Patents Assigned to BASF Aktiengesellschaft
  • Patent number: 4845266
    Abstract: A process for the preparation of polyester polyols having an acid number of less than 1, a hydroxyl number of approximately 20 to about 400, and having a functionality of efficaciously 2 to 3, wherein polycarboxylic acids and/or their anhydrides and multivalent alcohols are polycondensed, preferably in the absence of common esterification catalysts, at temperatures of from about 150.degree. to 250.degree. C., optionally under reduced pressure, up to an acid number of from 20 to 5. The resulting polycondensate is then oxyalkylated per carboxyl group using from 1 to 5 moles of an alkylene oxide, for example 1,2-propylene oxide and/or preferably ethylene oxide, in the presence of at least one tertiary amine catalyst from the group consisting of N-methylimidazole, diazabicyclo[2,2,2]octane, diazabicyclo[5,4,0]undec-7-ene and pentamethyldiethylenetriamine and mixtures thereof, in a quantity of from about 0.001 to 1.0 weight percent based on the weight of the polycondensate, at temperatures from about 100.degree.
    Type: Grant
    Filed: April 10, 1987
    Date of Patent: July 4, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Marx, Joachim Jaehme, Joachim Streu
  • Patent number: 4845269
    Abstract: 3-pentenoates are prepared from 2-pentenoates by a process in which(a) a 2-pentenoate of the formula ##STR1## where R.sup.1 is alkyl of 1 to 12 carbon atoms, cycloalkyl of 5 to 8 carbon atoms, aralkyl of 7 to 10 carbon atoms or aryl of 6 to 10 carbon atoms, is reacted with a compound of the formula IIR.sup.2 -X-H IIwhere R.sup.2 has the meanings given for R.sup.1 and X is an oxygen or sulfur atom, or with a compound of the formula III ##STR2## where R.sup.3 is hydrogen or R.sup.3 and R.sup.4 are each alkyl of 1 to 12 carbon atoms, cycloakkyl of 5 to 8 carbon atoms, aralkyl of 7 to 10 carbon atoms or aryl of 6 to 10 carbon atoms, and R.sup.3 and R.sup.4 together with the nitrogen atom on which they are substituents may form a 5-membered to 7-membered ring which may additionally contain a nitrogen or oxygen atom as a hetero atom, at from 20.degree. to 300.degree. C., in the presence or absence of a basic catalyst, to give a compound of the formula IV ##STR3## where Y is --XR.sup.2 or ##STR4## in which X, R.sup.
    Type: Grant
    Filed: November 25, 1987
    Date of Patent: July 4, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Rolf Fischer, Wolfgang Hoelderich, Manfred Sauerwald
  • Patent number: 4845218
    Abstract: A process for the preparation of N-methylpiperazine from diethanolamine and methylamine, wherein the reaction is carried out at elevated temperature and superatmospheric pressure in the presence of hydrogen over a metal-containing catalyst.
    Type: Grant
    Filed: February 17, 1987
    Date of Patent: July 4, 1989
    Assignee: BASF Aktiengesellschaft
    Inventor: Wolfgang Schroeder
  • Patent number: 4845147
    Abstract: Nonaqueous polymer dispersions are obtainable by polymerization of esters (A) of acrylic acid and/or methacrylic acid and/or ethylacrylic acid with C.sub.1 -C.sub.20 -alcohols in an organic solvent or a mixture of organic solvents in which the polymers formed are insoluble, and in the presence of copolymers (B) having a molecular weight of from 500 to 20,000 and obtainable by bulk or solution polymerization of monoolefinically unsaturated monomers at from 180.degree. to 400.degree. C. and from 1 to 200 bar, and the said dispersions are used for the production of finishes, coating materials and adhesives.
    Type: Grant
    Filed: April 1, 1988
    Date of Patent: July 4, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Blum, Gerd Rehmer, Rolf Osterloh, Hans Sander
  • Patent number: 4845013
    Abstract: Relief plates which are produced by imagewise photopolymerization of layers which contain, as binders, block copolymers of conjugated dienes and vinylaromatics are aftertreated with an aqueous solution of a mixture of bromates, bromides and acids by a process in which amidosulfonic acid and/or aliphatic di-, tri- and/or tetracarboxylic acids are used as the acids.
