Abstract: Polymerizable liquids for 3D printing applications are described herein which, in some embodiments, impart flame resistant and/or flame retardant properties to articles printed from the build materials. The polymerizable liquids may also impart desirable mechanical properties to the articles. In some embodiments, a polymerizable liquid comprises a curable isocyanurate component in an amount of at least 20 wt. %, based on total weight of the polymerizable liquid, and an organophosphate component comprises one or more organophosphate compounds. In some embodiments, the polymerizable liquid further comprises an acrylate component.

Abstract: In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, an ink described herein comprises 20-60 wt. % oligomeric curable material; 10-50 wt. % cyclocarbonate (meth)acrylate monomer; and 0.1-5 wt. % photoinitiator, based on the total weight of the ink. Additionally, in some cases, the ink further comprises one or more additional curable materials differing from the oligomeric curable material and the cyclocarbonate (meth)acrylate monomer. An ink described herein, in some embodiments, also comprises one or more additional component that are non-curable.

Abstract: Additives for three-dimensional build materials or inks are described herein which, in some embodiments, can impart one or more structural enhancements to articles printed from the build materials. In one aspect, a polymerizable liquid comprises at least one additive including a plurality of cyclopolymerizable functionalities separated by an aliphatic linker or alkylene oxide linker.

Abstract: A three-dimensional (3D) print engine includes (A) a plurality of walls laterally defining a build chamber, (B) a build box including a build plate, (C) a powder dispenser, (D) a beam system for fusing layers of powder, (E) a peripheral plate disposed between the build plate and the plurality of walls and having an upper surface, (F) a gas inlet that ejects a gas flow stream that passes over the build plate and the peripheral plate, (G) a gas outlet that receives the gas flow stream, (H) a plurality of projecting structures mounted to and extending above the upper surface of the peripheral plate, and (I) a gas handling system coupled to the gas inlet and gas outlet. The plurality of projecting structures shape the flow field of the gas flow stream to provide a more uniform velocity of gas flow velocities above the build plane.

Abstract: Systems and methods for the dispensing of liquid, and automated layering of liquid hydrogel patterns are disclosed. In some embodiments, the systems and methods described herein may utilize a bioprinter having a brush that is configured to pattern a collagen layer. In some embodiments, the bioprinter may be used to make layered bioprinted materials. In some embodiments, the systems and methods described herein may include a bioprinter having an atomizer needle that is configured to dispense liquid in an automated way. In some embodiments, the disclosed systems and methods may provide modified surfaces upon which materials may be printed using a three-dimensional (3D) bioprinter. In one embodiment, a modified surface may be formed of polydimethylsiloxane (PDMS), silicones and the like.

Abstract: Disclosed is a bioextruder assembly capable of “retro-fit” an existing three-dimensional (3D) printer such that it is capable of printing biomaterials. The bioextruder assembly may be modular, self-contained, and configured as “plug-and-play” unit. In some embodiments, the bioextruder assembly may be configured for use in zero-gravity environments such as space and configured to engage with existing 3D printers in space. In some embodiments the bioextruder assembly includes an extruder configured to extrude bio-materials stored in a syringe that is coupled to the extruder, and a converter. The converter may include an electromechanical coupling component that couples the converter to a three-dimensional printer system, and a motor configured to actuate the extrusion of bio-materials stored in the syringe based on signals received from the three-dimensional printing system via the electromechanical coupling component.

Abstract: A three-dimensional (3D) printing system for manufacturing a 3D article includes a resin vessel, a build tray, a movement mechanism, a light engine, a housing, a gas handling system, and a controller. The resin vessel includes a transparent sheet on a lower side. The housing defines two chambers including an upper chamber and a lower chamber. The upper chamber is in fluidic communication with the resin contained by the resin vessel. The lower chamber is in fluid communication with a lower surface of the transparent sheet. The controller is configured to (a) operate the gas handling system to reduce and control a partial pressure of oxygen in the upper and lower chambers, (b) operate the movement mechanism and the light engine to form the 3D article in a layer-by-layer manner.

