Abstract: The present invention relates to a pigmented aqueous basecoat material comprising a reaction product which is preparable by reaction of (a) at least one aliphatic linear polyester having two functional end groups (a.1), with (b) at least one diene polymer having two functional end groups (b.1), where at least one type of group (a.1) is reacted in a linking manner with at least one type of group (b.1), said components (a) and (b) are used in the reaction in a molar ratio of 2.3/0.7 to 1.7/1.6 and the resulting reaction product possesses a number-average molecular weight of 1000 to 15 000 g/mol.
Type:
Grant
Filed:
June 16, 2015
Date of Patent:
October 29, 2019
Assignee:
BASF Coatings GmbH
Inventors:
Bernhard Steinmetz, Peter Hoffmann, Hardy Reuter
Abstract: A pigmented aqueous basecoat material that includes a reaction product obtained by reacting (a) a compound of formula (I) with (b) a compound of formula (II) at a molar ratio of 2.3/0.7 to 1.7/1.6, the reaction product having a number-average molecular weight of 500 to 15,000 g/mol, an acid number of less than 10 mg KOH/g, and a hydroxyl number of 25 to 250 mg KOH/g: X1—Y—X2??(I), wherein: X1 and X2 are each independently an epoxide-reactive functional group, or hydrogen, where at least one of X1 and X2 is the epoxide-reactive functional group; and Y is a divalent aliphatic, aromatic or araliphatic hydrocarbon radical having a number-average molecular weight of 100 to 2,500 g/mol, wherein R is a C3 to C6 alkylene radical and n is selected such that compound (b) possesses an epoxide equivalent weight of 100 to 2,000 g/mol.
Type:
Grant
Filed:
April 30, 2015
Date of Patent:
October 22, 2019
Assignee:
BASF Coatings GmbH
Inventors:
Bernhard Steinmetz, Peter Hoffmann, Hardy Reuter
Abstract: Provided is a method for producing a coating that includes a surfacer coat and topcoat on a substrate and including applying a first coating material to an untreated substrate or a substrate coated with a cured electrodeposition coat, and applying a second coating material to the surfacer coat. The produced coating system is cured to form the coating. The first and second coating materials are compatible according to DIN EN ISO 12944-5:2008-01, and the second application takes place before the first coating material has reached drying stage 1 according to DIN 53150:2002-09, and the drying stage is determined according to EN ISO 9117-3:2010. The method is suitable for producing coatings on automobiles and commercial vehicles, such as trucks, vans, and buses.
Abstract: The present invention relates to a method for at least partly coating an electrically conductive substrate with an electrocoat material, comprising at least contacting the substrate with an aqueous coating composition (A) as step (1), which is carried out in at least two successive stages (1a) and (1b), i.e.
Type:
Grant
Filed:
November 18, 2013
Date of Patent:
October 8, 2019
Assignees:
BASF Coatings GmbH, Henkel AG & Company, KGaA
Inventors:
Konstantinos Markou, Christian Hammer, Kristof Wapner, Florian Gaspar
Abstract: Method for producing a multicoat coating comprises: applying a primer-surfacer coat (I) to an optionally pretreated substrate, curing coat (I), applying a basecoat (II) to coat (I), optionally curing the basecoat (II), applying a clearcoat (III) to basecoat (II), and curing basecoat (II) and/or clearcoat (III), wherein coat (I) is obtained by applying a nonaqueous, solventborne coating material comprising by weight: at least 20% of at least one organic solvent, at least 8% of at least one first polyester (A1), having a glass transition temperature of at least 20° C. and an acid number of 0 to 40 mg KOH/g; at least 8% by weight of at least one second polyester (A2), different from (A1) and having a glass transition temperature of not more than 10° C.; at least one crosslinker (B); and at least 8% of one or more fillers and/or pigments (C).
Type:
Grant
Filed:
February 20, 2013
Date of Patent:
September 24, 2019
Assignee:
BASF Coatings GmbH
Inventors:
Heinrich Wonnemann, Markus Oberhoff, Martin Rieping, Beate Podlaski-Pyzik, Carole Morcillo Ruiz, Michael Hartung
Abstract: A pigmented aqueous basecoat material that includes a dimer fatty acid/polyesterdiol reaction product which is preparable by reacting (a) dimer fatty acids with (b) at least one polyesterdiol of the general structural formula (I) where: R is a divalent radical including 2-10 carbon atoms; R1 and R2 are independently straight-chain or branched alkylene radicals having 2-10 carbon atoms; X and Y are independently O, S or NR3, where R3 is hydrogen or an alkyl radical having 1-6 carbon atoms; and m and n are selected accordingly such that the polyesterdiol possesses a number-average molecular weight of 450-2200 g/mol, components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.3/1.7, and the resulting dimer fatty acid/polyesterdiol reaction product possesses a number-average molecular weight of 1200-5000 g/mol and an acid number <10 mg KOH/g.
