Abstract: The present invention is directed to a catalyst suitable for catalyzing a Fischer-Tropsch reaction, said catalyst comprising cobalt metal supported on zinc-oxide and an amount of zirconium(IV)oxide and/or aluminium oxide of between 0.5 and 2.5 wt. % calculated as metal, based on the weight of the calcined catalyst.
Abstract: Disclosed are zeolite catalysts having the CHA crystal structure with a low silica to alumina ratio, as well as articles and systems incorporating the catalysts and methods for their preparation and use. The catalysts can be used to reduce NOx from exhaust gas streams, particularly those emanating from gasoline or diesel engines.
Abstract: A cracking catalyst contains a substantially inert core and an active shell, the active shell containing a zeolite catalyst and a matrix. Methods of making and using the cracking catalyst are also described.
Type:
Application
Filed:
June 12, 2008
Publication date:
January 6, 2011
Applicant:
BASF Catalysts LLC
Inventors:
David Matheson Stockwell, John M. Macaoay
Abstract: Disclosed are dehydrogenation catalyst composites and methods of making the dehydrogenation catalyst composites. The dehydrogenation catalyst composites contain alumina, lithium oxide, alkaline earth metal oxide, chromium oxide, and sodium oxide. Also disclosed are methods of dehydrogenating a dehydrogenatable hydrocarbon involving contacting the dehydrogenatable hydrocarbon with a dehydrogenation catalyst composite containing alumina, lithium oxide, alkaline earth metal oxide, chromium oxide, and sodium oxide to provide a dehydrogenated hydrocarbon, such as an olefin.
Type:
Application
Filed:
June 5, 2009
Publication date:
December 9, 2010
Applicant:
BASF CATALYSTS LLC
Inventors:
Wolfgang Ruettinger, Michael Joseph Breen, Richard Jacubinas, Saeed Alerasool
Abstract: A method for recovering catalytic elements from a fuel cell membrane electrode assembly is provided. The method includes converting the membrane electrode assembly into a particulate material, wetting the particulate material, forming a slurry comprising the wetted particulate material and an acid leachate adapted to dissolve at least one of the catalytic elements into a soluble catalytic element salt, separating the slurry into a depleted particulate material and a supernatant containing the catalytic element salt, and washing the depleted particulate material to remove any catalytic element salt retained within pores in the depleted particulate material.
Type:
Application
Filed:
May 15, 2009
Publication date:
November 18, 2010
Applicant:
BASF Catalysts LLC
Inventors:
Lawrence Shore, Ramail Matlin, Robert Heinz
Abstract: Sorbents for removal of mercury and other pollutants from gas streams, such as a flue gas stream from coal-fired utility plants, and methods for their manufacture and use are disclosed. The methods include injecting a sorbent consisting essentially of recovered and separated fluid cracking catalyst particles into a flue gas stream.
Type:
Application
Filed:
March 31, 2010
Publication date:
October 21, 2010
Applicant:
BASF Catalysts LLC
Inventors:
Xiaolin D. Yang, David M. Stockwell, Pascaline H. Tran, Lawrence Shore
Abstract: An oxidation catalyst composite, methods and systems for the treatment of exhaust gas emissions from an advanced combustion engine, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO) and the reduction of nitrogen oxides (NOx) from a diesel engine and an advanced combustion diesel engine are disclosed. More particularly, washcoat compositions are disclosed comprising at least two washcoat layers, a first washcoat comprising a palladium component and a second washcoat containing platinum and at least about 50% of the total platinum is located in the rear of the catalyst.
Abstract: Systems and methods for abating NOx emission in an exhaust stream are provided. Systems comprising hydrocarbon conversion over a partial oxidation catalyst in a slip stream and a hydrocarbon selective catalytic reduction catalyst are described. The emissions treatment system is advantageously used for the treatment of exhaust streams from lean burn engines including diesel engines, lean burn gasoline engines and locomotive engines.
Type:
Application
Filed:
March 26, 2010
Publication date:
October 7, 2010
Applicant:
BASF Catalysts LLC
Inventors:
Chung-Zong Wan, Patrick Burk, Xiaolai Zheng
Abstract: Systems and methods for abating NOx in an exhaust stream are provided. System using a lean NOx trap, an air injector and optional catalysts and filters are described. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.
Abstract: The invention is directed to a process for the purification of benzene feedstock containing contaminating sulfur compounds, more in particular thiophenic sulfur compounds, said process comprising contacting the benzene feedstock in the presence of hydrogen with a sulfided nickel adsorbent, wherein in said adsorbent part of the nickel is present in the metallic form, and subsequently contacting the said feedstock with a supported metallic copper adsorbent.
Abstract: Catalyst articles comprising palladium and related methods of preparation and use are disclosed. Disclosed is a catalyst article comprising a first catalytic layer formed on a substrate, wherein the first catalytic layer comprises palladium impregnated on a ceria-free oxygen storage component and platinum impregnated on a refractory metal oxide, and a second catalytic layer formed on the first catalytic layer comprising platinum impregnated on an oxygen storage component and rhodium impregnated on a zirconia-coated or yttria-coated alumina. The palladium component of the catalyst article is present in a higher proportion relative to the other platinum group metal components. The catalyst articles provide improved reductions in NOx in exhaust gases, particularly after lean-rich aging.
