Patents Assigned to Akzo Nobel N.V.
  • Publication number: 20110065812
    Abstract: A process for producing an aqueous silica-based sol is disclosed wherein a cationic ion exchange resin having part of its ion exchange capacity in hydrogen form is contacted with an aqueous alkali metal silicate to form a slurry having a pH from 5.0 to 11.5 and/or having particle aggregation or microgel formation corresponding to a S value up to 45%; adjusting the pH using a material comprising an aluminum compound; and separating the resin from the slurry. Silica-based sols having an S value from 15 to 25%, mole ratio Si:Al from 20:1 to 50:1, mole ratio Si:X, where X=alkali metal, from 5:1 to 17:1, SiO2 content of at least 5% by weight and containing silica-based particles having a specific surface area of at least 300 m2/g, as well as the use of such silica-based sols in producing paper are disclosed.
    Type: Application
    Filed: November 15, 2010
    Publication date: March 17, 2011
    Applicant: AKZO NOBEL N.V.
    Inventors: Johan NYANDER, Glenn MANKIN
  • Publication number: 20110054192
    Abstract: The present invention pertains to a process for the preparation of an alkenyl-substituted cyclic anhydride compound comprising the steps of subjecting one or more olefinically unsaturated C6-C28 hydrocarbons of which at least 30% by weight is alpha-olefin to a double bond isomerization step by contacting them with a catalyst comprising an alkali metal on a carrier, and reacting the resulting isomehzed olefinic C6-C28 hydrocarbons with a cyclic anhydride of an unsaturated dicarboxylic acid to form the alkenyl-substituted cyclic anhydride compound. Furthermore, it pertains to the thus obtained alkenyl-substituted cyclic anhydride and to its use as a paper additive.
    Type: Application
    Filed: April 24, 2009
    Publication date: March 3, 2011
    Applicant: AKZO NOBEL N.V.
    Inventors: Aaldert Johannes De Jong, Martin Werner, Oliver Struck
  • Patent number: 7897704
    Abstract: A protective crosslinkable coating composition comprising modified epoxy resin and crosslinker the modified epoxy resin being the reaction product, by weight, of i) from 80 to 99.9 parts of di-epoxy resin of epoxy equivalent weight from 500 to 5000 and formed from the reaction of bis phenol A diglycidyl ether and bis phenol A and ii) from 0.1 to 20 parts of reactive material characterised in that a) the di-epoxy resin contains minor amounts of resin components of molecular weight less than 1000 Daltons, and the reactive material comprises b) mono-functional organic material of molecular weight at: least 100 Daltons having one moiety capable of reacting with the epoxy moieties of the di-epoxy resin and c) dicarboxylic acid of molecular weight less than 300 Daltons having two moieties capable of reacting with the epoxy moieties of the di-epoxy resin.
    Type: Grant
    Filed: March 21, 2005
    Date of Patent: March 1, 2011
    Assignee: Akzo Nobel N.V.
    Inventors: Andre Masselin, Tung-Fai Lo, Pascal Helias, Francis Couaillet
  • Publication number: 20110046328
    Abstract: The invention pertains to a process wherein initiators having a half-life from 0.0001 hour to 0.05 hour at the polymerization temperature are dosed to a polymerization mixture. The dosing of such initiator allows improved control of the polymerization rate and faster polymerization rates, and the process will render a polymer with very low residual initiator levels.
    Type: Application
    Filed: October 25, 2010
    Publication date: February 24, 2011
    Applicant: AKZO NOBEL N.V.
    Inventors: Hans WESTMIJZE, Andreas Petrus Van Swieten, Lambertus Meulenbrugge, Koen Antoon Kornelis Vanduffel
  • Publication number: 20110045313
    Abstract: A paper coating composition is provided, comprising a polyvinyl alcohol graft copolymer comprising at least one side-chain polymer, formed from at least one carboxylic acid containing monomer, grafted onto a polyvinyl alcohol; and a further component selected from the group consisting of binders, thickeners and combinations thereof. The graft copolymer unexpectedly provides superior viscosification and water retention compared to results using a blend of the PVOH and carboxylated polymer where the two polymers were formed in the absence of one another.