Type:
Grant
Filed:
October 12, 2018
Date of Patent:
September 24, 2019
Assignee:
BASF Coatings GmbH
Inventors:
Bernhard Steinmetz, Hardy Reuter, Peter Hoffmann
Abstract: Described herein is a method for predicting visual texture parameters of a paint having a known paint formulation. The visual texture parameters of the paint are determined using an artificial neural network on the basis of a number of color components used in the known paint formulation. The method includes determining a value of at least one characteristic variable describing at least one optical property using a physical model for the known paint formulation. The method also includes assigning the value to the known paint formulation, and transmitting the value to the artificial neural network as an input signal for determining the visual texture parameters. The value describes the at least one optical property for at least some of the number of color components of the known paint formulation. The method further includes training the neural network using a plurality of color originals each having a respective known paint formulation.
Type:
Grant
Filed:
October 27, 2016
Date of Patent:
September 3, 2019
Assignee:
BASF Coatings GmbH
Inventors:
Guido Bischoff, Martin Schmitz, Donald R Baughman
Abstract: The present invention relates to a two-component coating composition comprising (1) a paint base component comprising (A) at least one polycarbonate diol, (B) at least one polyaspartic ester, and (C) at least one filler modified with at least one organosilane, and (2) a hardener component comprising (D) at least one hexamethylene diisocyanate isocyanurate containing aliphatic polyester groups and having an isocyanate content of 5% to 23%. The present invention also relates to a method for producing a coating using the coating composition, and to the coatings produced accordingly.
Type:
Grant
Filed:
December 22, 2014
Date of Patent:
August 6, 2019
Assignee:
BASF Coatings GmbH
Inventors:
Dieter Hohnholz, Oliver Boelke, Julia Krupp
Abstract: The present invention relates to a method for producing a multicoat paint system on a plastics substrate, in which a basecoat film or a plurality of directly successive basecoat films are produced on a plastics substrate, a clearcoat film is produced directly on the one basecoat film or on the topmost of the plurality of basecoat films, and subsequently the one or more basecoat films and the clearcoat film are jointly cured, this method being a method wherein at least one basecoat material used for the production of the basecoat films comprises at least one aqueous polyurethane-polyurea dispersion (PD) comprising polyurethane-polyurea particles, where the polyurethane-polyurea particles present in the dispersion (PD) comprise anionic groups and/or groups which can be converted into anionic groups, and have an average particle size of 40 to 2000 nm and also a gel fraction of at least 50%.
Type:
Grant
Filed:
March 31, 2016
Date of Patent:
July 30, 2019
Assignee:
BASF Coatings GmbH
Inventors:
Juergen Bauer, Audree Andersen, Hardy Reuter, Roland Ratz, Marita Buermann, Sina Winnen, Vera Diepenbrock
Abstract: The present invention relates to a polymer, preparable by reacting at least one polymer, preparable by reacting (a) dimer fatty acids with at least (b) one polyether having a C3 to C6 alkylene radical and a number-average molecular weight of 450 to 2200 g/mol, components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.3/1.
Type:
Grant
Filed:
January 9, 2015
Date of Patent:
July 23, 2019
Assignee:
BASF Coatings GmbH
Inventors:
Bernhard Lettmann, Peter Hoffmann, Raphaela Jasper, Kai Kuhn, Heinz-Juergen Kemper, Marion Siegert
Abstract: The present invention relates to an aqueous coating composition comprising at least one aqueous dispersion comprising at least one copolymer (CP), said copolymer (CP) being preparable by (i) initially charging an aqueous dispersion of at least one polyurethane, and then (ii) polymerizing a mixture of olefinically unsaturated monomers in the presence of the polyurethane from (i), in which (a) a water-soluble initiator is used, (b) the olefinically unsaturated monomers are metered in such that a concentration of 6.0% by weight, based on the total amount of olefinically unsaturated monomers used for polymerization, in the reaction solution is not exceeded over the entire reaction time, and (c) the mixture of the olefinically unsaturated monomers comprises at least one polyolefinically unsaturated monomer and at least one linear hydroxy-functional reaction product (R) having an acid number less than 20 mg KOH/g, the preparation of which involves using at least one compound (v) containing two functional groups (v.
