Abstract: Provided herein is a coating composition curable by condensation and/or addition reactions and including (A) at least one polymer as binder, (B) at least one crosslinking agent that can be reacted by condensation and/or addition reaction with component (A), and (C) at least one specific complex as catalyst. Also provided herein is a use of the complex for catalyzing the curing of coating compositions curable by condensation and/or addition reaction.

Abstract: Disclosed is a method for forming a multilayer coating film, including applying a first and second aqueous base coat, and a clear coat to an object, and thereafter simultaneously heating and curing the three-layer coating film. The first aqueous base coat includes a water-soluble or water-dispersible polyurethane resin having a glass transition temperature of ?20° C. or below and a weight average molecular weight of 30,000 to 500,000, and a crosslinkable resin having a weight average molecular weight of 600 or more. The first aqueous base coat-coated film has a breaking strength of 2050 N/cm2 or more and a loss tangent (tan ?) at ?20° C. of 0.075 or more. The migration amount of a melamine resin from the second aqueous base coat-coated film layer to the first aqueous base coat-coated film layer is within 3% by mass of a total resin solid content of the first aqueous base coat.

Abstract: The present disclosure relates to a method for transferring an embossed structure to at least a part of a surface of a coating (B2), using a composite (F1B1) composed of a substrate (F1) and of an at least partially embossed and at least partially cured coating (B1), where the coating (B2) and the coating (B1) of the composite (F1B1) have embossed structures which are mirror images of one another. Also described herein is a composite (B2B1F1). Further described herein is a use of this composite for producing an at least partially embossed coating (B2) in the form of a free film or a composite (B2KF2) composed of a substrate (F2), at least one adhesive (K), and the coating (B2).

Abstract: A heuristic process for color formula calculation of pigmented shades matched to a target shade, comprising the steps of i) using suitable calibration scales to compile an effect matrix for each of the ingredients included in a coloring system, ii) determining the optical materials parameters of the target shade, iii) selecting a suitable starting formula, iv) determining the color difference between the starting formula and the target shade, v) calculating a first matched color formula while taking account of the effect matrices, vi) repeating steps iv) and v) until an acceptable remaining color difference is reached, wherein the effect matrices are continually updated with shade-relevant information during ongoing operation, achieves an improvement on the existing processes for shade formula calculation, not only in terms of reducing the number of tinting steps needed but also in terms of minimizing the remaining color difference.

Abstract: The present invention relates to aqueous dispersions comprising multistage-prepared polymers of olefinically unsaturated compounds and to the preparation and use thereof, in particular in the field of automobile coating.

Abstract: Processes for producing flexible organic-inorganic laminates by atomic layer deposition are described, as well as barrier films comprising flexible organic-inorganic laminates. In particular, a process for producing a laminate including (a) depositing an inorganic layer by an atomic layer deposition process, and (b) depositing an organic layer comprising selenium by a molecular layer deposition process is provided.

Abstract: Provided herein is a pigmented aqueous basecoat material including a hydroxy-functional polyether-based reaction product that is prepared by a urethane group-forming reaction of: (a) at least one component including isocyanate groups that is prepared by the urethane group-forming reaction of at least one organic diisocyanate (a1) with at least one polyether (a2) of the general structural formula (I). R is a C3 to C6 alkylene radical, and n is selected accordingly such that a polyether (b) possesses a number-average molecular weight of 500 to 5000 g/mol, the components (a1) and (a2) being used in a molar ratio of 1.8/1.7 to 3.0/1.0, and the resulting component (a) having an isocyanate content of 0.5 to 10.0% with (b) at least one organic polyol.

Abstract: Cathodically depositable electrocoat materials comprising basic bismuth nitrate, further comprising at least one binder having reactive functional groups and at least one crosslinker containing the complementary reactive functional groups which are able to enter into thermal crosslinking reactions.

Abstract: The present invention relates to a pigmented aqueous basecoat material comprising a polyether-based reaction product which is preparable by reaction of (a) at least one cyclic carboxylic anhydride comprising a free carboxylic acid group and/or the halide of a carboxylic acid group with (b) at least one polyether of the general structural formula (I) in which R is a C3 to C6 alkylene radical and n is selected accordingly such that the polyether (b) possesses a number-average molecular weight of 800 to 4000 g/mol, the components (a) and (b) being used in the reaction in a molar ratio of 0.7/2.3 to 1.6/1.7 and the resulting reaction product possessing an acid number of 10 to 50 mg KOH/g.

