Patents Assigned to Basell Poliolefine Italia s.r.l.
  • Patent number: 10501616
    Abstract: A polyolefin composition made from or containing: A) from 85.0 wt % to 99.5 wt % of a propylene 1-hexene copolymer, based upon the weight of the polyolefin composition and B) from 0.5 wt % to 15.0 wt % of a propylene, ethylene copolymer composition, based upon the weight of the polyolefin composition, made from or containing: b1) from 12 wt % to 52 wt % of a propylene homopolymer or a propylene/ethylene copolymer, based upon the weight of the propylene, ethylene copolymer composition and b2) from 48 wt % to 88 wt % of a propylene ethylene copolymer, based upon the weight of the propylene, ethylene copolymer composition, having a content of ethylene derived units ranging from 15.0 wt % to 42.0 wt %; wherein the polyolefin composition has a melt flow rate (230° C./5 kg. ISO 1133) ranging from 0.2 g/10 min to 4.0 g/10 min; the sum A+B being 100 and the sum b1+b2 being 100.
    Type: Grant
    Filed: September 22, 2017
    Date of Patent: December 10, 2019
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Monica Galvan, Claudio Cavalieri, Francesca Tisi, Giampaolo Pellegatti, Thomas Boehm
  • Patent number: 10494468
    Abstract: A propylene composition comprising: A) from 60 wt % to 75 wt %, of a propylene homopolymer having a Polydispersity Index (P.I.) value from 4.3 to 4.9, a fraction insoluble in xylene at 25° C., higher than 95%, based upon the weight of the propylene homopolymer, and MFR (Melt Flow Rate according to ISO 1133, condition L, at 230° C. and 2.16 kg load) ranging from 20 to 75 g/10 min; B) from 25 wt % to 40 wt %, of a copolymer of propylene with from 46.0 wt % to 49.0 wt %; of ethylene derived units, based upon the weight of the propylene copolymer; wherein the propylene polymer composition having an intrinsic viscosity of the fraction soluble in xylene at 25° C. between 2.2 to 2.9 dl/g; and the relation: 10.7+1.3×MFRa?17.7×P.I.?29.3×IV+4.9×Xs??(I) between about 40 to about 66; wherein the amount of A+B is equal to 100 wt %.
    Type: Grant
    Filed: March 17, 2017
    Date of Patent: December 3, 2019
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Paola Massari, Marco Ciarafoni, Nicoletta Martini, Davide Tartari, Roberto Pantaleoni
  • Patent number: 10494517
    Abstract: A film made from or containing a polypropylene composition made from or containing: A) from 50 wt % to 90 wt %; of a propylene homopolymer; and B) from 10 wt % to 50 wt %; of a copolymer of propylene with from 30.0 wt % to 70.0 wt %, of ethylene derived units, based upon the weight of the copolymer; wherein the sum of the amount of component A) and B) being 100; the polypropylene composition having: i) an intrinsic viscosity of the fraction soluble in xylene at 25° C. between 2.2 to 4.0 dl/g; ii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, at 230° C. and 2.16 kg load) from 0.5 to 50 g/10 min; and iii) a xylene soluble fraction ranging from 20 wt % to 50 wt %, based upon the weight of the polypropylene composition; and the polypropylene composition being obtained by a polymerization process wherein the catalyst system contains bismuth.
    Type: Grant
    Filed: November 27, 2017
    Date of Patent: December 3, 2019
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Caroline Cathelin, Paola Massari, Claudio Cavalieri, Marco Ciarafoni, Roberto Pantaleoni
  • Publication number: 20190345317
    Abstract: A film made from or containing a polypropylene composition made from or containing: A) from 50 wt % to 90 wt %; of a propylene homopolymer; and B) from 10 wt % to 50 wt %; of a copolymer of propylene with from 30.0 wt % to 70.0 wt %, of ethylene derived units, based upon the weight of the copolymer; wherein the sum of the amount of component A) and B) being 100; the polypropylene composition having: i) an intrinsic viscosity of the fraction soluble in xylene at 25° C. between 2.2 to 4.0 dl/g; ii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, at 230° C. and 2.16 kg load) from 0.5 to 50 g/10 min; and iii) a xylene soluble fraction ranging from 20 wt % to 50 wt %, based upon the weight of the polypropylene composition; and the polypropylene composition being obtained by a polymerization process wherein the catalyst system contains bismuth.
