Abstract: Oligomeric polyfunctional initiators for anionic polymerization of dienes and/or alkenylaromatics are prepared by a process in which a mixture of dialkenylaromatics and alkenylaromatics in a molar ratio of from 1:4 to 1:100, in an inert solvent, is run, at from 25.degree. to 100.degree. C., continuously or in small portions, with thorough mixing, into an initially taken mixture which contains from 1.2 to 3.0 molar equivalents, based on the dialkenylaromatics, of one or more organolithium compounds and an inert solvent, and is polymerized completely. The resulting oligomeric initiators are used for the preparation of unfunctionalized or functionalized polymers or block copolymers from dienes and/or alkenylaromatics, and the functionalized polymers thus prepared are used as prepolymers for other resins.
Abstract: Triazolyl alcohols of the formula ##STR1## their addition salts with acids and their metal complexes, where the steroisomers are in certain ratios, the preparation of these compounds, the preparation of fungicides from these, and the use of these fungicides.
Type:
Grant
Filed:
June 16, 1986
Date of Patent:
April 18, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Hubert Sauter, Ludwig Schuster, Ernst-Heinrich Pommer, Eberhard Ammermann
Abstract: Organic sulfur compounds, such as sulfonic acids, sulfonyl halides, sulfonates, sulfonamides, sulfonic acid anhydrides, sulfones, sulfoxides and/or disulfanes, are reduced by a method in which the sulfur compound in the liquid or gas phase is reacted with a hydrocarbon in the presence of carbon at from 100.degree. to 500.degree. C.
Abstract: Substituted acrylates of the general formula ##STR1## where R.sup.1 and R.sub.2 are alkyl, alkenyl or alkynyl, X is hydrogen, halogen, alkyl, alkoxy, tirfluoromethyl, cyano or nitro, Y is ethylene, ethenylene, methyleneoxy, oxymethylene, thiomethylene, methylenethio or oxygen, R is hydrogen, substituted or unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl or cycloalkynyl, and fungicides containing these compounds.
Type:
Grant
Filed:
June 19, 1987
Date of Patent:
April 18, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Stefan Karbach, Ulrich Schirmer, Costin Rentzea, Ernst-Heinrich Pommer, Eberhard Ammermann, Wolfgang Steglich, Barbara A. M. Schwalge, Timm Anke
Abstract: Cyclopentanone is prepared from adipic esters by reacting adipic esters of the formulaR.sup.1 OOC--(CH.sub.2).sub.4 --COOR.sup.2where R.sup.1 and R.sup.2 are alkyl of 1 to 12 carbon atoms, cycloalkyl of 5 or 6 carbon atoms, aralkyl or aryl and R.sup.2 can additionally be hydrogen, in the gas or liquid phase at from 150.degree. C. to 450.degree. C. in the presence of zeolitic catalysts and/or phosphate catalysts, preferably zeolites of the pentasil type.
Type:
Grant
Filed:
November 5, 1987
Date of Patent:
April 18, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Helmut Lermer, Wolfgang Hoelderich, Matthias Schwarzmann
Abstract: The blanks punched out from a film web and folded to form the jacket are then heated for a short time and cooled again in order to eliminate stresses in the jacket material which give rise to deformations and are also produced by the action of heat during processing of the material.
Type:
Grant
Filed:
March 22, 1988
Date of Patent:
April 18, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Bernhard Lenz, Kurt Zwintzscher, Dietrich Gruehn, Hubert Fehrenbach, Norbert Holl
Abstract: The invention relates to photopolymerizable, sheet-like molding materials containing a mixture of an unsaturated polyester, monomers, a thickener, pulverulent and/or fibrous additives and metal wire inserts. The molding materials can be shaped, for example by pressing or deep-drawing, to give dimensionally staple semi-finished products which are cured to give finished articles. The latter can be employed as automotive components or domestic appliance components.
Abstract: Copolymers containing from 5 to 50 mol % of monomers having o-nitrocarbinol ester groups, from 94 to 30 mol % of methacrylonitrile, from 1 to 20 mol % of olefinically unsaturated copolymerizable carboxylic acid and from 0 to 30 mol % of other copolymerizable monomers as copolymerized units are useful for fabricating semiconductor components.
