Abstract: Method of analyzing and optimizing a multistage manufacturing process which includes a number of standard steps that are carried out identically and which are followed by tuning steps that are carried out in order to achieve predefined product properties, their type, number and exit being variable. The individual steps relate to at least one production-specific property an are recorded quantitatively in an electronic database. The property can be, for example, a proportion of the quantities, a proportion of the costs, or the effects of an individual step on a product property to be achieved. Examples of a multistage manufacturing process are the manufacture of a coating from a plurality of individual components and additives. With the aid of the information compiled in a database, individual steps can be reduced in terms of their number and their extent.
Abstract: The invention embraces basecoating compositions comprising as binder constituents
(i) an acrylate dispersion having a content of from 30 to 60% by weight of C1-C8-alkyl (meth)acrylate-containing monomers, from 30 to 60% by weight of vinylaromatic monomers and from 0.5 to 10% by weight of (meth)acrylic acid in the polymer, and
(ii) a dispersion of a polymer which is obtainable by subjecting an ethylenically unsaturated monomer or a mixture of ethylenically unsaturated monomers to free-radical polymerization in the presence of a water-insoluble initiator or of a mixture of water-insoluble initiators and in an aqueous dispersion of a polyurethane resin which has a number-average molecular weight Mn of from 1000 to 30,000 daltons and comprises on average from 0.05 to 1.
Type:
Grant
Filed:
April 18, 2000
Date of Patent:
August 19, 2003
Assignee:
BASF Coatings AG
Inventors:
Egon Wegner, Gudrun Wiemann, Ekkehard Sapper, Harald Angermüller
Abstract: Self crosslinking polyurethane comprising lateral or terminal ethenylarylene groups, produced by reacting a polyurethane pre-polymer with an adduct, obtained by reacting an ethenylarylene mono-isocyanate with a compound containing hydroxyl groups or amino groups such that at least one group that is reactive to isocyanate remains in the adduct. Also, a self crosslinking graft copolymer containing at least one (meth)acrylate copolymer and at least one polyurethane produced by dispersing at least one self crosslinking olefinically unsaturated polyurethane comprising lateral or terminal ethenylarylene groups and blocked isocyanate groups in an aqueous medium and by radical copolymerization of a mixture of a monomer comprising at least one functional group that is reactive to isocyanate with a monomer that can be copolymerised with the mixture.
Type:
Grant
Filed:
April 26, 2002
Date of Patent:
August 5, 2003
Assignee:
BASF Coatings AG
Inventors:
Stephan Schwarte, Egon Wegner, Harald Angermüller
Abstract: The invention relates to a water-dilutable coating containing polyester, polyurethane, amino resins and other usual paint additives and auxiliary agents. The polyurethane that is used is a mixture consisting of several, preferably two different polyurethane compounds (A, B) which preferably have a molecular weight of 1000 to 30000, preferably have an acid value of 5-20 mg KOH/g and can preferably be produced by reacting prepolymers containing isocyanate groups.
Abstract: An aqueous coating material curable thermally and/or with actinic radiation, comprising
A) at least one ionically and/or nonionically stabilized polyurethane which is saturated, unsaturated and/or grafted with olefinically unsaturated compounds and is based on bis(4-isocyanatocyclohexyl)methane with a trans/trans content of up to 30% by weight, based on the diisocyanate, as binder and
B) at least one crosslinking agent.
Type:
Grant
Filed:
November 7, 2001
Date of Patent:
June 24, 2003
Assignee:
BASF Coatings AG
Inventors:
Karl Haeberle, Heinz-Peter Rink, Bernhard Lettmann
Abstract: A polyisocyanate of formula (I)
OCN—R1—[—NX—CO—O—R2—O—CO—NH—R1—]n—NCO
in which the units R1, X and R2 have the meanings:
R1 is a unit of the formula (II):
—CH2—CH2—CH2—CH2—CH2—CH2— (II)
X is hydrogen or a unit of the formula (III):
—CO—NH—R1—NCO (III),
with the proviso that at least one of the units X in the polyisocyanates is a unit of formula (III); and
R2 • is a 4-, 5- or 6-membered cycloalkylene group containing radical.