    Type: Application
    Filed: November 27, 2017
    Publication date: November 14, 2019
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: CAROLINE CATHELIN, PAOLA MASSARI, CLAUDIO CAVALIERI, MARCO CIARAFONI, ROBERTO PANTALEONI
  • Publication number: 20190338055
    Abstract: The present disclosure provides a solid catalyst component obtainable by a process including: (a) a first step in which Ti(OEt)4, is reacted with a Mg based compound of formula MgCln(ORI)2-n, where n is from about 0.5 to about 1.5, RI is a C1-C10 alkyl groups, the Ti(OEt)4 and the Mg compound are used in amounts such that the Ti/Mg molar ratio is of about 0.2 to about 0.4, the reaction temperature is about 110 to about 130° C., and the reaction time is about 2 to about 5 hours; and (b) a subsequent step in which the product obtained in step (a) is reacted with a Ti compound of the formula Ti(ORI)4-yCly, where y is a number between 3 and 4.
    Type: Application
    Filed: April 24, 2017
    Publication date: November 7, 2019
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: SIMONA GUIDOTTI, TIZIANO DALL'OCCO, DARIO LIGUORI, GIAMPIERO MORINI
  • Publication number: 20190338113
    Abstract: A polyolefin composition made from or containing: A) from 85.0 wt % to 99.5 wt % of a propylene 1-hexene copolymer, based upon the weight of the polyolefin composition and B) from 0.5 wt % to 15.0 wt % of a propylene, ethylene copolymer composition, based upon the weight of the polyolefin composition, made from or containing: b1) from 12 wt % to 52 wt % of a propylene homopolymer or a propylene/ethylene copolymer, based upon the weight of the propylene, ethylene copolymer composition and b2) from 48 wt % to 88 wt % of a propylene ethylene copolymer, based upon the weight of the propylene, ethylene copolymer composition, having a content of ethylene derived units ranging from 15.0 wt % to 42.0 wt %; wherein the polyolefin composition has a melt flow rate (230° C./5 kg. ISO 1133) ranging from 0.2 g/10 min to 4.0 g/10 min; the sum A+B being 100 and the sum b1+b2 being 100.
    Type: Application
    Filed: September 22, 2017
    Publication date: November 7, 2019
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: MONICA GALVAN, CLAUDIO CAVALIERI, FRANCESCA TISI, GIAMPAOLO PELLEGATTI, THOMAS BOEHM
  • Publication number: 20190338065
    Abstract: The present disclosure provides a propylene composition made from or containing A) from 60 wt % to 75 wt %, of a propylene homopolymer having a Polydispersity Index (P.I.) value from 4.3 to 4.9, a fraction insoluble in xylene at 25° C., higher than 95%, based upon the weight of the propylene homopolymer, and MFR (Melt Flow Rate according to ISO 1133, condition L, at 230° C. and 2.16 kg load) ranging from 20 to 75 g/10 min; B) from 25 wt % to 40 wt %, of a copolymer of propylene with from 46.0 wt % to 49.0 wt %; of ethylene derived units, based upon the weight of the propylene copolymer; wherein the propylene polymer composition having an intrinsic viscosity of the fraction soluble in xylene at 25° C. between 2.2 to 2.9 dl/g; and the relation: 10.7+1.3×MFRa?17.7×P.I.?29.3×IV+4.9×Xs??(I) between about 40 to about 66; wherein MFRa is the melt flow rate of the component A); P.I. is the polydispersity index of component A); IV is the intrinsic viscosity of the fraction soluble in xylene at 25° C.
    Type: Application
    Filed: March 17, 2017
    Publication date: November 7, 2019
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: PAOLA MASSARI, MARCO CIARAFONI, NICOLETTA MARTINI, DAVIDE TARTARI, ROBERTO PANTALEONI
  • Publication number: 20190336930
    Abstract: A fluid is fed into a polymer bed of a fluidized bed gas phase polymerization reactor by introducing the fluid into the polymer bed through a distributor protruding into the fluidized bed zone of the reactor and terminating with a discharge end positioned so that the following equation is fulfilled: d/D>0.002 wherein d is the distance of the distributor's discharge end from the wall of the reactor, and D is the diameter of the reactor in the fluidized bed zone.
    Type: Application
    Filed: December 15, 2017
    Publication date: November 7, 2019
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: ENRICO BALESTRA, TIZIANA CAPUTO, MASSIMO COVEZZI, MAURIZIO DORINI, ANTONIO MAZZUCCO, GABRIELE MEI, RICARDO RINALDI
  • Publication number: 20190330388
    Abstract: A solid catalyst component for the polymerization of olefins made from or containing Mg, Ti and an electron donor of formula (I) wherein R1 and R7 groups, equal to or different from each other, are selected from C1-C15 hydrocarbon groups, R2 group is selected from C1-C10 hydrocarbon groups, and R3 to R6 groups, independently, are selected from hydrogen or C1-C15 hydrocarbon groups which can be fused together to form one or more cycles. The catalyst system based on the solid catalyst component is endowed with high activity and stereospecificity.
