Abstract: This invention provides adducts, mixtures of adducts and oligomers, and/or mixtures of adducts, oligomers, and low molecular weight polymers formed from monovinylaromatic hydrocarbons.
Type:
Grant
Filed:
March 15, 2013
Date of Patent:
September 2, 2014
Assignee:
Albemarle Corporation
Inventors:
William J. Layman, Jr., Arthur G. Mack, Charles H. Kolich
Abstract: Described is process technology for producing brominated aromatic polymer compositions from low molecular weight aromatic polymer compositions. The specified conditions used in the process enable the formation of products having superior color and thermal stability properties.
Type:
Grant
Filed:
April 29, 2010
Date of Patent:
August 12, 2014
Assignee:
Albemarle Corporation
Inventors:
William J. Layman, Jr., Zhongxin Ge, Arthur G. Mack, Chi Hung Cheng, Neal J. Colonius, Sarah C. Jones, Steven A. Anderson
Abstract: A process and system for feeding solids and carrier gases through the wall of a duct or chamber through which a gas stream flows to the flowing gas stream from a feed source exterior of the duct or chamber.
Abstract: This invention relates flame retardant compositions containing low molecular weight brominated anionic, chain transfer, vinyl aromatic polymers, hereinafter “ACTVAP”. The compositions can accommodate high bromine content while still exhibiting a low thermally labile bromine content. The compositions have glass transition temperatures, Tg, that are predictive of acceptable melt flows and heat distortion temperatures (HDT) in HIPS and ABS based formulations substrates. The compositions, are suitable flame retardant candidates for use in thermoplastic formulations, e.g. polystyrene and ABS formulations.
Type:
Grant
Filed:
June 6, 2008
Date of Patent:
August 5, 2014
Assignee:
Albemarle Corporation
Inventors:
William J. Layman, Jr., Arthur G. Mack, Charles H. Kolich, Govindarajulu Kumar
Abstract: The present invention provides methods to maintain selectivity to ethanol from syngas during mixed-alcohol synthesis when methanol is being recycled. In some variations, syngas is fed to an alcohol-synthesis reactor that contains a sulfided metal catalyst, and methanol is separated from ethanol to form a methanol recycle stream that contains sulfur-containing compounds. Recycling the methanol stream back to the alcohol-synthesis reactor allows for adding sulfur to, or reducing sulfur loss from, the sulfided metal catalyst. Optionally, additional sulfur compounds may be introduced to maintain sulfur levels in sulfided metal catalysts. Preferred sulfiding agents, concentrations, and recycle strategies are disclosed herein.
Type:
Application
Filed:
August 21, 2012
Publication date:
July 10, 2014
Applicant:
Albemarle Corporation
Inventors:
Ronald C. Stites, Shakeel H. Tirmizi, Karl Kharas
Abstract: Novel polymer compositions of specified formula are converted into pellets of this invention by process technology provided by this invention. By forming a binder free melt of a polymer of such polymer compositions, and converting the melt into pellets as described here-in, pellets can be formed produce during production, handling, and use, no more than acceptably small amounts of “fines” or air-entrainable dusts.
Type:
Grant
Filed:
April 29, 2010
Date of Patent:
June 17, 2014
Assignee:
Albemarle Corporation
Inventors:
Govindarajulu Kumar, William J. Layman, Jr., Bo Liu, Douglas W. Luther, Arthur G. Mack
Abstract: This invention relates to methods for producing cycloheptatriene from at least 7,7-dichloronorcarane and a liquid component comprising a C8 to C30 succinic anhydride, a carboxylic acid, or a C8 to C30 alkyldimethylamine at about 205 deg. C. to about 230 deg. C.
Type:
Grant
Filed:
February 22, 2011
Date of Patent:
April 8, 2014
Assignee:
Albemarle Corporation
Inventors:
Richmond M. Starrett, Christopher D. Claeboe, Anthony F. Skufca, Joseph H. Miller
Abstract: A new synthesis of 4-bromo-2-methoxybenzaldehyde is reported from 1,4 dibromo 2-fluorobenzene. First, 2-fluoro-4-bromobenzaldehyde is prepared through metal halogen exchange and formylation with a formyl source at 0° C. After crystallization, this intermediate is reacted with methanol in the presence of potassium carbonate. Subsequently, 4-bromo-2-methoxy-benzaldehyde is crystallized.
Type:
Grant
Filed:
July 1, 2011
Date of Patent:
April 8, 2014
Assignee:
Albemarle Corporation
Inventors:
Thierry J. Giard, Vincent L. Mutterer, Christophe Durvaux
Abstract: A high assay decabromodiphenylalkane product in which the alkylene group contains in the range of about 1-10 carbon atoms and has an occluded free bromine content of <500 ppm is prepared. The process comprises brominating, in a liquid phase reaction mixture, at least one ?,?-diphenylalkane having an alkylene group of 1-10 carbon atoms, with a limited excess of bromine, in the presence of an aluminum, aluminum halide or a ferric halide catalyst in which the original halogen atoms of such halides are chlorine atoms, bromine atoms, or both. The limited excess of bromine is such that the maximum excess amount of bromine used in conducting the reaction is about 20 mole % relative to the stoichiometric amount required to convert the amount of ?,?-diphenylalkane used to decabromodiphenylalkane. Crude high assay decabromodiphenylalkane product is prepared without use of heat treatment, oven ageing, or grinding or other forms of pulverization.
