Abstract: Methods and processes are provided by which inhibited-crystallization polymers may be employed as feedstock materials in thermoplastic extrusion-type additive manufacturing systems. Counteracting the tendency of such polymers to uncontrolledly settle into an amorphous state upon cooling under typically used conditions, techniques are disclosed for controlling process temperatures, exposure times and feed rates to produce parts with uniform crystallinity, high mechanical strength and efficient throughput.

Abstract: In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, an ink described herein comprises up to 80 wt. % oligomeric curable material; up to 80 wt. % monomeric curable material; up to 10 wt. % photoinitiator; up to 1 wt. % non-curable absorber material; and up to 10 wt. % one or more additional components, based on the total weight of the ink, and wherein the total amount of the foregoing components is equal to 100 wt. %. Additionally, the photoinitiator is operable to initiate curing of the oligomeric curable material and/or the monomeric curable material when the photoinitiator is exposed to incident curing radiation having a peak wavelength ?. Moreover, the ink has a penetration depth (Dp), a critical energy (Ec), and a print through depth (DPT) at the wavelength ? of less than or equal to 2×Dp.

Abstract: A three dimensional printing system includes a controller that is configured to (1) receive an incoming slice data array that defines an initial two dimensional object having an initial outer boundary; (2) process the incoming slice data array to define a simple outer boundary whereby if the object has two portions defining a channel therebetween, the channel is reduced or eliminated thereby reducing a perimeter of the outer boundary. In one embodiment the object is two objects. If the channel is defined between the two objects, then the processing merges the two objects. If the channel is a concave recess within one object, then the processing reduces the depth of or eliminates the concave recess.

Abstract: Polymerizable liquids for 3D printing applications are described herein which, in some embodiments, impart flame resistant and/or flame retardant properties to articles printed from the build materials. The polymerizable liquids may also impart desirable mechanical properties to the articles. In some embodiments, a polymerizable liquid comprises a curable isocyanurate component in an amount of at least 20 wt. %, based on total weight of the polymerizable liquid, and an organophosphate component comprises one or more organophosphate compounds. In some embodiments, the polymerizable liquid further comprises an acrylate component.

Abstract: Additives for three-dimensional build materials or inks are described herein which, in some embodiments, can impart one or more structural enhancements to articles printed from the build materials. In one aspect, a polymerizable liquid comprises at least one additive including a plurality of cyclopolymerizable functionalities separated by an aliphatic linker or alkylene oxide linker.

Abstract: A clamping device is disclosed having a rigid frame and a concavity for accepting items to be clamped together, a clamping action upon items entering into the concavity being facilitated by a contacting member in conjunction with a force-maintaining member and a displacement-limiting element to readily accommodate a range of clamped item dimensions without requiring separate opening or tightening adjustments to be performed by a user while applying the clamping device.

Abstract: Polymerizable liquids for 3D printing applications are described herein which, in some embodiments, impart flame resistant and/or flame retardant properties to articles printed from the liquids. The polymerizable liquids may also impart desirable mechanical properties to the articles. In some embodiments, a polymerizable liquid comprises a curable isocyanurate component in an amount of at least 5 wt. %, based on total weight of the polymerizable liquid, and a brominated acrylate ester component. Additionally, methods of printing three-dimensional articles using said polymerizable liquids are described herein.

Abstract: Various embodiments of the present disclosure disclose manifolds, methods, and systems for measuring cell functions. In various embodiments, a first reservoir storing a first fluid and a second reservoir storing a second fluid may be fluidically connected via a fluid channel. Further, the first fluid and the second fluid may be such that an entropic gradient force causes the first fluid to flow towards a container that is located therebetween and contains cells therein. The cells release cell products into the first fluid flowing in the fluidic channel, which in turn flows into the second reservoir. The cell products can be sampled from the second reservoir and/or from the container to measure the function of the cells.

Abstract: There is provided improved laser sintering systems that increase the powder density and reduce anomalies of the powder layers that are sintered, that measure the laser power within the build chamber for automatic calibration during a build process, that deposit powder into the build chamber through a chute to minimize dusting, and that scrubs the air and cools the radiant heaters with recirculated scrubbed air. The improvements enable the laser sintering systems to make parts that are of higher and more consistent quality, precision, and strength, while enabling the user of the laser sintering systems to reuse greater proportions of previously used but unsintered powder.

Abstract: Water dispersible support materials for use with a three-dimensional printing system are described herein. In some embodiments, a support material described herein comprises a phase change wax component and an ethoxylated polyethylene having the formula H—(CH2)m—(OCH2CH2)n—OH, wherein m is an integer from 22 to 60 and n is an integer from 2 to 200. In some cases, the phase change wax component and the ethoxylated polyethylene are each present in the support material in an amount of 20-80% by weight.

Abstract: Polymerizable liquids are described herein which, in some embodiments, can produce 3D printed articles of high resolution and desirable mechanical properties. In one aspect, a polymerizable liquid comprises an acrylate component, and a composite resin comprising a curable carrier and polymeric particles dispersed in the curable carrier. The polymerizable liquid also comprises a photoinitiator component.

