Patents Assigned to Babcock-Hitachi Kabushiki Kaisha
  • Patent number: 7922480
    Abstract: The invention provides a combustion apparatus which can inhibit an NOx generation even in the case of promoting a mixing between a high-temperature combustion gas and an air so as to intend to reduce an unburned combustible. In a combustion apparatus provided with a burner burning a fuel within a furnace in a theoretical air ratio or less, and an air port supplying a combustion air for a shortfall in the burner, a supply apparatus for supplying a nitrogen oxide generation inhibiting gas is provided in a mixing region between the both or near the mixing region. Further, the invention provides a wind box which can inhibit an NOx generation even in the case of promoting a mixing between a high-temperature combustion gas and an air so as to intend to reduce an unburned combustible.
    Type: Grant
    Filed: August 27, 2003
    Date of Patent: April 12, 2011
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Kenji Kiyama, Shigeki Morita, Osamu Okada, Koji Kuramashi, Takanori Yano, Kenichi Ochi, Akira Baba, Miki Shimogori, Takeru Fukuchi, Hiroshi Yamaguchi, Hironobu Kobayashi, Masayuki Taniguchi, Hirofumi Okazaki, Kenji Yamamoto
  • Publication number: 20110053102
    Abstract: An air nozzle provided on the outer side of a fuel nozzle of a solid fuel burner is divided into a plurality of regions, and has means for regulating air flow rates in nozzles divided in the upper and lower direction. The nozzles (regions) are connected to only the nozzle wall and have obstacles in the circumferential direction, dividing the inside of the nozzle into a plurality of regions, and by changing air flow rates in the respective regions in the outermost peripheral air nozzle, a deviation in momentum is caused in the vertical direction of the burner, a flame forming position is changed, and a combustion gas temperature at the furnace outlet, temperatures of a heat transfer tube installed on the furnace wall surface and a fluid flowing in the heat transfer tube or temperatures of heat transfer tubes provided in the furnace and a flue on the downstream side and temperatures of fluids flowing in the heat transfer tubes are controlled to be constant.
    Type: Application
    Filed: April 3, 2009
    Publication date: March 3, 2011
    Applicant: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: Hirofumi Okazaki, Kenji Kiyama, Yusuke Ochi, Kouji Kuramashi
  • Publication number: 20110033360
    Abstract: Provided is a method of operating a hydrolytic separator in which ammonia gas to be used as a reducing agent in a flue gas denitrization apparatus is generated by the hydrolysis of an aqueous urea solution. When the hydrolytic separator is started and ammonia gas injection is initiated, the hydrolytic separator is operated in a constant-pressure mode in which the internal pressure of the hydrolytic separator is kept constant regardless of the increasing temperature of the hydrolytic separator. Thereafter, the constant-pressure operation is switched to a variable pressure operation in which the pressure is raised as the temperature of the hydrolytic separator rises. In the method, the constant-pressure operation is switched to the variable pressure operation after the temperature of the hydrolytic separator in the constant-pressure operation has reached or exceeded the variable pressure operation temperature corresponding to that pressure.
    Type: Application
    Filed: May 27, 2009
    Publication date: February 10, 2011
    Applicant: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: Satoru Shishido, Tooru Ogasahara, Yoshiyuki Takeuchi, Yoshinori Nagai
  • Publication number: 20110017355
    Abstract: Disclosed is a ferritic heat-resistant steel which has the following chemical composition (by weight): C: from 0.01% to less than 0.08%; Si: 0.30-1.0%; P: 0.02 or less; S: 0.010% or less; Mn: 0.2-1.2%; Ni: 0.3% or less; Cr: 8.0-11.0%; Mo: 0.1-1.2%; W: 1.0-2.5%; V: 0.10-0.30%; Nb: 0.02-0.12%; Co: 0.01-4.0%; N: 0.01-0.08%; B: not less than 0.001% and less than 0.010%; Cu: 0.3% or less; and Al: 0.010% or less, provided that the chemical composition satisfies the following equations: Mo (%)+0.5×W (%)=1.0-1.6, and C (%)+N (%)=0.02-0.15%, and which comprises a tempered martensite single-phase tissue produced by thermal refining and contains 30% by weight or less of ? ferrite.
