Abstract: A combustion exhaust gas treatment system comprising: a heat exchanger (A) for recovering heat contained in the combustion exhaust gas into heat medium, an absorption column for obtaining CO2 removed gas by absorbing CO2 in the combustion exhaust gas into absorbent, a heat exchanger (B) for applying heat recovered by heat medium to the CO2 absorbed absorbent, a desorption column for desorbing the absorbent by removing CO2 from the CO2 absorbed absorbent, a flash tank for flash vaporizing the desorbed absorbent and a heat exchanger (E) for transferring heat from the desorbed absorbent to the CO2 absorbed absorbent, wherein the CO2 absorbed absorbent can be supplied from the absorption column to the desorption column via the heat exchanger (E) and the heat exchanger (B) in this order, and the desorbed absorbent can be supplied from the desorption column to the absorption column via the flash tank and the heat exchanger (E) in this order.

Abstract: In a system of absorbing CO2 from exhaust gas comprising absorbent regeneration equipment (a reclaimer), the present invention solves a problem of a water balance associated with operation of the reclaimer to keep the CO2 absorption system under optimal conditions.

Abstract: A solid fuel burner and a combustion device using the solid fuel burner includes: a throat provided to the outer periphery of a fuel nozzle and injecting combustion gas into a furnace; a duct for delivering the combustion gas to the throat, the duct being provided with an inlet opening into which the gas is introduced from a direction perpendicular to the central axis of the nozzle and having a flow path formed so as to be bent at a right angle in the direction of the central axis of the nozzle; a damper provided in the duct; and a differential pressure detection device for detecting the difference between the pressure of the combustion gas flowing through the upstream portion of the duct and the pressure of the combustion gas flowing through the downstream portion of the duct. The damper is provided near and downstream of the inlet opening of the duct.

Abstract: An oxygen combustion system includes a boiler to burn fuel using combustion gas composed of oxygen-rich gas and circulating flue gas, a dust remover disposed in a flue through which flue gas discharged from the boiler flows, a second flue leading the combustion gas to the boiler, the combustion gas being made by mixing the circulating flue gas extracted downstream of the dust remover with the oxygen-rich gas, a combustion gas heater exchanging heat between the flue gas flowing between the boiler and dust remover and the combustion gas flowing through the second flue, and a flue gas cooler disposed between the heater and the dust remover to cool the flue gas. A control unit controls at least one of a flow rate and cooling medium temperature of the flue gas cooler such that temperature of the flue gas introduced into the dust remover will be between 90° C. and 140° C.

Abstract: An object of the present invention is to easily reduce dust having large particle diameter that affects blocking and abrasion to prevent deposition thereof in a reactor. An exhaust gas NOx removal apparatus comprises a NOx removal rector having a catalyst layer for removing nitrogen oxides in a combustion exhaust gas; a duct structure having a stab-up point at which a flow of the exhaust gas changes from a horizontal direction to a vertical direction in an exhaust gas duct on the upstream side of the NOx removal reactor; a tilt thin plate slit in which a number of thin plates are disposed in the duct of the horizontal direction of an inlet of the stub-up point or/and in an inlet of the catalyst layer in the NOx removal reactor in a vertical direction with a slit width smaller than an opening width of the catalyst layer at a predetermined inclination angle relative to the cross-section of an exhaust gas flow path; and a dust collecting/discharging portion attached to the lower end of a tilt thin plate slit.

Abstract: An object of the present invention is to provide a CO2 removal apparatus that prevents release of an amine compound of an absorbing solution from a CO2 absorption device. The CO2 removal apparatus includes a desorption column 13 that heats and regenerates an amine compound aqueous solution discharged from a decarbonator 1 making counterflow contact of a combustion exhaust gas and an amine compound aqueous solution; and reflux means that refluxes an amine compound aqueous solution regenerated in the desorption column 13 to the decarbonator 1 via a cooler 19. A contact section that makes counterflow contact of reflux water of the desorption column 13 and a CO2-removed combustion exhaust gas is formed in two stages, and the cooler 19 on the downstream side of the desorption column is also formed in two stages. Reflux water from the first stage cooler is supplied to the first stage contact section, and reflux water from the second stage cooler is supplied to the second stage contact section.

Abstract: A boiler operating method operates a boiler by switching between air combustion mode and oxygen combustion mode when burning fossil fuel with first combustion gas and second combustion gas. The second combustion gas compensates for oxygen deficiency in the first combustion gas. The air combustion mode uses air as the first combustion gas and the second combustion gas while the oxygen combustion mode uses mixed gas of combustion flue gas and oxygen-rich gas as the first combustion gas and the second combustion gas, the combustion flue gas being produced when the fossil fuel is burned. By mixing the oxygen-rich gas in the air in the process of switching between air combustion mode and oxygen combustion mode, the air being the first combustion gas used in the air combustion mode, the boiler operating method can switch between the air combustion mode and oxygen combustion mode while maintaining stable combustion.

