Abstract: A system for balancing energy delivery devices within the one or more battery packs and for providing isolated monitoring of the battery packs includes at least one group of energy delivery devices electrically connected in series. For each group of energy delivery devices, the system includes a balancing circuit for each adjacent pair of energy delivery devices. The balancing circuit adjusts charge stored in each energy delivery device of the pair so that the charge stored in the energy delivery devices of the pair is substantially equal, and the charge stored in each energy delivery device remains above a threshold. The system also includes a voltage monitoring module for sequentially selecting each of the energy delivery devices and providing a voltage associated with the selected device at an output port. The voltage monitoring module uses a low on-resistance differential multiplexer to select each of the energy delivery devices.

Abstract: Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particle to suspensions and the surface modification of the solid in semi-solids: coating the solid with a more electron conductive coating material to increase the power of the device. High energy density and high power redox flow devices are disclosed.

Abstract: Methods are provided for making bipolar electrochemical devices, such as batteries, using electrophoresis. A bipolar device is assembled by applying a field that creates a physical separation between two active electrode materials, without requiring insertion of a discrete separator film or electrolyte layer.

Abstract: Exemplary embodiments of the present invention provide flexible, multi-voltage battery modules having multiple cells that are nested together. The cells can be, for example, cylindrical lithium ion cells. To increase cell package density, the cells can be disposed in a nested configuration so that adjacent cell centers form equilateral triangles. The cells can be placed in a housing or case with interlocking tabs that allow multiple modules to be connected together. Within a module, the cells can be connected in different configurations by buss bars at the top and the bottom of the battery cells. The different configurations may provide different voltages for the module.

Abstract: A system for charging a battery includes a battery pack having at least two lithium ion cells. A controller detects a rate of change of voltage with respect to a state of charge (dV/dSOC) of the battery pack based on a calculated dV/dSOC that represents the battery pack as a whole, without calculating dV/dSOC individually on a cell-by-cell basis. Charging is terminated when dV/dSOC reaches a predetermined value.

Abstract: An energy storage device includes a first electrode comprising a first material and a second electrode comprising a second material, at least a portion of the first and second materials forming an interpenetrating network when dispersed in an electrolyte, the electrolyte, the first material and the second material are selected so that the first and second materials exert a repelling force on each other when combined. An electrochemical device, includes a first electrode in electrical communication with a first current collector; a second electrode in electrical communication with a second current collector; and an ionically conductive medium in ionic contact with said first and second electrodes, wherein at least a portion of the first and second electrodes form an interpenetrating network and wherein at least one of the first and second electrodes comprises an electrode structure providing two or more pathways to its current collector.

Abstract: A composite material having utility as an anode for lithium ion batteries comprises silicon, a transition metal, a ceramic and an electrically conductive diluent such as carbon. In particular instances, the ceramic is electrically conductive, and may comprise vanadium carbide or tungsten carbide. The transition metal may, in some instances, comprise iron. The material may be fabricated by grinding together a starting mixture of the components, and grinding may be accomplished in a high impact ball milling process, and the grinding step may cause partial alloying of the silicon with the metal and/or carbon. Further disclosed is a method for making the material as well as electrodes which incorporate the material.

Abstract: An electrochemical cell is provided. The cell includes a plurality of electrode sheets separated by at least one separator sheet. A positive extension tab is attached to a current collecting tabs of positive electrode sheets, and a negative extension tab is attached to current collecting tabs of the negative electrode sheets. The dimensions of the positive extension tab and the negative extension tab are selected such that temperature difference between positive extension tab and the negative extension tab are minimized when the electrochemical cell is in use.

Abstract: An electrochemical device includes a first electrode in electrical communication with a first current collector, a second electrode in electrical communication with a second current collector and a crosslinked solid polymer in contact with the first and second electrodes. At least one of the first and second electrodes includes a network of electrically connected particles comprising an electroactive material, and the particles of one electrode exert a repelling force on the other electrode when the first and second electrodes are combined with an uncrosslinked precursor to the solid polymer.

Abstract: A high capacity, high charge rate lithium secondary cell includes a high capacity lithium-containing positive electrode in electronic contact with a positive electrode current collector, said current collector in electrical connection with an external circuit, a high capacity negative electrode in electronic contact with a negative electrode current collector, said current collector in electrical connection with an external circuit, a separator positioned between and in ionic contact with the cathode and the anode, and an electrolyte in ionic contact with the positive and negative electrodes, wherein the total area specific impedance for the cell and the relative area specific impedances for the positive and negative electrodes are such that, during charging at greater than or equal to 4C, the negative electrode potential is above the potential of metallic lithium.

