Patents Assigned to Applied Materials, Inc.
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Patent number: 6018616Abstract: In general, the present invention provides a single thermal cycling module for baking and chilling a substrate, such as a wafer, that is in thermal contact with a foil heater, a heat exchanger, and a radiation heater. The radiation heater thermally heats a fluid contained by the heat exchanger, which in turn, thermally bakes the substrate at a desired temperature. When the radiation heater is deactivated, a fluid circulates through the heat exchanger to chill the substrate. The foil heater assists the baking and chilling phases by elevating the temperature of the substrate when necessary to prevent or regulate temperature fluctuations of the substrate temperature. Both the radiation heater and the foil heater can provide several zones for varying the heat applied across the substrate, and a single fluid temperature is provided to the heat exchanger for both baking and chilling cycles.Type: GrantFiled: February 23, 1998Date of Patent: January 25, 2000Assignee: Applied Materials, Inc.Inventor: Charles D. Schaper
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Patent number: 6017144Abstract: The present invention is to a chemical vapor deposition process for depositing a substantially planar, highly reflective layer on a substrate, and is particularly useful for filling high aspect ratio holes in the substrate with metal-containing material. The substrate is placed in a process zone, and successive seeding and oriented crystal growth stages are performed on the substrate. In the seeding stage, the substrate is heated to temperatures T.sub.s, within a first lower range of temperatures .DELTA. T.sub.s, and a seeding gas is introduced into the process zone. The seeding gas deposits a substantially continuous, non-granular, and planar seeding layer on the substrate. Thereafter, in an oriented crystal growth stage, the substrate is maintained at deposition temperatures T.sub.d, within a second higher range of temperatures .DELTA. T.sub.D, and deposition gas is introduced into the process zone.Type: GrantFiled: October 24, 1996Date of Patent: January 25, 2000Assignee: Applied Materials, Inc.Inventors: Ted Tie Guo, Mehul Bhagubhai Naik, Liang-Yu Chen, Roderick Craig Mosely, Israel Beinglass
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Patent number: 6015591Abstract: An improved deposition chamber (2) includes a housing (4) defining a vacuum chamber (18) which houses a substrate support (14). A set of first nozzles (34) have orifices (38) opening into the vacuum chamber in a circumferential pattern spaced apart from and generally overlying the periphery (40) of the substrate support. One or more seconds nozzle (56, 56a), positioned centrally above the substrate support, inject process gases into the vacuum chamber to improve deposition thickness uniformity. Deposition thickness uniformity is also improved by ensuring that the process gases are supplied to the first nozzles at the same pressure. If needed, enhanced cleaning of the nozzles can be achieved by slowly drawing a cleaning gas from within the vacuum chamber in a reverse flow direction through the nozzles using a vacuum pump (84).Type: GrantFiled: February 13, 1998Date of Patent: January 18, 2000Assignee: Applied Materials, Inc.Inventors: Shijian Li, Fred C. Redeker, Tetsuya Ishikawa
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Patent number: 6015761Abstract: A microwave-activated plasma process for etching dielectric layers (20) on a substrate (25) with excellent control of the shape and cross-sectional profile of the etched features (40), high etch rates, and good etching uniformity, is described. A process gas comprising (i) fluorocarbon gas (preferably CF.sub.4), (ii) inorganic fluorinated gas (preferably NF.sub.3), and (iii) oxygen, is used. The process gas is introduced into a plasma zone (55) remote from a process zone (60) and microwaves are coupled into the plasma zone (55) to form a microwave-activated plasma. The microwave-activated plasma is introduced into the process zone (60) to etch the dielectric layer (20) on the substrate (25) with excellent control of the shape of the etched features.Type: GrantFiled: June 26, 1996Date of Patent: January 18, 2000Assignee: Applied Materials, Inc.Inventors: Walter Richardson Merry, William Brown, Harald Herchen, Michael D. Welch
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Patent number: 6016383Abstract: A rapid thermal heating apparatus including an infrared camera located outside an evacuable chamber to sense infrared radiation emitted from different regions of a substrate.Type: GrantFiled: February 27, 1998Date of Patent: January 18, 2000Assignee: Applied Materials, Inc.Inventors: Christian M. Gronet, James F. Gibbons