Type:
Grant
Filed:
January 26, 2001
Date of Patent:
May 20, 2003
Assignees:
BASF Aktiengesellschaft, BASF Coatings AG
Abstract: A reactive polyurethane with a number average molecular weight Mn of 800 to 14,000 daltons, a branching degree of 0.0 to 3.0 Mol/kg and an isocyanate functionality of 2.0 to 6.0. The reactive polyurethane is produced by reacting polyester and/or polyether, which both have at least two functional groups that are reactive with isocyanate and which have a molecular weight of 400 to 2,500 daltons and a branching degree of 0 to 3.5 Mol/kg; with at least one polyol with a molecular weight of 62 to 400 daltons and a functionality of 2 to 4; polyamines and/or alkanolamines; compounds with at least one functional group capable of producing anions and at least one functional group that is reactive with isocyanates; polyisocyanates and/or polyisocyanate adducts; blocking agents for the isocyanate groups and neutralizer. Also, a polyurethane dispersion containing the reactive polyurethanes.
Type:
Grant
Filed:
September 7, 2001
Date of Patent:
April 29, 2003
Assignee:
BASF Coatings AG
Inventors:
Ulrich Poth, Ulrike Röckrath, Ingrid Heid
Abstract: An aqueous coating material preparable by mixing (A) at least one base paint comprising (a1) at least one optionally water-soluble or -dispersible binder, (a2) at least one color and/or effect pigment, and (a3) at least one water-miscible organic solvent, and further comprising if desired (a4) water, (a5) at least one crosslinking agent and/or (a6) at least one auxiliary and/or additive; (B) at least one solid, finely divided mixing varnish comprising (b1) at least one water-soluble or -dispersible, finely divided, solid binder; and (C) an aqueous medium with one another; and also a modular system for preparing aqueous coating materials, comprising (I) at least one color and/or effect module comprising at least one base paint (A), (II) at least one solid module comprising at least one solid, finely divided mixing varnish (B) and (III) at least one dispersing module comprising an aqueous medium (C).
Abstract: The invention relates to a binder for powder coating materials having an oligomeric or polymeric substructure which are curable thermally and/or by means of high-energy radiation, said binder comprising in each case terminally and/or laterally at least one vinyl ether group a) and at least one group b) which is different from the vinyl ether groups a) but is coreactive with said groups a), there being on average at least one vinyl ether group a) and one coreactive group b) per oligomer or polymer molecule. The invention also relates to powder coating materials comprising such a binder and to the use of said powder coating materials for coating surfaces, especially in the form of an automotive top coat and a coil coating material.
Abstract: A coating composition comprising
A) at least one hydroxyl-containing polyacrylate containing in copolymerized form at least one polysiloxane macromonomer as binder and
B) at least one tris(alkoxycarbonylamino)triazine as crosslinking agent,
and its use to produce multicoat clearcoats and multicoat topcoats.
Type:
Grant
Filed:
June 18, 2001
Date of Patent:
March 18, 2003
Assignee:
BASF Coatings AG
Inventors:
Hubert Baumgart, Thomas Farwick, Ulrich Poth, Ulrike Röckrath, Andrea Zumbrink
Abstract: A coating composition consisting of at least three components, comprising a component (I) comprising at least one oligomeric or polymeric resin containing functional groups which react with isocyanate groups, as binder (A), a component (II) comprising at least one polyisocyanate as crosslinking agent (F), and a component (III) which consists of water or comprises water and at least one binder (A), wherein component (I) and/or (III) comprise or comprises at least one branched, cyclic and/or acyclic C9-C16-alkane which is functionalized using at least two hydroxyl groups.
Abstract: Hyperbranched compounds having a tetrafunctional central group of the general formula I
C[—Aq—X—]m[—Ar—X—]n[—As—X—]o[—At—X—]p (I),
in which the indices and variables have the following meanings:
m+n+o+p=4; where
m=an integer from 1 to 3 and
n, o and p=0 or an integer from 1 to 3;
q,r,s and t=an integer from 1 to 5, where q>r, s and t;
X=—O—, —S— or —NH—;
A=—CR2—; where
R=—H, —F, —Cl, —Br, —CN, —NO2, C1-C3 alkyl or C1-C3 haloalkyl or C1-C3 alkoxy radical or,
if q, r, s and/or t=at least 2, a C2-C4 alkanediyl and/or C2-C4 oxaalkanediyl radical which bridges 2 to 5 carbon atoms, and/or an oxygen atom —O—, which bridges 3 to 5 carbon atoms, of the radical —A—.
Abstract: Novel powder clearcoat materials and novel powder clearcoat slurries comprising a) at least one epoxide-containing binder containing from 0.5 to 40% by weight, based on the binder, of copolymerized glycidyl-containing monomers, and b) at least one tris(alkoxy-carbonylamino)triazine and at least one polycarboxylic acid, in particular a straight-chain dicarboxylic acid, and/or a carboxy-functional polyester as crosslinking agent, or alternatively a) at least one tris(alkoxy-carbonylamino)triazine and at least one oligomeric or polymeric, epoxide-containing crosslinking agent containing from 0.5 to 40% by weight, based on the crosslinking agent, of copolymerized glycidyl-containing monomers, and/or a low molecular mass, epoxide-containing crosslinking agent, and b) at least one carboxyl-containing polymer as binder, both variants comprising c) at least one polyol.
