Abstract: A post-treatment process for making a water-resistant polymeric coating composition or a strongly-swellable polymeric gel includes providing a stable, aqueous two-phase polymeric composition by the steps of forming a reaction mixture in a reaction vessel which includes a water-soluble vinyl monomer, optionally with one or more water-soluble comonomers, first amount of a crosslinking agent, and water, heating the mixture, then periodically adding a predetermined amount of an initiator, and polymerizing at about 30-130° C., optionally removing the resultant two-phase composition from the reaction vessel, adding a predetermined amount of an additional crosslinker or proteinaceous compound thereto, optionally coating the mixture onto a support, and optionally heating to further polymerize the mixture.
Type:
Grant
Filed:
June 15, 2001
Date of Patent:
March 30, 2004
Assignee:
ISP Investments Inc.
Inventors:
David K. Hood, Stephen L. Kopolow, Michael Tallon, Yoon Tae Kwak, Laurence Senak, Drupesh Patel, John Mc Kittrick
Abstract: A flashing device for covering a wall mounted service feed line entering or exiting a building which device comprises a flat plate having a central keyhole shaped opening and a downwardly or horizontally extending hollow sleeve member integrally mounted to the eye portion of the keyhole shaped opening on a plane approximately perpendicular to said plate; the underside of said sleeve having a slot horizontally disposed along its entire length, wherein the opposed edges ends of the horizontal slot are contiguous with the bottom eye portion and the top leg portion of the keyhole shaped opening and the width of the slot is commensurate with the width of the service feed line to or from the building.
Type:
Grant
Filed:
November 9, 2001
Date of Patent:
March 16, 2004
Assignee:
Building Materials Investment Corporation
Abstract: What is described is a polymeric hydrogel of a polymeric anhydride or acid, e.g. maleic anhydride or maleic acid polymer, or copolymer thereof, crosslinked with a crosslinking agent containing at least 2 crosslinkable groups, particularly, —OH or —NH2, or both. The reaction product is a crosslinked polymeric ester or amide/imide, or both, suitably having a mole ratio of —OH, or —NH2, to —COOH, of 1:10 to 10:1, preferably 2:10 to 7:1. The hydrogel is particularly swellable in water, e.g. >100% in 1 hour in aqueous media; and forms a thin, tacky layer on a substrate, which property is useful in bioadhesive products.
Abstract: The invention relates to a coated fiber mat of improved tear strength upon dividing pieces of the coated mat and the coating which comprises a cured, non-woven, fiber glass mat containing a polysiloxane wherein the fibers are fixedly distributed in a formaldehyde type binder containing a binder modifier which is a crosslinked styrene/acrylic polymer, and to a process for the preparation of the mat.
Type:
Grant
Filed:
December 9, 2002
Date of Patent:
March 16, 2004
Assignee:
Building Materials Investment Corporation
Abstract: An inkjet printing composition for coating a substrate to receive dye images thereon includes: (a) a polymer for absorbing said dye images, and (b) a dye fixative therein to inhibit migration of dye images from one part of the substrate to other portions thereof.
Type:
Grant
Filed:
June 27, 2002
Date of Patent:
January 27, 2004
Assignee:
ISP Investments Inc.
Inventors:
Stephen L. Kopolow, John M C Kittrick, Michael Tallon
Abstract: A stable, aqueous cationic hydrogel of, by weight, 1-50% of a crosslinked cationic copolymer of 5-95% vinylpyrrolidone (VP) and 5-95% 3-dimethylaminopropyl(meth)acrylamide (DMAPMA) monomers, a crosslinking agent in an amount of 0.05-1% of said monomers, and water is described. The hydrogel has a pH of about 10 and a Brookfield viscosity of about 650 (Model DV-II+, RV spindle #3, speed 10 rpm); it can increase its viscosity by up to 40× at a pH of 3-9 and absorb up to 200× its weight of water. The hydrogel also can effectively condition hair even in the presence of an anionic surfactant.
Type:
Grant
Filed:
January 12, 2001
Date of Patent:
December 23, 2003
Assignee:
ISP Investments Inc.
Inventors:
Yuanzhen Zhong, Janusz Jachowicz, Philip F. Wolf, Roger L. Mc Mullen, Jr.
Abstract: This invention relates to a non-leachable, oil based carrier derived from the anhydrous free radical solution polymerization of a water insoluble acrylate and/or acrylamide monomer in an oil medium for use in long lasting skin lubricating formulations.
Abstract: A method of color inkjet printing on a substrate coated with a substantially colorless, 90-10 to 30-70, wt/wt, copolymer of vinyl pyrrolidone and vinyl imidazole, by inkjet printing dye images on the thus-coated substrate, characterized in that the dye images obtained exhibit excellent light fastness.
Type:
Grant
Filed:
June 5, 2002
Date of Patent:
November 4, 2003
Assignee:
ISP Investments Inc.