Abstract: Provided herein is a mixer system for producing refinish compositions, more particularly for the sector of automotive finishing, including at least mutually different components (1), (2), and (3), namely component (1) as base varnish, component (2) as tinting base, and component (3) as rheology module, with at least one of components (1) to (3) including at least one aqueous dispersion including at least one polymer prepared by multistage emulsion polymerization, and at least one of components (1) to (3) including at least one aliphatic monoalcohol having 5 carbon atoms and/or at least one aliphatic monoalcohol having 6 carbon atoms. Further provided herein is an aqueous refinish composition that is produced by the mixing of components (1) to (3), and a method for producing aqueous refinish compositions. Further provided herein is a use of the mixer system for producing aqueous refinish compositions for automotive refinishing.

Abstract: The present invention relates to a pigmented aqueous basecoat material comprising a polyether-based reaction product which is preparable by reaction of (a) at least one cyclic carboxylic anhydride comprising a free carboxylic acid group and/or the halide of a carboxylic acid group with (b) at least one polyether of the general structural formula (I) in which R is a C3 to C6 alkylene radical and n is selected accordingly such that the polyether (b) possesses a number-average molecular weight of 800 to 4000 g/mol, the components (a) and (b) being used in the reaction in a molar ratio of 0.7/2.3 to 1.6/1.7 and the resulting reaction product possessing an acid number of 10 to 50 mg KOH/g.

Abstract: The present invention relates to an aqueous polyurethane-polyurea dispersion (PD) having polyurethane-polyurea particles, present in the dispersion, having an average particle size of 40 to 2000 nm, and having a gel fraction of at least 50%, obtainable by (I) preparing a composition (Z) comprising based each case on the total amount of the composition (Z), (Z.1) 15 to 65 wt % of at least one intermediate containing isocyanate groups and having blocked primary amino groups, its preparation comprising the reaction (Z.1.1) of at least one polyurethane prepolymer containing isocyanate groups and comprising anionic groups and/or groups which can be converted into anionic groups, with (Z.1.2) at least one polyamine comprising at least two blocked primary amino groups and at least one free secondary amino group, by addition reaction of isocyanate groups from (Z.1.1) with tree secondary amino groups from (Z.1.2), (Z.

Abstract: A coating composition includes a flexible hyperbranched polyol preparable by (a) reacting a polyol comprising at least three hydroxyl groups with an aliphatic dicarboxylic acid having from 6 to 36 carbon atoms or an esterifiable derivative of the aliphatic dicarboxylic acid to form a hydroxyl-functional first intermediate product; (b) reacting the first intermediate product with a cyclic carboxylic acid anhydride to form a carboxylic acid-functional second intermediate product; and (c) reacting the second intermediate product with an epoxide-functional compound having one epoxide group to form the hyperbranched polyol. The coating composition may be cured to a coating layer having excellent flexibility.

Abstract: The present invention relates to a mixture (M) which can be used as curing agent and as adhesion promoter and which comprises at least two components (M1) and (M2), which are different from one another and have in each case independently of one another free and/or blocked isocyanate groups, and which optionally comprises a further component (M3) different from (M1) and (M2); component (M1) comprises at least one aliphatic polyisocyanate, and component (M2) comprises at least one aliphatic polyisocyanate having polyether units, wherein the relative weight ratio of (M1) and (M2) in (M) to one another is in a range from 25:1 to 3:1, based in each case on the solids content of (M1) and (M2), and at least one of the components (M1), (M2), and optionally (M3) present in (M) has hydrolyzable silane groups, to a use of (M) as curing agent and adhesion promoter in a coating composition, to such a coating composition, and to methods for at least partly coating a substrate with a surfacer coat and for at least partly co

Abstract: The present invention relates to a dimer fatty acid/dimer diol reaction product which is preparable by reacting (a) dimer fatty acids with (b) at least one dimer diol, where components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.3/1.7 and the resulting dimer fatty acid/dimer diol reaction product possesses a number-average molecular weight of 1200 to 5000 g/mol and an acid number <10 mg KOH/g. The invention further relates to a pigmented aqueous basecoat material which comprises this dimer fatty acid/dimer diol reaction product, and also to the use of said dimer fatty acid/dimer diol reaction product in pigmented aqueous basecoat materials. It relates, further, to a method for producing multicast paint systems, and also to the multicoat paint systems producible by means of said method. The present invention relates, furthermore, to the refinishing of defects on multicoat paint systems.

