Patents Assigned to Basell Poliolefine Italia s.r.l.
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Publication number: 20230099166Abstract: A polypropylene composition made from or containing: T1) 35-65 wt % of a recycled polypropylene mixture containing at least 80 wt % of rigid polypropylene items and having a purity of at least 90 wt %; T2) 20-50 wt % of an ethylene/propylene copolymer; T3) 5-20 wt % of a propylene/ethylene heterophasic copolymer composition made from or containing a) from 12 wt % to 52 wt % of a propylene homopolymer or a propylene/ethylene copolymer; and b) from 48 wt % to 88 wt % of a propylene/ethylene copolymer having a content of ethylene derived units ranging from 15 wt % to 42 wt %; wherein the propylene composition has a melt flow rate (ISO 1133 230° C./2.16 kg) ranging from 0.5 to 20 g/10 min.Type: ApplicationFiled: February 4, 2021Publication date: March 30, 2023Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: CLAUDIO CAVALIERI, EMANUELE BURGIN, MONICA GALVAN, THOMAS BOEHM
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Publication number: 20230095189Abstract: A propylene/1-hexene copolymer having i) the content of 1-hexene derived units, measured by C13-NMR, ranging from 1.5 wt % to 2.5 wt % and the content of propylene derived units ranging from 97.5 to 98.5 wt. %; ii) a melting temperature, measured by DSC, ranging from 148 to 153° C.; iii) an amount of fraction insoluble in xylene at 25° C. higher than 97.0%; and iv) a melt flow rate (MFR), measured according to ISO 1133, 230° C., 2.16 kg, ranging from 35 to 65 g/10 min.Type: ApplicationFiled: February 23, 2021Publication date: March 30, 2023Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: GIANPIERO FERRARO, MARCO CIARAFONI, CLAUDIO CAVALIERI, CAROLINE CATHELIN, GIANSIRO PRINI
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Patent number: 11613637Abstract: A multilayer film made from or containing at least one core layer made from or containing a polypropylene composition made from or containing: A) from 95 wt % to 60 wt %; of a propylene homopolymer having a fraction insoluble in xylene at 25° C. greater than 90 wt %, based upon the total weight of the propylene homopolymer; and B) from 5 wt % to 40 wt %; of an heterophasic propylene ethylene copolymer, the sum of the amounts of A) and B) being 100.Type: GrantFiled: August 30, 2018Date of Patent: March 28, 2023Assignee: Basell Poliolefine Italia S.r.l.Inventors: Paola Massari, Andrea Felisati, Marco Izzi, Paolo Bassi, Caroline Cathelin, Michele Grazzi, Claudio Cavalieri
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Publication number: 20230028786Abstract: A solid catalyst component for the homopolymerization or copolymerization of olefins, made from or containing Ti, Mg, halogen, and at least one non-aromatic diazo compounds.Type: ApplicationFiled: November 30, 2020Publication date: January 26, 2023Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: SIMONA GUIDOTTI, DARIO LIGUORI, GIAMPIERO MORINI
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Publication number: 20230009131Abstract: Pre-treatment methods for polyolefin-based feed streams before depolymerization are described. Polyolefins are separated from other material in the polyolefin-based feed stream using density differences in an aqueous solution, which allows for a pre-treatment method that does not affect the depolymerization catalyst. By removing the non-polyolefin materials from the feed stream, the depolymerization of the polyolefin material can proceed at lower temperatures for longer cycles. This results in a more efficient process with a smaller carbon footprint.Type: ApplicationFiled: July 8, 2022Publication date: January 12, 2023Applicant: Basell Poliolefine Italia S.r.l.Inventors: Sandor Nagy, Diego Brita, Christopher D. Smith, David A. Heaps, Daniel F. White, David L. Ramage
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Publication number: 20230002516Abstract: A catalyst for the polymerization of olefins made from or containing (a) a solid catalyst component containing Mg, Ti and optionally an internal electron donor compound (ID), (b) an aluminum alky compound, and (c) an external electron donor (ED) selected from non-aromatic diazo compounds.Type: ApplicationFiled: November 28, 2020Publication date: January 5, 2023Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: SIMONA GUIDOTTI, DARIO LIGUORI, GIAMPIERO MORINI