    Type: Application
    Filed: October 8, 2010
    Publication date: January 27, 2011
    Applicants: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: Takashi SATO, Kohji TAMURA, Toshio FUJITA
  • Patent number: 7842644
    Abstract: A catalyst is provided having higher mercury oxidation performance than a conventional catalyst without increasing catalyst quantity or enhancing SO2 oxidation performance and constitutes an oxidation catalyst for metal mercury, which contains a molybdenum and vanadium complex oxide, for example, MoV2O8, as a main component having a catalytic activity and is formed by placing the molybdenum and vanadium complex oxide in layers only on the surface of a plate-like or honeycomb-like porous carrier. The porous carrier contains Ti and W and has a function of an NOx removal catalyst as a whole.
    Type: Grant
    Filed: September 21, 2007
    Date of Patent: November 30, 2010
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Keiichiro Kai, Yasuyoshi Kato
  • Patent number: 7833501
    Abstract: A method and apparatus for treating an exhaust gas comprising heavy metals, wherein the apparatus comprises a heat recovery unit, recovering exhaust gas heat at an exit of the air preheater; a precipitator, collecting soot/dust contained in an exhaust gas at an exit of the heat recovery unit; a wet flue gas desulfurizer, removing sulfur oxides contained in the exhaust gas at the exit of the precipitator; and a reheater, heating the exhaust gas at the exit of the wet flue gas desulfurizer. Each of the heat recovery unit and the reheater has a heat exchanger tube, and a circulation line is disposed to connect the heat exchanger tubes. A sulfur trioxide (SO3) removing agent is supplied to the upstream side of the heat recovery unit, and the temperature of the exhaust gas at the exit of the heat recovery unit is adjusted to not more than a dew point of sulfur trioxide.
    Type: Grant
    Filed: December 24, 2007
    Date of Patent: November 16, 2010
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Kazuki Kobayashi, Hirofumi Kikkawa, Hiroshi Ishizaka, Goki Sasaki, Hiroyuki Nosaka
  • Patent number: 7824635
    Abstract: A particulate material removing filter for exhaust gas from a diesel engine is provided. The particulate material removing filter is formed by laminating metal laths having an oxidation catalyst layer containing a noble metal that oxidizes nitrogen oxide in exhaust gas into nitrogen dioxide. The metal laths are laminated to form a laminate in such a manner that the drawing direction of the metal lath processing differs by 90 degrees with each other.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: November 2, 2010
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Yasuyoshi Kato, Eiji Miyamoto, Masatoshi Fujisawa, Naomi Imada, Hiroshi Ishizaka, Kazuki Kobayashi, Takeshi Hirota
  • Publication number: 20100226814
    Abstract: Disclosed is a low-thermal-expansion Ni-based super-heat-resistant alloy for a boiler, which has excellent high-temperature strength. The alloy can be welded without the need of carrying out any aging treatment. The alloy has a Vickers hardness value of 240 or less. The alloy comprises (by mass) C in an amount of 0.2% or less, Si in an amount of 0.5% or less, Mn in an amount of 0.5% or less, Cr in an amount of 10 to 24%, one or both of Mo and W in such an amount satisfying the following formula: Mo+0.5 W=5 to 17%, Al in an amount of 0.5 to 2.0%, Ti in an amount of 1.0 to 3.0%, Fe in an amount of 10% or less, and one or both of B and Zr in an amount of 0.02% or less (excluding 0%) for B and in an amount of 0.2% or less (excluding 0%) for Zr, with the remainder being 48 to 78% of Ni and unavoidable impurities.
    Type: Application
    Filed: August 29, 2008
    Publication date: September 9, 2010
    Applicants: HITACHI METALS, LTD., BABCOCK-HITACHI KABUSHIKI KAISHA, HITACHI, LTD.