    Type: Application
    Filed: April 28, 2009
    Publication date: February 24, 2011
    Applicant: AKZO NOBEL N.V.
    Inventors: Chistopher G. Gore, Milagros C. Barron
  • Publication number: 20110046025
    Abstract: Low molecular weight graft copolymer comprising a synthetic component formed from at least one or more olefinically unsaturated carboxylic acid monomers or salts thereof, and a natural component formed from a hydroxyl-containing natural moiety. The number average molecular weight of the graft copolymer is about 100,000 or less, and the weight percent of the natural component in the graft copolymer is about 50 wt % or greater based on total weight of the graft copolymer. Processes for preparing such graft copolymers are also disclosed.
    Type: Application
    Filed: September 23, 2010
    Publication date: February 24, 2011
    Applicant: Akzo Nobel N.V.
    Inventors: Klin A. Rodrgues, Jannifer Sanders
  • Patent number: 7893114
    Abstract: The invention relates to a process for producing aqueous silica-based sols which comprises providing a cationic ion exchange resin having at least part of its ion exchange capacity in hydrogen form; bringing said ion exchange resin in contact with an aqueous alkali metal silicate to form an aqueous slurry; adjusting the pH of the aqueous slurry and separating the ion exchange resin from the aqueous slurry, as well as the silica-based sols obtained by the process; the invention also relates to silica-based sols obtained by the process, as well as a process for producing paper which comprises providing an aqueous suspension comprising cellulosic fibres; adding to the suspension one or more drainage and retention aids comprising a silica-based sol according to the invention; and dewatering the obtained suspension to provide a sheet or web of paper.
    Type: Grant
    Filed: June 2, 2010
    Date of Patent: February 22, 2011
    Assignee: Akzo Nobel N.V.
    Inventors: Glenn Mankin, Marek Tokarz, Freddie Hansson
  • Patent number: 7892398
    Abstract: The invention relates to an aqueous dispersion of cellulose-reactive sizing agent containing an acid anhydride, an anionic polyelectrolyte and a nitrogen-containing organic compound which is an amine or quaternary ammonium thereof having a molecular weight less than 180 and/or having one or more hydroxyl groups. The invention further relates to a process for the production of paper which comprises adding the aqueous dispersion of cellulose-reactive sizing agent to an aqueous cellulosic suspension.
    Type: Grant
    Filed: December 13, 2006
    Date of Patent: February 22, 2011
    Assignee: Akzo Nobel N.V.
    Inventors: Hans Johansson-Vestin, Jonas Liesén, Marie Turunen, Jan Emanuelsson
  • Publication number: 20110039984
    Abstract: The present invention pertains to a rheological additive to replace casein in minerally setting building material compounds, characterized in that the rheological additive contains at least two different dispersing agents and at least one stabilizer, or at least one dispersing agent and at least two different stabilizers, wherein said at least one dispersing agent is or said at least two dispersing agents are selected from the group of lignin sulfonate, polycarboxylate, polycarboxylate ether, melamine formaldehyde sulfonate, alkylphenol glycol ether and/or naphthaline sulfonates, and said at least one stabilizer is or said at least two stabilizers are selected from the group of modified or unmodified, fully or partially hydrolyzed polyvinyl alcohol, polyvinyl acetal, polyvinyl pyrrolidone, polyalkylene glycol, polyalkylene oxide, agar-agar, carob seed grain, pectin, poly(meth)acrylate and/or (meth)acrylate thickeners, poly(meth)acrylamides, polyurethanes, associative thickeners, gelatine and/or soy protein.
    Type: Application
    Filed: April 10, 2009
    Publication date: February 17, 2011
    Applicant: AKZO NOBEL N.V.