Abstract: Described are highly concentrated liquid biocidal solutions formed in water from (a) specified bromine sources (e.g., BrCl or mixtures of BrCl and Br2) and (b) alkali metal salt of sulfamic acid and/or sulfamic acid and alkali metal base, wherein the solution contains >160,000 ppm of active bromine. Solutions of this type have been found to have greater stability than a commercially-available solution made from the same components containing 148,600 ppm of active bromine. Also described are new, water-soluble, solid state biocidal products formed by removing the water from solutions made in water from (a) and (b) irrespective of the initial concentration of active bromine. Removal of water can be accomplished by flashing or distillation at reduced pressure or preferably by spray drying. Such solid state products are typically in the form of powders or small particles, but can be compacted into larger forms preferably with the aid of one or more suitable binding agents.
Type:
Grant
Filed:
March 11, 2013
Date of Patent:
March 25, 2014
Assignee:
Albemarle Corporation
Inventors:
Christopher J. Nalepa, Robert M. Moore, Jr.
Abstract: SO3 is formed from a replenished circulating inventory of fresh and recycled SO2. Also, a feed stream of replenished SO2 is heated by indirect heat exchange with a hot stream of SO2 and SO3 whereby the hot stream is cooled for separating the two gases. The heated feed stream of replenished SO2 serves as a hot gaseous feed to a sulfur burner. This SO2 feed is divided into two feed streams, one being oxygenated with pure oxygen and the other remains as an SO2 feed. These feeds plus a feed of molten sulfur are concurrently and separately introduced into the sulfur burner where additional SO2 is formed via continuous exothermic reaction. Although heated, the oxygenated feed(s) of SO2 bring in the needed oxygen for the reaction and the feeds of the oxygenated and non-oxygenated SO2 serve as a heat sink in the sulfur burner to reduce the temperature therein.
Type:
Grant
Filed:
January 4, 2012
Date of Patent:
March 25, 2014
Assignee:
Albemarle Corporation
Inventors:
Tyson J. Hall, Jason M. Selzer, Utkarsh R. Vasaiwala
Abstract: This invention provides stabilized biodiesels comprising (1) biodiesel, such as fatty acid methyl ester (FAME), (2) mono- or bis-hindered phenolic derived from 2,6-di-tert-butylphenol, and (3) N,N-di-substituted para-phenylene diamine. Also methods of stabilizing biodiesel are provided involving adding (2) and (3) to (1).
Type:
Grant
Filed:
July 30, 2008
Date of Patent:
March 4, 2014
Assignee:
Albemarle Corporation
Inventors:
Emily R. Schneller, William E. Moehle, Gangkai Zhao
Abstract: The present invention provides methods and compositions for the chemical conversion of syngas to alcohols. The invention includes catalyst compositions, methods of making the catalysts, and methods of using the catalysts including techniques to maintain catalyst stability. Certain embodiments teach compositions for catalyzing the conversion of syngas into products comprising at least one C1-C4 alcohol, such as ethanol. These compositions generally include cobalt, molybdenum, and sulfur, and avoid metal carbides both initially and during reactor operation.
Abstract: This invention relates to novel and useful toluene and styrene derived telomer distributions, such distributions being desirable substrates for the preparation of brominated flame retardants.
Type:
Grant
Filed:
November 30, 2009
Date of Patent:
February 11, 2014
Assignee:
Albemarle Corporation
Inventors:
William J. Layman, Jr., Charles H. Kolich, Arthur G. Mack, Steven A. Anderson, Jonathan P. McCarney, Junzuo Wang
Abstract: Described are multi-ring antioxidant products comprising at least one sulfur-bridged aromatic hydrocarbon compound substituted on at least one of its aromatic rings by at least one sterically hindered 3,5-dihydrocarbyl-4-hydroxybenzyl moiety. Such products have the formula: R—Sn—R[—S—R]m wherein each R is, independently, an aromatic hydrocarbon group having 6-12 carbon atoms, wherein m is 0-20, wherein n is 1-6 when m is 0, and when n is 1, m is 1-20; and wherein at least one of R, R1, and R2 is substituted by at least one such sterically hindered moiety. The preparation of such products and their use as antioxidants in compositions normally susceptible to oxidative degradation in oxygen or air, e.g., liquid fuel and lubricants, are also described.
Abstract: A process for the preparation of organic cation tetrakis(Faryl) borate salts. The process includes preparation of intermediate, mono-hydrazine substituted (Faryl) compound, from (Faryl) compound using hydrazine at temperatures below 78° C. A stoichiometric excess of hydrazine to the (Faryl) compound to the (Faryl) compound is used. The process further includes the preparation of the organic cation tetrakis(Faryl) borate in ethereal medium.
Abstract: This invention relates to novel and useful toluene and styrene derived telomer distributions, such distributions being desirable substrates for the preparation of brominated flame retardants.
Type:
Grant
Filed:
November 30, 2009
Date of Patent:
February 4, 2014
Assignee:
Albemarle Corporation
Inventors:
William J. Layman, Jr., Charles H. Kolich, Arthur G. Mack, Steven A. Anderson, Jonathan P. McCarney, Jorge Morice, Zhongxin Ge, Junzuo Wang
Abstract: This invention provides a process for the N-halogenation of at least one 5-hydrocarbyl hydantoin and/or at least one 5,5-dihydrocarbyl hydantoin. The process comprises concurrently feeding into a reaction zone (i) water, inorganic base, and 5,5-dimethylhydantoin, these being fed separately and/or in any combination(s), (ii) a separate feed of a brominating agent, and (iii) a separate feed of a chlorinating agent, in proportions such that during all or substantially all of the time the concurrent feeding is occurring halogenation of the 5-hydrocarbyl hydantoin and/or 5,5-dihydrocarbyl hydantoin occurs and resultant halogenated product precipitates in the liquid phase of an aqueous reaction mixture, and in which the pH of the liquid phase is continuously or substantially continuously maintained in the range of about 2.0 to about 8.0 during all or substantially all of the time the concurrent feeding is occurring.