    Inventors: Toshihiro Uehara, Takehiro Ohno, Akihiro Toji, Takashi Sato, Gang Bao, Shinya Imano, Hiroyuki Doi
  • Publication number: 20100227180
    Abstract: A spraying material for coating a metallic member, being inexpensive and having superior corrosion and erosion resistance even in high temperature environments, wherein the material is composed of an Fe—Si based compound and comprises an alloy composed of 10 to 35% by weight of Si and the remainder of Fe and inevitable impurities, and further, up to 5% by weight of B may be added to the material in terms of improvement in hardness and adhesiveness of the coating is provided in order to protect components such as heaters and water walls of coal fired boilers and heat exchanger tubes of fluidized bed boilers, etc., from corrosion and erosion. The spraying material is formed into a coating by, for example, high velocity flame spraying or atmospheric plasma spraying.
    Type: Application
    Filed: March 5, 2009
    Publication date: September 9, 2010
    Applicant: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: Toshinari OKAGAITO, Yuji FUKUDA, Yoshitaka KOJIMA
  • Publication number: 20100183492
    Abstract: To overcome the problem of a conventional catalyst and to provide an exhaust gas purifying catalyst that meets the requirement concerning Hg oxidation activity and SO2 oxidation activity; i.e., an exhaust gas purifying catalyst which specifically reduces percent SO2 oxidation, while maintaining percent Hg oxidation at a high level. The invention provides an exhaust gas purifying catalyst which comprises a composition containing oxides of (i) titanium (Ti), (ii) molybdenum (Mo) and/or tungsten (W), (iii) vanadium (V), and (iv) phosphorus (P), wherein the catalyst contains Ti, Mo and/or W, and V in atomic proportions of 85 to 97.5:2 to 10:0.5 to 10, and has an atomic ratio of P/(sum of V and Mo and/or W) of 0.5 to 1.
    Type: Application
    Filed: September 7, 2007
    Publication date: July 22, 2010
    Applicant: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: Yasuyoshi Kato, Keiichiro Kai, Naomi Imada
  • Publication number: 20100162930
    Abstract: Provided is a solid fuel burner (60) suitable for controlling a flame to be formed by combustion of fuel ejected from the burner (60) and a temperature distribution in a furnace, a combustion apparatus using the solid fuel burner (60), and a method of operating the combustion apparatus. Providing in the fuel nozzle (10) a plurality of gas ejection nozzles (81), (82) and a restriction (obstacle) (19) downstream thereof, and ejecting a relatively large amount of gas from a portion of the gas ejection nozzles (81) provides a circumferential distribution in fuel concentration. Further, having the restriction (obstacle) (19) on a downstream side increases a deviation in fuel concentration. Providing a fuel concentration deviation in the circumferential direction makes it possible to change the forming position of a flame.
    Type: Application
    Filed: March 6, 2008
    Publication date: July 1, 2010
    Applicant: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: Hirofumi Okazaki, Koji Kuramashi, Yusuke Ochi, Akira Baba, Takanori Yano
  • Patent number: 7731926
    Abstract: Flue gas of boiler is introduced through gas inlet part of flue-gas desulfurization apparatus, and absorbent liquid sprayed from spray nozzle is trapped in recirculation tank. There, agitation is performed by oxidation agitator to thereby oxidize SO2 absorbed from the flue gas into gypsum. In the tank, oxidation air is fed from posterior air pipe and anterior air pipe behind and ahead of liquid propulsion by the propeller. Thus, even when the amount of oxidation air must be increased in accordance with an increase of boiler load, the oxidation efficiency can be enhanced without increasing the number of agitators. Then the apparatus with which even when the amount of oxidation air fed to the liquid trapping section is increased, highly efficient oxidation can be performed without increasing the number of agitators installed and the operating cost.