Abstract: Compounds of the formula I ##STR1## where R.sup.1 and R.sup.2 are identical or different and are each hyrogen or alkyl of 1 to 5 carbon atoms, the radicals X are identical or different substituents selected from the group consisting of halogen, cyano, trifluoromethyl, nitro, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, unsubstituted or substituted phenyl or hydrogen, m is from zero to 5, n is an integer from 2 to 6 and Y is --CO-- or --CH(OH)--, their intermediates of the formula (II) ##STR2## and the use of the compounds (I) as plant growth regulators.
Type:
Grant
Filed:
April 25, 1986
Date of Patent:
April 18, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Costin Rentzea, Hubert Sauter, Wolfgang Tuerk, Bernd Wenderoth, Winfried Richarz, Johann Jung, Wilhelm Rademacher
Abstract: Decene oligomers useful with or without hydrogenation as basis for synthetic lubricating oils are prepared by oligomerizing decene-1 in the presence of an alkylaluminum chloride catalyst and an alkyl halide cocatalyst, in a first reaction stage the decene-1 being mixed with the catalyst at from 0 to +25.degree. C. and being kept in contact therewith within the same temperature range for not less than 15 minutes and in a second reaction stage the cocatalyst being added at from 0 to +35.degree. C. in the course of a period of from 15 to 180 minutes.
Type:
Grant
Filed:
December 3, 1987
Date of Patent:
April 18, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Klaus Bronstert, Helmut Mach, Hans P. Rath, Hans-Michael Walter
Abstract: A low-dust, free-flowing choline chloride powder based on natural carriers or silica, the choline chloride content on natural carriers being from 30 to 60% by weight and that on silica being from 30 to 80% by weight, based on the choline chloride powder, is prepared by a process in which(a) choline chloride solution is mixed with the carrier in the desired ratio within the stated range,(b) the resulting mixture is sprayed continuously into a fluidized bed already containing dry choline chloride powder and is dried there at from 90.degree. to 180.degree. C., and(c) the dried end product is removed from the fluidized bed and cooled to below 50.degree. C.
Type:
Grant
Filed:
June 30, 1987
Date of Patent:
April 11, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Robert Bayer, Guenter Boettger, Rainer Hiller, Michael Huber, Wolfgang Koernig, Wolfgang Fritz
Abstract: Novel compounds of the general formula I ##STR1## where X is hydrogen, nitro or unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aryl or hetaryl, Y is cyano, nitro, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl, R is unsubstituted or substituted alkyl or aryl, R.sup.1 is hydrogen or R.sup.2, and R.sup.2 is unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl or aryl, are useful for dyeing textile fibers, in particular polyesters.
Abstract: Pyridazinone derivatives of the formula ##STR1## where R.sup.1 is alkyl, alkenyl, cycloalkyl or unsubstituted or substituted phenyl, R.sup.2 is chlorine or bromine, R.sup.3 is hydrogen, alkyl, cycloalkyl or unsubstituted or substituted phenyl and X is SO or SO.sub.2, with the proviso that R.sup.1 is not methyl when X is SO.sub.2, R.sup.2 is chlorine and R.sup.3 is phenyl, and fungicides containing these compounds.
Abstract: Benzaldehyde dialkyl acetals of the formula ##STR1## where R is alkyl of 1 to 4 carbon atoms, are prepared by electrochemical oxidation of 3-tert-butyl-4-methoxytoluene in the presence of an alkanol of the formula ROH and are used as scents or scent intermediates.
