Patents Assigned to Afton Chemical Corporation
  • Patent number: 10584297
    Abstract: Ethylene-C3-C10 alpha olefin copolymers, dispersants and lubricating oils/fuel compositions incorporating dispersants, and related methods are generally described herein. The copolymer may comprise ethylene-derived units and C3-C10 alpha-olefin-derived units. The C3-C10 alpha-olefin-derived units may have a carbon number from three to ten. For example, the C3-C10 alpha-olefin-derived units may be propylene-derived units.
    Type: Grant
    Filed: December 13, 2016
    Date of Patent: March 10, 2020
    Assignee: AFTON Chemical Corporation
    Inventors: Nathaniel Cain, John T. Loper, Lawrence Cunningham, Joseph W. Roos
  • Publication number: 20200072112
    Abstract: Particulate filters are used to remove particulate matter such as soot and ash in the emissions control systems of vehicles, including gasoline direct injection (GDI) engines. Methods are provided to predict the long-term performance and durability of emissions control systems having particulate filters. The methods account for factors such as thermal aging, soot accumulation and regeneration, and ash loading.
    Type: Application
    Filed: September 4, 2018
    Publication date: March 5, 2020
    Applicant: Afton Chemical Corporation
    Inventors: Huifang Shao, Joseph W. Roos, Joseph E. Remias
  • Publication number: 20200072102
    Abstract: Gasoline Direct Injection (GDI) engines require gasoline particulate filters (GPFs) as a key component of the emissions control system to reduce particulate emissions. GPFs are known to have poor initial performance, with performance increasing after the filter develops a cake. This poor initial performance make it impossible to accurately assess vehicle emissions performance at the mileage requirements for vehicle certification. Compositions and methods are disclosed to improve filtration efficiency in a fresh or low mileage GPF.
    Type: Application
    Filed: September 4, 2018
    Publication date: March 5, 2020
    Applicant: Afton Chemical Corporation
    Inventors: Huifang Shao, Joseph W. Roos, Joseph E. Remias
  • Patent number: 10563146
    Abstract: In accordance with the disclosure, one aspect of the present application is directed to a lubricant additive composition. The lubricant additive composition includes a component or mixture of components selected from (a) an aminoalkylphosphonic acid dialkyl ester; (b) a cyclized product of an aminoalkylphosphonic acid dialkyl ester; and a mixture of (a) and (b). Preparation and use of the additive composition in a lubricant for antiwear and/or friction reduction are also disclosed.
    Type: Grant
    Filed: September 7, 2012
    Date of Patent: February 18, 2020
    Assignee: Afton Chemical Corporation
    Inventors: Helen T. Ryan, Bevin W. Parks-Lee, Jeffrey J. Soden, Stuart Wickson
  • Patent number: 10550349
    Abstract: A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition includes a major amount of a base oil, one or more overbased calcium-containing detergents having a total base number of greater than 225 mg KOH/gram, to provide greater than 900 ppm by weight to less than 2400 ppm by weight of calcium to the lubricating oil composition, and a low speed pre-ignition reducing amount of one or more titanium-containing compounds to provide from 10 ppm to 3000 ppm titanium and/or one or more tungsten-containing compounds to provide from 125 ppm to 3000 ppm tungsten, all based on the total weight of the lubricating composition. The low speed pre-ignition events in the boosted internal combustion engine may be reduced relative to a number of low speed pre-ignition events in the same engine lubricated with the same lubricating oil without the titanium- and/or tungsten-containing additive.
    Type: Grant
    Filed: May 5, 2016
    Date of Patent: February 4, 2020
    Assignee: AFTON CHEMICAL CORPORATION
    Inventors: Kristin Fletcher, William Y. Lam, Kongsheng Yang, Jeremy Styer
  • Patent number: 10550350
    Abstract: The present invention generally relates to compositions for use in lubricating oils. In certain aspects, the present invention is generally directed to boroxine compounds having alkyl groups where one or more of the alkyl groups contains at least 8 carbon atoms. Such compounds may present improved hydrolytic stability, compared to other boroxine compounds. Such boroxine compounds may be used, for example, to improve seal compatibility in an engine. Other aspects of the invention are generally directed to systems and methods for making such boroxine compounds, engine oils containing such boroxine compounds, methods of using such boroxine compounds, or the like.
