Abstract: The invention relates to fuel additive compositions for internal combustion engines and to fuels that contain the corresponding additives for internal combustion engines. The inventive fuel additive compositions for internal combustion engines have an excellent performance in keeping the inlet system clean and improved viscosity properties, especially at low temperatures.
Abstract: A reactor (1) for gas/liquid or gas/liquid/solid reactions having a vertical longitudinal axis and an inlet (2) for a liquid or liquid/solid feed stream in the upper region of the reactor and an inlet (3) for a gaseous stream in the lower region of the reactor (1), wherein the gaseous stream (3) is conveyed through a gas distributor module (9) which is made up exclusively of straight tube sections (14, 15).
Type:
Application
Filed:
July 1, 2004
Publication date:
January 6, 2005
Applicant:
BASF Aktiengesellschaft
Inventors:
Werner Weinle, Oliver Bey, Peter Zehner
Abstract: The invention relates to a process for obtaining anhydrous or substantially anhydrous formic acid in which, during the work-up, a compound of the general formula I where the radicals R1 and R2 are alkyl, cycloalkyl, aryl or aralkyl groups, or R1 and R2 jointly, together with the N atom, form a heterocyclic 5- or 6-membered ring, and only one of the radicals is an aryl group, and where R3 is hydrogen or a C1-C4-alkyl group, is employed simultaneously as extractant for formic acid and as antifoam for a distillation process.
Type:
Grant
Filed:
January 24, 2001
Date of Patent:
January 4, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Heinz Auer, Bernd Bessling, Hans Hammer, Hans Hasse, Friedrich Sauer, Maximilian Vicari, Gerhard Wagner, Till Adrian
Abstract: Adhesive-coated, peelable protective films and peelable labels, wherein the adhesive contains a copolymer that is capable of undergoing free-radical polymerization and which comprises, to an extent of from 0.1 to 10 wt %, based on the copolymer, a compound A compound of at least one copolymerizable, ethylenically unsaturated group and a group of the formula in which R1 and R2 independently stand for hydrogen or a C1-C5 alkyl group or R1 and R2 together form a bridging C2-C4 alkylene group which can be mono- or di-substituted by a C1-C4 alkoxy group or hydroxyl group and X stands for O or S.
Type:
Grant
Filed:
March 7, 2001
Date of Patent:
January 4, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Christelle Staller, Karl-Heinz Schumacher, Oliver Hartz, Harald Röckel
Abstract: A reactor (1) of high cylindrical construction for continuously carrying out gas-liquid, liquid-liquid or gas-liquid-solid reactions, provided with a downward-directed jet nozzle (2) via which the starting materials and the reaction mixture are fed in and which is located in the upper region of the reactor, and provided with an offtake (3), preferably in the lower region of the reactor, via which the reaction mixture is conveyed via an external circuit back to the jet nozzle (2) by means of a pump (P), wherein a guide tube (4) which extends essentially over the total length of the reactor (1) with the exception of the reactor ends and has a cross-sectional area in the range from one tenth to one half of the cross-sectional area of the reactor (1) is located concentrically in the reactor (1), and the jet nozzle (2) is located above the upper end of the guide tube (4), preferably at a distance of from one eighth of the guide tube diameter to one guide tube diameter, or projects into the guide tube (4) to a dept
Type:
Grant
Filed:
November 23, 1999
Date of Patent:
January 4, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Stefan Berg, Peter Zehner, Regina Benfer, Jörn Müller, Michael Nilles, Ralf Schulz, Dieter Stützer
Abstract: The present invention provides processes for preparing terpyridine compounds. In particular, the present invention provides a process for the preparation of a C1-C4-alkyl pyridine-2-carboxylate compound, a 1,5-bis(2-pyridyl)pentane-1,3,5-trione compound, and a 2,6-bis(2-pyridyl)-4(1H)pyridinone compound.
Type:
Application
Filed:
April 14, 2004
Publication date:
December 30, 2004
Applicant:
BASF Aktiengesellschaft
Inventors:
Ralph Lunkwitz, Gunther Pabst, Gunter Scherr
Abstract: The present invention relates to a container for uptaking, or storing, or releasing, or uptaking and storing, or uptaking and releasing, or storing and releasing, or uptaking, storing and releasing at least one gas, comprising at least one opening for allowing the at least one gas to enter and exit or at least one opening for allowing the at least one gas to enter and at least one opening for allowing the at least one gas to exit said container, and a gas-tight mechanism capable of storing the at least one gas under a pressure of from greater than 45 to 750 bar inside the container, said container further comprising a metallo-organic framework material comprising pores and at least one metal ion and at least one at least bidentate organic compound which is bound to said metal ion, as well as to a fuel cell comprising said container, and to a method of using said container or said fuel cell for supplying power to power plants, cars, trucks, busses, cell phones, and laptops.