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Publication number: 20220403064Abstract: A process (and a related system) for collecting samples of a polymerization catalyst or of a catalyst-containing polymer from an operation unit, having an upper end and a lower end, of a polymerization plant, including the steps of: a) extracting a prefixed amount of product from the lower end of the operation unit through a discharge valve; b) directing the product towards a filtering unit through an inlet valve; c) flushing an inert gas through the filtering unit; d) outgassing the filtering unit, through the outlet valve; and e) displacing the filtering unit, for collecting the sample.Type: ApplicationFiled: November 9, 2020Publication date: December 22, 2022Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: PAOLO CAPISANI, NICOLO ARICH DE FINETTI, PIETRO BAITA
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Publication number: 20220403059Abstract: A process for preparing a catalyst component made from or containing Mg, Ti, and at least an electron donor compound (ID), including the steps of: (a) reacting a Mg based compound with a Ti compound, having at least a Ti—Cl bond, in an amount such that the Ti/Mg molar ratio is greater than 3 and at a temperature ranging from 0 to 150° C., thereby yielding an intermediate solid catalyst component containing Mg and Ti; and (b) contacting the intermediate solid catalyst component with a gaseous stream containing the electron donor compound (ID) in a gaseous dispersing medium, thereby yielding a final solid catalyst component having an ID/Ti molar ratio ranging from 0.5:1 to 20:1.Type: ApplicationFiled: November 5, 2020Publication date: December 22, 2022Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: DIEGO BRITA, GIANNI COLLINA, DANIELE EVANGELISTI, BENEDETTA GADDI, PIERO GESSI, GIAMPIERO MORINI, SILVIA SOFFRITTI, PAOLO VINCENZI
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Publication number: 20220396649Abstract: A process for the continuous solution polymerization including the step of polymerizing a first olefin monomer of formula CH2?CHR1, wherein R1 is hydrogen or a hydrocarbon radical having from 1 to 8 carbon atoms with a second olefin monomer of formula CH2?CHR2, wherein R2 is a hydrocarbon radical having from 3 to 8 carbon atoms, in the presence of a polymerization catalyst and in the absence of an inert solvent, at a polymerization temperature (Tp) satisfying the following relationship: Tp?Tm+20° C. wherein Tm is the melting temperature of the obtained polymer.Type: ApplicationFiled: November 3, 2020Publication date: December 15, 2022Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: NICOLO ARICH DE FINETTI, PIETRO BAITA, ANTONIO MAZZUCCO, ROBERTA PICA
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Publication number: 20220372198Abstract: A polypropylene composition made from or containing a first polymer consisting of component (1) made from or containing a propylene homopolymer having an MFR of 80 to 300 and containing 97.5% by weight or more of xylene insolubles (XI), wherein XI of the propylene homopolymer has a Mw/Mn of 4 to 10; and component (2) made from or containing an ethylene/propylene copolymer containing 35 to 50% by weight of an ethylene-derived unit; wherein the polypropylene composition has the following characteristics: 1) the relative proportions of component (2)/[component (1) and component (2)] is more than 30% by weight and not more than 50% by weight, 2) the intrinsic viscosity of xylene solubles (XSIV) of the first polymer is in the range of 1.5 to 4.0 dl/g, and 3) the MFR of the first polymer is in the range of 20 to 100 g/10 min.Type: ApplicationFiled: October 22, 2020Publication date: November 24, 2022Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: Yutaka Yokoyama, Akihiro Kamimura, Hiroshi Kajioka