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Patent number: 6016131Abstract: An inductively coupled plasma reactor for processing a substrate has an inductively coupled coil antenna including plural inductive antenna loops which are electrically separated from one another and independently connected to separately controllable plasma source RF power supplies. The RF power level in each independent antenna loop is separately programmed and instantly changeable to provide a perfectly uniform plasma ion density distribution across the entire substrate surface under a large range of plasma processing conditions, such as different process gases or gas mixtures. In a preferred embodiment, there are as many separately controllable RF power supplies as there are independent antenna loops, and all the separately controllable power supplies receive their RF power from a commonly shared RF generator.Type: GrantFiled: May 3, 1999Date of Patent: January 18, 2000Assignee: Applied Materials, Inc.Inventors: Arthur H. Sato, Xue-Yu Qian
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Patent number: 6014979Abstract: A process for etching a substrate 20 in a process chamber 25 having sidewalls 30 and a sacrificial collar 100, and for cleaning the sacrificial collar without eroding or otherwise damaging the sidewalls. The process comprises an etching stage in which a substrate 20 is placed in the process chamber 25, and the sacrificial collar 100 is maintained around the substrate to add or remove species from a process gas to affect a processing rate of the substrate periphery. The process further comprises a localized cleaning stage in which the substrate 20 is removed, a cleaning gas introduced into the process chamber 25, and a localized cleaning plasma sheath 95 is formed to clean process residues formed on the sacrificial collar 100 substantially without extending the localized cleaning plasma sheath 95 to the sidewalls 30 of the process chamber.Type: GrantFiled: June 22, 1998Date of Patent: January 18, 2000Assignee: Applied Materials, Inc.Inventors: Luc Van Autryve, Stefan Oswald Lang
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Patent number: 6015476Abstract: The invention is embodied in a magnetically enhanced plasma reactor for processing a semiconductor workpiece, including a reactor enclosure defining a vacuum chamber, a wafer support for holding the workpiece inside the chamber, a plasma power source for applying plasma source power into the chamber, a first plurality of electrically conductive elongate filaments, each being of a finite length, distributed about a periphery of the chamber enclosure, each of said filaments extending at least generally in an axial direction relative to the chamber. The plurality of filaments is capable of permitting different currents through different ones of at least some of the filaments in accordance with a distribution of currents among the filaments corresponding to a desired magnetic field configuration. Respective current sources are preferably connected to deliver respective currents to different ones of the plurality of filaments.Type: GrantFiled: February 5, 1998Date of Patent: January 18, 2000Assignee: Applied Materials, Inc.Inventors: Ross D. Schlueter, Steve Marks
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Patent number: 6015465Abstract: A temperature control system 10 is used to control the temperature of a chamber surface 15, such as a convoluted external surface, of a process chamber 25 that is used to process a semiconductor substrate 30. The temperature control system 10 comprises a vapor chamber 100 that forms an enclosure adjoining or surrounding the process chamber surface 15. A fluid distributor 115 in the vapor chamber 100 applies a fluid film 130 onto the process chamber surface 15. Vaporization of the fluid film 130 from the chamber surface 15 controls the temperature of the chamber surface. Optionally, a vent 165 in the vapor chamber 100 can be used to adjust the vaporization temperature of the fluid in the vapor chamber.Type: GrantFiled: April 8, 1998Date of Patent: January 18, 2000Assignee: Applied Materials, Inc.Inventors: Arnold Kholodenko, Ke Ling Lee, Maya Shendon, Efrain Quiles
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Patent number: 6013582Abstract: The present disclosure pertains to a method for plasma etching a semiconductor patterning stack. The patterning stack includes at least one layer comprising either a dielectric-comprising antireflective material or an oxygen-comprising material. In many instances the dielectric-comprising antireflective material will be an oxygen-comprising material, but it need not be limited to such materials. In one preferred embodiment of the method, the chemistry enables the plasma etching of both a layer of the dielectric-comprising antireflective material or oxygen-comprising material and an adjacent or underlying layer of material. In another preferred embodiment of the method, the layer of dielectric-comprising antireflective material or oxygen-comprising material is etched using one chemistry, while the adjacent or underlying layer is etched using another chemistry, but in the same process chamber.Type: GrantFiled: December 8, 1997Date of Patent: January 11, 2000Assignee: Applied Materials, Inc.Inventors: Pavel Ionov, Sung Ho Kim, Dean Li
