
    Inventors: Frederick T. Clark, Albert L. Hensley, Jr., David Lyzinski, Lawrence B. Peck
  • Patent number: 5009770
    Abstract: A process of concurrently dedusting and upgrading particulate laden raw, whole retort oil is provided which comprises the steps of: retorting solid hydrocarbon-containing material such as oil shale to liberate an effluent stream of dust laden hydrocarbons; injecting the dust-laden retort effluent product stream into a catalytic hydrotreater; agitating the product stream in the hydrotreater to constantly maintain the particulates in suspension within the oil; catalytically hydrotreating the agitated product stream in the presence of a hydroprocessing gas at a pressure of from 500 to 3000 psi, a temperature of from 650.degree. to 850.degree. F. and a space velocity of from 0.1 to 6.0 hr.sup.-1, whereby the suspended particulates are agglomerated to facilitate solid-liquid separation and substantial amounts of sulfur and nitrogen contaminants are simultaneously removed from the resulting ungraded oil; and mechanically separating the agglomerated particulates from the upgraded whole oil.
    Type: Grant
    Filed: August 31, 1988
    Date of Patent: April 23, 1991
    Assignee: Amoco Corporation
    Inventors: Jeffrey T. Miller, Albert L. Hensley, Jr.
  • Patent number: 5008338
    Abstract: A process is disclosed for preparing hydroxyethers of epoxidized polybutenes wherein the epoxide groups of said epoxidized polybutenes are about 70% trisubstituted and about 20% tetrasubstituted. Hydroxyl compounds are reacted with epoxidized polybutenes to obtain compounds of increased flexibility, water resistance, lubricity, and adhesion as compared with said hydroxyl compounds.
    Type: Grant
    Filed: January 31, 1989
    Date of Patent: April 16, 1991
    Assignee: Amoco Corporation
    Inventors: Wayne T. Riddick, Vincent F. Smith, Jr.
  • Patent number: 5008737
    Abstract: A composite comprised of diamond particles embedded in a metal matrix is a highly satisfactory heat sink material for use with a semiconductor.
    Type: Grant
    Filed: October 11, 1988
    Date of Patent: April 16, 1991
    Assignee: Amoco Corporation
    Inventors: Robert D. Burnham, Ricardo S. Sussmann
  • Patent number: 5008366
    Abstract: A process is disclosed for preparing adhesives from polyethylene terephthalate which comprises reacting a trimellitic acid polyester ether with polyethylene terephthalate to prepare a nonlinear copolymer with crosslinking characteristics suitable for use as an adhesive either as a hot-melt adhesive or as a pressure-sensitive adhesive.
    Type: Grant
    Filed: April 25, 1990
    Date of Patent: April 16, 1991
    Assignee: Amoco Corporation
    Inventor: Oscar M. Bathe
  • Patent number: 5006587
    Abstract: A polypropylene composition which demonstrates good color stability and water carry-over properties comprises polypropylene containing a hindered amine light stabilizer and about 0.01 to about 0.5 wt. % of a fluoborate salt. Ammonium fluoborate, sodium fluoborate and potassium fluoborate are particularly useful.
    Type: Grant
    Filed: September 25, 1989
    Date of Patent: April 9, 1991
    Assignee: Amoco Corporation
    Inventor: Ivor R. Fielding
  • Patent number: 5004860
    Abstract: The filter system includes a plurality of porous metal filter tubes and is used in a method for extracting high purity solid para-xylene crystals from a mother liquor feed slurry of mixed xylenes in liquid and crystal form utilizing a separation unit which includes a crystallization stage where the mother liquor slurry is cooled in at least one crystallizer to crystallize liquid para-xylene into solid crystals, an isomerization stage where xylenes, such as ortho-xylene and meta-xylene, are reacted over a catalyst bed to convert these xylenes into para-xylene, and a distillation stage where the mixed xylenes are separated from the impurities from which byproducts are obtained.
    Type: Grant
    Filed: July 28, 1986
    Date of Patent: April 2, 1991
    Assignee: Amoco Corporation
    Inventors: John S. Hansen, William A. Waranius
  • Patent number: 5004830
    Abstract: A process is disclosed for liquid phase oxidation of alkyl aromatic hydrocarbons to aromatic carboxylic acids in presence of a multivalent catalyst promoted by a source of bromine. The oxidation is conducted in at least two oxidation reactions. Exothermic heat of reaction is controlled by means of a liquid phase heat exchanger to control temperature and pressure. Oxygen partial pressure in each stage is at least 1.5 psia to minimize oxygen starvation and improve selectivity. Low reactor temperature, high reactor pressure and improved selectivity improve product yield and product quality.
    Type: Grant
    Filed: November 29, 1989
    Date of Patent: April 2, 1991
    Assignee: Amoco Corporation
    Inventors: Chang M. Park, Wayne P. Schammel