Abstract: A three-dimensional (3D) printing system includes a vessel, a coating subsystem, a calibration block, and a controller. The vessel is configured to contain a photocurable resin having a resin upper surface. The coating subsystem includes a coater module including a coater blade, a lateral movement mechanism coupled to the coater module, a sensor mounted to the coater module, and a vertical actuator system. The calibration block has a calibration surface. The controller is configured to operate the lateral movement mechanism to position the coater blade over the calibration block, operate the vertical actuator system to lower the coater blade into engagement with the calibration surface of the calibration block, operate the sensor to measure a distance to the calibration block, and store the distance as indicative of a vertical position of a lower edge of the coater blade.

Abstract: Applied within an automated robotic manufacturing system that includes additive manufacturing capabilities, methods and enabling devices are disclosed for achieving precise multi-dimension positional alignment among a plurality of diverse took that are involved in collaboratively constructing a solid object. The enabling devices according to various embodiments include an automatically deployed contact sensing probe and a tool center point sensor that detects contact with tools in multiple axes. At least one disclosed method advantageously utilizes both sensing devices in complement.

Abstract: Provided herein is a system for producing a product. The system generally comprises a large-area micro-stereolithography system, an optical imaging system, and a controller in communication with the large-area micro-stereolithography system and the optical imaging system. The large-area micro-stereolithography system is capable of generating the product by optically polymerizing successive layers of a curable resin at a build plane. The controller is capable of analyzing a focus level of the reference target based on the captured image; and based on the analyzing, adjusting a focus property of the projected image beam of the stereolithography system.

Abstract: Build materials for 3D printing applications are described herein which, in some embodiments, comprise monomeric species operable for producing articles with high Tg and/or high heat deflection temperature while maintaining shelf stability. In one aspect, a polymerizable liquid comprises at least 20 weight percent isocyanurate polyacrylate; a photoinitiator component; and a crystallization inhibitor component comprising monomeric curable material, oligomeric curable material or mixtures thereof, wherein the polymerizable liquid does not exhibit crystallization over a period of 28 days at a storage temperature of 5-10° C.

Abstract: A system for manufacturing a three-dimensional (3D) article includes a controller. The controller is configured to (A) receive a solid model defining the 3D article having an unsupported (downward facing) surface and (B) define a support structure for the unsupported surface. The support structure includes (1) a lower support beam, (2) a node body, and (3) at least three branches. The node body is defined at an upper end of the lower support beam. The node body has an upper surface that is generally in facing relation with the unsupported surface. The at least three branches extend with a diverging geometry away from the upper surface of the node body and to the unsupported surface. The branches are individually defined by a vertical sequence of contour scan patterns.

Abstract: In one aspect, build materials and support materials for use with a 3D printer are described herein. Such materials include a phosphor component in combination with other components. In some embodiments, the phosphor component of a build material or support material is present in the material in an amount of 0.001-0.5 wt. % and has a peak photoluminescence (PL) emission wavelength of 430-750 nm and a photoluminescence quantum yield (QY) of 0.10-1.

Abstract: A three-dimensional (3D) printing system includes a resin vessel, a fabrication subsystem, a waste collection subsystem, and a controller. The resin vessel is configured to contain photocurable resin. The fabrication subsystem is configured to form the 3D article with layer-by-layer selective curing of the photocurable resin. The fabrication subsystem includes a build plate, a build plate support structure, and a vertical movement mechanism. The waste collection subsystem is attached to the build plate support structure and configured to capture partially polymerized resin as the build plate support structure moves in an upward direction. The controller is configured to (a) operate the vertical movement mechanism to translate the build plate support structure to a lower position and (b) operate the vertical movement mechanism to raise the waste collection subsystem up through the resin and to a position at which partially polymerized resin can be unloaded from the waste collection subsystem.

Abstract: A three-dimensional (3D) printing system includes a resin vessel containing photocurable resin, an imaging system, a build plate with a plate upper surface, a vertical positioner, a volume compensator (VC), and a controller. The controller is configured to: (a) operate the VC to maintain a resin upper surface proximate to a build plane, (b) operate the imaging system and the vertical positioner to generate a plurality of base layers upon the plate upper surface, (c) receive a first signal responsive to vertical motion of the resin upper surface, (d) analyze the first signal to determine a metric that is related to an extent of immersion of the plate upper surface below the resin upper surface during formation of the base layers, and (e) operate the imaging system and the vertical positioner to begin generation of the 3D article after the metric has reached a predefined threshold.

Abstract: Additives for three-dimensional build materials or inks are described herein which, in some embodiments, can impart flame retardant properties and/or structural enhancements to articles printed from the build materials. In some embodiments, such an additive comprises a compound of Formula I herein, wherein L and Z are ring substituents comprising at least one polymerizable point of unsaturation, and wherein R1 and R2 are independently selected from the group consisting of alkylene and alkenylene, and R3-R6 each represent one to four optional ring substituents, each one of the one to four ring substituents independently selected from the group consisting of alkyl, heteroalkyl, haloalkyl, halo, hydroxyl, alkoxy, amine, amide, and ether, and wherein n is an integer from 1 to 7.