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Publication number: 20220348751Abstract: An injection molded article made from or containing a propylene-based composition made from or containing: T1) from 90 wt % to 50 wt % of a propylene homopolymer; and T2) from 10 wt % to 50 wt % of a polymer composition made from or containing A) 5-35% by weight of a propylene homopolymer or a propylene ethylene copolymer; B) 20-50% by weight of a copolymer of ethylene and a C3-C8 alpha-olefin containing from 0.1% to 20% by weight of alpha-olefin units; and C) 30-60% by weight of a copolymer of ethylene and propylene containing from 25% to 75% by weight of ethylene units.Type: ApplicationFiled: August 28, 2020Publication date: November 3, 2022Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: MONICA GALVAN, MICHELE GRAZZI, CLAUDIO CAVALIERI, MIKHAIL SERGEEVICH DUREEV
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Publication number: 20220340744Abstract: A polyolefin composition made from or containing a first heterophasic polyolefin polymer A) made from or containing a first crystalline propylene homopolymer matrix, a first propylene ethylene copolymer having an ethylene content ranging from 20.0 wt% up to 35.0 wt%, a second propylene ethylene copolymer having an ethylene content ranging from 55.0 wt% up to 70.0 wt%, and a second heterophasic polyolefin polymer B) made from or containing a second crystalline propylene homopolymer matrix, an ethylene C4-C10 ?-olefin copolymer having an ethylene content ranging from 65.0 wt% up to 85.0 wt%, and a third propylene ethylene copolymer having an ethylene content ranging from 40.0 wt% up to 50.0 wt%.Type: ApplicationFiled: September 4, 2020Publication date: October 27, 2022Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: SEAN COMERFORD, MONICA GALVAN, GIAMPAOLO PELLEGATTI, FRANCESCA TISI
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Publication number: 20220332856Abstract: A solid catalyst component for the polymerization of olefins made from or containing Mg, Ti and an electron donor of formula (I) where the R1 and R5 groups, equal to or different from each other, are selected from C1-C15 hydrocarbon groups, R2 group is selected from C2-C10 hydrocarbon groups, R3 to R4 groups, independently, are selected from hydrogen or C1-C20 hydrocarbon groups, optionally fused together to form one or more cycles, with the proviso that at least one of R3 to R4 groups is a C1-C20 alkyl group.Type: ApplicationFiled: June 24, 2020Publication date: October 20, 2022Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: ALESSANDRO MIGNOGNA, DARIO LIGUORI, GIAMPIERO MORINI
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Patent number: 11466107Abstract: A solid catalyst component for the polymerization of olefins CH2?CHR, wherein R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, made from or containing Mg, Ti, Bi, a halogen and an electron donor.Type: GrantFiled: January 25, 2019Date of Patent: October 11, 2022Assignee: Basell Poliolefine Italia S.r.l.Inventors: Simona Guidotti, Dario Liguori, Giampiero Morini, Gianni Vitale
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Patent number: 11459454Abstract: A polypropylene composition made from or containing a polymer made from or containing: (i) component (1) made from or containing a propylene homopolymer having MFR of 100 to 300 (at a temperature of 230° C. under a load of 2.16 k(g) and containing more than 97.5% by weight of xylene insolubles (XI), wherein XI has a Mw/Mn of 4 to 10; (ii) component (2) made from or containing an ethylene/propylene copolymer containing 15 to 50% by weight of an ethylene-derived unit; wherein 1) relative proportions of component (1) and component (2) are, respectively, not less than 50 parts by weight but less than 70 pbw and more than 30 pbw but not more than 50 pbw, 2) intrinsic viscosity of xylene solubles (XSIV) of the polymer is in the range of 1.5 to 4.0 dl/g, 3) MFR of the polymer is in the range of 20 to 100 g/10 min.Type: GrantFiled: April 25, 2019Date of Patent: October 4, 2022Assignee: Basell Poliolefine Italia S.r.l.Inventors: Yutaka Yokoyama, Akihiro Kamimura, Hiroshi Kajioka