Abstract: A system for balancing energy delivery devices within the one or more battery packs and for providing isolated monitoring of the battery packs includes at least one group of energy delivery devices electrically connected in series. For each group of energy delivery devices, the system includes a balancing circuit for each adjacent pair of energy delivery devices. The balancing circuit adjusts charge stored in each energy delivery device of the pair so that the charge stored in the energy delivery devices of the pair is substantially equal, and the charge stored in each energy delivery device remains above a threshold. The system also includes a voltage monitoring module for sequentially selecting each of the energy delivery devices and providing a voltage associated with the selected device at an output port. The voltage monitoring module uses a low on-resistance differential multiplexer to select each of the energy delivery devices.

Abstract: Compositions and methods are provided for coating electroactive particles. Coating materials include a conductive component and a low refractive index component. Coatings are provided in which the conductive and low refractive index components are linked and/or do not form phases having lengthscales greater than about 0.25 ?m. Coatings are provided in which the components are contained in sequential layers.

Abstract: An energy delivery system includes at least one string of two or more energy delivery modules electrically coupled in series. Each energy delivery module includes one or more energy delivery devices for storing and delivering electrical current, and a module monitor for monitoring and controlling each of the energy delivery devices. Each string of energy delivery modules includes a string communication path accessible to each of the energy delivery modules, wherein the module monitor of each energy delivery module is operable to communicate information associated with its energy delivery module through the string communication path. Each string also includes a string manager device for communicating with each module monitor in the string, through the string communication path. The energy delivery system also includes a system controller for communicating with each string manager device through a system communication path.

Abstract: A high capacity, high charge rate lithium secondary cell includes a high capacity lithium-containing positive electrode in electronic contact with a positive electrode current collector, said current collector in electrical connection with an external circuit, a high capacity negative electrode in electronic contact with a negative electrode current collector, said current collector in electrical connection with an external circuit, a separator positioned between and in ionic contact with the cathode and the anode, and an electrolyte in ionic contact with the positive and negative electrodes, wherein the total area specific impedance for the cell and the relative area specific impedances for the positive and negative electrodes are such that, during charging at greater than or equal to 4C, the negative electrode potential is above the potential of metallic lithium.

Abstract: A compact, robust, multifunctional and highly manufacturable rechargeable battery cell is provided. The cell design dedicates minimal internal volume to inert components of the cell. This is accomplished, in part, by providing multiple functionalities to individual cell components.

Abstract: Nanoscale ion storage materials are provided that exhibit unique properties measurably distinct from their larger scale counterparts. For example, the nanoscale materials can exhibit increased electronic conductivity, improved electromechanical stability, increased rate of intercalation, and/or an extended range of solid solution. Useful nanoscale materials include alkaline transition metal phosphates, such as LiMPO4, where M is one or more transition metals. The nanoscale ion storage materials are useful for producing devices such as high energy and high power storage batteries, battery-capacitor hybrid devices, and high rate electrochromic devices.

Abstract: Electrodes for use in electrochemical devices are disclosed. More particularly coated electrode particles for use in solid electrochemical cells and materials and systems for improving electronic conductivity and repulsive force characteristics of an electrode network are disclosed. An article containing a plurality of distinct first particles that form an electrode network in which the distinct first particles are coated with a system of electrically conductive material is also disclosed. In some embodiments, the coating layer also includes a low refractive index material. In some embodiments, the coating layer of the electroactive material includes a plurality of second particles.

Abstract: An electrochemical storage device is described, and a method for making the same. In some aspects, a guidewire is co-wound with sheet or ribbon-like electrode materials so that contact is made between the guidewire and collector extensions of the electrode materials thereby forming an endcap with low impedance and high thermal sinking capabilities. In one embodiment, the storage device includes a negative electrode sheet have an edge which is substantially free of electrode active material, a positive electrode sheet have an edge which is substantially free of electrode active material, a first conductive guidewire disposed adjacent to the edge of the negative electrode sheet which is substantially free of electrode active material, and a second conductive guidewire disposed adjacent to the edge of the positive electrode sheet which is substantially free of electrode active material.

Abstract: Methods are provided for making bipolar electrochemical devices, such as batteries, using electrophoresis. A bipolar device is assembled by applying a field that creates a physical separation between two active electrode materials, without requiring insertion of a discrete separator film or electrolyte layer.

Abstract: Compositions and methods are provided for coating electroactive particles. Coating materials include a conductive component and a low refractive index component. Coatings are provided in which the conductive and low refractive index components are linked and/or do not form phases having lengthscales greater than about 0.25 ?m. Coatings are provided in which the components are contained in sequential layers.