    Type: Grant
    Filed: November 10, 2016
    Date of Patent: February 4, 2020
    Assignee: AFTON CHEMICAL CORPORATION
    Inventors: Jason Richard Bell, Carl W. Bennett
  • Publication number: 20200024542
    Abstract: A lubricating oil composition having greater than 50 wt % of a base oil and 0.1 wt % to 20 wt %, both based on the total weight of the lubricating oil composition, of a dispersant viscosity modifier obtainable by: A) reacting: a) at least one of a lactone of formula (I) or a derivative thereof: wherein X is oxygen, and R is an optionally substituted hydrocarbylene group having from 1 to 20 carbon atoms; and b) at least one compound selected from amines, alcohols and oxazolines; and B) reacting the reaction product of step A) onto an acylated olefin copolymer obtainable by acylating a copolymer of ethylene and one or more C3-C10 alpha-olefins having a number average molecular weight of 5,000 to 200,000 g/mol as measured by GPC, with an acylating agent. Methods employing the lubricating oil compositions and uses of the lubricating compositions as engine oils are also described.
    Type: Application
    Filed: July 18, 2018
    Publication date: January 23, 2020
    Applicant: Afton Chemical Corporation
    Inventors: Arturo Carranza, Sheng Jiang
  • Patent number: 10513668
    Abstract: An engine oil composition including greater than 50 wt. % of a base oil of lubricating viscosity selected from a Group III, a Group IV or a Group V base oil, and mixtures thereof, 0.1-10 wt. % of a dispersant viscosity index improver that a reaction product of an olefin copolymer, an acylating agent and a polyamine, one or more calcium-containing detergents that provide from about 900 ppmw to about 2500 ppmw of calcium to the engine oil composition, and one or more molybdenum-containing compounds. The engine oil composition has an SAE viscosity grade of 0W-X or 5W-X, wherein X=16, 20, 30, or 40; from about 500 ppmw to about 1000 ppmw of phosphorus; and a total sulfated ash content of no greater than 1.2 wt. %, as measured by ASTM D874. Methods of using the engine oil composition to lubricate or operate an engine are also described.
    Type: Grant
    Filed: October 25, 2017
    Date of Patent: December 24, 2019
    Assignee: AFTON CHEMICAL CORPORATION
    Inventors: Paul Ransom, Guillaume Carpentier
  • Publication number: 20190367835
    Abstract: A lubricant composition having greater than 50 percent by weight of a base oil, a dispersant composition comprising: i) a first dispersant comprising one or more reaction products of at least one polyisobutenyl succinic acid or anhydride having a polyisobutenyl group with a number average molecular weight that is less than or equal to 1300, and at least one polyamine; and ii) a second dispersant comprising one or more reaction products of at least one polyisobutenyl succinic acid or anhydride having a polyisobutenyl group with a number average molecular weight greater than 1300, and at least one polyamine; and at least one ashless antioxidant; and wherein a weight ratio of the second dispersant to the dispersant composition is 0.66:1 to 1:1 or a ratio of the weight percentages of nitrogen contributed by the second dispersant to nitrogen of the dispersant composition is 0.62:1 to 1:1.
    Type: Application
    Filed: June 5, 2018
    Publication date: December 5, 2019
    Applicant: Afton Chemical Corporation
    Inventor: Paul Ransom
  • Patent number: 10494583
    Abstract: Lubricant compositions including an additive composition and methods for its use in engines that produce soot. The lubricant composition contains a base oil and an additive composition having (a) at least 0.05 percent by weight of a first dispersant that is a reaction product of A) a hydrocarbyl-dicarboxylic acid or anhydride, and B) at least one polyamine; and (b) at least 0.05 percent by weight, both based on a total weight of the lubricant composition, of a second dispersant that is a reaction product of A?) a hydrocarbyl-dicarboxylic acid or anhydride, and B?) at least one polyamine, wherein the reaction product is post-treated with C) an aromatic carboxylic acid, an aromatic polycarboxylic acid, or an aromatic anhydride wherein all carboxylic acid or anhydride groups are attached directly to an aromatic ring, and/or D) a non-aromatic dicarboxylic acid or anhydride having a number average molecular weight of less than about 500.
