Patents Assigned to Basell Poliolefine Italia s.r.l.
  • Publication number: 20210388192
    Abstract: A polypropylene composition made from or containing: (i) component (1) made from or containing a propylene homopolymer or copolymer containing 0 to 0.5% by weight of an ethylene-derived unit; and (ii) component (2) made from or containing an ethylene/propylene copolymer containing 65 to 85% by weight of an ethylene-derived unit; wherein 1) the Mw/Mn value of xylene insolubles (XI) of the polypropylene composition as measured by GPC is in the range of 6 to 20, 2) the weight ratio of component (1) to component (2) is in the range of 70:30 to 85:15, 3) the intrinsic viscosity of xylene solubles (XSIV) of the polypropylene composition is in the range of 1.0 to 3.0 dl/g, and 4) the MFR (at 230° C. under a load of 2.16 kg) of the polypropylene composition is in the range of 3 to 15 g/10 min.
    Type: Application
    Filed: October 17, 2019
    Publication date: December 16, 2021
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: TAKESHI NAKAJIMA, KUNIO YAMAMOTO, MASASHI UCHIDA
  • Patent number: 11186664
    Abstract: A propylene ethylene copolymer having: i) xylene soluble fraction at 25° C. ranging from 14 wt % to 27 wt %; ii) intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 1.0 to 2.4 dl/g; iii) melt flow rate, MFR, ranging from 1.0 g/10 min to 50.0 g/10 min; iv) an ethylene derived units content ranging from 5.0 wt % to 12.0 wt %; v) the ethylene derived units content on the fraction insoluble in xylene at 25° C. ranging from 2.5 wt % to 6.0 wt %; vi) the ethylene derived units content on the fraction soluble in xylene at 25° C. ranging from 15.2. wt % to 30.2 wt %; and vii) C13 NMR sequences PEP measured on the fraction insoluble in xylene at 25° C. ranging from 3.5 mol % to 5.5 mol % and C13 NMR sequences PEP measured on the fraction soluble in xylene at 25° C. ranging from 11.0 mol % to 14.2 mol %.
    Type: Grant
    Filed: August 30, 2018
    Date of Patent: November 30, 2021
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Paola Massari, Claudio Cavalieri, Davide Tartari, Tiziana Caputo, Isabella Maria Vittoria Camurati
  • Patent number: 11174379
    Abstract: A polyolefin composition made from or containing: T1) 70-95 wt %, of a polyolefin component containing: a1) from 30 wt % to 70 wt % of a propylene based polymer; and a2) from 30 wt % to 70 wt % of an ethylene based polymer; and T2) 5-30 wt % of a polyolefin component containing: A) 5-35% by weight of a propylene homopolymer or a propylene ethylene copolymer; B) 25-50% by weight of a copolymer of ethylene and a C3-C8 alpha-olefin containing 0.1-20% by weight of C3-C8 alpha-olefin units; and C) 30-60% by weight of a copolymer of ethylene and propylene containing 25-75% by weight of ethylene units.
    Type: Grant
    Filed: November 5, 2018
    Date of Patent: November 16, 2021
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Roberto De Palo, Claudio Cavalieri
  • Publication number: 20210340367
    Abstract: A polypropylene composition made from or containing: A) from 88.0 wt. % to 98.0 wt. %, of a random copolymer of propylene containing from 0.8 wt. % to 4.8 wt. % of 1-hexene derived units; the random copolymer of propylene having: a Melt Flow Rate: measured according to ISO 1133 (230° C., 5 Kg) ranging from 0.5 to 4.4 g/10 min; and B) from 2.0 wt. % to 12.0 wt. % of a terpolymer of propylene ethylene and 1-hexene having a content of ethylene derived units ranging from 35 wt. % to 60 wt.; and a content of 1-hexene derived units ranging from 1 wt. % to 6 wt. %; wherein the polypropylene composition has a Melt Flow Rate: measured according to ISO 1133 (230° C., 5 Kg) ranging from 0.5 to 5.0 g/10 min.
