Abstract: A battery management system includes one or more lithium ion cells in electrical connection, each said cell comprising: first and second working electrodes and one or more reference electrodes, each reference electrode electronically isolated from the working electrodes and having a separate tab or current collector exiting the cell and providing an additional terminal for electrical measurement; and a battery management system comprising a battery state-of-charge monitor, said monitor being operable for receiving information relating to the potential difference of the working electrodes and the potential of one or more of the working electrodes versus the reference electrode.

Abstract: A positive electrode material is provided including an electroactive material having one or more phases comprising lithium (Li), an electroactive metal (M), and phosphate (PO4), wherein in the fully lithiated state, the overall composition has a ratio of Li:M ranging from greater than about 1.0 to about 1.3, a ratio of (PO4):M ranging from about 1.0 to about 1.132, M is one or more metals selected from the group consisting of Cr, Mn, Fe, Co, and Ni, and at least one phase includes an olivine lithium electroactive metal phosphate. In some instances, a composite cathode material including an electroactive olivine transition metal phosphate and a lithium and phosphate rich secondary phase is disclosed for use in a lithium ion battery.

Abstract: Systems and methods for adjusting sampling and switching rates of a battery management system are provided. For example, a rate at which different battery cells of a battery cell stack are in communication with an analog to digital converter may be adjusted in response to conditions of a battery cell.

Abstract: Methods are provided for making bipolar electrochemical devices, such as batteries, using electrophoresis. A bipolar device is assembled by applying a field that creates a physical separation between two active electrode materials, without requiring insertion of a discrete separator film or electrolyte layer.

Abstract: An electrochemical cell is provided. The cell includes a plurality of electrode sheets separated by at least one separator sheet. A positive extension tab is attached to a current collecting tabs of positive electrode sheets, and a negative extension tab is attached to current collecting tabs of the negative electrode sheets. The dimensions of the positive extension tab and the negative extension tab are selected such that temperature difference between positive extension tab and the negative extension tab are minimized when the electrochemical cell is in use.

Abstract: The invention provides bipolar articles (e.g., batteries and capacitors) with new architectures and methods of making and using the same. Articles are provided with interpenetrating anode and cathode structures that allow for improved power density, and arbitrary form factors that allow for formation in substantially any desired shape. The articles are useful for embedding or integral formation in various electronic devices to provide more efficient use of space in the devices. The articles optionally include self-organizing bipolar structures.

Abstract: Exemplary embodiments of the present invention provide flexible, multi-voltage battery modules having multiple cells that are nested together. The cells can be, for example, cylindrical lithium ion cells. To increase cell package density, the cells can be disposed in a nested configuration so that adjacent cell centers form equilateral triangles. The cells can be placed in a housing or case with interlocking tabs that allow multiple modules to be connected together. Within a module, the cells can be connected in different configurations by buss bars at the top and the bottom of the battery cells. The different configurations may provide different voltages for the module.

Abstract: The grid load synchronization system described herein permits proactive mitigation of the effects of large loads transitioning on and off the power grid and the resultant risks and power quality issues associated therewith. The disclosed proactive system permits a grid-connected power consumer to synchronize demand with power storage equipment in real time using a digital communication link. The power consumer transmits requests to bring a load online or offline to a control site. The control site coordinates power grid source(s) and power grid loads to maintain power quality when loads go on and offline. The control sites manage requests from multiple power consumers and schedule the various loads for the consumers to mitigate the effects of large loads transitioning on and off the power grid. The resulting power quality can be guaranteed when adequate battery resources are made proactively available, rather than reacting to line conditions to engage compensation actions.

Abstract: Materials useful as electrodes for lithium batteries have very good electronic and ionic conductivities. They are fabricated from a starting mixture which includes a metal, a phosphate ion, and an additive which enhances the transport of lithium ions in the resultant material. The mixture is heated in a reducing environment to produce the material. The additive may comprise a pentavalent metal or a carbon. In certain embodiments the material is a two-phase material. Also disclosed are electrodes which incorporate the materials and lithium batteries which incorporate those electrodes.

Abstract: A multi-directional power conversion system for providing power to a motor of a hybrid vehicle includes an electric control unit; an electric motor which provides a driving force to the vehicle; a primary energy storage device; and a secondary energy storage device. An energy management system communicates parameters of the energy storage devices to the electronic control unit. A power manipulating device is coupled between the primary energy storage device and the secondary energy storage device that is configured to manage power between the energy sources and deliver electricity external the vehicle.

