Abstract: A method is provided for operating a fuel cell stack with improved performance recovery from sub-saturated conditions, the method comprising setting an alert for the performance recovery of the fuel cell stack, performing at least one oxidant starvation by supplying oxidant at a stoichiometric ratio below 1 to the fuel cell stack in at least one pulse for a preset amount of time and at low current while the fuel cell stack does not generate power. The fuel cell system with an improved performance recovery comprises a shorting circuit which is connected to the fuel cell stack at predetermined times (startup, shutdown or standby mode) and an air compressor powered by a DC-DC converter which supplies a predetermined number of oxidant pulses of a predetermined duration to the fuel cell stack.

Abstract: A membrane electrode assembly comprises an anode electrode comprising an anode catalyst layer and an anode gas diffusion layer, a cathode electrode comprising a cathode catalyst layer and a cathode gas diffusion layer, a polymer electrolyte membrane interposed between the anode catalyst layer and the cathode catalyst layer, and a layer comprising a fluoroalkyl-phosphonic acid compound between at least one of the anode gas diffusion layer and the anode catalyst layer, the anode catalyst layer and the polymer electrolyte membrane, the polymer electrolyte membrane and the cathode catalyst layer, and the cathode catalyst layer and the cathode gas diffusion layer.

Abstract: A membrane electrode assembly comprises a polymer electrolyte interposed between an anode electrode and a cathode electrode, the anode electrode comprising an anode catalyst layer adjacent at least a portion of a first major surface of the polymer electrolyte, the cathode electrode comprising a cathode catalyst layer adjacent at least a portion of a second major surface of the polymer electrolyte; at least one of the anode and cathode catalyst layers comprising: a first catalyst composition comprising a noble metal; and a second composition comprising a metal oxide; wherein the second composition has been treated with a fluoro-phosphonic acid compound.

Abstract: A membrane electrode assembly comprises an anode electrode comprising an anode catalyst layer; a cathode electrode comprising a cathode catalyst layer; and a polymer electrolyte membrane interposed between the anode electrode and the cathode electrode; wherein at least one of the anode and cathode catalyst layers comprises a block co-polymer comprising poly(ethylene oxide) and poly(propylene oxide).

Abstract: A solid polymer electrolyte fuel cell comprises a membrane electrode assembly comprising a polymer electrolyte disposed between an anode electrode and a cathode electrode, the anode and cathode electrodes each comprising a catalyst, a central region and a peripheral region, wherein the peripheral region of the cathode electrode comprises a cathode edge barrier layer; a fluid impermeable seal in contact with at least a portion of the anode and cathode peripheral regions and the cathode edge barrier layer; an anode flow field plate adjacent the anode electrode; and a cathode flow field plate adjacent the cathode electrode, wherein the cathode flow field separator plate comprises a cathode peripheral flow channel and at least one cathode central flow channel; wherein at least a portion of the cathode edge barrier layer traverses at least a portion of the cathode peripheral flow channel.

Abstract: A membrane electrode assembly including: an anode electrode; a cathode electrode; and a polymer electrolyte membrane; wherein the cathode includes a first cathode catalyst sublayer including a first precious metal catalyst composition and a first ionomer composition including a first ionomer and a second ionomer; and a second cathode catalyst sublayer including a second precious metal catalyst composition and a second ionomer composition including a third ionomer; wherein the first ionomer is different from the second ionomer in at least one of chemical structure and equivalent weight.

Abstract: A sealed membrane electrode assembly (MEA) and a method of sealing the MEA comprises the steps of providing a frame around a periphery of the MEA to form a framed MEA; providing a through-hole in the frame; placing the framed MEA into a seal mold, the seal mold comprising a reservoir region, a seal bead region, and at least one runner region; feeding a flow-processable seal material into the reservoir region in the seal mold that is aligned with the throughhole in the frame; feeding the flow-processable seal material from the reservoir region to the seal bead region through the at least one runner region; wherein a hydraulic diameter of the at least one runner region is less than a hydraulic diameter of the reservoir region.

Abstract: Systems and methods to provide a low voltage interface coupleable between an energy storage device or a DC power source (e.g., fuel cell stack, battery) and one or more AC signal diagnostic systems. The low voltage interface reduces a voltage of the DC power source and supplies the reduced voltage to the one or more AC signal diagnostic systems without affecting the results of the measurements obtained by the one or more AC signal diagnostic systems. Such functionality provides a safer method for performing advanced analysis (e.g., EIS, frequency analysis) while utilizing lower cost and/or smaller components.

Abstract: A fuel cell stack assembly is disclosed comprising: a fuel cell stack comprising a first end plate, a second end plate, and a plurality of fuel cells interposed between the first and the second end plates; and a compression band which urges the first end plate towards the second end plate along a first face of the fuel cell stack and also along an opposing second face of the fuel stack in a stacking direction thereof in at least two passes on each face of fuel cells stack, thereby applying a compressive force upon the plurality of fuel cells in the fuel cell stack.

Abstract: Methods for detecting a hydrogen leak and quantifying a rate of the same in a polymer electrolyte membrane fuel cell stack are provided, as well as a fuel cell diagnostic apparatus that diagnoses a hydrogen leak in a fuel cell stack.