    Type: Grant
    Filed: September 20, 2006
    Date of Patent: June 8, 2010
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Naoki Oda, Takanori Nakamoto, Hiroyuki Nosaka
  • Patent number: 7722844
    Abstract: An exhaust smoke denitrating apparatus in which using an NH3 injection unit, compressed air is fed from blower to ejector for extracting of exhaust gas from HRSG1, and with thus obtained mixed gas, NH3-containing gas is produced from NH3 water by NH3 water evaporator, the NH3-containing gas injected through NH3-containing gas injection nozzle of the HRSG1 disposed on a front stream side of denitration catalyst layer. As any high-temperature exhaust gas is cooled and diluted by compressed air, there is no danger of oxidation of NH3 during the stage of evaporation of NH3 water. The moisture level of exhaust gas can be lowered, thereby enabling inhibition of any drain generation in exhaust gas extraction piping. Air warming within NH3 water evaporation system can be carried out at an early stage.
    Type: Grant
    Filed: December 10, 2004
    Date of Patent: May 25, 2010
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Ryosuke Nakagawa, Tetsurou Hikino
  • Publication number: 20100116126
    Abstract: A system is provided that prevents inhibition of adsorption of Hg and other heavy metals by activated carbon or other heavy metal adsorbent due to prior adsorption of sulfur trioxide (SO3) in an exhaust gas containing SO3. As it has been found that while SO3 is adsorbed, the adsorption of SO3 precedes the adsorption of Hg and other heavy metals onto activated carbon, a basic substance injection system is disposed along an exhaust gas flow channel at an upstream side of an activated carbon injection system, thereby attaining effective removal of Hg and other heavy metals from the exhaust gas by adsorption thereof onto surface pores of the activated carbon. The SO3 concentration after removal by basic substance conversion is computed from the SO3 concentration before removal, and the activated carbon injection rate can be controlled based on the concentration after removal.
    Type: Application
    Filed: April 11, 2008
    Publication date: May 13, 2010
    Applicant: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: Jun Shimamura, Takanori Nakamoto, Toshio Katsube, Hirofumi Kikkawa, Hiroyuki Nosaka, Takayuki Saitou, Yoshinori Taguchi, Hiroshi Ishizaka
  • Patent number: 7691349
    Abstract: An exhaust gas processing method using a device having an air preheater for preheating air for combustion in a combustion device by using an exhaust gas emitted from the combustion device; a gas-gas heater (GGH) heat recovery device composed of a heat transfer tube for recovering the heat of the exhaust gas to a heat medium; a dust collector; a wet-type desulfurization device; a gas-gas heater (GGH) re-heater composed of a heat transfer tube for heating the exhaust gas at its outlet by using the heat medium supplied from the gas-gas heater heat recovery device, which are installed in that order from the upstream to the downstream of an exhaust gas duct of the combustion device.
    Type: Grant
    Filed: May 8, 2008
    Date of Patent: April 6, 2010
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Kouji Muramoto, Takayuki Saitou, Hiromichi Shimazu, Takanori Nakamoto, Toshio Katsube
  • Publication number: 20100077925
    Abstract: In an absorbing tower including an absorption unit of relatively small diameter capable of absorption and removal by an absorbent slurry for exhaust gas purification and a tank unit of relatively large diameter for temporarily storing the absorbent slurry flowing down from the absorption unit, the tank unit and the absorption unit are joined together by a conical member. By disposing an entrance flue at the conical member, a distance from an upper portion of the conical member to a spray header is shortened, and a height of the absorbing tower can be reduced accordingly. By extending a front end of the entrance flue to the absorption unit into which droplets of the absorbent slurry fall, a high-temperature exhaust gas from a boiler, etc., that has passed through the entrance flue, is made to pass through a circumference of the conical member so that an inexpensive material can be used in the conical member.
