Patents Assigned to Afton Chemical Corporation
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Patent number: 9663743Abstract: A lubricant composition, lubricant concentrate and method for reducing engine deposits. The composition and method include a base oil of lubricating viscosity; an organo-molybdenum compound; a deposition reducing amount of a reaction product of an alkyl-substituted dicarboxylic acid compound selected from the group consisting of alkyl-substituted dicarboxylic acids, alkyl-substituted dicarboxylic acid anhydrides, and mixtures thereof, and a basic salt of aminoguanidine, in an amount sufficient to provide a product rich in alkyl bis-3-amino-1,2,4-triazole; and optionally a phenate detergent. The lubricant composition and method provide engine deposits that are less than an amount of engine deposits in the absence of component (c) and/or optional component (d).Type: GrantFiled: June 10, 2009Date of Patent: May 30, 2017Assignee: AFTON CHEMICAL CORPORATIONInventors: Paul G. Griffin, Ian A. Bell, John T. Loper, William Y. Lam, Gregory H. Guinther
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Patent number: 9657252Abstract: A lubricant additive, method for reducing a boundary friction coefficient of a lubricant composition, and method for improving fuel economy. The additive includes a synergistic mixture of a) a metal-containing phosphorus antiwear compound derived from at least one secondary alcohol in an amount sufficient to provide the lubricant composition with from about 200 to about 1000 ppm by weight phosphorus, and b) a polyol derived from a diol and a mono-ol having a diol to mono-ol molar ratio ranging from about 0.3:1 to about 2.0:1, wherein the diol contains from 6 to 36 carbon atoms and the mono-ol contains from 12 to 16 carbon atoms. The polyol is present in the lubricant additive in an amount sufficient to provide a synergistic reduction in the boundary friction coefficient of the lubricant composition in combination with component (a).Type: GrantFiled: April 17, 2014Date of Patent: May 23, 2017Assignee: Afton Chemical CorporationInventors: Carl W. Bennett, Mark T. Devlin
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Publication number: 20170082019Abstract: A method of introducing additives to an air intake system of an engine in order to overcome one or more of the various problems created by formulation of additives in fuels. The method controls at least one of the amount, aerosol particle size and timing of introduction of additives based on information relevant to operation of the engine. The introduced additives form an air-additive mixture and are carried by the airflow in the air-intake system to the combustion chamber of the engine. Another aspect of the invention is an additive introduction system that includes one or more containers for additives, a control system for determining at least one of the amount, aerosol particle size and timing of introduction of the additives, and a device to introduce the additives into the air intake system under the control of the control system.Type: ApplicationFiled: September 29, 2016Publication date: March 23, 2017Applicant: Afton Chemical CorporationInventor: Gregory Guinther
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Patent number: 9587190Abstract: In order to blend fuels to meet specific regulatory and industry requirements, for instance octane requirements, different octane blending components can be used. One added component includes a composition of higher aromatics content. Unfortunately, this aromatic content may increase the particulate emissions of an internal combustion engine when the high aromatic fuel is combusted in that engine. As explained herein, reducing the aromatics content and replacing that octane increasing requirement with an alternative octane enhancer results in a formulated fuel that will have lower particulate emissions in the real-world driving of that engine as compared with a fuel having higher aromatic content.Type: GrantFiled: October 17, 2014Date of Patent: March 7, 2017Assignee: Afton Chemical CorporationInventors: Michael Wayne Meffert, John David Morris, Joseph W. Roos, Huifang Shao
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Patent number: 9574149Abstract: A fuel composition for a direct fuel injected diesel engine, a method for improving performance of fuel injectors and a method for cleaning fuel injectors for a diesel engine. The fuel composition includes a major amount of fuel and a minor, effective amount of a quaternary ammonium salt having a thermogravimetric analysis (TGA) weight loss of greater than 50 wt. % at 350° C. The amount of quaternary ammonium salt present in the fuel is sufficient to improve performance of the direct fuel injected diesel engine having combusted the composition compared to the performance of such engine having combusted a fuel composition that does not contain the quaternary ammonium salt.Type: GrantFiled: November 11, 2011Date of Patent: February 21, 2017Assignee: Afton Chemical CorporationInventors: Xinggao Fang, Julienne M. Galante-Fox