    Type: Application
    Filed: November 10, 2017
    Publication date: October 31, 2019
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: ALESSANDRO MIGNOGNA, DARIO LIGUORI, GIAMPIERO MORINI
  • Publication number: 20190322779
    Abstract: A butene-1 polymer composition having MFR values of from 400 to 2000 g/10 min, measured according to ISO 1133 at 190° C. with a load of 2.16 kg, made from or containing A) a butene-1 homopolymer or a copolymer of butene-1 with a comonomer selected from the group consisting of ethylene and higher alpha-olefins, having a copolymerized comonomer content of up to 5% by mole; B) a copolymer of butene-1 with a comonomer selected from the group consisting of ethylene and higher alpha-olefins, having a copolymerized comonomer content of from 6% to 20% by mole; wherein the composition having a total copolymerized comonomer content from 4% to 15% by mole, referred to the sum of A) and B), and a content of fraction soluble in xylene at 0° C. of 60% by weight or less, determined on the total weight of A) and B).
    Type: Application
    Filed: July 3, 2017
    Publication date: October 24, 2019
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: ROBERTA MARCHINI, STEFANO SPATARO, EMANUELE BURGIN, ROBERTA PICA
  • Publication number: 20190322850
    Abstract: A nucleated propylene polymer composition made from or containing: A) a propylene homopolymer; B) a copolymer of propylene with ethylene derived units; the nucleated composition having a fraction soluble in xylene at 25° C. between 9.0 and 21.0 wt %, an intrinsic viscosity of the fraction soluble in xylene at 25° C. between 1.0 and 1.9 dl/g, a total melt flow rate between 1.5 and 5 g/10 min and the value of the relation (I): 22.5+0.2*MFR?1.2*Xs+0.2*IV??(I) is higher than 5.9; wherein MFR is the melt flow rate of the nucleated composition; IV is the intrinsic viscosity of the fraction soluble in xylene at 25° C.; and Xs is the fraction soluble in xylene at 25° C., the amount of A+B is equal to 100 wt %, and the nucleating agent is selected from the group consisting of aromatic or aliphatic carboxylic acids, aromatic metal phosphates, sorbitol derivatives and talc.
    Type: Application
    Filed: October 5, 2017
    Publication date: October 24, 2019
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: PAOLA MASSARI, ANDREA FELISATI, MARCO IZZI, CLAUDIO CAVALIERI, MARCO CIARAFONI, SILVIA GUERRA, ROBERTO PANTALEONI, FEDERICA MALIZIA
  • Patent number: 10435490
    Abstract: A Prepolymerized catalyst component for the polymerization of olefins comprising a solid catalyst component which comprises Mg, Ti, and chlorine atoms and an electron donor (ID) said prepolymerized catalyst component being characterized by the fact that: the electron donor (ID) is constituted by at least 80% mol of 1,3 diethers with respect to the total molar amount of electron donor compounds; the prepolymerized catalyst has a porosity due to pores with diameters up to 1 ?m of less than 0.2 cm3/g; it contains an amount of ethylene prepolymer of less than 45% with respect to the total weight of prepolymerized catalyst.
    Type: Grant
    Filed: July 14, 2016
    Date of Patent: October 8, 2019
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Giuseppina Maria Algozzini, Diego Brita, Massimo Cenci, Gianni Collina, Tiziano Dall'occo, Maria Di Diego, Benedetta Gaddi, Ofelia Fusco, Giampiero Morini, Lorella Pedriali
  • Publication number: 20190292281
    Abstract: A catalyst component made from or containing Ti, Mg, chlorine, an amount of a first internal donor selected from esters of aliphatic monocarboxylic acids (EAA), and an amount of a second internal donor selected from cyclic ethers (CE), wherein the EAA/CE molar ratio ranges from 0.02 to less than 20.
    Type: Application
    Filed: December 12, 2017
    Publication date: September 26, 2019
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: GIANNI COLLINA, MARIA DI DIEGO, BENEDETTA GADDI, PIERO GESSI, LORELLA MARTURANO, GIAMPIERO MORINI
  • Publication number: 20190283322
    Abstract: A plate for use in an extrusion-based additive manufacturing system made from or containing a top layer made from or containing a sheet or film made from or containing polyolefin composition A) made from or containing (i) 5-35% by weight of a propylene homopolymer or a propylene ethylene copolymer; (ii) 20-50% by weight of a copolymer of ethylene and a C3-C8 alpha-olefin; and (iii) 30-60% by weight of a copolymer of ethylene and propylene wherein the amounts of (i), (ii) and (iii) being referred to the total weight of (i)+(ii)+(iii) and the sum of the amount of (i), (ii) and (iii) being 100.
    Type: Application
    Filed: September 22, 2017
    Publication date: September 19, 2019
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: ROBERTO DE PALO, CLAUDIO CAVALIERI, MONICA GALVAN
  • Publication number: 20190284316
    Abstract: A catalyst component for the polymerization of olefins, comprising Ti, Mg, halogen, an electron donor (ID) selected from the group consisting of aliphatic cyclic ethers and alkyl esters of aliphatic monocarboxylic acids and a compound of a metal selected from the group consisting of Zn and Cu, wherein the catalyst component is devoid of Zn—C or Cu—C bonds and the Mg/Ti molar ratio ranges from 4.0 to 50.0.