    Type: Application
    Filed: September 19, 2007
    Publication date: April 1, 2010
    Applicant: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: Tomoyuki KONISHI, Takanori NAKAMOTO, Kouji MURAMOTO, Hiroyuki NOSAKA, Atsushi KATAGAWA, Takuro UEDA
  • Publication number: 20100071348
    Abstract: After adjusting an exhaust gas temperature at an exit of a heat recovery unit (11) of an exhaust gas treating apparatus to not more than a dew point temperature of sulfur trioxide (SO3), a heavy metal adsorbent is supplied from a heavy metal adsorbent supply unit (16) disposed in an exhaust gas at an entrance of a precipitator (4) or an intermediate position within the precipitator (4), and the exhaust gas containing the heavy metal adsorbent is supplied into the precipitator (4). Preferably at this stage, the heavy metal adsorbent is supplied into the exhaust gas at the entrance of the precipitator (4) 0.1 seconds after the exhaust gas temperature at the exit of the heat recovery unit (11) has been adjusted to not more than the dew point temperature of SO3.
    Type: Application
    Filed: December 24, 2007
    Publication date: March 25, 2010
    Applicant: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: Kazuki Kobayashi, Hirofumi Kikkawa, Hiroshi Ishizaka, Hiroshi Takezaki, Hiroyuki Nosaka
  • Publication number: 20100074817
    Abstract: The following devices are successively disposed in the following order from an upstream side to a downstream side in an exhaust gas duct of a combustion apparatus: an air preheater, preheating combustion air for use in an exhaust gas treating apparatus; a heat recovery unit, recovering exhaust gas heat at an exit of the air preheater; a precipitator, collecting soot/dust contained in an exhaust gas at an exit of the heat recovery unit; a wet flue gas desulfurizer, removing sulfur oxides contained in the exhaust gas at the exit of the precipitator; and a reheater, heating the exhaust gas at the exit of the wet flue gas desulfurizer. Each of the heat recovery unit and the reheater has a heat exchanger tube, and a circulation line is disposed to connect the heat exchanger tubes. A sulfur trioxide (SO3) removing agent is supplied to the upstream side of the heat recovery unit, and the temperature of the exhaust gas at the exit of the heat recovery unit is adjusted to not more than a dew point of sulfur trioxide.
    Type: Application
    Filed: December 24, 2007
    Publication date: March 25, 2010
    Applicant: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: Kazuki Kobayashi, Hirofumi Kikkawa, Hiroshi Ishizaka, Goki Sasaki, Hiroyuki Nosaka
  • Publication number: 20100064986
    Abstract: The present invention provides a solid fuel burner, which, while rendering the capacity larger than that in the conventional art, can suppress an increase in an unignited region and thus can realize the prevention of an increase in NOx concentration in a combustion gas and the prevention of a lowering in combustion efficiency, and a combustion equipment and boiler including the burner. The burner includes a fuel-containing fluid supply nozzle (12) which supplies a fuel-containing fluid, from a connecting part in a fluid transfer flow passage (10) for transferring a fuel-containing fluid including a fuel and a medium for transfer of the fuel, toward an outlet part provided on the wall of a furnace (4).
    Type: Application
    Filed: March 27, 2007
    Publication date: March 18, 2010
    Applicant: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: Kenji Kiyama, Akira Baba, Takanori Yano, Osamu Okada, Hirofumi Okazaki, Kouji Kuramashi
  • Patent number: 7655064
    Abstract: A particulate matter-removing filter being resistant to clogging and ash blocking, requiring no special means such as back-washing and heating combustion, and being formed of inexpensive materials; and exhaust emission controlling method and device using this. (1) A particulate-matter-containing exhaust emission controlling filter which uses as a basic unit a pair of porous corrugated sheet and a porous flat sheet that support an exhaust emission controlling catalyst, has a molding formed by laminating the porous corrugated sheets so that their ridge lines alternately cross perpendicularly, has one of side surfaces, perpendicularly crossing the corrugated sheet ridge lines, of the molding or mutually-adjoining two surfaces that are the perpendicularly-crossing side surfaces sealed, and has exhaust gas in-flow passage and out-flow passage respectively formed between porous corrugated sheets via a porous flat sheet.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: February 2, 2010
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Yasuyoshi Kato, Takashi Michimoto, Eiji Miyamoto, Naomi Imada, Masatochi Fujisawa, Kazuki Kobayashi, Hiroshi Ishizaka, Takeshi Hirota