Abstract: A subject of the present invention is a composition comprising: at least one recycled bituminous product, at least one epoxidized oil, and at least one bitumen additive. The invention also relates to the use thereof for the preparation of a mix. Another subject of the invention is a mix comprising the composition according to the invention.
Abstract: The invention relates to a process for preparing methyl mercaptan from a mixture of carbon oxide, hydrogen sulfide and hydrogen, in the presence of a catalyst based on molybdenum and potassium supported on zirconia, said catalyst not comprising any promoter.
Type:
Grant
Filed:
December 20, 2018
Date of Patent:
March 21, 2023
Assignees:
Arkema France, Universite Lille 1-Sciences et Technologies, Centre National de la Recherche Scientifique (CNRS)
Inventors:
Georges Frémy, Hélori Salembier, Carole Lamonier, Pascal Blanchard
Abstract: The use of a composition including a mixture of at least one non-reactive thermoplastic polymer of Tg >40° C., especially >100° C., in particular >120° C., and at least one reactive thermoplastic prepolymer, with a fibrous material, for the preparation of a fibrous material impregnated with the composition, the composition having an initial melt viscosity during the impregnation, as measured in plate-plate rheology under 1 Hz and 2% strain, at a temperature of 300° C., of less than the viscosity of the same composition devoid of reactive prepolymer, measured under the same conditions, and/or a ductility, after in situ polymerization of the reactive thermoplastic prepolymer in the composition during the impregnation and after the impregnation, that is at least equivalent to the ductility of the same composition devoid of non-reactive thermoplastic polymer, and of which said reactive thermoplastic prepolymer is polymerized to the same number-average molecular mass (Mn).
Type:
Application
Filed:
February 23, 2021
Publication date:
March 16, 2023
Applicant:
ARKEMA FRANCE
Inventors:
Thibaut SAVART, Lise DEVES, Gilles HOCHSTETTER
Abstract: The invention relates to a crosslinkable composition, which comprises a component a) at least one halogenated bisphenol A diglycidyl ether tetra(meth)acrylate and a component b) at least one diluent from mono(meth)acrylates of a monoalcohol comprising a biphenyl structure, and at least one optional component from components c), d), e), f) and g). It also relates to its use for coatings or materials, in particular for 3D printed articles for optical applications, as it also relates to the crosslinked composition and to the finished product, in particular the 3D article which results therefrom.
Abstract: Multilayer structure for transporting hydrogen, including, from the inside, at least one sealing layer and at least one composite reinforcing layer, an innermost composite reinforcing layer being wound around an outermost adjacent sealing layer, the sealing layers of a composition predominantly of at least one semi-crystalline, long-chain polyamide thermoplastic polymer P1i (i=1 to n, n being the number of sealing layers), the Tf of which, as measured according to ISO 11357-3: 2013, is greater than 160° C., with the exception of one polyether block amide (PEBA), up to 50% by weight of impact modifier relative to the total weight of the composition and up to 1.5% by weight of plasticiser relative to the total weight of the composition, the composition being free of nucleating agent, and at least one of the composite reinforcing layers being of a fibrous material.
Type:
Application
Filed:
January 26, 2021
Publication date:
March 9, 2023
Applicant:
ARKEMA FRANCE
Inventors:
Nicolas DUFAURE, Patrick DANG, Antoine GOUPIL
Abstract: The invention relates to the use of an additive chosen from the compounds of formula (1) and the compounds of formula (2) as follows: in which A, B, E, Y, Z and d and j are as defined in the description, the anti-ageing additive being present in an amount of between 0.01% and 10% by weight, relative to the total weight of the bituminous product, in order to delay the ageing of the bitumen. The invention also relates to a composition comprising:—a bituminous product,—at least one anti-ageing additive as described above, and—at least one anti-oxidant agent, the anti-ageing additive being present in an amount of between 0.01% and 10% by weight, relative to the total weight of the bituminous product.
Abstract: The present invention relates to a multilayer tubular structure (MLT) intended for the transport of fluids, in particular of petrol, especially alcohol-containing petrol, comprising, from the outside inwards, at least one barrier layer (1) and at least one inner layer (2) located below the barrier layer, said inner layer (2), or all the layers (2) and the other optional layers located below the barrier layer, containing on average from 0 to 1.5% by weight of plasticizer relative to the total weight of the composition of the layer (2) or to the total weight of all the compositions of the layers (2) and the other optional layers located below the barrier layer, respectively, said inner layer (2) predominantly comprising at least one polyamide of aliphatic type or consisting of more than 75% of aliphatic units, said aliphatic polyamide being chosen from: a polyamide denoted A, having a mean number of carbon atoms per nitrogen atom, denoted CA, of from 4 to 8.