Type:
Application
Filed:
February 17, 2010
Publication date:
August 26, 2010
Applicant:
BASF Catalysts LLC
Inventors:
Xinsheng Liu, Ye Liu, Pascaline Tran, Michael Galligan, Wenyong Lin, Keshavaraja Alive
Abstract: Provided are catalyst composites that can be used in methods for treating exhaust gas from internal combustion engines, including diesel and gasoline engines, systems including such catalyst composites and methods of using the catalyst composites to treat internal combustion engine exhaust. The catalyst composites may provide diesel oxidation catalysts and three-way catalysts. A catalyst composite is provided which a catalytic material on a carrier, the catalytic material including a palladium component dispersed on a first support comprising at least 60% by weight of a zirconia component, and one or more rare earth oxides selected from the group consisting of lanthana, neodymia, praseodymia, yttria, the first support optionally containing no more than 15% by weight ceria, and being free of alumina. Layered catalyst composites having one or more washcoats on the carrier are also provided.
Type:
Application
Filed:
February 17, 2010
Publication date:
August 26, 2010
Applicant:
BASF Catalysts LLC
Inventors:
Michel Deeba, Tian Luo, Josephine Ramos
Abstract: A method for generating chlorine dioxide is disclosed in which chlorine dioxide generation is activated with a dry polar material. A system for generating chlorine dioxide is also disclosed, as well as compositions useful in the system and method.
Abstract: Provided is a process for producing ammonia by the catalytic reduction of nitrogen oxide in the presence of a hydrocarbon, and in certain embodiments, in the presence of an oxygenated hydrocarbon.
Type:
Application
Filed:
January 28, 2010
Publication date:
August 19, 2010
Applicant:
BASF Catalysts LLC
Inventors:
Howard FURBECK, Gerald S. Koermer, Ahmad Moini, Steven J. Schmieg
Abstract: Sorbents for removal of mercury and other pollutants from gas streams, such as a flue gas stream from coal-fired utility plants, and methods for their manufacture and use are disclosed. Embodiments include brominated sorbent substrate particles having a carbon content of less than about 10%. Other embodiments include one or more oxidatively active halides of a nonoxidative metal dispersed on sorbent substrate particles mixed with activated carbon in an amount up to 30% by weight. Further embodiments include physical blending of a flow modifier into the sorbent composition.
Type:
Application
Filed:
February 17, 2010
Publication date:
August 12, 2010
Applicant:
BASF Catalysts LLC
Inventors:
Xiaolin D. Yang, Pascaline H. Tran, Lawrence Shore
Abstract: Methods, compositions, devices, and systems for administration to a biological tissue of a composition comprising a chlorine dioxide source are provided.
Type:
Application
Filed:
January 20, 2010
Publication date:
August 5, 2010
Applicant:
BASF Catalysts LLC
Inventors:
Barry Keven Speronello, Linda Hratko, Frank S. Castellana, Andrew Patrick Full, Marcos Gomez
Abstract: A conductive composition having a conductive component, a glass frit component, an organic medium, a boride component and a platinum group metal component, is provided. Embodiments of the conductive composition incorporate a palladium component and boride component selected from ZrB2, TiB2 and LaB6 and combinations thereof and having a Mohs hardness of about 7 or greater. Embodiments of articles with a conductive composition disposed thereon and methods of preparing such articles are also provided.
Type:
Application
Filed:
February 2, 2009
Publication date:
August 5, 2010
Applicant:
BASF Catalysts LLC
Inventors:
Robert Prunchak, Francisco Vieira, Xuerong Gao, Virginia Garcia
Abstract: Methods, devices, compositions, and systems for the alleviation of non-oral biological tissue infections by administration of chlorine dioxide are provided.
Type:
Application
Filed:
January 20, 2010
Publication date:
August 5, 2010
Applicant:
BASF Catalyst LLC
Inventors:
Andrew Patrick Full, Marcos Gomez, Frank S. Castellana, Barry Keven Speronello
Abstract: Provided is an emissions treatment system and method for reducing NOx emissions in the exhaust stream produced from an internal combustion engine. The system has an injector for periodically metering ammonia or an ammonia precursor into an exhaust stream; and a first substrate with a first SCR catalyst composition, downstream of the injector. The first substrate has an inlet end, an outlet end, a length extending between the inlet end to the outlet end, and wall elements. The first SCR catalyst composition is disposed on the wall elements from the inlet end toward the outlet end to form an inlet zone. The first substrate also has an NH3 destruction catalyst composition with a platinum group metal component dispersed on a refractory metal oxide. The NH3 destruction catalyst is disposed on the wall elements from the outlet end to form an outlet zone.
Type:
Grant
Filed:
December 18, 2008
Date of Patent:
August 3, 2010
Assignee:
BASF Catalysts LLC
Inventors:
Joseph Allan Patchett, Joseph Charles Dettling