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Patent number: 9574156Abstract: A lubricant composition comprising lubricating oil and a compound containing phosphorus and an amine of formula I: wherein R1 is a hydrocarbon group and at least one of R1 is selected from: —(C1-C20)alkyl, —(C1-C20)alkenyl, —(C5-C20)cycloalkyl; R is selected from: —(C4-C20)alkyl, —(C4-C20)alkenyl, —(C5-C20)cycloalkyl; and wherein R2, R3 and R4 are independently selected from: —H, —(C6-C36)alkyl, —(C6-C36)alkenyl, —(C6-C36)cycloalkyl, wherein at least one of R2, R3 and R4 is not H; X is O or S; Y1 and Y2 are selected from S and O; m is 1 or 2, n is 0 or 1, p is 1 or 2, provided that m+n+p=3 and q=0.8 to 1.2*p, wherein the compound provides at least 48 ppm of phosphorus and a molar ratio phosphorus to nitrogen (P/N) in the range of about 0.40 to about 1.50.Type: GrantFiled: December 10, 2013Date of Patent: February 21, 2017Assignee: Afton Chemical CorporationInventors: Hong-Zhi Tang, Lee D. Saathoff
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Patent number: 9574158Abstract: A compression-ignited engine lubricant and a method for reducing engine wear. The lubricant including, (a) a base oil; (b) oleamide; (c) zinc dihydrocarbyl dithiophosphate; and (d) a functionalized dispersant. The functionalized dispersant is made by reacting together (i) a hydrocarbyl-dicarboxylic acid or anhydride, (ii) a polyamine, (iii) a dicarboxyl-containing fused aromatic compound or anhydride thereof, and optionally, (iv) a non-aromatic dicarboxylic acid or anhydride, wherein the hydrocarbyl group of the hydrocarbyl-dicarboxylic acid or anhydride has a number average molecular weight of greater than 1800 Daltons as determined by gel permeation chromatography.Type: GrantFiled: May 1, 2015Date of Patent: February 21, 2017Assignee: Afton Chemical CorporationInventors: Jason A. Lagona, John T. Loper
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Patent number: 9574150Abstract: A fuel additive composition, fuel comprising said additive, and methods of use thereof are provided. The fuel additive composition comprises a synergistic combination of a hydrocarbyl-substituted succinimide dispersant and a compound of the following formula: and tautomers and enantiomers thereof, wherein R3 is a hydrocarbyl group having a number average molecular weight ranging from about 100 to about 5000, and wherein the weight ratio of (a) to (b) ranges from about 5:1 to about 1:5. The fuel additive composition is present in fuel in an amount sufficient to improve the conductivity properties of the fuel.Type: GrantFiled: January 18, 2013Date of Patent: February 21, 2017Assignee: Afton Chemical CorporationInventors: Joshua J. Bennett, John Donner, Duncan Richardson
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Patent number: 9562498Abstract: There is disclosed a biodegradable fuel additive composition derived from at least one animal or plant source, and a fuel composition containing a biodegradable fuel additive composition derived from at least one animal or plant source useful for reducing the formation of engine deposits and for improving fuel economy of a vehicle combusting the fuel composition.Type: GrantFiled: June 6, 2014Date of Patent: February 7, 2017Assignee: Afton Chemical CorporationInventor: Lawrence J. Cunningham
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Patent number: 9550955Abstract: A lubricating oil comprises a major amount of a base oil and a minor amount of an additive package, and the additive package comprises at least one friction modifier of formula I: where R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 22 carbon atoms or R is represented by: and R1 is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 22 carbon atoms and R2 is hydrogen or a hydrocarbyl having about 1 to about 2 carbon atoms. Methods of using the lubricating oil to improve thin film and/or boundary layer friction in an engine are also disclosed.Type: GrantFiled: December 21, 2012Date of Patent: January 24, 2017Assignee: Afton Chemical CorporationInventors: John T. Loper, Jeremy P. Styer
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Publication number: 20170015926Abstract: A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition includes greater than 50 wt. % of a base oil, an overbased detergent having a TBN greater than 225 mg KOH/g and a low-based/neutral detergent having a TBN up to 175 mg KOH/g. A total amount of calcium from the overbased and low-based/neutral detergent is greater than 1100 ppm to less than 2400 ppm by weight based on a total weight of the lubricating oil composition. The lubricating oil composition and method may be effective to reduce low-speed pre-ignition events in a boosted internal combustion engine lubricated with the lubricating oil composition relative to commercially available lubricating oil compositions.Type: ApplicationFiled: May 5, 2016Publication date: January 19, 2017Applicant: Afton Chemical CorporationInventors: Kristin Fletcher, William Y. Lam, Kongsheng Yang, Jeremy Styer
