Abstract: An aqueous ionomer gel having a high viscosity, particularly a proton conducting ionomer, as well as to related products incorporating such gels. Such aqueous ionomer gels are suitable for suspending catalysts for formation of catalyst inks, which in turn are suitable for screen printing on a variety of surfaces. Representative surfaces are the electrode or membrane surfaces in an electrochemical fuel cell. Methods for making aqueous ionomer gels are also disclosed.

Abstract: In a liquid feed fuel cell system, substantially pure fuel needs to be added to a dilute mixture of fuel in water so as to maintain the fuel concentration at an appropriate level for use with the fuel cell system. Under passive control of the fuel concentration, a first equilibrium concentration is established between the substantially pure fuel and a fuel transfer medium. A second equilibrium concentration is then established between the fuel transfer medium and the dilute mixture for use with the fuel cell system. The system is “passive” as it does not rely on the measurement of the fuel concentration and direct injection of fuel. The fuel transfer medium can be solid, liquid or gas.

Abstract: The invention relates to an ion-conductive polymer membrane for a fuel cell, whereby the polymer membrane is configured from a polymer-forming hydrocarbon material and to a method for producing the same. The membrane also has a metal-containing gel which has been hydrolysed and/or condensed from a metal alkoxide starting material and which is deposited in the polymer and/or is chemically bonded to the polymer. The proportion of metal alkoxide by weight, in relation to the membrane, lies between 25% and 1%.

Abstract: A solid polymer electrolyte fuel cell stack having a plurality of fuel cells, wherein at least one cell of the fuel cell stack has a resistance to corrosion that is greater than a significant portion of the other fuel cells of the stack. In one embodiment, the at least one fuel cell of the fuel cell stack that is more resistant to corrosion is one or both end cells of the stack. Also disclosed is a fuel cell system containing such a stack, as well as methods for reducing degradation of the same during operation.

Abstract: A black start operation employs the accumulation of power resulting from a reaction of fuel and ambient oxidant passively seeped or diffused into a fuel cell stack to bootstrap the fuel cell system operation.

Abstract: In a method and apparatus for cutting expanded graphite sheet material, at least one cutting tool is urged against the sheet(s). The cutting tool has at least one ridge extending therefrom that includes a substantially tapered cross-section having sloping sides and an edge surface. At least a portion of the sheet material is displaced as the ridge is urged against the sheet. A region of the sheet material in contact with the ridge is compressed so that the density of the region reaches or exceeds the breaking density of the sheet.

Abstract: The invention relates to a metal bipolar plate for a fuel cell, provided with a low-ohmic chemically stable coating. According to the invention, said coating is a multi-phase coating, at least in the region of the contacting outer surface thereof. One phase is a metal phase and/or ? phase belonging thereto and another phase is a compound phase consisting of one or several metals of the metal phase and one of the elements N,O,C,B.

Abstract: A fuel cell system includes a fuel cell stack, a battery, and a control system. A power circuit couples the fuel cell system selectively between the fuel cell stack and the battery. The power circuit includes a battery supply switch responsive to a voltage across the fuel cell stack, and a stack supply switch responsive to an operating state of the fuel cell system. The battery supply switch uncouples the battery from an on-board power supply when a voltage across the fuel cell stack exceeds a first threshold voltage and couples the battery to the on-board power supply when the fuel cell stack voltage is less than a second threshold voltage. The stack supply switch couples power the fuel cell stack to the on-board power supply when in a running state. A diode-OR circuit couples the source with the highest potential to the on-board power supply.

Abstract: A fuel cell fluid distribution layer, in one embodiment, comprises perforated graphite foil. The fluid distribution layer can have one or more reactant flow field channels formed in one or both major surfaces, one or more manifold openings, conductive filler on one or both major surfaces, conductive filler at least partially filling some or all perforations and/or an electrocatalyst one or both major surfaces.

Abstract: An electrochemical power generation system includes a fuel cell stack having an oxidant delivery system, an oxygen sensor for measuring the oxygen concentration of ambient air in the vicinity of the power generation system, and a hydrogen concentration sensor for measuring a hydrogen concentration in the ambient air in the vicinity of the power generation system. A controller is configured to cease operation of the power generation system, for example ceasing delivery of fuel to the fuel cell stack, when either the hydrogen concentration measured by the hydrogen concentration sensor exceeding a hydrogen concentration threshold or the oxygen concentration measured by the oxygen sensor falling below an oxygen concentration threshold.

Abstract: A purge system for fuel cell stack includes a purge valve to regulate exhaust from the fuel cell stack in response control signals from a controller in response to a voltage across a purge cell portion of a fuel cell stack. The purge valve is opened when the voltage across the purge cell portion falls below a defined percentage of a threshold voltage. The threshold voltage can be equal to an average cell voltage of some or all of the fuel cells of the fuel cell stack. The purge may include one or more successive openings of the purge valve of controlled purge durations.

Abstract: A respective bipolar junction transistor is coupled across pairs of fuel cells in a fuel cell stack to monitor the voltage across each fuel cell pairs for a drop in voltage below a threshold voltage. A respective optoisolator coupled to each of the transistors produces a digital signal corresponding to the status of the respective pair of fuel cells. An “AND” circuit produces a single digital signal corresponding to the status of one or more pairs of fuel cells.