Abstract: Curable compositions contain at least one polymerizable ionic species and, when cured (for example, by photocuring), provide cured compositions which are thermoplastic and yet fragmentable by a protic liquid medium such as water. The polymerizable ionic species corresponds to Formula (I) A+B? wherein A+ is a cationic species having a cationic functional group and a first polymerizable, ethylenically unsaturated functional group; and B? is an anionic species having an anionic functional group and a second polymerizable, ethylenically unsaturated functional group which is the same as or different from the first polymerizable, ethylenically unsaturated functional group. The curable compositions are useful for forming sacrificial or temporary articles, for example by three-dimensional printing methods.
Abstract: The field of molded articles and fiber-reinforced thermoplastic compositions for obtaining them. The use of the reinforced thermoplastic composition for obtaining a thin molded article with reduced warpage. The composition may include: from 30 to 70% by weight of an amorphous polyamide matrix by total weight of the composition; from 30 to 70% by weight of glass fibers with a circular cross-section by total weight of the composition; and optionally additives.
Type:
Application
Filed:
June 25, 2020
Publication date:
March 2, 2023
Applicant:
Arkema France
Inventors:
Stefânia CASSIANO GASPAR, Benoît BRULE, Mathieu SABARD, Xiong YAO, Marie POMMIER DE SANTI
Abstract: Curable compositions having desirable attributes such as rapid curing rates and enhanced physical properties are prepared using admixtures of one or more (meth)acrylate-functionalized compounds and one or more reactive comonomers, such as 1,1-diester-1-alkenes (e.g., methylene malonates), 1,1-diketo-1-alkenes, 1-ester-1-keto-1-alkenes and/or icatonates.
Type:
Grant
Filed:
May 23, 2018
Date of Patent:
February 28, 2023
Assignee:
Arkema France
Inventors:
Margaux Guichard, Brendan T. McGrail, William C. Wolf, Jeffrey A. Klang
Abstract: A composition including a lubricant based on polyol esters (POEs) or PVE and a refrigerant F including from 1 to 99% by weight of trans-1,3,3,3-tetrafluoropropene (trans-HFO-1234ze) and from 1 to 99% by weight of 1,1,1,2-tetrafluoroethane. Also, the use of the composition including a lubricant and refrigerant in refrigeration, air conditioning and heat pumps.
Abstract: Heterocyclic-functional resins, such as epoxides, oxetanes, cyclic carbonates, lactides and lactones, are used in radiation-curable formulations along with ethylenically unsaturated materials such as (meth)acrylates to achieve improved mechanical properties and/or lower shrinkage in the cured compositions prepared therefrom as compared to formulations containing the ethylenically unsaturated materials but no heterocyclic-functional resin. Polymerizable, ethylenically unsaturated metal complexes, such as Zn and Ca carboxylates prepared using unsaturated carboxylic acids or anhydrides, may be employed to effect thermal cure of the heterocyclic-functional resin component of such formulations, which are particularly useful in the production of 3D-printed articles and the like.
Abstract: The field of molded articles and fiber-reinforced thermoplastic compositions for obtaining them. The use of the reinforced thermoplastic composition for obtaining a thin molded article with reduced warpage. The composition may include: from 30 to 70% by weight of an amorphous polyamide matrix by total weight of the composition; from 30 to 70% by weight of glass fibers with a circular cross-section by total weight of the composition; and optionally additives.
Type:
Application
Filed:
June 28, 2019
Publication date:
February 23, 2023
Applicant:
Arkema France
Inventors:
Mathieu SABARD, Benoît BRULE, Stefania CASSIANO GASPAR, Marie POMMIER DE SANTI, Xiong YAO
Abstract: The use of a heat-transfer composition including at least one refrigerant chosen from halogenated hydrocarbons, perhalogenated hydrocarbons, fluorinated ketones, fluorinated ethers and also combinations thereof, and at least one dielectric fluid, for cooling a battery of an item of equipment, such as an electric or hybrid vehicle, the heat-transfer composition having a volume resistivity of greater than or equal to 106 ?·cm at 25° C.
