Abstract: The invention relates to a coating material containing a binding agent and a cross-linking agent, in addition to a thixotropic agent, wherein said material is a mixture of silicic acids and urea and/or urea derivatives.
Abstract: A coating composition consisting of at least three components, comprising a component (I) comprising at least one oligomeric or polymeric resin containing functional groups which react with isocyanate groups, as binder (A), a component (II) comprising at least one polyisocyanate as crosslinking agent (F), and a component (III) which comprises water, wherein component (I), (II) and/or (III) comprise or comprises at least one constituent which is curable with actinic light and/or electron beams.
Abstract: The invention relates to a coating material containing a binding agent and a cross-linking agent as well as a thixotropic agent based on ureas and/or ureas derivatives, whereby the coating material additionally contains a wetting agent that improves the wettability of the thixtropic agent.
Abstract: A highly scratch-resistant multicoat paint system on a primed or unprimed substrate, comprising above one another in this order
(A) a basecoat,
(B) a first clearcoat as intermediate coat, and
(C) a second clearcoat as the topmost coat, wherein the second clearcoat (C) is producible from a coating coating material
(C) comprising
(C1) at least one oligomer and/or polymer containing at least one pendant carbamate and/or allophanate group (c11), especially carbamate group (c11), of the formula:
—O—(CO)—NH2—O—(CO)—NH—(CO)—NH2
and
(C2) at least one crosslinking agent containing at least two functional groups (c21) which undergo crosslinking reactions with the carbamate group and/or allophanate group (c11);
and also a process for producing highly scratch-resistant multicoat systems.
Type:
Grant
Filed:
August 2, 2001
Date of Patent:
November 25, 2003
Assignee:
BASF Coatings AG
Inventors:
Donald H. Campbell, Hubert Baumgart, Thomas Farwick, Ulrike Röckrath
Abstract: A coating composition consisting of at least three components, comprising a component (I) comprising at least one hydroxyl-containing oligomeric or polymeric resin dispersed or dissolved in one or more organic, optionally water dilutable solvents, as binder (A), a component (II) comprising at least one polyisocyanate dispersed or dissolved in one or more organic, optionally water dilutable solvents, as crosslinking agent (F), and a component (III) which comprises water, wherein component (I) comprises at least one hydroxyl-containing polyacrylate resin (A) containing polyether sidegroups and/or endgroups of the general formula I
Y—(—O—R—)n— (I)
in which the index and variables have the following meanings:
n=3 to 100;
R=C2 to C6 alkanediyl and C3 to C8 cycloalkanediyl;
Y=hydrogen atom or C1 to C4 alkyl;
as binder (A).
Abstract: A thixotroping agent comprising a reaction product of a isocyanto-containing compound and an amine. The isocyanto-containing compound comprises at least one of Ia) at least one isocyanate with at least one diisocyanate structural unit that has an unsaturated/aromatic or non-aromatic ring structure with 5-10 ring atoms and two isocyanate groups that are bound to the ring structure; Ib) at least one oligomer of the isocyanate Ia) with 2 to 10 isocyanate units; and Ic) at least one partially blocked isocyanate Ia) and/or at least one partially blocked oligomer Ib).
Type:
Grant
Filed:
November 14, 2001
Date of Patent:
November 18, 2003
Assignee:
BASF Coatings AG
Inventors:
Ingrid Heid, Helmut Kleine Beckmann, Ulrike Röckrath, Hubert Baumgart
Abstract: The invention relates to a binder, preferably for coating materials, which is curable thermally and/or by high-energy radiation and comprises a mixture of substances comprising
(a) as one component, monomers or polymers which have a least one vinyl ether, vinyl ester, (meth)acrylic and/or allyl group and
(b) as a further component, saturated polymers and/or unsaturated polymers different from component (a), with the proviso that
at least one of components (a) and (b) has structural units of the formulae (I) and/or (II)
the other component (b) has structural units of the formulae (I) and/or (II) at least when it contains saturated polymers.
The invention also relates to a process for preparing the binder and to a formulation which comprises the binder of the invention. This formulation is in the form of a pigmented or unpigmented coating material or powder coating material.