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Publication number: 20170015930Abstract: A lubricating oil composition and method of for providing an acceptable number of low-speed pre-ignition events in a boosted internal combustion engine using the lubricating oil composition. The lubricating oil composition includes greater than 50 wt. % of a base oil of lubricating viscosity, and an additive composition that includes an overbased calcium-containing detergent having a TBN greater than 225 mg KOH/g, and one or more zinc dialkyl dithiophosphate compounds are derived from a molar ratio of secondary alcohol to primary alcohol of 20:100 to about 100:0 and have an average total carbon content of greater than 10 carbon atoms per mole of phosphorous. The lubricating oil compositions contains the overbased calcium-containing detergent in an amount to provide greater than 900 ppm to less than 2400 ppm by weight calcium, and at least 0.01 wt. % of the zinc dialkyl dithiophosphate, both amounts based on the total weight of the lubricating oil composition.Type: ApplicationFiled: May 5, 2016Publication date: January 19, 2017Applicant: Afton Chemical CorporationInventors: Kristin Fletcher, William Y. Lam, Kongsheng Yang, Jeremy Styer
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Publication number: 20170015928Abstract: A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition includes a major amount of a base oil, one or more overbased calcium-containing detergents having a total base number of greater than 225 mg KOH/gram, to provide greater than 900 ppm by weight to less than 2400 ppm by weight of calcium to the lubricating oil composition, and a low speed pre-ignition reducing amount of one or more titanium-containing compounds to provide from 10 ppm to 3000 ppm titanium and/or one or more tungsten-containing compounds to provide from 125 ppm to 3000 ppm tungsten, all based on the total weight of the lubricating composition. The low speed pre-ignition events in the boosted internal combustion engine may be reduced relative to a number of low speed pre-ignition events in the same engine lubricated with the same lubricating oil without the titanium- and/or tungsten-containing additive.Type: ApplicationFiled: May 5, 2016Publication date: January 19, 2017Applicant: Afton Chemical CorporationInventors: Kristin Fletcher, William Y. Lam, Kongsheng Yang, Jeremy Styer
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Publication number: 20170015927Abstract: A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition includes greater than 50 wt. % of a base oil, one or more overbased calcium-containing detergents having a TBN greater than 225 mg KOH/g and one or more magnesium-containing detergents. A total amount of calcium from the one or more overbased calcium-containing detergents is from 900 ppm to less than 2400 ppm by weight, and a total amount of magnesium from the one or more magnesium-containing detergents is from 50 ppm to 500 ppm by weight, both based on a total weight of the lubricating oil composition. The lubricating oil composition and the method of using it are effective to reduce low speed pre-ignition events in a boosted internal combustion engine lubricated with the lubricating oil composition.Type: ApplicationFiled: May 5, 2016Publication date: January 19, 2017Applicant: Afton Chemical CorporationInventors: Kristin Fletcher, William Y. Lam, Kongsheng Yang, Jeremy Styer
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Publication number: 20170015929Abstract: A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition has not more than 150 ppm sodium and includes a major amount of a base oil and an additive composition that includes one or more overbased calcium-containing detergents having a total base number of greater than 225 mg KOH/gram, in an amount sufficient to provide greater than 1100 ppm by weight to less than 2400 ppm by weight of calcium to the lubricating oil composition, and one or more molybdenum-containing compounds in an amount sufficient to provide at least about 80 ppm by weight molybdenum to the lubricating oil composition, all based on the total weight of the lubricating composition. The oil and method may reduce low-speed pre-ignition events in the boosted internal combustion engine relative to a number of low-speed pre-ignition events in the same engine lubricated with a reference lubricating oil.Type: ApplicationFiled: May 5, 2016Publication date: January 19, 2017Applicant: Afton Chemical CorporationInventors: Kristin Fletcher, William Y. Lam, Kongsheng Yang, Jeremy Styer