Abstract: A flow field plate comprises a first flow field; an opposing second flow field; and at least one flow channel formed in the first flow field, the at least one flow channel comprising: a first side and an opposing second side separated by an open-faced top and a bottom; and a first side channel formed in a portion of the open-faced top and in a portion of the first side along a continuous length of the at least one flow channel, the first side channel comprising a first side wall and a first bottom wall; wherein the first side wall of the first side channel and the first bottom wall of the first side channel form an obtuse angle in cross-section; and a depth of the bottom of the at least one flow channel is greater than a depth of the bottom wall of the first side channel.

Abstract: The bootstrap start-up system (42) achieves an efficient start-up of the power plant (10) that minimizes formation of soot within a reformed hydrogen rich fuel. A burner (48) receives un-reformed fuel directly from the fuel supply (30) and combusts the fuel to heat cathode air which then heats an electrolyte (24) within the fuel cell (12). A dilute hydrogen forming gas (68) cycles through a sealed heat-cycling loop (66) to transfer heat and generated steam from an anode side (32) of the electrolyte (24) through fuel processing system (36) components (38, 40) and back to an anode flow field (26) until fuel processing system components (38, 40) achieve predetermined optimal temperatures and steam content. Then, the heat-cycling loop (66) is unsealed and the un-reformed fuel is admitted into the fuel processing system (36) and anode flow (26) field to commence ordinary operation of the power plant (10).

Abstract: An anode exhaust recycle turbocharger (100) has a turbocharger turbine (102) secured in fluid communication with a compressed oxidant stream within an oxidant inlet line (218) downstream from a compressed oxidant supply (104), and the anode exhaust recycle turbocharger (100) also includes a turbocharger compressor (106) mechanically linked to the turbocharger turbine (102) and secured in fluid communication with a flow of anode exhaust passing through an anode exhaust recycle loop (238) of the solid oxide fuel cell power plant (200). All or a portion of compressed oxidant within an oxidant inlet line (218) drives the turbocharger turbine (102) to thereby compress the anode exhaust stream in the recycle loop (238). A high-temperature, automotive-type turbocharger (100) replaces a recycle loop blower-compressor (52).

Abstract: A fuel cell stack formed of repeating cell units is provided wherein each cell unit includes a fuel cell having an anode side and a cathode side; an anode side frame; a cathode side frame; a bipolar plate having an anode side interconnect adjacent to the anode side frame and a cathode side interconnect adjacent to a cathode side frame of an adjacent cell unit; a cathode side seal between the fuel cell and the cathode side frame; and an anode side seal between the fuel cell and the anode side frame, wherein at least one of the anode side interconnect, cathode side interconnect, anode side seal and cathode side seal are compliant.

Abstract: In solid polymer fuel cells employing framed membrane electrode assemblies, a conventional anode compliant seal is employed in combination with a cathode non-compliant seal to provide for a thinner fuel cell design, particularly in the context of a fuel cell stack. This approach is particularly suitable for fuel cells operating at low pressure.

Abstract: An object of the present invention is to provide a production method which can increase the activity of a catalyst particle comprising a core particle and an outermost layer, the core particle comprising at least one of palladium and a palladium alloy, and the outermost layer comprising at least one of platinum and a platinum alloy and covering the core particle.

Abstract: A system and method satisfies temperature and pressure requirements of solid oxide fuel cell system 10 in a manner that increases the overall efficiency and decreases the overall weight of system 10. The system and method include a secondary blower 30 for boosting air stream pressure level sufficient for operation of a reformer 12 that is designed to minimize pressure drop; an integrated heat exchanger 18 for recovering heat from exhaust 36 and comprising multiple flow fields 18A, 18B, 18C for ensuring inlet temperature requirements of a solid oxide fuel cell 14 are met; and a thermal enclosure 46 for separating hot zone 48 components from cool zone 50 components for increasing thermal efficiency of the system and better thermal management.

Abstract: An electrochemical device includes a ceramic electrode, a metallic interconnect, and a ceramic bond material that bonds the ceramic electrode and the metallic interconnect together. The ceramic material includes manganese-cobalt-oxide that is electrically conductive such that electric current can flow between the ceramic electrode and the metallic interconnect.

Abstract: An exemplary fuel cell component comprises a reactant distribution plate including a plurality of channels configured for facilitating gas reactant flow such that the gas reactant may be used in an electrochemical reaction for generating electricity in a fuel cell. Each of the channels has a length that corresponds to a direction of reactant gas flow along the channel. A width of each channel is generally perpendicular to the length. A depth of each channel is generally perpendicular to the width and the length. At least one of the width or the depth has at least two different dimensions at a single lengthwise location of the channel.

Abstract: A controller (11a) of a DC/DC converter (10a) responsive to power output of a fuel cell power plant (13) operates under a control strategy which determines if fuel cell voltage exceeds a limit, and if so, provided neither fuel cell output current nor DC/DC converter output current is excessive, causes an increase in DC/DC converter duty cycle to thereby increase power demanded from the fuel cell stack. This eliminates the need for conventional voltage limiting to protect fuel cells from corrosion. Digital control loops and state machines are illustrated.