Abstract: An electrochemical fuel cell stack with improved reactant manifolding and sealing includes a pair of separator plates interposed between adjacent membrane electrode assemblies. Passageways fluidly interconnecting the anodes to a fuel manifold and interconnecting the cathodes to an oxidant manifold are formed between adjoining non-active surfaces of the pairs of separator plates. The passageways extend through one or more ports penetrating the thickness of one of the plates thereby fluidly connecting the manifold to the opposite active surface of that plate, and the contacted electrode. The non-active surfaces of adjoining separator plates in a fuel cell stack cooperate to provide passageways for directing both reactants from respective stack fuel and oxidant supply manifolds to the appropriate electrodes. The fuel and oxidant reactant streams passageways are fluidly isolated from each other, although they both traverse adjoining non-active surfaces of the same pair of plates.

Abstract: In a solid polymer fuel cell series, various circumstances can result in the fuel cell being driven into voltage reversal. For instance, cell voltage reversal can occur if that cell receives an inadequate supply of fuel (for example, fuel starvation). In order to pass current during fuel starvation, reactions other than fuel oxidation may take place at the fuel cell anode, including water electrolysis and oxidation of anode components. The latter may result in significant degradation of the anode. Such fuel cells can be made more tolerant to cell reversal by promoting water electrolysis over anode component oxidation at the anode. This can be accomplished by incorporating a catalyst composition at the anode to promote the water electrolysis reaction, in addition to the typical anode electrocatalyst for promoting fuel oxidation.

Abstract: In the present fuel cell systems, fuel cell stacks operate on a fuel stream having a pressure that is below the pressure of the surrounding environment, for example below atmospheric pressure. In the event of a leak, the fuel stream will not escape to the surrounding atmosphere, but rather gases from the surrounding environment will leak into the fuel stream. The fuel stream generally cannot exit the fuel cell stack during normal operation. The fuel cell stack may be periodically purged by increasing the pressure of the fuel stream above the pressure of the surrounding environment and by permitting exit through the fuel stream outlet. A monitoring device can be employed to determine when to purge the fuel cell stack.

Abstract: In an improved electrochemical fuel cell assembly, a reactant flow path extends substantially linearly across the electrochemically active area of an electrode. The electrode has an in-plane nonuniform structure in its electrochemically active area as the active area is traversed in the direction of the substantially linear reactant flow path. Embodiments in which the structure of the fuel cell electrode varies substantially symmetrically along the reactant flow path are particularly preferred in fuel cells in which the flow direction of a reactant is periodically reversed.

Abstract: An electric power generating system is provided that comprises a fuel cell stack having at least one solid polymer fuel cell, a cooling system having a coolant flow path that directs coolant to and from the stack, a fuel regulating system having a fuel flow path and for regulating the supply of fuel from a fuel supply to the stack via the fuel flow path, and a hydrogen concentration sensor. The sensor is located in the vicinity of the fuel regulating system and in the coolant flow path at a location downstream of the stack to detect hydrogen that may have been discharged by components of the power generating system in the coolant flow path upstream of the sensor, or by the fuel regulating system. In the event the measured hydrogen concentration exceeds a threshold level, steps are taken to reduce or stop the discharge of hydrogen from the power generating system.

Abstract: A significant problem in PEM fuel cell durability is in premature failure of the ion-exchange membrane and in particular by the degradation of the ion-exchange membrane by reactive hydrogen peroxide species. Such degradation can be reduced or eliminated by the presence of an additive in the anode, cathode or ion-exchange membrane. The additive may be a radical scavenger, a membrane cross-linker, a hydrogen peroxide decomposition catalyst and/or a hydrogen peroxide stabilizer. The presence of the additive in the membrane electrode assembly (MEA) may however result in reduced performance of the PEM fuel cell. Accordingly, it may be desirable to restrict the location of the additive to locations of increased susceptibility to membrane degradation such as the inlet and/or outlet regions of the MEA.

Abstract: Radio frequency identification (RFID) devices may be used to monitor various operating parameters in fuel cells. For example, RFID devices may be used to monitor the voltage of individual cells in a fuel cell stack and thus to check for voltage reversal conditions during stack operation.

Abstract: A membrane electrode assembly has two gas diffusion layers, two catalyst layers and an ion-exchange membrane interposed therebetween wherein the ion-exchange membrane is cast from a sulphonated polyether ketone/sulfone ionomer. Specifically, the ionomer can be represented as A-B-C wherein Further x, y, z represent the mole ratios of each moiety in the ionomer such that x is between 0.25 and 0.40; y is between 0.01 and 0.26; and z is between 0.40 and 0.67. Melt viscosity of the corresponding base polymer also affects performance in the fuel cell, particularly at values over 0.4 kNsm?2 as measured at 400° C., 1000 s?1. In preparing the membrane electrode assembly, the catalyst layers may be coated directly on the membrane and then bonded with two gas diffusion layers.