    Type: Application
    Filed: July 7, 2017
    Publication date: September 19, 2019
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: TIZIANO DALL'OCCO, SIMONA GUIDOTTI, DARIO LIGUORI, GIAMPIERO MORINI
  • Publication number: 20190284384
    Abstract: A polyolefin composition made from or containing: (A) from 97.0 to 45.0 wt % of a propylene-1-hexene random copolymer, (B) from 2.0 to 50.0 wt % of fibers, and (Q) from 0.3 wt % to 5.0 wt % of a compatibilizer, the sum (A)+(B)+(Q) being 100, wherein (i) the copolymer has a content of 1-hexene derived units ranging from 0.6 wt % to 3.0 wt % with respect to the copolymer, (ii) the copolymer has the melt flow rate (MFR) measured according to the method ISO 1133 (230° C., 2.16 kg) ranging from 0.2 up to 40 g/10 min, (iii) the fibers are selected from the group consisting of glass fibers, carbon fibers, metal fibers, mineral fibers, ceramic fibers, and polymer fibers.
    Type: Application
    Filed: November 6, 2017
    Publication date: September 19, 2019
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: THOMAS MECKLENBURG, KLAUS KLEMM, ERIK HANS LICHT, JUERGEN ROHRMANN, PAOLA MASSARI, MARA DESTRO, MARCO CIARAFONI
  • Publication number: 20190284383
    Abstract: The disclosure provides a film made from or containing a polyolefin composition made from or containing A) 5-35% by weight, based upon the total weight of the polyolefin composition, of a propylene homopolymer or a propylene ethylene copolymer; B) 25-50% by weight, based upon the total weight of the polyolefin composition, of a copolymer of ethylene and a C3-C8 alpha-olefin containing from 0.1% to 20% by weight of alpha-olefin units; and C) 30-60% by weight, based upon the total weight of the polyolefin composition, of a copolymer of ethylene and propylene containing from 25% to 75% by weight of ethylene units.
    Type: Application
    Filed: May 9, 2017
    Publication date: September 19, 2019
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: MONICA GALVAN, GIANNI PERDOMI, CLAUDIO CAVALIERI
  • Publication number: 20190276566
    Abstract: A gas-phase process for the homopolymerization or copolymerization of olefins carried out in the presence of a catalyst system formed by a contacting, in a liquid hydrocarbon and in the presence of hydrogen, (a) a solid catalyst component comprising Ti, Mg, and Cl, and optionally an internal electron donor compound, (b) an aluminum alkyl compound and optionally (c) an external donor compound.
    Type: Application
    Filed: November 2, 2017
    Publication date: September 12, 2019
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: PIETRO BAITA, MASSIMO COVEZZI, MARIA DI DIEGO, LORELLA MARTURANO, ANTONIO MAZZUCCO, GABRIELE MEI, ROBERTA PICA
  • Patent number: 10407519
    Abstract: Solid adducts comprising MgCl2 and an alcohol ROH in which R is a C1-C20 hydrocarbon group, in which the amount of alcohol ranges from higher than 42% to 60% by weight and the porosity determined with Hg method due to pores up to 1 ?m and expressed in cm3/g, is such that the value of its ratio with the amount of alcohol in percentage falls above the straight line defined by the equation y=?0.0158x+1.03 in which y is the porosity of the adduct and x is the alcohol percentage by weight.
    Type: Grant
    Filed: November 29, 2017
    Date of Patent: September 10, 2019
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Daniele Evangelisti, Benedetta Gaddi, Gianni Collina
  • Publication number: 20190256747
    Abstract: A butene-1 polymer composition having MFR values of from 400 to 2000 g/10 min, measured according to ISO 1133 at 190° C. with a load of 2.16 kg, made from or containing A) a butene-1 homopolymer or a copolymer of butene-1 with a comonomer selected from the group consisting of ethylene and higher alpha-olefins, having a copolymerized comonomer content of up to 5% by mole; B) a copolymer of butene-1 with a comonomer selected from the group consisting of ethylene and higher alpha-olefins, having a copolymerized comonomer content of from 6% to 25% by mole; wherein the composition having a total copolymerized comonomer content from 5% to 18% by mole, referred to the sum of A) and B), and a content of fraction soluble in xylene at 0° C. of 65% by weight or more, determined on the total weight of A) and B).
    Type: Application
    Filed: July 3, 2017
    Publication date: August 22, 2019
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: ROBERTA MARCHINI, STEFANO SPATARO, EMANUELE BURGIN, ROBERTA PICA