    Inventors: Erwin Bühler, Hanspeter Waser
  • Publication number: 20110040085
    Abstract: The invention relates to a dry or slurry process to prepare phosphate-crosslinked cellulose ethers from a cellulose starting material comprising the steps of adding an alkalizing agent to the cellulose starting material to achieve mercerization, adding an ethehfying agent to the reaction mixture to achieve etherification of the cellulose, and adding a crosslinking agent to the reaction mixture to achieve crosslinking of the cellulose, wherein at least part of the alkalizing agent is added to the cellulose starting material before the etherification and/or crosslinking reactions take place to obtain alkalized cellulose; the crosslinking agent and the etherifying agent are added one after the other in random order or simultaneously; the crosslinking agent is an alkali metal thmetaphosphate; and the crosslinking and etherification steps are performed at an elevated temperature.
    Type: Application
    Filed: April 10, 2009
    Publication date: February 17, 2011
    Applicant: AKZO NOBEL N.V.
    Inventor: Paulus Pieter De Wit
  • Publication number: 20110028371
    Abstract: Hybrid copolymers include a synthetic polymer which is derived from at least one anionic or non-anionic ethylenically unsaturated monomer and a naturally derived hydroxyl containing chain transfer agent as an end group. The hybrid copolymer may be prepared as a blend with a builder or a chelating agent. Hybrid copolymers also include a synthetic portion derived from at least one ester monomer and a naturally derived hydroxyl containing chain transfer agent as an end group. Ester graft copolymers include a naturally derived hydroxyl moiety backbone and side chains derived from at least one ester monomer. Further, a method of determining the concentration of a hybrid copolymer in an aqueous system and methods of preparing a hybrid copolymer are also included.
    Type: Application
    Filed: July 31, 2009
    Publication date: February 3, 2011
    Applicant: AKZO NOBEL N.V.
    Inventors: Klin A. RODRIGUES, Allen M. Carrier, Jannifer Sanders
  • Patent number: 7875359
    Abstract: A self-stabilizing dispersion composition having a copolymer having at least one polymerizable acid-containing moiety, wherein the at least one acid-containing moiety is at least partially neutralized before or during polymerization, and at least one hydrophobic moiety. A process for producing such compositions is also provided, as well as a process for encapsulating water-insoluble actives in such copolymers.
    Type: Grant
    Filed: January 13, 2005
    Date of Patent: January 25, 2011
    Assignee: Akzo Nobel N.V.
    Inventors: Klein A. Rodrigues, Darin K. Griffith
  • Publication number: 20110009543
    Abstract: A glass adhesion composition containing a copolymer having an acid and a substituted amide, silanol, or amine oxide functionality. The substituted amide, silanol, or amine oxide functionality provide excellent adhesion of the copolymer to glass, silica, sand and other silicon-based substances. The copolymer is useful as a fiberglass binder, and also useful in providing protective coatings on glass sheets. A fiberglass sizing composition is also provided having a copolymer that includes at least one acid group derived from at least one acid monomer, a hydrophobic comonomer, and a crosslinker.
    Type: Application
    Filed: September 21, 2010
    Publication date: January 13, 2011
    Applicant: Akzo Nobel N.V.
    Inventors: Klein A. Rodrigues, James C. Long
  • Publication number: 20100330376
    Abstract: Polysaccharide thermosetting systems and composites utilizing such systems include formaldehyde free binders formed from at least one polysaccharide and at least one polysaccharide crosslinker.
    Type: Application
    Filed: December 18, 2008
    Publication date: December 30, 2010
    Applicant: AKZO NOBEL N.V.