    Type: Grant
    Filed: December 11, 2018
    Date of Patent: December 3, 2019
    Assignee: AFTON CHEMICAL CORPORATION
    Inventors: Diane Campbell, Jason Lagona
  • Patent number: 10479953
    Abstract: The present disclosure relates to emulsifying agents produced from succinic acids or anhydrides and polyalkylene glycols. The present disclosure also relates to lubricating oils containing such emulsifying agents. The emulsifying agent provides a lubricating oil that is substantially free of an aqueous layer after about 24 hours when tested according to ASTM D7563-10.
    Type: Grant
    Filed: January 12, 2018
    Date of Patent: November 19, 2019
    Assignee: AFTON CHEMICAL CORPORATION
    Inventors: Andrew Yeung, Anthony Jarvis, Matthew Ross
  • Publication number: 20190330554
    Abstract: A viscosity index improver comprising a reaction product of (i) an acylated copolymer obtainable by acylating a copolymer of ethylene and one or more C3-C10 alpha-olefins having an Mn of 3,000 to 250,000 g/mol; and (ii) a compound of the formulae (I)-(V): wherein R1, R6, R8, R9, R10, R12 and R15 are independently selected from a hydrogen and an optionally substituted linear or branched alkyl or alkenyl group, and R2, R3, R4, and R5 R7, R11, R13, R14, R16, and R17 are independent selected from an optionally substituted linear or branched alkyl or alkenyl group, and a sum of the number of carbon atoms in each compound of the formulae (I)-(V) is from 6 to 31.
    Type: Application
    Filed: April 25, 2018
    Publication date: October 31, 2019
    Applicant: Afton Chemical Corporation
    Inventors: Sheng Jiang, Arturo Carranza
  • Publication number: 20190330555
    Abstract: A lubricating oil composition including greater than 50 wt. % of a base oil, from 100 ppm to less than 1800 ppm by weight of total metal from metal-containing detergent(s) including an overbased calcium detergent and a magnesium containing detergent. The composition has a total nitrogen of 900 ppm to less than 1600 ppm by weight, and a ratio of total metal from the detergent(s) in ppm to the total nitrogen in ppm of less than 1.9. The composition also includes a borated compound to provide greater than 50 ppm by weight to 1000 ppm by weight of boron, and a ppm ratio of metal from the detergent(s) in ppm to the total boron is less than 7.5 and a molybdenum compound to provide greater than 80 ppm to 1200 ppm by weight molybdenum and a ppm ratio of total metal from the detergent(s) to the molybdenum is less than 23.8.
    Type: Application
    Filed: July 12, 2019
    Publication date: October 31, 2019
    Applicant: Afton Chemical Corporation
    Inventors: Kongsheng Yang, Kristin Fletcher, William Y. Lam, Jeremy Styer
  • Patent number: 10457884
    Abstract: A detergent additive package, fuel additive concentrate, fuel composition and method for operating an engine on an unleaded gasoline fuel. The additive package includes a Mannich base detergent mixture, wherein the mixture contains a first Mannich base detergent component derived from a di- or polyamine and a second Mannich base detergent component derived from a monoamine. A weight ratio of the first Mannich base detergent to the second Mannich base detergent in the mixture ranges from about 1:6 to about 3:1.
    Type: Grant
    Filed: November 6, 2014
    Date of Patent: October 29, 2019
    Assignee: Afton Chemical Corporation
    Inventors: Joseph M. Russo, William Jay Colucci
  • Patent number: 10443558
    Abstract: A lubricating oil composition and method of operating a boosted internal combustion engine with reduced low-speed pre-ignition events and corrosion resistance. The oil composition includes a base oil, one or more overbased calcium sulfonate detergents, one or more overbased calcium phenate detergents, and one or more overbased magnesium-containing detergents. A ratio of ppm of calcium to TBN of the oil composition is less than 170; a ratio of ppm of magnesium to total soap content in wt. % is greater than 700; and there are limited amounts of boron and molybdenum, and all weight percentages and ppm values being based on the total weight of the oil composition. The compositions give low LSPI ratios and pass the Ball Rust test.