Abstract: A composition including at least one polyamide polymer obtained from at least one reactive polyamide prepolymer including at least one chain extender (PA1-All1-PA1), the polyamide polymer being prepared at a temperature T1 no lower than the temperature melting temperature or glass transition temperature of the polymer and having a mean molecular weight Mn1. The composition has a melt viscosity which can be modulated according to the temperature to which the composition is exposed, wherein the temperature is between T2 and T3, T2 and T3 being higher than T1, and the melt viscosity ?2 or ??3 observed at the temperature T2 or T3, respectively, being lower than the melt viscosity ?2 or ?3 of the polyamide polymer, which does not include a chain extender and has the same mean molecular weight Mn1(PA1) observed at the same temperature T2 or T3. The composition includes one or more polyamides.
Abstract: The invention relates to a block copolymer comprising at least one rigid polyamide block and at least one flexible block, characterized in that the flexible block has an NH2/OH ratio of concentrations of amine chain ends to alcohol chain ends which is within the range from 30 to 150, said concentrations being measured by 1H NMR (TFanh./CD2Cl23). The invention also relates to the use of a flexible block for manufacturing a copolymer containing polyamide blocks and flexible blocks that is both hydrolysis-resistant and CO2-permeable, with a permeability to CO2 of at least 10 000 cm3/m2/24 h/atm for a 25 ?m film of said copolymer, characterized in that said flexible block has a ratio of amine chain ends to acid chain ends which is within the range from 30 to 150.
Type:
Grant
Filed:
December 7, 2018
Date of Patent:
February 14, 2023
Assignee:
ARKEMA FRANCE
Inventors:
Patrick Dang, Quentin Pineau, Inci Turan-Altuntas
Abstract: The invention relates to the use of low levels of glycols and short chain diols to control air void formation in any polymerization reaction having carbonyl-containing monomers, and preferably carboxylic acid ester monomers, at a level of at least 10% of total monomer, where the monomer has a peak polymerization exotherm temperature of greater than the boiling point of the monomer. The glycols and short chain diols are used in the polymization mixture at levels of 0.5 to 10 weight percent, based on the carboxylic acid ester-containing monomer. It is believed the glycols and short chain diols hydrogen bond with the —(C?O)O— containing monomer to increase the monomer boiling point, and decrease or even eliminate the formation of air voids due to monomer boiling. The invention is especially useful in polymerization of methyl methacrylate polymers and copolymers, either neat, or as a polymer composite system.
Type:
Grant
Filed:
December 13, 2017
Date of Patent:
February 14, 2023
Assignee:
ARKEMA FRANCE
Inventors:
Alaaeddin Alsbaiee, Evan Crocker, Dana Lee Swan
Abstract: A process for conditioning air, by means of a main circuit, the main circuit being a vapor compression circuit, wherein a first refrigerant circulates, and a secondary circuit with no compressor, wherein a non-flammable second refrigerant including a hydrofluoroolefin and/or a hydrochlorofluoroolefin circulates, the main circuit and the secondary circuit being coupled to one another; the process including a heat exchange between the surroundings and the first refrigerant, a heat exchange between the first and second refrigerants, and a heat exchange between the second refrigerant and the air to be conditioned. Also, an air conditioning plant for implementing the process.
Abstract: A multilayer structure for storing hydrogen, including, from the inside, at least one sealing layer and at least one composite reinforcement layer, an innermost composite reinforcement layer being welded to an outermost adjacent sealing layer, the sealing layers being a composition predominantly of: at least one semi-crystalline polyamide thermoplastic polymer P1i, i=1 to n, n being the number of sealing layers, excluding an amide polyether block (PEBA), up to 50% by weight of impact modifier relative to the total weight of the composition, up to 1.5% by weight of plasticizer relative to the total weight of the composition, and at least one of the composite reinforcement layers of a fibrous material in the form of continuous fibers, which is impregnated with a composition predominantly of at least one semi-crystalline polyamide polymer P2j, j=1 to m, m being the number of reinforcement layers.
Type:
Application
Filed:
January 26, 2021
Publication date:
February 9, 2023
Applicant:
ARKEMA FRANCE
Inventors:
Nicolas DUFAURE, Patrick DANG, Antoine GOUPIL