Abstract: An exhaust gas purification catalyst contains titanium oxide as a main component and an oxide of one element or two or more elements selected from the group consisting of tungsten (W), molybdenum (Mo), and vanadium (V) as an active component, wherein the exhaust gas purification catalyst contains phosphoric acid or a water soluble phosphoric acid compound so that the atomic ratio of phosphorus (P) to a catalytically active component represented by the following formula is more than 0 and 1.0 or less; P/catalytically active component (atomic ratio)=number of moles of P/(number of moles of W+number of moles of Mo+number of moles of V).

Abstract: To inhibit corrosion of water wall tubes of a boiler and stabilize combustion on a burner during oxygen combustion operation, a boiler combustion system includes a boiler equipped with a burner and a two-staged combustion gas input port; a flue gas supply fan extracting flue gas from a flue gas treatment system via a flue gas circulation line; a combustion gas supply line, fuel carrier gas supply line, and two-staged combustion gas supply line branched off from the flue gas circulation line downstream of the flue gas supply fan; an oxygen supply line supplying oxygen-rich gas to the combustion gas supply line and fuel carrier gas supply line; combustion air supply fans; a switching unit switching operation between the flue gas supply fan and the combustion air supply fans; and dampers regulating gas flow rates on the combustion gas supply line and the two-staged combustion gas supply line, respectively.

Abstract: An oxygen combustion system includes a boiler to burn fuel using combustion gas composed of oxygen-rich gas and circulating flue gas, a dust remover disposed in a flue through which flue gas discharged from the boiler flows, a second flue leading the combustion gas to the boiler, the combustion gas being made by mixing the circulating flue gas extracted downstream of the dust remover with the oxygen-rich gas, a combustion gas heater exchanging heat between the flue gas flowing between the boiler and dust remover and the combustion gas flowing through the second flue, and a flue gas cooler disposed between the heater and the dust remover to cool the flue gas. A control unit controls at least one of a flow rate and cooling medium temperature of the flue gas cooler such that temperature of the flue gas introduced into the dust remover will be between 90° C. and 140° C.

Abstract: To overcome the problem of a conventional catalyst and to provide an exhaust gas purifying catalyst that meets the requirement concerning Hg oxidation activity and SO2 oxidation activity; i.e., an exhaust gas purifying catalyst which specifically reduces percent SO2 oxidation, while maintaining percent Hg oxidation at a high level. The invention provides an exhaust gas purifying catalyst which comprises a composition containing oxides of (i) titanium (Ti), (ii) molybdenum (Mo) and/or tungsten (W), (iii) vanadium (V), and (iv) phosphorus (P), wherein the catalyst contains Ti, Mo and/or W, and V in atomic proportions of 85 to 97.5:2 to 10: 0.5 to 10, and has an atomic ratio of P/(sum of V and Mo and/or W) of 0.5 to 1.

Abstract: The present invention provides a catalyst base material and a catalyst which have high strength, high porosity or high activity and methods of producing the catalyst base material and catalyst. The present invention relates to a method of producing a catalyst base material, the method comprising dispersing or dissolving a hydrophilic polymer coagulant as a first component, a water-soluble thickener as a second component, a colloidal inorganic binder as a third component and an inorganic fiber as a fourth component in water to form a catalytic slurry or paste, supporting the catalytic slurry or paste on a net-like substrate such that the meshes of the net-like substrate are filled up with the slurry or paste, by drying and/or calcinating the substrate.

Abstract: In an absorbing tower including an absorption unit of relatively small diameter capable of absorption and removal by an absorbent slurry for exhaust gas purification and a tank unit of relatively large diameter for temporarily storing the absorbent slurry flowing down from the absorption unit, the tank unit and the absorption unit are joined together by a conical member. By disposing an entrance flue at the conical member, a distance from an upper portion of the conical member to a spray header is shortened, and a height of the absorbing tower can be reduced accordingly. By extending a front end of the entrance flue to the absorption unit into which droplets of the absorbent slurry fall, a high-temperature exhaust gas from a boiler, etc., that has passed through the entrance flue, is made to pass through a circumference of the conical member so that an inexpensive material can be used in the conical member.

Abstract: To provide a catalyst having excellent performance and durability by improving a NOx reduction ratio at 350° C. or higher without deteriorating excellent durability of a Ti—V—Mo—P catalyst in view of problems of conventional art.

