Abstract: Compositions of elastoplastic ionomeric polymers having hardness below 92 points Shore A. comprising polar elastomers (10-45 wt. %), such as polyacrylic and nitrile rubbers, apolar crystalline polyolefins (15-40 wt. %) and elastoplastic polyolefins (25-75 wt. %). These compositions are used for making single-layer and multilayer laminar products that can be bonded by radio-freqeuncy welding, and manufactured articles possessing antistatic properties.

Abstract: A process for preparing spherical support particles used in the preparation of catalytic components for the polymerization of olefins by (a) forming an emulsion of an adduct of a Mg dihalide and a Lewis base compound in a liquid medium, and (b) cooling the emulsion by transferring it into a cooling bath containing a cooling liquid in motion wherein the cooling liquid is moving inside a tubular zone and the ratio Ve/Vref of the velocity (Ve) of the emulsion coming from step (a) to the velocity of the cooling liquid (Vref) of step (b) is between 0.25 and 4. The resulting spherical support particles have a very narrow size distribution and particularly regular morphology.

Abstract: Polymers containing N-phenylimide groups are made by reacting polymers containing succinic or glutaric anhydride groups with a substituted or unsubstituted aminobenzoic acid in a devolatilizing extruder at a barrel temperature of about 180° to about 320° C., whereby complete decarboxylation takes place during the formation of the N-phenylimide groups.

Abstract: The present invention relates to a solid catalyst component for the polymerization of olefins CH2?CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from substituted succinates of a particular formula. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.

Abstract: A catalyst system for the polymerization of olefins comprising the product obtained by contacting: (A) at least one transition metal organometallic compound, pyrrolidyl bis(?-cyclopentadienyl)methylzirconium being excluded, and (B) an organometallic compound obtained by contacting: a) a Lewis base having formula (I): ?wherein Ra, Rb, Rc and Rd, equal to or different from each other, are selected from the group consisting of hydrogen, halogen, linear or branched, saturated or unsaturated, C1-C10 alkyl, C6-C20 aryl, C7-C20 arylalkyl and C7-C20 alkylaryl groups; with b) a Lewis acid of formula (II) MtR13??(II) ?wherein Mt is a metal belonging to Group 13 of the Periodic Table of th Elements; R1, equal to or different from each other, are selected from the group consisting of halogen, halogenated C6-C20 aryl and halogenated C7-C20 alkylaryl groups; and (C) optionally an alkylating agent.

Abstract: The present invention relates to catalyst components for the polymerization of olefins comprising Mg, Ti, halogen and at least two electron donor compounds, said catalyst component being characterized by the fact that at least one of the electron donor compounds, present in an amount from 20 to 50% by mol with respect to the total amount of donors, is selected from esters of succinic acids which are not extractable, for more than 25% by mol and at least another electron donor compound which is extractable, for more than 35%. The said catalyst component are capable to give polymers with high xylene insolubility, high stereoblock content and broad MWD suitable for making the polymers usable in the BOPP sector.

Abstract: Ethylene based polymers having high molecular weights can be obtained in high yields at temperatures of industrial interest, by carrying out the polymerization reaction in the presence of catalysts comprising silicon bridged metallocenes having a particular ligand system containing a heteroatom.

Abstract: The present invention relates to a solid catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from substituted succinates of a particular formula. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.

Abstract: An apparatus for gas-phase catalytic polymerization comprising a first vertical reactor (1), a second vertical reactor (2), the upper region of said reactor (1) being connected by a connecting part (3) to a solid as separator (4), which is in turn connected to the upper region of second reactor (2), the lower region of second reactor (2) being connected to the lower region of first reactor (1) by a connecting part (5), the solid/gas separator (4) being connected through a recycle line (6) to one or more points of reintroduction into connecting part (5) or into reactor (1), the apparatus having a line (12) for feeding catalyst into reactor (1), a polymer discharge system (11) from reactor (2), a line (13) for feeding monomers, the apparatus being further characterized in that it comprises a line (15) for feeding gas or liquid into reactor (2).

Abstract: Polypropylene sheet for thermoforming having at least one layer comprises a propylene polymer containing at least 0.8% by weight of ethylene and, optionally, one or more C4-C10 &agr;-olefins, or a propylene polymer composition containing at least 0.8% by weight of one or more comonomers selected from the group consisting of ethylene and C4-C10 &agr;-olefins, and having I) a melting temperature of 155° C. or higher; and II) a xylene soluble fraction at room temperature lower than 4% by weight, and a value of the ratio of the polymer fraction collected at 25° C. to 95° C. to the xylene soluble fraction higher than 8.

Abstract: A fluorine-containing graft copolymer is made from a backbone of an olefin polymer material to which is graft polymerized (a) at least one gaseous fluorinated monomer such as vinylidene fluoride, (b) at least one fluorinated acrylic acid or ester, (c) a mixture of (a) and (b), or (d) a mixture of (a) and/or (b) and a non-fluorinated monomer such as methyl methacrylate. An organic peroxide or a polymeric peroxide is used as the initiator for the graft polymerization process. The graft copolymers have improved surface properties and oxygen barrier properties, and improved thermal stability.