    Type: Application
    Filed: September 11, 2019
    Publication date: November 4, 2021
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: MONICA GALVAN, CLAUDIO CAVALIERI, THOMAS BOEHM, ROBERTO PANTALEONI
  • Patent number: 11149101
    Abstract: A propylene 1-hexene copolymer containing from 5.7 to 7.7% by weight of 1-hexene derived units, based upon the total weight of the propylene 1-hexene copolymer, having: a) a solubility in xylene at 25° C. ranging from 7.0 wt % to 15.0 wt %, based upon the total weight of the propylene 1-hexene copolymer; b) a melting temperature, measured by DSC ranging from 143.0° C. to 148.0° C.; c) a Melt Flow Rate (MFR, measured according to ASTM D 1238, 230° C./2.16 kg) from 3.5 to 8.0 g/10 min.; and d) a content of 1-hexene derived units in the fraction soluble in xylene at 25° C. ranging from 13.5 wt % to 18.5 wt %, based upon the total weight of the soluble fraction.
    Type: Grant
    Filed: July 3, 2018
    Date of Patent: October 19, 2021
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Paola Massari, Caroline Cathelin, Claudio Cavalieri, Marco Ciarafoni, Roberto Pantaleoni, Giampiero Morini, Gianni Vitale, Fabrizio Piemontesi, Gianni Collina, Benedetta Gaddi
  • Publication number: 20210317347
    Abstract: A polyolefin-based hot melt adhesive composition made from or containing: (A) 28-75 wt. % of a copolymer of butene-1 with Melt Flow Rate values, measured according to ISO 1133 (190° C., 2.16 kg), from 200 to 1500 g/10 min.; and (B) 25-72 wt. % of at least one additional component selected from the group consisting of waxes, resins, plasticizers, additional polymers and mixtures thereof, wherein the amounts of A) and B) are referred to the total weight of A)+B).
    Type: Application
    Filed: July 15, 2019
    Publication date: October 14, 2021
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: ROBERTA MARCHINI, SILVIA GUERRA, STEFANO PASQUALI, ANKUR RASTOGI, STEFANO SPATARO
  • Publication number: 20210309892
    Abstract: A polyolefin-based hot melt adhesive composition made from or containing (A) 25-75 wt. % of a copolymer of butene-1 with a Melt Flow Rate, measured according to ISO 1133 (190° C., 2.16 kg), higher than 1500; and (B) 75-25 wt. % of at least one additional component selected from the group consisting of waxes, resins, plasticizers, additional polymers and mixtures thereof, wherein the amounts of A) and B) are referred to the total weight of A)+B).
    Type: Application
    Filed: July 15, 2019
    Publication date: October 7, 2021
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: ROBERTA MARCHINI, SILVIA GUERRA, STEFANO PASQUALI, ANKUR RASTOGI, STEFANO SPATARO
  • Publication number: 20210309676
    Abstract: A solid catalyst component for the polymerization of olefins CH2?CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, made from or containing Mg, Ti, Bi, halogen and an electron donor obtained from a process including the steps: (a) dissolving a Mg(OR)2 compound wherein R groups, equal to or different from each other, are C1-C15 hydrocarbon groups optionally containing a heteroatom selected from O, N and halogen, in an organic liquid medium, thereby forming a first liquid mixture; (b) contacting the first liquid mixture (a) with TiCl4, thereby forming a second liquid mixture absent a solid phase, and (c) subjecting the second liquid mixture (b) to conditions, whereby solid catalyst particles are formed, wherein (i) a Bi compound and (ii) a bidentate electron donor compound are present in one or more of steps (a) to (c) and/or contacted with the solid catalyst particles obtained from (c).
    Type: Application
    Filed: July 25, 2019
    Publication date: October 7, 2021
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: SIMONA GUIDOTTI, DARIO LIGUORI, GIAMPIERO MORINI, GIANNI VITALE
  • Patent number: 11124636
    Abstract: A propylene polymer composition made from or containing: a) from 35 wt % to 65 wt %, based upon the total weight of the propylene polymer composition, of a propylene 1-hexene copolymer containing from 10.2 to 13.0% by weight, based upon the weight of the propylene 1-hexene copolymer, of 1-hexene derived units and having a Melt Flow Rate (MFR, measured according to ASTM D 1238, 230° C./2.16 kg, (at 230° C., with a load of 2.16 kg)) from 3.5 to 12.0 g/10 min; b) from 35 wt % to 65 wt %, based upon the total weight of the propylene polymer composition, of a propylene ethylene copolymer containing from 1.5 wt % to 6.5 wt %, based upon the weight of the propylene ethylene copolymer, of ethylene derived units and having a Melt Flow Rate (MFR, measured according to ASTM D 1238, 230° C./2.16 kg, (at 230° C., with a load of 2.16 kg)) from 3.5 to 12.0 g/10 min.