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Patent number: 6012600Abstract: A method and apparatus is provided which secures the lid of a processing chamber in abutting engagement with the walls of the chamber to form an airtight processing environment and which provides for the release of pressure within the chamber in the event of a sudden change in pressure such as an over pressure excursion. The method and apparatus generally comprise a clamp member having a base portion for mounting the clamp to a first surface, a contact portion for contacting a second surface and maintaining a desired relationship between the first and second surfaces, and a deflecting portion which allows separation of the first and second surfaces to relieve pressure behind the first or second surface and return to the desired relationship between the first and second surfaces.Type: GrantFiled: February 2, 1996Date of Patent: January 11, 2000Assignee: Applied Materials, Inc.Inventors: Thanh Pham, Eugene Fukshansky, David Wanamaker
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Patent number: 6013315Abstract: A dispense nozzle (10), having a narrow oblong orifice (14), is positioned over and near the surface of the substrate (22), close to the edge of the substrate. While the substrate is rotating, the nozzle dispenses fluid through the narrow oblong orifice onto the substrate surface, starting from near the outer edge (24) moving toward the substrate's rotational center (26). The narrow oblong orifice may have lips of unequal size to help direct fluid flow. A controlled rate of acceleration is maintained for the rate of translation of the nozzle across the substrate surface. Once the nozzle approaches the substrate's rotational center, the nozzle is raised to a higher height above the surface of the substrate while continuing to dispense fluid. Then the dispense stream of fluid is terminated, and the substrate is rapidly accelerated to a predetermined spin speed to evenly distribute the fluid over the surface of the substrate to a uniform film of desired thickness.Type: GrantFiled: January 22, 1998Date of Patent: January 11, 2000Assignee: Applied Materials, Inc.Inventor: Robert P. Mandal
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Patent number: 6013584Abstract: An apparatus and methods for forming a dielectric layer, such as PSG, that exhibits low moisture content, good gap fill capability, good gettering capability, and compatibility with planarization techniques. The PSG film deposited using the apparatus and methods of the present invention are particularly suitable for use as a PMD layer. According to one embodiment, the present invention provides a process for depositing a film on a substrate disposed on a pedestal in a processing chamber. The process includes introducing a process gas into said processing chamber, where the process gas includes SiH.sub.4, PH.sub.3, O.sub.2, and argon. The process also includes controlling the temperature of the pedestal to between about 400-650.degree. C. during a first time period, maintaining a pressure ranging between about 1-10 millitorr in the processing chamber during the first time period.Type: GrantFiled: February 19, 1997Date of Patent: January 11, 2000Assignee: Applied Materials, Inc.Inventor: Hichem M'Saad
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Patent number: 6013159Abstract: A plasma sputtering reactor in which a magnet is linearly scanned over the back of the sputtering target to enhance the sputtering. The magnet's linear scan is extended to beyond the wafer processing area. When the magnet reaches that point, conditions are changed within the reactor to cause particles otherwise trapped by the magnet to fall into an area of the reactor where they do not fall on the substrate being processed. The changed conditions may include extinguishing the plasma, reducing or reversing the target voltage, positively charging walls of the trap area, or pulsing gas through the plasma. Also, according to the invention, the plasma is ignited with the magnet positioned over the trap area so that particles generated in the ignition process are not immediately deposited on the wafer or the walls of the processing area, and they tend to stay in the trap area.Type: GrantFiled: November 16, 1997Date of Patent: January 11, 2000Assignee: Applied Materials, Inc.Inventors: Bret W. Adams, Ivo Raaijmakers
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Patent number: 6010966Abstract: A process for anisotropically etching a metal-containing layer 15 on a substrate 10 is described. The etching process uses an energized process gas of a comprising halogen-containing etchant gas for etching the metal-containing layer to form volatile metal compounds, and hydrocarbon inhibitor gas having a carbon-to-hydrogen ratio of from about 1:1 to about 1:3, to deposit inhibitor on etched metal features and provide anisotropic etching. More preferably, the hydrocarbon inhibitor gas comprises a high carbon-to-hydrogen ratio of from about 1:1 to 1:2.Type: GrantFiled: August 7, 1998Date of Patent: January 4, 2000Assignee: Applied Materials, Inc.Inventor: Pavel Ionov