Abstract: The present invention relates to an aqueous polyurethane-polyurea dispersion (PD) having polyurethane-polyurea particles, present in the dispersion, having an average particle size of 40 to 2000 nm, and having a gel fraction of at least 50%, obtainable by (I) preparing a composition (Z) comprising, based in each case on the total amount of the composition (Z), (Z.1) 15 to 65 wt % of at least one intermediate containing isocyanate groups and having blocked primary amino groups, its preparation comprising the reaction (Z.1.1) of at least one polyurethane prepolymer containing isocyanate groups and comprising anionic groups and/or groups which can be converted into anionic groups, with (Z.1.2) at least one polyamine comprising at least two blocked primary amino groups and at least one free secondary amino group, by addition reaction of isocyanate groups from (Z.1.1) with free secondary amino groups from (Z.1.2), (Z.

Abstract: Disclosed herein is a coating material compositions containing (A) a polyhydroxyl group-containing component, (B) a component (B) having on average at least one isocyanate group and having on average at least one of: at least one hydrolyzable silane group of the formula (I): —NR—(X—SiR?x(OR?)3-x), and at least one hydrolyzable silane group of the formula (II): —N(X—SiR?x(OR?)3-x)n(X?—SiR?y(OR?)3-y)m, (D) a phosphorus and nitrogencontaining catalyst, and a catalyst (Z), wherein: the catalyst (Z) is selected from zinc and bismuth carboxylates, of aluminum, zirconium, titanium and/or boron chelates and/or of inorganic, tin-containing catalysts, and mixtures thereof; and the coating material composition comprises at least one reaction accelerator (R) which is selected from the group of inorganic acids and/or of organic acids and/or of partial esters of the inorganic acids and/or of partial esters of the organic acids.

Abstract: The present invention relates to an aqueous two-component basecoat material (b) comprising (b.1) a base component comprising (1) at least one polyurethane resin having a hydroxyl number of 15 to 100 mg KOH/g and an acid number of 10 to 50 mg KOH/g, (2) at least one aqueous dispersion comprising water and a polyurethane resin fraction consisting of at least one polyurethane resin, the polyurethane resin fraction having a gel fraction of at least 50%, having its glass transition at a temperature of less than ?20° C. and having its melting transition at a temperature of less than 100° C., (3) at least one color and/or effect pigment, at least one pigment (3) being used in the form of at least one pigment paste comprising at least one polyurethane resin (1) as pasting resin, and (b.2) a curing component comprising (4) at least one hydrophilically modified polyisocyanate (4) having an isocyanate content of 8% to 18%.

Abstract: The present invention relates to an aqueous dispersion (P) of at least two polymeric resins (P1) and (P2) which are different from one another, (P1) being a copolymer obtainable by copolymerizing ethylenically unsaturated monomers in the presence of at least one polyurethane resin having polymerizable carbon double bonds, and (P2) being a polyester having functional hydroxyl groups, which has an acid number of <25 mg of KOH per g of polyester, and (P) being obtainable by a process encompassing at least four steps (1), (2), (3), and (4), to an aqueous coating composition comprising the aqueous dispersion (P), to a process for at least partly coating at least one substrate metal surface, coated with at least one primer coat, with a topcoat, using the aqueous coating composition, and to an at least partly coated substrate obtainable by such a process.

Abstract: Provided herein is a method of forming a multilayer coating film including coating, onto an object to be coated, a water-based primer coating composition, wet-on-wet coating a first water-based coloring coating composition, wet-on-wet coating a second water-based coloring coating composition, coating a clear coating composition, and simultaneous hardening of the formed multilayer coating film. The water-based primer coating composition contains a water-based polyolefin resin, a water-based polyurethane resin, a curing agent, and conductive carbon. The first and second water-based coloring coating compositions, each, as base resins, contain a core/shell-type emulsion including an acrylic resin core portion and a polyurethane resin shell portion. The clear coating composition contains a hydroxy-group-containing acrylic resin and a polyisocyanate compound.