Type:
Grant
Filed:
April 13, 1988
Date of Patent:
April 11, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Dieter Degner, Walter Gramlich, Franz Lanzendoerfer, Hardo Siegel
Abstract: .beta.-Aryl alcohols for the general forumla I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different and each is hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, aryl, C.sub.7 -C.sub.12 -aralkyl or C.sub.7 -C.sub.12 -alkaryl, n is 0, 1, 2, 3 or 4, or where two adjacent R.sup.1 's are linked to form a 5- or 6-membered ring, are prepared by reacting an aromatic of the formula II ##STR2## with an alkylene oxide of the formula III ##STR3## where R.sup.1, R.sup.2 and R.sup.3 have the abovementioned meanings, in the presence of a Friedel-Crafts catalyst, by carrying out the reaction in the presence of a titanium(IV) alcoholate at from -20.degree. to +40.degree. C. in the presence or absence of a solvent.
Abstract: Novel 1-phenyl-4(1H)-pyridazinone-imines of the formula (I) ##STR1## which are substituted at the imine nitrogen, and their addition salts with a physiologically tolerated acid, processes for their preparation, pharmaceutical formulations containing these compounds, and their use as drugs, in particular as antidepressants, antiparkinson drugs and antihypotonic agents.
Type:
Grant
Filed:
April 17, 1987
Date of Patent:
April 11, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Rudolf Kropp, Marco Thyes, Rainer Schlecker, Albrecht Franke, Franz Reicheneder, Dora I. Reicheneder, August Amann, Hans-Juergen Teschendorf, Rolf Kretzschmar, Martin Traut, Josef Gries
Abstract: The yield of 2,5,6-trimethyl-cyclohex-2-en-1-one is increased by reacting diethyl ketyone, in the presence of an alkali, with crotonaldehyde or a compound which is converted to crotonaldehyde under the reaction conditions chose, and working up the reaction mixture by distillation, by a method in which the distillation residue obtained is either(a) heated at from 120.degree. to 250.degree. C. in particular from 120.degree. to 200.degree. C., with the addition of a catalytic amount of an alkali, or(b) heated at from 150.degree. to 250.degree. C. without the addition of such a substance,and the mixture of 2,5,6-trimethylcyclohex-2-en-1-one and diethyl ketone which is formed from the distillation residue as a result of the heat treatment is separated by distillation.
Type:
Grant
Filed:
October 23, 1987
Date of Patent:
April 11, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter Tavs, Harald Laas, Horst Schauer, Lothar Arnold
Abstract: Cyclohexenone derivatives of the general formula ##STR1## where R is C.sub.1 -C.sub.6 -alkyl, cyclopropyl, phenyl or C.sub.2 -C.sub.6 -alkoxyalkyl, R.sup.1 is hydrogen, tetrahydropyran-2-yl, benzoyl or unsubstituted or halo-substituted C.sub.1 -C.sub.6 -alkanoyl, and R.sup.2 is hydrogen or C.sub.1 -C.sub.6 -alkyl, and phytophysiologically tolerable salts thereof, and their use for regulating plant growth.
Type:
Grant
Filed:
December 3, 1987
Date of Patent:
April 11, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Michael Keil, Ulrich Schirmer, Dieter Kolassa, Juergen Kast, Wilhelm Rademacher, Johann Jung
Abstract: Photostabilized polymers, including polyurethanes and plastics coatings, contain as photostabilizer one or more compounds of the formula ##STR1## or a novel imidazole-2-carboxanilide of the formula ##STR2##
Type:
Grant
Filed:
March 14, 1988
Date of Patent:
April 11, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter Spang, Peter Neumann, Gerhard Wagenblast, Hubert Trauth
Abstract: Paper and paperboard of high dry strength are produced by adding a dry strength enhancer to the paper stock and dewatering the paper stock with sheet formation by using as the dry strength enhancer a mixture of a cationic polymer which contains as characteristic monomers copolymerized units of(a) diallyldimethylammonium chloride,(b) N-vinylamine or(c) a substituted or unsubstituted N-vinylimidazoline and has a K value of not less than 30, and natural potato starch which is converted into a water-soluble form by heating in an aqueous medium at above the gelatinization temperature of natural potato starch in the absence of any oxidizing agents or alkali.
Type:
Grant
Filed:
February 12, 1988
Date of Patent:
April 4, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Hans-Juergen Degen, Sigberg Pfohl, Volkmar Weberndoerfer, Gerd Rehmer, Michael Kroener, Andreas Stange