Type:
Grant
Filed:
April 2, 2001
Date of Patent:
January 28, 2003
Assignee:
BASF Coatings AG
Inventors:
Günther Ott, Ulrike Röckrath, Stephan Schwarte, Joachim Woltering, Heinrich Wonnemann
Abstract: The present invention provides a coating composition comprising
a) one or more polyester resins (A),
b) one or more polyacrylate resins (B),
c) one or more di- and/or polyisocyanates (C) having free or blocked isocyanate groups,
d) one or more light stabilizers (L1) based on a UV absorber,
e) one or more light stabilizers (L2) based on sterically hindered amines, and
f) one or more organic solvents (D),
where
1.) the polyester (A) has an OH number of from 80 to 200 mg KOH/g and an acid number <10 mg KOH/g,
2.) the polyacrylate resin (B) has an OH number of from 80 to 200 mg KOH/g and an acid number <20 mg KOH/g,
3.) the light stabilizer (L2) based on sterically hindered amines is amino ether functionalized, and
4.) the light stabilizer (L1) is included herein in an amount of at least 3% by weight, based on the coating composition.
Abstract: A process for preparing a reaction product (A), comprising the following stage (i):
(i) reacting under free-radical conditions a reaction mixture comprising at least one free-radically reactable monomer (a) in the presence of at least one free-radical initiator and of a compound (I) of the formula:
in which R1 to R4 each independently of one another are hydrogen, a substituted or unsubstituted alkyl radical, cycloalkyl radical or arakyl radical, or an unsubstituted or a substituted aromatic hydrocarbon radical, with the proviso that at least two of R1 to R4 are an unsubstituted or a substituted aromatic hydrocarbon radical in aqueous phase.
Type:
Grant
Filed:
July 30, 2001
Date of Patent:
January 14, 2003
Assignees:
BASF Aktiengesellschaft, BASF Coating AG
Inventors:
Wolfgang Bremser, Frank Strickmann, Maximilian Bendix, Wolfgang Paulus, Roman Benedikt Raether, David Christie
Abstract: The present invention relates to an aqueous dispersion comprising a solid pulverulent component A and an aqueous component B, said component A comprising a UV-curable powder coating material.
Type:
Grant
Filed:
March 2, 2001
Date of Patent:
November 26, 2002
Assignee:
BASF Coatings AG
Inventors:
Günther Ott, Joachim Woltering, Uwe Meisenburg, Rainer Blum, Maximilian Bendix, Rainer Königer, Horst Binder, Reinhold Schwalm
Abstract: An architectural coating material comprising a) an aqueous dispersion of at least one polyacrylate and b) at least one branched, cyclic and/or acyclic C9-C16 alkane functionalized with at least two hydroxyl groups.
Type:
Grant
Filed:
July 26, 2001
Date of Patent:
November 5, 2002
Assignee:
BASF Coatings AG
Inventors:
Vijay Kadambande, Heinz-Peter Rink, Detlef Thiel, Ernst Häring
Abstract: Apparatus and method for measuring coated test panels, the test panels (2) being taken from a feed magazine (1) by a gripping and moving device, e.g. a laboratory robot, placed on a measuring station (9) and, finally, transferred to a delivery station (5). In the measuring station (9) measurement of the various properties of the coating is carried out by the laboratory robot (3) using various measuring devices (4). This process can in particular involve spatial resolution and electronic recording. The test panels can furthermore be distinguished by a bar code system which is recorded and evaluated electronically.
Type:
Grant
Filed:
May 19, 1999
Date of Patent:
October 1, 2002
Assignee:
BASF Coatings AG
Inventors:
Harald Berlin, Bernd Biallas, Wolfgang Duschek, Werner Rotz
Abstract: The present invention relates to a mixer system for the preparation of water-thinnable coating compositions with accurately defined colors, produced from various base colorants, characterized in that the mixer system comprises
A) various base colorants A which contain less than 5% by weight of water, at least one colored and/or special effect pigment, an organic solvent, at least one water-thinnable or water-dispersible binder and, optionally, auxiliary substances and additives, and
B) at least one water-containing, pigment-free component B.
In addition, the present invention relates to a process for the production of coating compositions using this mixer system and to the use of the mixer system for the production of waterborne paints for coating automobile bodies and/or plastic components, especially for automobile refinishing.