    Type: Grant
    Filed: November 28, 1988
    Date of Patent: July 4, 1989
    Assignee: BASF Aktiengesellschaft
    Inventor: Helmut Bach
  • Patent number: 4844733
    Abstract: N-aryltetrahydrophthalimide derivatives and intermediates therefor of the general formula I ##STR1## where A is O.sub.2 N--, H.sub.2 N-- or ##STR2## corresponding to compounds Ia, Ib and Ic, R.sup.1 is hydrogen, fluorine or chlorine,R.sup.2 is hydrogen or cyano,R.sup.3 is C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, which each may be substituted by halogen or C.sub.1 -C.sub.4 -alkoxy, or is C.sub.1 -C.sub.3 -alkyl, which may be substituted by C.sub.3 -C.sub.8 -alkenyl, C.sub.3 -C.sub.8 -alkynyloxycarbonyl or C.sub.2 -C.sub.10 -alkoxycarbonyl which may be substituted in the alkoxy moiety by C.sub.1 -C.sub.4 -alkoxy, halogen or phenyl,and herbicides which contain compounds of the formula Ic.
    Type: Grant
    Filed: March 5, 1987
    Date of Patent: July 4, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl Eicken, Peter Plath, Bruno Wuerzer, Norbert Meyer
  • Patent number: 4844714
    Abstract: Fuels for gasoline engines and diesel engines contain small amounts(A) of an alkoxylate which is obtained by reacting ethylene oxide, propylene oxide or butylene oxide with a mono- or polyhydroxy compound and has a number average molecular weight (molecular mass) of from 500 to 6,000 and(B) of an imide or amidoimide, or a mixture of these, obtained from nitrilotriacetic acid and/or ethylenediaminetetraacetic acid and an amine of 7 to 18 carbon atoms, or a mixture of such amines, of the formula I ##STR1## where the radicals X are identical or different --HN--R radicals or adjacent radicals X are the radical >N--R and form a ring ##STR2## m is 0 or 1 and R is a straight-chain or branched aliphatic radical of 7 to 18 carbon atoms.
    Type: Grant
    Filed: March 4, 1988
    Date of Patent: July 4, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Henning Vogel, Hans P. Rath, Knut Oppenlaender, Charalampos Gousetis
  • Patent number: 4845214
    Abstract: Isoindoline pigments are conditioned by means of a heat treatment of the pigment in a mixture of water and benzenemonocarboxylic and/or benzenedicarboxylic acids.Well crystallized, very weatherfast pigmentary forms which give colorations possessing improved purity of shade are obtained.
    Type: Grant
    Filed: July 7, 1986
    Date of Patent: July 4, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Lotsch, Reinhard Kemper
  • Patent number: 4843171
    Abstract: 1,1-Dialkoxy-2-methyl-4,4-diacyloxy-2-butenes having the general structure: ##STR1## in which R.sub.1 represents alkyl substituents having from 1 to 5 carbon atoms, or both R.sub.1 substituents together represent a single ethylene or propylene substituent, or a single C.sub.1 -C.sub.2 alkyl substituent, and R.sub.2 represents alkyl substituents having from 1 to 5 carbon atoms, or cycloalkyl substituent having from 5 to 7 carbon atoms, or aromatic substituents (preferably phenyl substituents). These new compounds are useful as building blocks in the synthesis of terpenes and carotenoids.
    Type: Grant
    Filed: July 1, 1987
    Date of Patent: June 27, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernhard Schulz, Rolf Fischer
  • Patent number: 4842638
    Abstract: Tetrahydro(thio)pyran-2,4-dione derivatives of the formula ##STR1## where R.sup.1 is hydrogen, a cation, alkylcarbonyl, C.sub.2 -C.sub.10 -alkenylcarbonyl, or benzoyl which is unsubstituted or substituted by alkyl, R.sup.2 is alkyl, R.sup.3 is a non-aromatic, unsubstituted or alkyl-substituted heterocyclic compound of 5 to 7 ring members and having at most one double bond in the heterocyclic ring, X is oxygen or sulfur, and Z is oxygen or the radical NO--R.sup.4, R.sup.4 denoting alkyl, alkenyl, alkynyl, haloalkyl, hal oalkenyl, alkoxyalkyl or the radical CH.sub.2 --R.sup.5, where R.sup.5 is a he terocyclic compound of 5 ring members and containing from 1 to 3 hetero-atoms and from 0 to 2 double bonds and bearing either no substituents or one or two substituents selected from the group consisting of alkyl, alkoxy, halogen, trifluoromethyl, alkoxymethyl, alkylthiomethyl and vinyl, or R.sup.