    Inventors: Ralph Trksak, Daniel B. Solarek, Solweig Vitry, Klin A. Rodrigues, Qingwen Wendy Yuan-Huffman, Andreas Puhlfuerss
  • Patent number: 7858058
    Abstract: The invention pertains to removing soluble alkali metal or ammonium salt of a divalent anion from brine comprising following steps: obtaining brine with NaCl-concentration between 150g/L and saturation in the presence or absense of a cyrstal growth inhibitor for NaCl(GCI-NaCl),or with NaCl concentration above saturation in the presence of a CGI-NaCl, said brine optionally comprising a crystal growth inhibitor for the alkali metal or ammonium salt of the divalent anion(CGI-DA); if necessary, acidify the solution to pH<11.5; if the concentration of CGI-DA is less than 20 mg/L, adding CGI-DA to obtain at least 20 mg CGI-DA/L; subjecting the solution to a membrane filtration; if the concentration of CGI-DA in the concentration from the separation is less than 20 mg/L, adding CGI-DA to obtain at least 20 mg CGI-DA/L; crystalling the concentration; removing the crystallized alkali metal or ammonium salt of the divalent anion.
    Type: Grant
    Filed: October 18, 2005
    Date of Patent: December 28, 2010
    Assignee: Akzo Nobel N.V.
    Inventors: Gerrald Bargeman, René Lodewijk Maria Demmer, Boris Kuzmanovic, Cornelis Elizabeth Johannus Van Lare, Mateo Jozef Jacques Mayer, Maarten André Irène Schutyser, Jan Barend Westerink
  • Publication number: 20100324334
    Abstract: The present invention relates to an alkalimetal salt of glutamic acid-N,N-diacetic acid (GLDA) of the formula NaxKyHzGLDA, wherein x is equal to or more than 2 and lower than 4 and y is more than 0 and equal to or lower than 2, x+y is 3.5-4, and x+y+z=4, to processes to prepare such salt and the use thereof.
    Type: Application
    Filed: August 14, 2008
    Publication date: December 23, 2010
    Applicant: AKZO NOBEL N.V.
    Inventors: Tjerk Oedse Boonstra, Martin Heus
  • Publication number: 20100319577
    Abstract: The present invention generally relates to an additive package for warm-mix asphalt formulations for the pavement of road surfaces, said additive package comprising a) surfactant component, and b) an asphalt rheology modifying component, wherein said asphalt rheology modifying component comprises at least one of a i) a wax component and ii) a resin component. The invention also relates to a warm mix asphalt having improved compaction at lower temperatures, and to a pavement made from said warm mix asphalt.
    Type: Application
    Filed: November 11, 2008
    Publication date: December 23, 2010
    Applicant: Akzo Nobel N.V.
    Inventors: Premnathan Naidoo, Sundaram Logaraj, Alan Duncan James
  • Patent number: 7854947
    Abstract: Personal care compositions having plant fiber such as tapioca fiber, and methods of applying those formulations. The addition of fiber to personal care formulations can provide performance improvement such as cleansing, exfoliation, irritation reduction, suspending, foam enhancement, and rheological property modification.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: December 21, 2010
    Assignee: Akzo Nobel N.V.
    Inventors: Hongjie Cao, Gary T. Martino, Joanne Golas
  • Patent number: 7854925
    Abstract: This patent pertains to the use of anionic polyurethanes in a solubilized state which contribute to enhanced aesthetics to skin care compositions. The polyurethanes may be used alone or in combination with another polymer, particularly acrylate and methacrylate polymers.
    Type: Grant
    Filed: April 4, 2002
    Date of Patent: December 21, 2010
    Assignee: Akzo Nobel N.V.
    Inventors: Jean-Pierre Leblanc, Mussarat Noor, Joseph Pasapane, Tamara Babenko
  • Patent number: 7851571
    Abstract: Hybrid copolymers for use as anti-sealant and dispersant. The polymers are useful in compositions used in aqueous systems. The polymers include at least one synthetic monomeric constituent that is chain terminated by a naturally occurring hydroxyl containing moiety. A process for preparing these hybrid copolymers is also provided.
    Type: Grant
    Filed: November 24, 2009
    Date of Patent: December 14, 2010
    Assignee: Akzo Nobel N.V.
    Inventors: Klin A. Rodrigues, Darin K. Griffith