Type:
Grant
Filed:
February 7, 2001
Date of Patent:
October 14, 2003
Assignee:
BASF Coatings AG
Inventors:
Rainer Blum, Rodriguez Jorge Prieto, Wolfgang Reich
Abstract: A polyurethane comprising lateral and/or terminal ethenylarylene groups produced by reacting a polyurethane prepolymer containing free isocyanate groups with an adduct obtained by reacting an ethenylarylene monoisocyanate with a polyol, polyamine, and/or a compound containing hydroxyl and amino groups in a molar ratio of 1:1. Also, a graft copolymer comprising a hydrophobic core comprising at least one monomer and a hydrophilic shell comprising the polyurethane, or a hydrophobic core comprising the polyurethane and a hydrophilic shell that comprises at least one monomer. Also, a graft copolymer comprising a hydrophobic core comprising at least one monomer and a hydrophilic shell comprising a polyurethane produced by dispersing at least one hydrophilic olefinic unsaturated polyurethane comprising lateral, and optionally terminal, ethenylarylene groups in an aqueous medium and copolymerizing at least one hydrophobic monomer in the polyurethane in emulsion.
Type:
Grant
Filed:
March 20, 2002
Date of Patent:
October 14, 2003
Assignee:
BASF Coatings AG
Inventors:
Stephan Schwarte, Egon Wegner, Harald Angermüller
Abstract: The invention relates to the utilization of tricyclodecandimethanol for producing multilayer lacquers, in particular, multilayer transparent lacquer coatings, and as a binding agent in multilayer lacquers. The invention als relates to a coating substrance, especially transparent lacquer, containing at least one binding agent, at least one cross-linking agent and tricylodecandimethanol. In addition, the invention relates to a method for improving the adherence of the intermediate layer in multilayer transparent lacquer coatings.
Type:
Grant
Filed:
October 4, 2001
Date of Patent:
October 7, 2003
Assignee:
BASF Coatings AG
Inventors:
Hubert Baumgart, Heinz-Peter Rink, Ulrike Röckrath, Thomas Farwick
Abstract: A two-component coating composition comprising (I) a component comprising at least one isocyanate as crosslinking agent and (II) a component comprising at least one binder having functional groups which react with isocyanate groups. Component (I) comprises at least one isocyanate Ia) having at least one diisocyanate structural unit which has an unsaturated/aromatic or non-aromatic ring structure having 5-10 ring atoms and two isocyanate groups attached to the ring structure. Instead of this isocyanate Ia) or in addition thereto it is possible to use an oligomer Ib) of this isocyanate Ia) having from 2 to 10 isocyanate units, especially a trimer Ib) and/or partially blocked isocyanates Ia) and/or oligomers Ib)(=crosslinkers Ic).
Abstract: Aqueous dispersion of an acrylate-modified alkyd resin, preparable in the presence of at least one water-miscible diol by (1) dispersing in water at least one alkyd resin containing pendant and/or terminal allyloxy groups, (2) graft copolymerizing a mixture of methacrylic acid and at least one further, carboxyl-free olefinically unsaturated monomer in dispersion 1, and (3) once or n times graft copolymerising (3.1) at least one olefinically unsaturated monomer which is free from acid groups and/or (3.2) at least one mixture of at least one olefinically unsaturated monomer which contains acid groups and at least one olefinically unsaturated monomer which is free from acid groups, in dispersion 2 or 2 to n−1, with the proviso that in step (3) or (n) of the process, acid groups are incorporated in a total amount to not more than 90 mol % of the amount of acid groups incorporated in step (2) of the process.
Abstract: In a method of determining the shade stability of paints, the total color difference &Dgr;E(FT) between the color at the film thickness FT and the color at a predetermined film thickness FT0 is measured for different film thicknesses FT. Subsequently, the slope &sgr;(FT) of the plot &Dgr;E(FT) is determined, which represents a useful parameter for the shade stability. Alternatively to &sgr;(FT), it is also possible to determine the limiting film thickness FTlim at which the total color difference &Dgr;E(FT) passes below a predetermined limit. The method of determining the shade stability is additionally employed in order to optimize paint formulations.
Type:
Grant
Filed:
May 15, 2001
Date of Patent:
September 30, 2003
Assignee:
BASF Coatings AG
Inventors:
Bernd Biallas, Wolfgang Duschek, Werner Rotz, Harald Berlin
Abstract: A pseudoplastic powder clearcoat slurry which is free from organic solvents and external emulsifiers and comprises solid spherical particles with an average size of from 0.8 to 20 &mgr;m and a maximum size of 30 &mgr;m, at least one ionic thickener and at least one nonionic associative thickener, the powder clearcoat slurry having an ion-forming group content of from 0.05 to 1 meq/g, a neutralizing agent content of from 0.05 to 1 meq/g, and a viscosity of (i) from 50 to 1 500 mPas at a shear rate of 1 000 s−1, (ii) from 150 to 8 000 mPas at a shear rate of 10 s−1, and (iii) from 180 to 12 000 mPas at a shear rate of 1 s−1.