Abstract: A battery system including: a plurality of subunits each of which has a heatsink and a battery cell and two voltage terminals symmetrically positioned with respect to a centerline of that battery cell, wherein all of the battery cells are arranged so that their voltage terminals are aligned along two rows; a plurality of identical busbar supports equal in number to the plurality of subunits, each having two slots and mounted on a corresponding different one of the subunits with each of the terminals of the battery cell extending up through the two slots; and a plurality of bimetallic busbars, each one supported by a different corresponding subset of the busbar supports and electrically connected directly to either a first or second terminal of each of the battery cells of each of the modules on which those busbar supports are mounted.

Abstract: A compact, robust, multifunctional and highly manufacturable rechargeable battery cell is provided. The cell design dedicates minimal internal volume to inert components of the cell. This is accomplished, in part, by providing multiple functionalities to individual cell components.

Abstract: An electrode has a front face furthest from the current collector and a back face closest to the current collector and Is disposed on the current collector, and the electrode has a primary gradient of one of a chemical, physical and performance properties of the electroactive particle composition between the front and back faces, with the proviso that the primary gradient is not a bulk porosity gradient. In some embodiments, the electrode further comprises one or more secondary gradients Imposed over the primary gradient.

Abstract: Nanoscale ion storage materials are provided that exhibit unique properties measurably distinct from their larger scale counterparts. For example, the nanoscale materials can exhibit increased electronic conductivity, improved electromechanical stability, increased rate of intercalation, and/or an extended range of solid solution. Useful nanoscale materials include alkaline transition metal phosphates, such as LiMPO4, where M is one or more transition metals. The nanoscale ion storage materials are useful for producing devices such as high energy and high power storage batteries, battery-capacitor hybrid devices, and high rate electrochromic devices.

Abstract: A nanocomposite electrode that includes a current collector, an electroactive layer a conductive adhesive contacting the surface of the current collector and an interlayer region in electrical communication with the current collector and the electroactive material. The interlayer region is interposed between the current collector and the electroactive layer and includes a portion of the conductive adhesive intermixed with a portion of the electroactive layer. The electroactive layer includes electroactive material having a surface area of at least about 10 m2/g. The conductive adhesive may be at least partially soluble in electrode casting solvent. Electrochemical devices, such as lithium secondary cells, containing an electrode with an interlayer region are also provided, as are processes for making such electrodes and electrochemical devices.

Abstract: Systems and methods for detecting and managing a plurality of cells within a battery pack supplying power to propel a vehicle are disclosed. One example method comprises, monitoring voltage of a plurality of battery cells of a battery pack, activating a power supply when a voltage of at least one battery cell of the plurality of battery cells exceeds a threshold, and draining a portion of charge from the at least one battery cell.

Abstract: A battery comprises a battery cell having two voltage terminals and a flexible sidewall; a wall structure against which the battery cell is located, the wall structure including a sidewall that is adjacent to the sidewall of the battery cell; and a tooth structure that extends away from the sidewall of the wall structure and towards the sidewall of the battery cell, wherein the tooth structure includes a distal end sufficiently sharp to puncture the flexible sidewall of the battery cell when the flexible sidewall of the battery cell is forced up against the tooth structure due to a build up of excess pressure inside the battery cell.

Abstract: A battery system including: a plurality of subunits each of which has a heatsink and a battery cell and two voltage terminals symmetrically positioned with respect to a centerline of that battery cell, wherein all of the battery cells are arranged so that their voltage terminals are aligned along two rows; a plurality of identical busbar supports equal in number to the plurality of subunits, each having two slots and mounted on a corresponding different one of the subunits with each of the terminals of the battery cell extending up through the two slots; and a plurality of bimetallic busbars, each one supported by a different corresponding subset of the busbar supports and electrically connected directly to either a first or second terminal of each of the battery cells of each of the modules on which those busbar supports are mounted.

Abstract: An electrochemical device includes a first electrode in electrical communication with a first current collector, a second electrode in electrical communication with a second current collector and a crosslinked solid polymer in contact with the first and second electrodes. At least one of the first and second electrodes includes a network of electrically connected particles comprising an electroactive material, and the particles of one electrode exert a repelling force on the other electrode when the first and second electrodes are combined with an uncrosslinked precursor to the solid polymer.

Abstract: Materials useful as electrodes for lithium batteries have very good electronic and ionic conductivities. They are fabricated from a starting mixture which includes a metal, a phosphate ion, and an additive which enhances the transport of lithium ions in the resultant material. The mixture is heated in a reducing environment to produce the material. The additive may comprise a pentavalent metal or a carbon. In certain embodiments the material is a two-phase material. Also disclosed are electrodes which incorporate the materials and lithium batteries which incorporate those electrodes.