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Publication number: 20170009175Abstract: The present invention generally relates, in certain aspects, to corrosion inhibiting compositions useful for metalworking fluids, as well as concentrates, additives and metalworking fluids containing such compositions. The invention furthermore relates, in some aspects, to the use of such compositions for providing to a metalworking fluid one or more of anticorrosion performance, antifoam performance, antiwear performance, load carrying capacity, long fluid life, biological stability, lubricity, hard water tolerance, formulation stability.Type: ApplicationFiled: July 6, 2015Publication date: January 12, 2017Applicant: Afton Chemical CorporationInventors: Steven Anderson, Carl Williams
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Patent number: 9523057Abstract: A diesel fuel additive package, diesel fuel containing the additive and methods for operating an engine on the diesel fuel and additive. The fuel additive includes a reaction product of (a) a hydrocarbyl substituted dicarboxylic acid or anhydride, and (b) an amine compound or salt thereof of the formula wherein R is selected from hydrogen and a hydrocarbyl group containing from about 1 to about 15 carbon atoms, and R1 is selected from hydrogen and a hydrocarbyl group containing from about 1 to about 20 carbon atoms. The reaction product contains at least one amino triazole group. Component (2) of the additive is a hydrocarbyl succinimide dispersant. The additive also includes (3) a C2 to C10 alkyl alcohol; and (4) optionally, a lubricity additive. In the additive, a weight ratio of component (1) to component (2) in the fuel ranges from about 1:3 to about 1:5.Type: GrantFiled: February 22, 2011Date of Patent: December 20, 2016Assignee: Afton Chemical CorporationInventors: James Wager, David P. Cleaver, Matthew H. Lindner, Julienne M. Galante-Fox, Scott D. Schwab, John Bennett
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Patent number: 9518242Abstract: The invention relates to thiophosphates and derivatives thereof useful as antiwear additive components, lubricant additive compositions and lubricant compositions each comprising such compounds, methods for making and using the same, including methods of lubricating machines and machine parts and methods of extending the useful life of elastomeric seal components of such machines. In one aspect, the invention relates to a lubricant additive composition comprising a compound of formula (I): or a tribologically acceptable salt thereof, and a sulfonate or a phenate detergent.Type: GrantFiled: May 24, 2016Date of Patent: December 13, 2016Assignee: Afton Chemical CorporationInventors: David Edwards, Kristine Durbin, Robert E. McCovick
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Patent number: 9499763Abstract: A lubricating oil comprising a major amount of base oil and a minor amount of an additive package, wherein the additive package comprises: (A) a friction modifier component selected from: (a) one or more a reaction products of an alcohol with a compound of the formula IV: and (b) one or more compounds of the Formulae II-III: wherein R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 22 carbon atoms, R2 and R3 are independently selected from hydrogen C1-C18 hydrocarbyl groups, and C1-C18 hydrocarbyl groups containing one or more heteroatoms; X is an alkali metal, alkaline earth metal or ammonium cation and n is the valence of cation X, and reaction products of amines, amino alcohols, alkali or alkaline earth metal hydroxides, alkali or alkaline earth metal oxides and mixtures thereof with compounds of the Formula IV: Where R is as defined above; and (B) at least one friction modifier that is different from the one orType: GrantFiled: December 21, 2012Date of Patent: November 22, 2016Assignee: Afton Chemical CorporationInventors: John T. Loper, Jeremy P. Styer
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Patent number: 9499761Abstract: A lubricating composition comprising a major amount of base oil and a minor amount of an additive package, wherein the additive package comprises: (A) a friction modifier component selected from: (a) one or more a reaction products of an alcohol with a compound of the formula IV: and (b) one or more compounds of the Formulae II-III: wherein R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 22 carbon atoms; R2 and R3 are independently selected from hydrogen, C1-C18 hydrocarbyl groups, and C1-C18 hydrocarbyl groups containing one or more heteroatoms; and X is an alkali metal, alkaline earth metal, or ammonium cation and n is the valence of cation X; and (B) at least one metal dialkyl dithio phosphate salt.Type: GrantFiled: December 21, 2012Date of Patent: November 22, 2016Assignee: Afton Chemical CorporationInventors: John T. Loper, Jeremy P. Styer