Type:
Grant
Filed:
March 12, 2001
Date of Patent:
September 23, 2003
Assignee:
BASF Coatings AG
Inventors:
Günther Ott, Ulrike Röckrath, Maximilian Bendix, Joachim Woltering, Fatmir Raka, Ute Schuhmacher, Ulrich Poth
Abstract: A powder coating slurry, especially a powder clearcoat slurry, comprising at least one hydroxyl-containing binder A, at least one polyisocyanate crosslinking agent B, and water, where
1) the hydroxyl-containing binders A and the polyisocyanates B have been homogenized such that not less than 30, preferably not less than 60 and in particular not less than 90% by weight of the polyisocyanate B are present in solution or dispersion in the particles comprising the binders A, and
2) the particles of the crosslinking agent B which may still be present in the aqueous phase, and the particles comprising the binders A and the crosslinking agents B, have been stabilized, by way of the isocyanate groups present on their surface, by means of a deactivator added to the aqueous phase.
Abstract: The present invention relates to a powder coating material which contains preferably from 0.05 to 5% by weight, preferably from 0.5 to 2% by weight, of at least one polyethylene wax distributed homogeneously within the powder coating material.
Type:
Grant
Filed:
April 26, 2001
Date of Patent:
September 23, 2003
Assignee:
BASF Coatings AG
Inventors:
Helmut Riestenpatt, Rolf Boysen, Birgit Perdun
Abstract: Oligomeric and high molecular mass products of reaction of alkyl and aryl allophanates with nucleophilic compounds, and also low molecular mass, oligomeric and high molecular mass compounds containing lateral and/or terminal allophanate groups, and also the use of the reaction products and/or of the compounds in coating compositions, adhesives and sealing compounds or for producing films.
Type:
Grant
Filed:
March 2, 2001
Date of Patent:
September 23, 2003
Assignee:
BASF Coatings AG
Inventors:
Heinz-Peter Rink, Werner Jung, Ulrike Röckrath, Thomas Savino
Abstract: The present invention provides a coating composition comprising
a) one or more polyester resins (A),
b) one or more polyacrylate resins (B),
c) one or more di- and/or polyisocyanates (C) having free or blocked isocyanate groups,
d) one or more light stabilizers (L1) based on a UV absorber,
e) one or more light stabilizers (L2) based on sterically hindered amines,
f) one or more pigments (P), and g) one or more organic solvents (D), where
1.) the polyester (A) has an OH number of from 80 to 200 mg KOH/g and an acid number <10 mg KOH/g,
2.) the polyacrylate resin (B) has an OH number of from 80 to 200 mg KOH/g and an acid number <20 mg KOH/g,
3.) the light stabilizer (L2) based on, sterically hindered amines is amino ether functionalized, and
4.) effect pigments (EP) are included herein in a nonhiding concentration.
Abstract: Aqueous coating material comprising (A) water-dispersible hydroxy-functional binder component containing urethane groups, (B) water-dispersible binder component containing urethane groups and blocked isocyanate groups, (C) water-dispersible amino resin, and optionally (D) water-dispersible hydroxy-functional polyester, the binder component (B) being preparable by (B1) preparing a polyurethane prepolymer containing isocyanate groups from at least one polyol and at least one polyisocyanate, (B2) reacting the polyurethane prepolymer (B1) containing isocyanate groups with a chain extender to give a hydroxyl-containing chain-extended polyurethane prepolymer, (B3) reacting the hydroxyl-containing chain-extended polyurethane prepolymer (B2) with at least one polyisocyanate to give a further polyurethane prepolymer containing isocyanate groups, and (B4) blocking some or all of the isocyanate groups of the chain-extended polyurethane prepolymer (B3) containing isocyanate groups with a blocking agent to give a polyuret
Abstract: A process for producing scratch-resistant coatings, especially scratch-resistant multicoat finishes, involving use of coating compositions which after curing have a storage modulus E′ in the rubber-elastic range of at least 107.5 Pa and a loss factor tan &dgr; at 20° C. of at least 0.05, the storage modulus E′ and the loss factor having been measured by dynamic mechanical thermoanalysis on free films having a film thickness of 40±10 &mgr;m, and comprise as binders one or more polyacrylate resins having a hydroxyl number of from 100 to 240, an acid number of from 0 to 35, and a number-average molecular weight of from 1500 to 10,000, and as crosslinkers one or more free or blocked isocyanates and/or triazine-based components which crosslink with the hydroxyl groups of the binder to form ether and/or ester structures.
Type:
Grant
Filed:
February 27, 2002
Date of Patent:
September 16, 2003
Assignee:
BASF Coatings AG
Inventors:
Ulrike Röckrath, Peter Betz, Fritz Bartol, Georg Wigger, Hubert Baumgart