Abstract: The present invention discloses the preparation of a novel family of polytetramethyleneglycol monooctaneoate ester-ethers and their use as internal plasticizers for propellant compositions.
Type:
Grant
Filed:
May 23, 1983
Date of Patent:
November 13, 1984
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: This invention involves the synthesis of a novel family of azido nitramino ethers and their utilization as energetic plasticizers for advanced solid propellant compositions. They include the novel compounds bis (2-azidoethoxymethyl) nitramine and 1,12-diazido-3,10-dioxa-5,8-dinitrazadodecane.
Type:
Grant
Filed:
December 6, 1983
Date of Patent:
November 13, 1984
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: This invention discloses the synthesis of a polytetramethyleneglycol pivalate polyether and its use as a plasticizer for propellant compositions.
Type:
Grant
Filed:
May 23, 1983
Date of Patent:
November 13, 1984
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: The present invention concerns itself with the synthesis of N-octyldecylbutyl urethane and its use as an internal plasticizer for solid propellants.
Type:
Grant
Filed:
May 23, 1983
Date of Patent:
November 13, 1984
Assignee:
The United States of Amercia as represented by the Secretary of the Air Force
Abstract: The present invention concerns itself with the synthesis of N-octyl(2-ethylhexyl)urethane and its use as an internal plasticizer for isocyanate-cured solid propellant compositions.
Type:
Grant
Filed:
May 23, 1983
Date of Patent:
November 13, 1984
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: Polyaromatic ether-sulfone-ketones containing fluoro-substituted-p-cyclophane units were prepared from isophthaloyl chloride, terephthaloyl chloride, diphenyl ether, diphenoxydiphenyl sulfone and a small amount of either 1,1,2,2,9,9,10,10-octafluoro[2,2]-p-cyclophane (type B) or pseudo-p-1,1,2,2,9,9,10,10-octofluoro[2,2]-p-cyclophane bis-acid chloride (type A) by a Friedel-Crafts type polymerization procedure. The p-cyclophane units were incorporated as cross-linking sites.
Type:
Grant
Filed:
November 16, 1983
Date of Patent:
October 9, 1984
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: A process for introducing a fluorine atom into an aromatic hydrocarbon by effecting a substitution reaction between an aromatic hydrocarbon and an NF.sub.4.sup.+ cation containing salt.
Type:
Grant
Filed:
September 20, 1983
Date of Patent:
October 9, 1984
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: A device for detecting the degree of contamination of a gas filter system by a contaminating gas. The device comprises a filter chamber having a pair of grids positioned therewithin and coated with a semiconductive polymer whole bulk conductivity changes due to a chemical reaction between the polymer and a contaminating gas. Measurement of the change is then utilized to indicate the degree of contamination in the filter system.
Type:
Grant
Filed:
January 27, 1982
Date of Patent:
September 18, 1984
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: The present invention concerns itself with a method for synthesizing hypofluorite compounds by utilizing fluorine fluorosulfate as a fluorinating agent and to a novel pentafluorotellurium hypofluorite compound prepared thereby.
Type:
Grant
Filed:
March 24, 1983
Date of Patent:
July 31, 1984
Assignee:
The United States of America as represented by the Secretary of the Air Force
Inventors:
Carl J. Schack, William W. Wilson, Karl O. Christe
Abstract: A method and apparatus for producing molecular oxygen in the excited singlet delta oxygen electronic state for use as an excited species reactant in a high energy, continuous-wave, chemically pumped laser. In this invention, small amounts of sodium hydroxide and hydrogen peroxide are continuously mixed, reacted, cooled and then combined with chlorine to form a mixture which is injected into a mixing chamber as very fine droplets to provide an efficient means for effecting a reaction which produces excited molecular oxygen.
Type:
Grant
Filed:
September 30, 1982
Date of Patent:
July 24, 1984
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: An improved method for synthesizing poly (carbonyl fluoride) oligomers by using bis(trifluoromethyl)trioxide as a reaction initiator in the photo-oxidation of F-3 methylbutene-1.
Type:
Grant
Filed:
September 16, 1982
Date of Patent:
July 17, 1984
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: This invention involves the synthesis of a novel family of azido nitramino ethers and their utilization as energetic plasticizers for advanced solid propellant compositions. They include the novel compounds bis (2-azidoethoxymethyl) nitramine and 1,12-diazido-3,10-dioxa-5,8-dinitrazadodecane.
Type:
Grant
Filed:
April 8, 1982
Date of Patent:
April 3, 1984
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: This invention involves the synthesis of a novel family of azido fluorodinitro amines and their utilization as energetic plasticizers for advanced solid propellant compositions.
Type:
Grant
Filed:
April 12, 1983
Date of Patent:
February 21, 1984
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: This invention involves the synthesis of a novel family of azido esters and their utilization as energetic plasticizers for advanced solid propellant compositions. This family includes as an illustrative member, the novel compound 6-azidohexyl-6-azidohexanoate.
Type:
Grant
Filed:
April 13, 1983
Date of Patent:
February 21, 1984
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: This invention involves the synthesis of a novel family of azido nitrocarbamates and their utilization as energetic liquid plasticizers for advanced solid propellant compositions. The novel family of plasticizers is represented specifically by the novel compound, 1,3-diazido-2-propyl-N-nitro-N-trinitropropyl carbamate.
Type:
Grant
Filed:
March 25, 1982
Date of Patent:
February 21, 1984
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: A process for introducing a fluorine atom into an aromatic hydrocarbon by effecting a substitution reaction between an aromatic hydrocarbon and an NF.sub.4.sup.+ cation containing salt.
Type:
Grant
Filed:
January 27, 1982
Date of Patent:
December 27, 1983
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: This invention involves the synthesis of a novel family of azido esters and their utilization as energetic plasticizers for advanced solid propellant compositions. This family includes as an illustrative member, the novel compound 6-azidohexyl-6-azidohexanoate.
Type:
Grant
Filed:
April 21, 1982
Date of Patent:
December 6, 1983
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: This invention involves the synthesis of a novel family of azido fluorodinitro amines and their utilization as energetic plasticizers for advanced solid propellant compositions.
Type:
Grant
Filed:
February 19, 1982
Date of Patent:
December 6, 1983
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: A method for fabricating a homogenous and uniformly sized mixture of alkaline earth metal carbonates found to be especially useful as an emission type coating material for application to a cathodic element of a thermionic vacuum tube.