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Patent number: 6009830Abstract: A plasma etch reactor having independent gas feeds above the wafer and either at the sides or below the wafer. Preferably, a carrier gas such as argon is supplied from a showerhead electrode above the wafer while an etching gas is supplied from below. In the case of selectively etching an oxide over a non-oxide layer, the etchant gas should include one or more fluorocarbons.Type: GrantFiled: November 21, 1997Date of Patent: January 4, 2000Assignee: Applied Materials Inc.Inventors: Haojiang Li, Robert W. Wu
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Patent number: 6011622Abstract: An improved particle monitoring sensor is described which uses a variety of techniques to prolong the effective life of the optical surfaces within the particle monitoring'sensor. Substantially inert purging gas is directed over the particle monitoring sensor windows, which are normally exposed to a harsh operating environment. The surfaces of these windows are heated by heating elements in direct thermal contact with the windows. In addition, a restrictive slit is placed over the detector window to reduce the exposed area and to increase the velocity of gas flowing over the window surface. While this slit reduces the detector's field of view, the signal loss is reduced by using a linearly polarized light source and aligning the elongated slit's major axis with the direction of polarization.Type: GrantFiled: June 16, 1997Date of Patent: January 4, 2000Assignee: Applied Materials, Inc.Inventors: Boris Fishkin, Phil Salzman
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Patent number: 6010603Abstract: Copper can be pattern etched at acceptable rates and with selectivity over adjacent materials using an etch process which utilizes a solely physical process which we have termed "enhanced physical bombardment". Enhanced physical bombardment requires an increase in ion density and/or an increase in ion energy of ionized species which strike the substrate surface. To assist in the removal of excited copper atoms from the surface being etched, the power to the ion generation source and/or the substrate offset bias source may be pulsed. In addition, when the bombarding ions are supplied from a remote source, the supply of these ions may be pulsed. Further, thermal phoresis may be used by maintaining a substrate temperature which is higher than the temperature of a surface in the etch chamber.Type: GrantFiled: July 9, 1997Date of Patent: January 4, 2000Assignee: Applied Materials, Inc.Inventors: Yan Ye, Diana Xiaobing Ma, Gerald Yin
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Patent number: 6009827Abstract: A method and apparatus for ramping down the deposition pressure in a SACVD process. The present invention also provides a method and apparatus for subsequently ramping up the pressure for a PECVD process in such a manner as to prevent unwanted reactions which could form a weak interlayer interface. In particular, the deposition pressure in the SACVD process is ramped down by stopping the flow of the silicon containing gas (preferably TEOS) and/or the carrier gas (preferably helium), while diluting the flow of ozone with oxygen. A ramp down of the pressure starts at the same time. The diluting of the ozone with oxygen limits reactions with undesired reactants at the end of a process.Type: GrantFiled: November 5, 1996Date of Patent: January 4, 2000Assignee: Applied Materials, Inc.Inventors: Stuardo Robles, Visweswaren Sivaramakrishnan, Maria Galiano, Victoria Kithcart
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Patent number: 6008140Abstract: Copper can be pattern etched in a manner which provides the desired feature dimension and integrity, at acceptable rates, and with selectivity over adjacent materials. To provide for feature integrity, the portion of the copper feature surface which has been etched to the desired dimensions and shape must be protected during the etching of adjacent feature surfaces. To avoid the trapping of reactive species interior of the etched copper surface, hydrogen is applied to that surface. Hydrogen is adsorbed on the copper exterior surface and may be absorbed into the exterior surface of the copper, so that it is available to react with species which would otherwise penetrate that exterior surface and react with the copper interior to that surface. Sufficient hydrogen must be applied to the exterior surface of the etched portion of the copper feature to prevent incident reactive species present due to etching of adjacent feature surfaces from penetrating the previously etched feature exterior surface.Type: GrantFiled: August 13, 1997Date of Patent: December 28, 1999Assignee: Applied Materials, Inc.Inventors: Yan Ye, Allen Zhao, Xiancan Deng, Diana Xiaobing Ma