    Type: Grant
    Filed: January 12, 1988
    Date of Patent: June 27, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Kast, Michael Keil, Dieter Kolassa, Ulrich Schirmer, Bruno Wuerzer, Norbert Meyer, Wilhelm Rademacher, Johann Jung
  • Patent number: 4843153
    Abstract: Thienothiophene dyes of the formula ##STR1## wherein Z is carboxylate, acyl, carboxyl, substituted or unsubstituted carbamoyl, cyano or nitro, X is hydrogen, fluorine, chlorine, bromine, Z or a group of the formula ##STR2## T.sup.1 and T.sup.2 are identical or different and each is independently of the other cyano, substituted or unsubstituted alkoxycarbonyl, alkenyloxycarbonyl, carbamoyl or alkylcarbamoyl and W is hydrogen, methyl or ethyl, Y is hydrogen, chlorine or bromine and K is the radical of a coupling component, are highly suitable for dyeing synthetic fibers, in particular polyesters wherein the dyeing obtained have good fastness properties.
    Type: Grant
    Filed: July 1, 1987
    Date of Patent: June 27, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinz Eilingsfeld, Karl-Heinz Etzbach, Guenter Hansen, Helmut Reichelt
  • Patent number: 4842700
    Abstract: Cyclic hemiacetals thereof of the formula ##STR1## where A is saturated hydrocarbyl of 2 to 16 carbon atoms which may contain --O-- as a bridge member are prepared by subjecting cyclic ethers of the formula ##STR2## where A has the abovementioned meaning, to anodic oxidation in aqueous solution at current densities of over 30 mAcm.sup.-2.
    Type: Grant
    Filed: May 7, 1987
    Date of Patent: June 27, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Fritz Beck, Bernd Wermeckes, Harry Schulz
  • Patent number: 4842896
    Abstract: Magnetic recording media, consisting of a non-magnetic base and a magnetic layer firmly bonded thereto, exhibit improved properties in sustained operation if, in the course of their production, a dispersion of inorganic particles in a solvent is applied to the magnetic layer, and the solvent is then removed.
    Type: Grant
    Filed: September 22, 1987
    Date of Patent: June 27, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Werner Grau, Albert Kohl, Jenoe Kovacs, Werner Balz, Wulf Muenzer
  • Patent number: 4843132
    Abstract: Polymers of propene are prepared using a Ziegler-Natta catalyst system consisting of (1) a titanium component which contains titanium, magnesium, chlorine and a benzenecarboxylic acid derivative on a carrier, (2) an aluminum component and (3) a silane component. The process employs a titanium component (1) which is obtained by a method in which (1.1) first a solid-phase intermediate is prepared from (I) magnesium chloride, (II) an alkanol, (III) a carrier which in turn consists of a finely divided inorganic oxide carrier material which has been pretreated with an alkylchlorosilane, (IV) titanium tetrachloride and (V) a phthalic acid derivative, in such a way that (1.1.1) first (I) is reacted with (II), (1.1.2) then the carrier (III) is introduced into the substance resulting from (1.1.1), (1.1.3) thereafter the solid-phase substance resulting from (1.1.2) is reacted with (IV) in a liquid hydrocarbon, with the proviso that (V) is also introduced in (1.1.1) or (1.1.2) or (1.1.3), the (1.
    Type: Grant
    Filed: April 1, 1988
    Date of Patent: June 27, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer A. Werner, Ralf Zolk
  • Patent number: 4842987
    Abstract: A photosensitive recording element which is suitable for the production of printing plates or resist images possesses a photopolymerizable recording layer which is applied to a dimensionally stable base, can be developed in an aqueous alkaline medium and contains, as a polymeric binder, one or more film-forming copolymers which are insoluble in water but soluble or dispersible in aqueous alkaline solutions and consist of from 10 to 50% by weight of one or more N-vinylamides, preferably N-vinylcaprolactam and/or N-vinylpyrrolidone, from 5 to 30% by weight of acrylic acid and/or methacrylic acid, from 30 to 80% by weight of one or more comonomers from the group consisting of the vinyl aromatics and (meth)acrylates of monoalkanols and from 0.2 to 5% by weight of an olefinically unsaturated compound which contains basic nitrogen atoms and has a pK.sub.a >4.