Type:
Application
Filed:
June 30, 2003
Publication date:
December 30, 2004
Applicants:
BASF Aktiengesellschaft, University of Michigan
Inventors:
Ulrich Muller, Michael Hesse, Reinhard Hess, Rainer Senk, Markus Hoelzle, Omar M. Yaghi
Abstract: Thermoplastic molding materials containing the following ingredients with regard to components A-F: A) 5-70 wt. % of at least one graft copolymer A) consisting of a rubber elastic base with a glass transition temperature below 0° and a grafted overlay made of a styrene compound and acrylonitrile or methacrylonitrile or mixture thereof in addition to, optionally, other monoethylenically unsaturated monomers, B) 29-90 wt. % of a hard copolymer made of at least one styrene compound, acrylonitrile or methacrylonitrile or mixtures thereof and, optionally, other monoethylenically unsaturated monomers, C) 0-5 wt. % of at least one three-block copolymer X-Y-X with a middle block Y propylenoxide units and terminal block X made of ethyleneoxide units, D) 0.01-5 wt. % of at least one butylated reaction product of cresol with dicyclopentadiene, E) 0.01-5 wt. % of at least one thiocarboxylic acid ester, F) 0.01-5 wt.
Type:
Grant
Filed:
November 25, 2002
Date of Patent:
December 28, 2004
Assignee:
BASF Aktiengesellschaft
Inventors:
Norbert Güntherberg, Bernhard Czauderna, Peter Ittemann
Abstract: A process for preventing undesired polymerization is conducted by maintaining an effective concentration of a stabilizer which comprises N-oxyl radicals in a mixture containing ethylenically unsaturated compounds, wherein
(i) an electronic signal which correlates with the concentration of the N-oxyl radicals in the mixture is obtained periodically or continuously,
(ii) the electronic signal is compared with a reference value, and
(iii) addition of a stabilizer to the mixture is controlled according to the comparison (ii).
The signal is preferably obtained by ESR measurement. The process permits efficient use of the stabilizer.
Type:
Grant
Filed:
December 11, 2001
Date of Patent:
December 28, 2004
Assignee:
BASF Aktiengesellschaft
Inventors:
Heinz Friedrich Sutoris, Konrad Mitulla
Abstract: In a process for the hydroformylation of ethylenically unsaturated compounds, at least one ethylenically unsaturated compound is reacted with carbon monoxide and hydrogen in the presence of a ligand-metal complex of ruthenium, rhodium, palladium, iridium and/or platinum, where the ligand-metal complex comprises a monophosphine, monophosphinite or monophosphinamidite ligand of the formula I
where
A together with the phosphorus atom to which it is bound forms a 2-phosphatricyclo[3.3.1.1{3,7}]decyl radical in which one or more nonadjacent carbon atoms may be replaced by heteroatoms and which may be substituted, and
R′ is hydrogen or an organic radical having a molecular weight of up to 20 000 bound via a carbon atom or oxygen atom or nitrogen atom.
The process is particularly useful for the hydroformylation of internal branched olefins and lower pressures and/or temperatures are required in the hydroformylation than when using other phosphorus ligands.
Abstract: The graft copolymer made from
a1: from 10 to 90% by weight of a particulate graft base A1, made from a particulate emulsion polymer with a glass transition temperature below 0° C.
Type:
Grant
Filed:
October 31, 2002
Date of Patent:
December 28, 2004
Assignee:
BASF Aktiengesellschaft
Inventors:
Michael Breulmann, Sabine Oepen, Norbert Niessner, Norbert Güntherberg, Wil Duijzings, Graham Edmund Mc Kee, Peter Rossmanith
Abstract: A polymer dispersion is prepared by copolymerization of from 20 to 70 parts by weight of a monomer mixture comprising
a) from 2.5 to 100% by weight of one or more (meth)acrylates of monohydric, saturated C3-C8-alcohols as monomers A and
b) from 0 to 97.5% by weight of one or more further ethylenically unsaturated monomers as monomers B
in 100 parts by weight of an aqueous solution which contains from 5 to 35% by weight of a starch or of a starch derivative by emulsion polymerization in the presence of an initiator containing peroxide groups, by a process in which the initiator and monomers are metered in continuously and wherein, a first amount of initiator is metered in over a first feed period of from 5 to 60 minutes and a second amount of initiator is metered in over a second feed period of from 15 to 180 minutes, the first amount of initiator being greater than the second amount of initiator.