Abstract: In one aspect, inks for use with a three-dimensional printing system are described herein. In some embodiments, an ink described herein comprises a thiol monomer component and an ene monomer component. Moreover, in some cases, an ink described herein further comprises an additional (meth)acrylate monomer component differing from the ene monomer component. In some such cases, the additional (meth)acrylate monomer component can be polymerized separately from the thiol and ene monomers of the ink.

Abstract: A three-dimensional (3D) printing system is configured to manufacture a three-dimensional 3D article in a layer-by-layer manner. The 3D printing system includes a resin vessel, a tank agitation subsystem, a fabrication subsystem, and a controller. The resin vessel is configured to contain photocurable resin and has a lower region within a distance H of a bottom surface of the resin vessel. The agitation subsystem includes (a) a grating disposed within the lower region of the resin vessel and (b) an agitation movement mechanism coupled to the grating. The fabrication subsystem is configured to form the 3D article by a layer-by-layer selective curing of the photocurable resin. The controller is configured to operate the agitation movement mechanism to oscillate the grating along a lateral Y-axis to remix filler particulates within the photocurable resin.

Abstract: A three-dimensional printing system includes a resin vessel containing resin, an imaging bar, a movement mechanism coupled to the imaging bar, and a controller. The imaging bar includes an arrangement of light emitting devices that selectively emit radiation from an exit surface of the imaging bar to define a build plane in the resin. The exit surface of the imaging bar is preferably less than 10 millimeters from the build plane. The controller is configured to scan the imaging bar along a scan axis and, concurrent with scanning, operate the imaging bar to selectively image a layer of resin at the build plane.

Abstract: A three-dimensional (3D) printing system for manufacturing a three-dimensional article includes a resin vessel for containing a volume of photocurable resin having a resin upper surface, an imaging system configured to define a build plane, a build plate having a build plate upper surface, a build plate positioner, a sensor configured to generate a signal indicative of a fluid-related vertical position of one or more of the resin upper surface and a component of a volume compensator (VC), and a controller. The controller is configured to (1) operate the build plate positioner to vertically translate build plate upper surface, (2) concurrent with operating the build plate positioner, receiving the signal from the sensor, (3) analyze the signal to determine a build plate geometric signature, and (4) determine or suspend a build plan for building the 3D article based upon the determined geometric signature.

Abstract: An additive manufacturing system for producing a three-dimensional article includes a print engine, a post-fabrication powder removal apparatus, a transport mechanism, and a controller. The post fabrication removal apparatus includes a rotary frame defining an internal receptacle cavity, a plurality of clamps coupled to a corresponding plurality of actuators, a clamping plate coupled to a lift apparatus, and an agitation device mounted to the clamping plate. The controller is configured to perform the following steps: (1) Operate the transport mechanism to transport the build box to the internal receptacle cavity. (2) Operate the plurality of actuators to engage the build box with the plurality of clamps to secure the build box to the rotary frame. (3) Operate the rotary frame to rotate the build box until unfused powder begins to exit the build box. (4) Operate the agitation device to facilitate pouring of the unfused powder from the build box.

Abstract: A three-dimensional printing system includes a build vessel, a plate, a vertical movement mechanism coupled to the plate, a powder coater, an energy source, and a controller. The build vessel includes one or a plurality of vertical chamber walls. The vertical chamber wall(s) laterally enclose a build chamber and have inward facing surfaces that collectively define a lateral extent or width of the build chamber. The build vessel includes a lip that defines an upper surface of the build vessel. The lip extends inwardly from the inward facing surfaces to define an opening having a lateral extent that is smaller than the lateral extent of the build chamber. The plate has an upper surface and a lateral extent that is larger than the lateral extent of the opening. The plate laterally overlaps with the lip.