Inventors:
Stephen L. Kopolow, Drupesh Patel, Yoon Tae Kwak, Michael Tallon, David K. Hood, Laurence Senak, John M C Kittrick
Abstract: A process for making a solution of a copolymer of maleic anhydride (MA) and methyl vinyl ether (MVE) monomers the specific viscosity (SV) of the product being about 2.5-6, preferably 3-5, indicating a weight average molecular weight of substantially above one million, preferably above 1.5 million and a solids content of about 20-45%, preferably 30-40, in isopropyl acetate (IPAc), solvent includes the steps of (a) precharging part of MVE in IPAc into a reactor heated to about 50-90° C., and then (b) feeding (i) a solution of MA in IPAc, (ii) the rest of MVE, at a mole ratio of MA:MVE of 1:≧1.5 to 1:<3, preferably 1:2.4, and (iii) a free radical initiator dissolved in IPAc, in an amount of 0.02-0.3%, preferably 0.05-0.2%, based on total monomers, into the reactor over time. Powders of such MA/MVE copolymers are made by removing the solvent from the solution.
Type:
Grant
Filed:
November 26, 2002
Date of Patent:
September 23, 2003
Assignee:
ISP Investments Inc.
Inventors:
Yoon Tae Kwak, Stephen L. Kopolow, Alan J. Carlin
Abstract: An aqueous dispersion of (a) 0.1-40% by wt. of a low molecular weight, low melting point, water-insoluble polymer in which the polymer particles have a size <10 microns, and (b) 0.001-30% by wt. of an anionic emulsifier.
Type:
Grant
Filed:
August 8, 2001
Date of Patent:
September 23, 2003
Assignee:
ISP Investments Inc.
Inventors:
James F. Curry, Kolazi S. Narayanan, Ronald H. Goehner, Jr., Domingo I. Jon, George B. Beestman
Abstract: A tablet coating composition including a mixture of (a) sodium alginate and (b) a polyvinylpyrrolidone-vinyl acetate copolymer, and, optionally, (c) hydroxypropylmethyl cellulose, and/or hydroxypropyl cellulose.
Type:
Grant
Filed:
June 5, 2001
Date of Patent:
September 16, 2003
Assignee:
ISP Investments Inc.
Inventors:
Antonio Moroni, Nadhamuni G. Nerella, William Drefko
Abstract: What is described herein is a process for preparing a lightly-crosslinked copolymer of (a) vinyl pyrrolidone (VP) and (b) dimethylaminopropyl methacrylamide (DMAPMA) under more reproducible conditions. Suitably the weight ratio of (a):(b) is 50-95:50-5, preferably 80:20. The copolymer has a Brookfield viscosity of 5,000 to 45,000 cps; preferably 10,000 to 30,000 cps, and a haze of <100 NTU; it includes about 0.1 to 0.5 wt. %, preferably 0.2 to 0.4 wt. %, of a cross-linking agent based upon the total weight of the monomers in the copolymer.
Abstract: What is described herein is a pharmaceutical excipient which is a proliferous copolymer of vinyl pyrrolidone and vinyl acetate, having advantageous dissolution and disintegration properties.
Type:
Grant
Filed:
February 7, 2002
Date of Patent:
September 16, 2003
Assignee:
ISP Investments Inc.
Inventors:
Edward G. Malawer, James P. Cullen, Chi-San Wu, Laurence Senak, William J. Drefko
Abstract: What is described is a polymeric hydrogel product of a stable, aqueous polymeric composition which composition forms a clear to translucent film upon application to a substrate, and includes, by weight, 5-75% of (a) a water-soluble polymer having (b) in situ-formed, substantially water-insoluble resinous particles of said polymer substantially uniformly dispersed therein, and (c) 25-95% of water, made by irradiating the composition with high energy electron beam or gamma-radiation.
Abstract: Liquid compositions consisting essentially of by weight, 0.1-50% IPBC in 99.9-50% polyethylene glycol, polypropylene glycol or polypropylene glycol glyceryl ester, or mixtures thereof, which do not contribute to the VOC of paints and coatings and is stabilized effectively against discoloration even at elevated temperatures or direct sunlight.
Type:
Grant
Filed:
December 6, 2002
Date of Patent:
September 9, 2003
Assignee:
ISP Investments Inc.
Inventors:
Karen Winkowski, Xianbin Liu, Claudinei A. Fava, Daniel H. Brown
Abstract: Colored roofing granules and methods for their preparations, having decorative metallic appearance and enhanced stability against discoloration of color containing a silica-encapsulated metallic flake or colored lamellar effect pigment distributed in an insolubilized alkali silicate coating.
Abstract: A laundry detergent composition which includes a standard detergent formulation and an effective soil releasing amount of vinyl caprolactam homopolymer having a K-value of at least 40, preferably 40-50.