    Type: Grant
    Filed: April 12, 2018
    Date of Patent: September 21, 2021
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Paola Massari, Claudio Cavalieri, Marco Ciarafoni, Roberto Pantaleoni
  • Publication number: 20210269564
    Abstract: A solid catalyst component for the polymerization of olefins CH2?CHR, wherein R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, made from or containing Mg, Ti, Bi, a halogen and an electron donor.
    Type: Application
    Filed: January 25, 2019
    Publication date: September 2, 2021
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: SIMONA GUIDOTTI, DARIO LIGUORI, GIAMPIERO MORINI, GIANNI VITALE
  • Patent number: 11098184
    Abstract: A masterbatch composition made from or containing: 65 to 85 wt % of a propylene homopolymer or copolymer as component (1) containing 0 to 3 wt % of ethylene or one or more C4-C10-?-olefin-derived units; and 15 to 35 wt % of a propylene-ethylene copolymer as component (2) containing 25 to 35 wt % of ethylene-derived units, wherein the masterbatch composition has: 1) a melt flow rate (230° C., load: 21.18 N) of 5 to 30 g/10 minutes; 2) xylene insolubles with an Mw of 10×104 to 30×104 and an Mw/Mn of 6 to 20 as measured by GPC; and 3) xylene solubles with an intrinsic viscosity of 5.5 to 9.0 dl/g.
    Type: Grant
    Filed: December 18, 2017
    Date of Patent: August 24, 2021
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Kazuhisa Yasumoto, Miyuki Abe, Takeshi Nakajima
  • Patent number: 11098143
    Abstract: A process for the polymerization of olefins in gas phase carried out in a reactor having two interconnected polymerization zones, a first zone (riser) and a second zone (downcomer), wherein growing polymer particles: a) flow through the riser under fast fluidization conditions established by feeding a mixture of gas and liquid; b) leave the riser and enter the downcomer, through which the growing polymer particles flow downward in a densified form; and c) leave the downcomer and are reintroduced into the riser, thereby establishing a circulation of polymer between the riser and the downcomer; the reactor is operated at a temperature between 0° C. and 5° C. above the dew point of the riser gas at the operating pressure, and in the riser, besides the growing polymer particles and gas flow, an amount of liquid is present.
    Type: Grant
    Filed: September 13, 2018
    Date of Patent: August 24, 2021
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Antonio Mazzucco, Enrico Balestra, Roberto Pantaleoni, Davide Tartari, Riccardo Rinaldi
  • Publication number: 20210253837
    Abstract: A polypropylene composition made from or containing (i) component (1) made from or containing a propylene homopolymer or copolymer containing 0 to 0.5% by weight of an ethylene-derived unit; (ii) component (2) made from or containing an ethylene/propylene copolymer containing 15 to 30% by weight of an ethylene-derived unit; and (iii) 0.01 to 1.0 parts by weight of a crystal nucleating agent based on a total of 100 parts by weight of component (1) and component (2); wherein 1) the Mw/Mn value of xylene insolubles (XI) is in the range of 6 to 20, 2) the weight ratio of component (1) to component (2) is in the range of 82:18 to 90:10, 3) the intrinsic viscosity of xylene solubles (XSIV) is in the range of 2.5 to 3.4 dl/g, 4) the MFR (at 230° C. under a load of 2.16 kg) is in the range of 3 to 10 g/10 min.
    Type: Application
    Filed: June 19, 2019
    Publication date: August 19, 2021
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: TAKESHI NAKAJIMA, KAZUHIKO SAKAI, KUNIO YAMAMOTO, MASASHI UCHIDA
  • Patent number: 11090625
    Abstract: An apparatus and a method to withdraw samples from a polymerization plant using a defined sequence of steps combined with locking devices for valves opened by a single key.
    Type: Grant
    Filed: January 4, 2019
    Date of Patent: August 17, 2021
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Pier Luigi Di Federico, Martin Andries De Zeeuw
  • Patent number: 11084016
    Abstract: A manhole for a polymerization unit having a through-hole formed with a shoulder matching a corresponding shoulder of a plug of a closure member operatively inserted in the through-hole. The through-hole can be closed with a minimum clearance, such that polymer particles do not deposit in the gap between the wall of the unit and the plug of the closure member.