    Type: Grant
    Filed: January 18, 2017
    Date of Patent: October 15, 2019
    Assignee: AFTON CHEMICAL CORPORATION
    Inventors: Paul Ransom, Guillaume Carpentier, Kristin Fletcher
  • Patent number: 10443011
    Abstract: A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil includes greater than 50 wt. % of a base oil, one or more overbased calcium-containing detergents, one or more overbased magnesium-containing detergents and one or more molybdenum compounds and leads to a more than 60% reduction in LSPI compared to the LSPI of a reference oil and passes the Ball Rust Test. The ratio of wt % calcium from the overbased detergents to wt. % of magnesium from the overbased detergents is less than 11.9. A ratio of total ppm of magnesium to total TBN of the lubricating oil in mg KOH/g is greater than 19. A ratio of the total ppm of calcium to the total TBN of the lubricating oil is less than 222. The oil and method may reduce low-speed pre-ignition events in a boosted internal combustion relative to commercially available lubricating oils.
    Type: Grant
    Filed: January 18, 2017
    Date of Patent: October 15, 2019
    Assignee: AFTON CHEMICAL CORPORATION
    Inventors: Kristin Fletcher, Lisa Dingwell
  • Patent number: 10421922
    Abstract: A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition includes greater than 50 wt. % of a base oil, one or more overbased calcium-containing detergents having a TBN greater than 225 mg KOH/g and one or more magnesium-containing detergents. A total amount of calcium from the one or more overbased calcium-containing detergents is from 900 ppm to less than 2400 ppm by weight, and a total amount of magnesium from the one or more magnesium-containing detergents is from 50 ppm to 500 ppm by weight, both based on a total weight of the lubricating oil composition. The lubricating oil composition and the method of using it are effective to reduce low speed pre-ignition events in a boosted internal combustion engine lubricated with the lubricating oil composition.
    Type: Grant
    Filed: May 5, 2016
    Date of Patent: September 24, 2019
    Assignee: AFTON CHEMICAL CORPORATION
    Inventors: Kristin Fletcher, William Y. Lam, Kongsheng Yang, Jeremy Styer
  • Publication number: 20190284496
    Abstract: A lubricating oil composition including greater than 50 wt. % of a base oil; a reaction product of a hydrocarbyl acid phosphate and a nitrogen containing compound; and an oil soluble hydrocarbyl borate. A method for reducing gear scuffing in a transmission including a step of lubricating the transmission with the above-mentioned lubricating oil composition and a method of operating a transmission including steps of lubricating said transmission with the lubricating oil composition described above and operating the transmission, are also described.
    Type: Application
    Filed: March 16, 2018
    Publication date: September 19, 2019
    Applicant: Afton Chemical Corporation
    Inventor: Xinggao Fang
  • Patent number: 10414784
    Abstract: The present invention relates to novel aminobisphosphonate compounds useful as antiwear and/or friction modifier additive components, lubricant additive compositions and lubricant compositions each comprising such compounds, and methods for making and using the same.
    Type: Grant
    Filed: August 20, 2018
    Date of Patent: September 17, 2019
    Assignee: Afton Chemical Corporation
    Inventors: John Marshall Baker, Guillaume Carpentier
  • Patent number: 10407636
    Abstract: A fuel composition, a lubricant composition, and methods for reducing friction or wear of moving parts. The fuel composition includes gasoline and from about 10 to about 500 ppm by weight of a dialkylaminoalkanol of the formula R1(R2)NCH2CH(R3)R4. The lubricant composition includes base oil of lubricating viscosity and from about 0.05 to about 5.0 weight percent of a dialkylaminoalkanol of the formula R1(R2)NCH2CH(R3)R4. In the above formulas wherein R1 is an alkyl group or a hydroxy alkyl group containing from 8 to 50 carbon atoms; R2 is an alkyl group containing from 1 to 4 carbon atoms; R3 is selected from H and OH; and R4 is selected from H, an alkyl group containing from 1 to 4 carbon atoms, and CH2OH and wherein at least one of R3 and R4 contains a hydroxyl group and provided that when R1 is a hydroxyalkyl group, R3 is OH and R4 is CH2OH.
    Type: Grant
    Filed: January 4, 2018
    Date of Patent: September 10, 2019
    Assignee: Afton Chemical Corporation
    Inventors: Scott Culley, Xinggao Fang, Scott D. Schwab