Abstract: Olefin polymers produced using components of catalysts obtained by contacting a Ti compound of formula Ti(OR)n-yXy, where n is the valence of titanium and y is a number between 1 and n, with a pre-polymer having a porosity higher than 0.3 cc/g and containing from 0.5 to 100 g of polymer per g of solid catalyst component, the pre-polymer being obtained by (co)polymerizing an olefin or a diolefin in the presence of a catalyst comprising a Ti, V, Zr or Hf compound supported on a Mg dihalide having a mean crystallite dimension lower than 30 nm.

Abstract: The thermal stability of graft copolymers can be improved by blending (1) a graft copolymer comprising a backbone of a propylene polymer material having graft polymerized thereto a monomer selected from the group consisting of (a) an ester of an acrylic acid substituted at the alpha carbon atom by a 1-3 alkyl group and (b) a combination of (i) an ester of an acrylic acid substituted at the alpha carbon atom by a 1-3 alkyl group and (ii) an ester of an unsubstituted acrylic acid, or an acrylic acid substituted at the alpha carbon atom by a 1-3 carbon alkyl group and (2) about 1 weight % to about 25 weight % of a fluorinated olefin polymer, wherein the ratio of the polymerized monomer to the fluorinated olefin polymer is about 25:1 to about 0.5:1.

Abstract: Disclosed are catalysts for the polymerization of alpha-olefins which comprise the reaction product of: (a) an Al-alkyl compound; (b) a silicon compound containing at least one Si—OR or Si—OCOR or Si—NR2 bond, R being a hydrocarbyl radical; (c) a solid comprising, as essential support, a Mg dihalide in active form and, supported thereon, a Ti halide or a halo-Ti-alcoholate and a particular type of electron donor compound. The present invention refers to new supported components of catalysts for the polymerization of CH2═CHR olefins wherein R is an alkyl radical with 1 to 4 carbon atoms, or an aryl radical, and mixtures of said olefins with ethylene and the catalysts obtained from said components.

Abstract: A process is provided for the preparation of a solid catalyst component for the polymerization of olefins, comprising continuously feeding a liquid containing a titanium compound having at least one titanium-halogen bond into a vessel containing a solid comprising a magnesium halide and continuously discharging liquid from the vessel, whereby the concentration of the solid is maintained within the range of between 80 and 300 g/l, and the product between the average residence time of the liquid in the vessel and the concentration of the solid is maintained below 10,000 min*g/l. An advantage of the process is the reduced time and reactor volume necessary to prepare the catalysts, which show good activity and stereospecificity.

Abstract: A new class of methylene-bridged metallocenes of formula (I), wherein M is a transition metal of group 3, 4, 5, 6, lanthanide or actinide; X is a monoanionic sigma ligand; R1 can be alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl radicals; R2 can be halogen, alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl radical; p is 0-3; m is 0-2; and n is 0-4. Furthermore, the corresponding ligands, a new process for their preparation and catalysts systems containing said methylene-bridged metallocenes are described.

Abstract: Polypropylene molding composition for the production of moldings having a decorative surface A polypropylene molding composition containing from 0.3 to 3% by weight of carbon fibers having a fiber length of from 0.5 to 18 mm can be converted into moldings having a decorative surface. These moldings are used, in particular, in the interior of motor vehicles, but are also suitable for other applications.

Abstract: A polyolefin composition suitable for preparing single ply roofing membranes, comprising: (A) from about 15 to about 40% by weight of a crystalline copolymer of propylene with at least one alpha-olefin of formula H2C═CHR1, where R1 is H or a C2−8 linear or branched alkyl, containing at least about 90% by weight of propylene, having solubility in xylene at room temperature lower than about 15% by weight; (B) from about 60 to about 85% by weight of an elastomeric fraction comprising: (1) a copolymer of propylene with ethylene containing about 20 to about 35% by weight ethylene, and having solubility in xylene at room temperature greater than about 70% by weight, the intrinsic viscosity of the xylene soluble fraction being higher than about 3.0 dl/g up to about 6.

Abstract: Irradiated, oxidized olefin polymer dispersing aids for use in the manufacture of additive concentrates and additive-containing olefin polymer compositions.

Abstract: Multilayer heat-shrinkable films in which the skin layers A consist of a polyolefin selected from: A1) a composition containing 25-45% b.w. of a random copolymer of propylene with ethylene and 55-75% b.w. of a random terpolymer of propylene, ethylene and one or more C4-C10 alpha-olefins; and A2) random copolymer(s) of propylene and one or more C4-C10 alpha-olefins. Core layer B comprises a heterophasic composition comprising: a) 20-60% b.w. of a propylene homopolymer with an isotacticity index higher than 80 or of a propylene crystalline copolymer with ethylene and/or C4-C10 alpha-olefins containing at least 85% b.w. of propylene units and having an isotacticity index of at least 80 or of mixtures thereof and b) 40-80% b.w. of an ethylene copolymer with propylene and/or 1-butene and possibly a diene, containing 20-60% b.w. of ethylene units and completely soluble in xylene at 25° C.