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Publication number: 20220306848Abstract: A process for preparing fibers made from or containing propylene homopolymer having: a melting point ranging from 150° C. to 164° C.; a fraction soluble in xylene at 25° C. between 6.0 wt % and 2.0 wt %; a fraction soluble in acetone 25° C. between 0.5 wt % and 2.0 wt %; a ratio fraction soluble in xylene at 25° C./fraction soluble in acetone 25° C. between 0.30 and 0.60; a polydispersity index ranging from 2.8 to 4.5; and a melt flow rate (ISO 1133, 230° C./2.16 kg) between 2 to 40 g/10 min.Type: ApplicationFiled: May 18, 2020Publication date: September 29, 2022Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: ROBERTO DE PALO, JAUME MARTI PORQUERES, RENAUD LEMAIRE, CLAUDIO CAVALIERI
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Patent number: 11453767Abstract: A propylene ethylene copolymer having: (i) an ethylene derived units content (C2) ranging from 2.0 wt % to 11.0 wt %, based upon the total weight of the copolymer; (ii)) a fraction soluble in xylene (Xs) at 25° C. (Xs) ranging from 7.1 wt % to 28.5 wt %, based upon the total weight of the copolymer; (iii) an intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 3.2 dl/g to 5.6 dl/g; (iv) a melting point (Tm) higher than 140.0° C. and fulfilling the relation (I): Tm>155?1.4×C2??(I); and (v) a flexural modulus (TM) higher than 500 MPa and fulfilling the relation (II) TM>1900?285×C2+50×Xs??(II).Type: GrantFiled: March 23, 2018Date of Patent: September 27, 2022Assignee: Basell Poliolefine Italia S.r.l.Inventors: Gabriele Mei, Antonio Mazzucco, Tiziana Caputo, Enrico Balestra, Davide Tartari, Gilberto Moscardi
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Publication number: 20220298343Abstract: A polypropylene composition made from or containing: A) from 60 to 90 wt %, based upon the total weight of the polypropylene composition, of a fraction insoluble in xylene at 25° C., is made from or containing more than 80% wt of propylene units, and B) from 10 to 40 wt %, based upon the total weight of the polypropylene composition, of a fraction soluble in xylene at 25° C. is made from or containing a copolymer of propylene and ethylene having an average content of ethylene derived units from 30.0 wt % to 55.0 wt %, wherein the fraction when subjected to GPC fractionation and continuous IR analysis for determining the ethylene content of the eluted fractions (GPC-IR analysis), shows that the content of ethylene increases along with the Mw for fractions having Mw higher than the average.Type: ApplicationFiled: August 31, 2020Publication date: September 22, 2022Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: FABRIZIO PIEMONTESI, ALESSANDRO MIGNOGNA, DARIO LIGUORI, GIAMPIERO MORINI, GIANNI VITALE
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Publication number: 20220298272Abstract: A solid catalyst component for the polymerization of olefins made from or containing a magnesium halide, a titanium compound having at least a Ti-halogen bond, a first electron donor compound selected from 1,3 diethers (DE), and a second electron donor compound selected from dicarbamates (DC), wherein the first and second electron donor compounds are present in a molar ratio DE:DC ranging from 4.5:1 to 20:1.Type: ApplicationFiled: August 27, 2020Publication date: September 22, 2022Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: FABRIZIO PIEMONTESI, ALESSANDRO MIGNOGNA, DARIO LIGUORI, GIAMPIERO MORINI, TIZIANO DALL'OCCO, GIANNI VITALE
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Publication number: 20220251745Abstract: A skin-core fiber having a skin of a propylene ethylene copolymer having: i) xylene soluble fraction from 14 wt % to 27 wt %; ii) intrinsic viscosity of the fraction soluble in xylene at 25° C. from 1.0 to 2.4 dl/g; iii) melt flow rate, MFR, from 12 g/10 min to 60 g/10 min; iv) an ethylene derived units content from 5.0 wt % to 12.0 wt %; v) the ethylene derived units content of the fraction insoluble in xylene from 2.5 wt % to 6.0 wt %; vi) the ethylene derived units content of the fraction soluble in xylene ranging from 15.2. wt % to 30.2 wt %; vii) C13 NMR sequences PEP on the fraction insoluble in xylene from 3.5 mol % to 5.5 mol %; and viii) C13 NMR sequences PEP on the fraction soluble in xylene from 11.0 mol % to 14.2 mol %; and a core of a polyethylene having a density between 0.940 g/cm3 to 0.975 g/cm3.Type: ApplicationFiled: May 26, 2020Publication date: August 11, 2022Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: ROBERTO DE PALO, RENAUD LEMAIRE, JAUME MARTI PORQUERES