Abstract: To overcome the problem of a conventional catalyst and to provide an exhaust gas purifying catalyst that meets the requirement concerning Hg oxidation activity and SO2 oxidation activity; i.e., an exhaust gas purifying catalyst which specifically reduces percent SO2 oxidation, while maintaining percent Hg oxidation at a high level. The invention provides an exhaust gas purifying catalyst which comprises a composition containing oxides of (i) titanium (Ti), (ii) molybdenum (Mo) and/or tungsten (W), (iii) vanadium (V), and (iv) phosphorus (P), wherein the catalyst contains Ti, Mo and/or W, and V in atomic proportions of 85 to 97.5:2 to 10:0.5 to 10, and has an atomic ratio of P/(sum of V and Mo and/or W) of 0.5 to 1.

Abstract: An object of the present invention is to provide a method for treating an exhaust gas containing CO2, that can adjust the concentration of an oxidation inhibitor in an absorbent to the concentration enough to inhibit oxidation, without measuring the concentration of the oxidation inhibitor in an alkanolamine contained in a CO2 absorbent. Disclosed are a method and a device for adjusting the compositional ratio of an absorbent, in which absorption and release of carbon dioxide are performed by adding an oxidation inhibitor to an alkanolamine absorbent when the sum of the concentrations of ammonia and an alkylamine in an absorber column outlet gas of a CO2 absorption equipment.

Abstract: An exhaust gas purification catalyst is made as a composition comprising titanium oxide (TiO2), aluminum sulfate (Al2(SO4)3), an oxide of vanadium (V), and an oxide of molybdenum (Mo) and/or tungsten (W), wherein on titanium oxide having sulfate ions and aluminum ions adsorbed thereon obtained by making contact with aluminum sulfate at more than 1 wt % and not more than 6 wt % relative to titanium oxide in the presence of water, an oxo acid salt of vanadium or a vanadyl salt and an oxo acid or an oxo acid salt of molybdenum and/or tungsten are supported in a proportion of more than 0 atom % and not more than 3 atom %, respectively. By this, the degradation of catalyst performance can be suppressed even with exhaust gas containing potassium compounds at a high concentration in combustion ash.

Abstract: To overcome the problem of a conventional catalyst and to provide an exhaust gas purifying catalyst that meets the requirement concerning Hg oxidation activity and SO2 oxidation activity; i.e., an exhaust gas purifying catalyst which specifically reduces percent SO2 oxidation, while maintaining percent Hg oxidation at a high level. The invention provides an exhaust gas purifying catalyst which comprises a composition containing oxides of (i) titanium (Ti), (ii) molybdenum (Mo) and/or tungsten (W), (iii) vanadium (V), and (iv) phosphorus (P), wherein the catalyst contains Ti, Mo and/or W, and V in atomic proportions of 85 to 97.5:2 to 10: 0.5 to 10, and has an atomic ratio of P/(sum of V and Mo and/or W) of 0.5 to 1.

Abstract: Disclosed is a low-thermal-expansion Ni-based super-heat-resistant alloy for a boiler, which has excellent high-temperature strength. The alloy can be welded without the need of carrying out any aging treatment. The alloy has a Vickers hardness value of 240 or less. The alloy comprises (by mass) C in an amount of 0.2% or less, Si in an amount of 0.5% or less, Mn in an amount of 0.5% or less, Cr in an amount of 10 to 24%, one or both of Mo and W in such an amount satisfying the following formula: Mo+0.5 W=5 to 17%, Al in an amount of 0.5 to 2.0%, Ti in an amount of 1.0 to 3.0%, Fe in an amount of 10% or less, and one or both of B and Zr in an amount of 0.02% or less (excluding 0%) for B and in an amount of 0.2% or less (excluding 0%) for Zr, with the remainder being 48 to 78% of Ni and unavoidable impurities.

Abstract: A vertical downflow type flue gas denitrification apparatus which has a plurality of catalyst blocks, each incorporating a catalyst unit provided therein, is provided with a first ash accumulation baffle plate and a second ash accumulation baffle plate which are slidable into a gap between catalyst blocks adjacent to each other, and processes an exhaust gas emitted from a combustor and turned to a vertical downflow. The denitrification apparatus has a simple configuration where the ash accumulation baffle plates prevent ash or the like from being accumulated in the gap between the catalyst blocks. The thermal expansion of the ash accumulation baffle plate can be absorbed even under the operating conditions which produce a change in temperature, and charging and replacing the catalyst in the catalyst blocks are possible without on-site welding of the ash accumulation baffle plates.