Abstract: The present invention provides a three-dimensional bioprinter for fabricating cellular constructs such as tissues and organs using electromagnetic radiation (EMR) at or above 405 nm. The bioprinter includes a material deposition device comprising a cartridge for receiving and holding a composition which contains biomaterial that cures after exposure to EMR. The bioprinter also includes an EMR module that emits EMR at a wavelength of about 405 nm or higher. Also provided is a bioprinter cartridge which contains cells and a material curable at a wavelength of about 405 nm or greater. The cells are present in a chamber and are extruded through an orifice to form the cellular construct.

Abstract: Build materials for 3D printing applications are described herein which, in some embodiments, comprise a dye component operable to alter spectral characteristics of the printed part over the course of the build cycle. In some embodiments, for example, the dye component can provide desirable light penetration depth during article printing and sufficient optical clarity during final light curing processes.

Abstract: A three-dimensional printing system includes a support plate, a transparent sheet, gas pressure source, and a conduit. The support plate includes a transparent central portion and defines a gas inlet and a gas outlet. The transparent sheet overlays the transparent central portion, the gas inlet, and the gas outlet of the support plate. A central chamber is defined between the transparent sheet and the support plate. The gas pressure source is coupled to the gas inlet through the conduit. An input fluid flow resistance Li is defined from the gas pressure source to the central chamber. An output fluid flow resistance Lo is defined out through the gas outlet and to an outside location. A ratio of Li to Lo is sufficient to allow a stable control of a physical configuration of the central unsupported portion of the transparent sheet above the support plate.

Abstract: A three-dimensional printing system includes a build platform, a movement mechanism, a coating module, a consolidation module, and a controller. The controller is configured to (1) operate the movement mechanism and the coating module to deposit a new powder layer over an upper surface of the build platform or powder, (2) operate the consolidation module to selectively consolidate the new powder layer, and (3) repeat (1) and (2) until a three-dimensional article is fabricated from a plurality of layers. Step (1) includes, at least one of the plurality of layers (a) operate the movement mechanism and the coating module to deposit a first sublayer of powder having a thickness T1 over the upper surface, and (b) operate the movement mechanism and the coating module to deposit a second sublayer of powder having at thickness T2 over the first sublayer of powder. T2 is less than 20% of T1.

Abstract: In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, an ink described herein comprises 10-70 wt. % cyclopolymerizable monomer, based on the total weight of the ink. The cyclopolymerizable monomer comprises a first ethenyl or ethynyl moiety and a second ethenyl or ethynyl moiety. Additionally, the ?-carbon of the first ethenyl or ethynyl moiety and the ?-carbon of the second ethenyl or ethynyl moiety have a 1,5-, 1,6-, 1,7-, or 1,8-relationship.

Abstract: A three dimensional printing system includes a vertical support, a support plate, a resin vessel, a fluid spill containment vessel, and a light engine. The support plate is affixed to the vertical support at a proximal end. The support plate has an inner surface defining a first central opening. The resin vessel is supported above the support plate and has an inner edges surrounding a second central opening. The resin vessel includes a transparent sheet that closes the second central opening. The fluid spill containment vessel is supported below the support plate and includes a transparent window. The light engine is supported below the fluid spill containment vessel. The first central opening, the second central opening, and the window laterally overlap to provide an optical path whereby the light engine can project light upwardly to a build plane in the resin vessel.

Abstract: A three-dimensional (3D) printing system includes a vessel, a coating subsystem, a calibration block, and a controller. The vessel is configured to contain a photocurable resin having a resin upper surface. The coating subsystem includes a coater module including a coater blade, a lateral movement mechanism coupled to the coater module, a sensor mounted to the coater module, and a vertical actuator system. The calibration block has a calibration surface. The controller is configured to operate the lateral movement mechanism to position the coater blade over the calibration block, operate the vertical actuator system to lower the coater blade into engagement with the calibration surface of the calibration block, operate the sensor to measure a distance to the calibration block, and store the distance as indicative of a vertical position of a lower edge of the coater blade.