Abstract: Process for preparing a supported catalyst (catalyst C) comprising a support (support S) and an active component (activator A), wherein
Type:
Application
Filed:
April 8, 2004
Publication date:
December 23, 2004
Applicant:
BASF Aktiengesellschaft
Inventors:
Markus Schubert, Michael Hesse, Jurgen Stephan, Volker Bohm, Andreas Brodhagen, Frank Poplow, Martina Sinner-Lang, Uwe Diehlmann, Gerhard Cox, Jochen Pfeifer
Abstract: The invention relates to a process for the production of isocyanates by reaction of primary amines with phosgene, in which isocyanate is used as solvent, wherein some or all of isocyanate used as solvent is added to the reaction mixture only after the amine and phosgene have been physically combined.
Type:
Grant
Filed:
December 10, 2003
Date of Patent:
December 21, 2004
Assignee:
BASF Aktiengesellschaft
Inventors:
Andreas Wölfert, Christian Müller, Eckhard Stroefer
Abstract: The use of free-radically polymerized, UV-crosslinkable polymers which consist to the extent of at least 50% by weight of C2 to C18alkyl(meth)acrylates as adhesives for the bonding of carriers coated with the polymer on substrates, wherein from 0.1 to 30% by weight of the monomers of which said polymer is composed are monomers A without carboxylic acid or carboxylic anhydride groups and with a water solubility of more than 5 g of monomers per liter of water and said substrates are moist substrates, especially refrigerated substrates.
Abstract: A process for preparing an aqueous dispersion of particles composed of addition polymer and finely divided inorganic solid (composite particles), in which process a mixture of ethylenically unsaturated monomers is dispersely distributed in aqueous medium and is polymerized by the method of free-radical aqueous emulsion polymerization by means of at least one free-radical polymerization initiator in the presence of at least one dispersely distributed, finely divided inorganic solid and at least one dispersant.
Abstract: In a process for purification of ethylene oxide by distillation an aqueous mixture comprising ethylene oxide, formaldehyde and at least 5% by weight of water is introduced via a feed into a distillation apparatus comprising at least one distillation column, the mixture being introduced at a height above the bottom of at least 8 theoretical stages, the ethylene oxide is taken off at the top and in the bottom phase a mixture is obtained which contains less than 5% by weight of ethylene oxide.
Type:
Grant
Filed:
July 21, 1999
Date of Patent:
December 21, 2004
Assignee:
BASF Aktiengesellschaft
Inventors:
Bernd Bessling, Hans Hasse, Jürgen Plückhan, Thomas Mayer, Heinz Auer
Abstract: The present invention relates to a process for the gas-phase hydrogenation of C4-dicarboxylic acids and/or their derivatives over a catalyst based on copper oxide to give substituted or unsubstituted &ggr;-butyrolactone and/or tetrahydrofuran, which comprises, which a first reaction zone in which the C4-dicarboxylic acid and/or its derivatives is/are reacted to give a mixture comprising a substituted or unsubstituted &ggr;-butyrolactone as main product and a subsequent second reaction zone in which the substituted or unsubstituted &ggr;-butyrolactone present in the mixture from the first hydrogenation step is reacted at a temperature lower than the temperature in the first hydrogenation step to give substituted or unsubstituted tetrahydrofuran.
Type:
Grant
Filed:
June 4, 2003
Date of Patent:
December 14, 2004
Assignee:
BASF Aktiengesellschaft
Inventors:
Holger Borchert, Stephan Schlitter, Rolf-Hartmuth Fischer, Markus Rösch, Frank Stein, Ralf-Thomas Rahn, Alexander Weck, Gerd Kaibel
Abstract: A process for preparing methylenedianiline by reacting aniline with formaldehyde in the presence of acid catalysts comprising, in a semicontinuous process, introducing aniline with or without acid catalyst, feeding formaldehyde with or without acid catalyst through a mixing element into a circuit in which aniline with or without acid catalyst and with or without previously added formaldehyde is circulated and, after feeding in at least 50% of the total amount of formaldehyde to be fed in, heating the reaction mixture to a temperature above 75° C.
In addition, the invention relates to a process for preparing polyisocyanates by phosgenation of amines obtainable in this manner and to the polyisocyanates obtainable by this process.
Type:
Grant
Filed:
May 21, 2002
Date of Patent:
December 14, 2004
Assignee:
BASF Aktiengesellschaft
Inventors:
Eckhard Ströfer, Jan Jacobs, Wilfried Seyfert, Hans Volkmar Schwarz, Olaf Schweers, Volker Scharr, Ulrich Penzel