    Type: Grant
    Filed: July 17, 2018
    Date of Patent: August 10, 2021
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Gian Luca Bonaccorsi, Giuseppe Penzo, Enrico Balestra, Maurizio Dorini, Riccardo Rinaldi
  • Publication number: 20210230412
    Abstract: A polypropylene composition made from or containing a polymer made from or containing: (i) component (1) made from or containing a propylene homopolymer having MFR of 100 to 300 (at a temperature of 230° C. under a load of 2.16 kg) and containing more than 97.5% by weight of xylene insolubles (XI), wherein XI has a Mw/Mn of 4 to 10; (ii) component (2) made from or containing an ethylene/propylene copolymer containing 15 to 50% by weight of an ethylene-derived unit; wherein 1) relative proportions of component (1) and component (2) are, respectively, not less than 50 parts by weight but less than 70 pbw and more than 30 pbw but not more than 50 pbw, 2) intrinsic viscosity of xylene solubles (XSIV) of the polymer is in the range of 1.5 to 4.0 dl/g, 3) MFR of the polymer is in the range of 20 to 100 g/10 min.
    Type: Application
    Filed: April 25, 2019
    Publication date: July 29, 2021
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: YUTAKA YOKOYAMA, AKIHIRO KAMIMURA, HIROSHI KAJIOKA
  • Patent number: 11041033
    Abstract: A butene-1 polymer having: a) a Melt Flow Rate value of from 20 to less than 100 g/10 min., measured according to ISO 1133 at 190° C. with a load of 2.16 kg; b) an intrinsic viscosity (IV) measured in tetrahydronaphthalene (THN) at 135° C. equal to lower than 0.95 dl/g; c) a Mw/Mn value equal to or lower than 3.5 and a lower limit of 1.5; d) a Mz value of 180,000 g/mol or higher; and e) optionally, a comonomer content of up to 10% by weight.
    Type: Grant
    Filed: August 3, 2018
    Date of Patent: June 22, 2021
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Roberta Marchini, Stefano Spataro, Roberta Pica
  • Publication number: 20210179751
    Abstract: A propylene ethylene copolymer having the following features: an ethylene content of between 1.0 and 4.0% by weight; a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 4.0; a content of xylene soluble fraction (XS) and ethylene content (C2) that fulfills the following relationship: (C2×1.1)+1.25<XS<(C2×1.1)+2.50 where: XS=% by weight of the fraction soluble in xylene at 25° C.; C2=% by weight of ethylene units in the copolymer determined via NMR; a melt flow rate (MFR; 230° C., 2.16 kg) of between 30 to 75 g/10 min; an intrinsic viscosity of the copolymer of lower than 1.5 dl/g; and an intrinsic viscosity of the fraction soluble in xylene at 25° C. of higher than 0.32 dl/g.
    Type: Application
    Filed: August 12, 2019
    Publication date: June 17, 2021
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: GIANPIERO FERRARO, GIANNI VITALE, FABRIZIO PIEMONTESI, BENEDETTA GADDI, GIANNI COLLINA, GIAMPIERO MORINI, CAROLINE CATHELIN, MARCO CIARAFONI, CLAUDIO CAVALIERI
  • Patent number: 11034781
    Abstract: A catalyst component made from or containing Ti, Mg, chlorine, an amount of a first internal donor selected from esters of aliphatic monocarboxylic acids (EAA), and an amount of a second internal donor selected from cyclic ethers (CE), wherein the EAA/CE molar ratio ranges from 0.02 to less than 20.
    Type: Grant
    Filed: December 12, 2017
    Date of Patent: June 15, 2021
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Gianni Collina, Maria Di Diego, Benedetta Gaddi, Piero Gessi, Lorella Marturano, Giampiero Morini
  • Publication number: 20210170380
    Abstract: A Mg compound based catalyst precursor made from or containing up to 50% by mols, with respect to Mg, of a compound of formula K(OR1) wherein R1 is H or a C1-C10 hydrocarbon group. When treated with transition metal compounds, the precursor is converted into catalyst with high activity in olefin polymerization.
    Type: Application
    Filed: December 12, 2018
    Publication date: June 10, 2021
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: SIMONA GUIDOTTI, DARIO LIGUORI, GIAMPIERO MORINI