    Type: Grant
    Filed: June 15, 1987
    Date of Patent: June 27, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Albert Elzer, Axel Sanner, Hans Schupp, Erich Beck
  • Patent number: 4841066
    Abstract: 3-Methyl-1-vinylimidazolium chlorides are prepared by quaternizing N-vinylimidazoles in aqueous solution with methyl chloride and are used for the preparation of water-soluble homo- or copolymers.
    Type: Grant
    Filed: May 13, 1987
    Date of Patent: June 20, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Helmut Goertz, Ferdinand Straub, Axel Sanner, Albrecht Kolb, Hans-Juergen Raubenheimer, Friedrich Vogel
  • Patent number: 4840990
    Abstract: The present invention relates to aqueous binder dispersions for the preparation of, inter alia, paints and finishes, substantially containing(A) from 0.5 to 50% by weight of a phenolic resin precondensate,(B) from 20 to 70% by weight of a copolymer of predominant proportions of alkyl acrylates and/or methacrylates, minor proportions of comonomers with groups capable of crosslinking and other comonomers, the copolymer being in the form of a dispersion and being crosslinkable by a condensation reaction, and(C) from 10 to 70% by weight of a graft elastomer comprising a diene polymer as the base polymer and a copolymer of, substantially, styrene, acrylonitrile and C.sub.1 -C.sub.6 -alkyl acrylates and/or methacrylates, as the graft polymer, the graft elastomer being in the form of a dispersion, the percentages being based on the solids content of the total amount of (A), (B) and (C).
    Type: Grant
    Filed: September 26, 1988
    Date of Patent: June 20, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Erich Gullbins, Graham E. McKee, Gregor Ley
  • Patent number: 4840976
    Abstract: Closed-celled foams of high compressive strength are obtained by extruding a mixture of a styrene polymer and from 8 to 16% by weight of a blowing agent mixture containing from 2 to 20% by weight of ethyl chloride, from 2 to 20% by weight of carbon dioxide, from 20 to 80% by weight of dichlorodifluoromethane and from 10 to 60% by weight of monochlorodifluoromethane.
    Type: Grant
    Filed: July 8, 1988
    Date of Patent: June 20, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Reinhold Weber, Ludwig Zuern, Manfred Weilbacher
  • Patent number: 4840736
    Abstract: A process for dewatering sewage sludges of which the sludge solids contain less than 70% of organic matter, and whose dewatering characteristics have been improved by adding organic flocculants, on a filter press, wherein the sewage sludges are concentrated by adding an organic flocculant during thickening by gravity sedimentation from 0.5-5.0% by weight of sludge solids to 6-14, and especially 8-12, % by weight of sludge solids, the sewage sludges are mixed with additives, such as finely divided coal or ash or mixtures thereof, in an amount of from 0.5 to 1.5 parts by weight per part by weight of sludge solids, and the sludges are treated, before, during or after admixture of the additives, with a further 2-8 kg or organic flocculant/tonne of sludge solids and are then dewatered on the filter press.
    Type: Grant
    Filed: September 22, 1983
    Date of Patent: June 20, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Bruno Sander, Herbert Lauer, Manfred Neuwirth
  • Patent number: 4840677
    Abstract: A plateletlike two-phase pigment which has a core with a hematite structure of the compositionAl.sub.x Fe.sub.2-x O.sub.3where x is from 0.02 to 0.5, and an outer layer with a spinal structure of the compositionAl.sub.y Fe.sub.3-y O.sub.4+zwhere y is from 0.03 to 0.75 and z is from 0 to 0.5, can be prepared by a hydrothermal treatment of plateletlike Al.sub.x Fe.sub.2-x O.sub.3 pigments (x from 0.02 to 0.5) in the presence of a reducing agent dissolved in the aqueous phase.
    Type: Grant
    Filed: June 2, 1988
    Date of Patent: June 20, 1989
    Assignee: BASF Aktiengesellschaft
    Inventor: Werner Ostertag