Type:
Grant
Filed:
November 18, 2014
Date of Patent:
July 9, 2019
Assignee:
BASF Coatings GmbH
Inventors:
Bernhard Steinmetz, Peggy Jankowski, Nadia Luhmann, Michael Matura, Hardy Reuter, Peter Hoffmann
Abstract: A method for producing a multicoat coating (M) on a substrate (S) that includes:(!) producing a basecoat (B) on the substrate by applying an aqueous basecoat material (b) to the substrate (S), the basecoat material being a two-component coating composition, and (II) producing a clearcoat (K) directly on the basecoat (B) by applying an aqueous clearcoat material (k) directly to the basecoat (B), the clearcoat material being a two-component coating composition.
Abstract: Described is a method for producing a multicoat color and/or effect paint system. A pigmented aqueous basecoat material is used which comprises at least one phosphite of the formula (I): wherein at least one of the radicals R1 to R3 is selected from the group of aliphatic hydrocarbons. The sum total of the weight percentage fractions of all of the phosphites of structural formula (I) here is 0.1% to 5% by weight, based on the total weight of the basecoat material used. Moreover, described are the corresponding basecoat materials, the corresponding multicoat color and/or effect paint system, and the use of the phosphites in pigmented aqueous coating materials. Also described is a method for repairing defects on multicoat color and/or effect paint systems produced with the aid of the above-identified method of the invention.
Type:
Grant
Filed:
September 20, 2013
Date of Patent:
May 21, 2019
Assignee:
BASF Coatings GmbH
Inventors:
Bernhard Steinmetz, Michael Matura, Bianca Göb, Peter Hoffmann
Abstract: The invention relates to physically, thermally and physically, or thermally curable aqueous coating compositions comprising A) at least one polyurethane selected from the group consisting of physically curable, thermally self-crosslinking and/or thermally externally crosslinking, ionically and/or nonionically stabilized polyurethanes, which are saturated, unsaturated and/or grafted with olefinically unsaturated compounds, as binder and B) at least one leaflet-shaped metallic pigment produced by PVD (Physical Vapor Deposition) methods, the amount of B), based on the total binder content of the coating composition, being less than 10% by weight, and the total binder content, based on the coating composition, being less than 12% by weight. The invention further relates to a process for producing the compositions and to their use in particular in the production of coatings.
Type:
Grant
Filed:
May 16, 2008
Date of Patent:
May 7, 2019
Assignee:
BASF Coatings GmbH
Inventors:
Norbert Low, Stephan Schwarte, Peter Sonntag, Melina Rutte, Kurt Hupp
Abstract: A method of forming a passivated pigment slurry includes combining a resin and a pigment to form a pigment-resin slurry, wherein the pigment includes a plurality of flakes each having a surface. After combining, the method includes firstly reacting an orthosilicate and the pigment in the presence of the resin to form a coated pigment-resin slurry. The coated pigment-resin slurry includes the resin and a coated pigment including the plurality of flakes each encapsulated by a first layer formed from the orthosilicate on the surface. The method further includes, concurrent to or after firstly reacting, secondly reacting the coated pigment-resin slurry and an organosilane compound having a hydrolysable group and an organic group to coat the first layer and form the passivated pigment slurry. The passivated pigment slurry includes the resin and a passivated pigment including the plurality of flakes each coated with a second layer disposed on the first.
Type:
Grant
Filed:
July 25, 2016
Date of Patent:
April 30, 2019
Assignee:
BASF Coatings GmbH
Inventors:
Donald Campbell, Prasad T Ramanna, Rajesh Rathod, Paragkumar Thanki
Abstract: Aryl-modified hyperbranched polyols are described, as are coating compositions containing these polyols. These polyols enable waterborne coating compositions that: include water-sensitive pigments; are storage stable; and have a low content of VOCs, as well as solventborne coating compositions that: include organic pigments; are storage stable; and enable certain enhanced color properties.
Abstract: Described is a solvent-based pigmented coating composition comprising (A) at least one binder comprising at least one acrylate polymer, polyurethane polymer, or a polyester, (B) at least one crosslinking agent selected from the group of blocked polyisocyanates and amino resins, (C) at least one pigment, and (D) at least one organic solvent selected from the group of alkyl acetates or alkyl monoglycol ethers, wherein alkyl is n-pentyl or n-hexyl, and wherein the solids content of the coating composition is at least 35% by weight.
Type:
Grant
Filed:
February 27, 2013
Date of Patent:
April 2, 2019
Assignee:
BASF Coatings GmbH
Inventors:
Jorn Lavalaye, Carmen Kunszt, Norbert Löw
Abstract: The present invention relates to a mixture (M) which can be used as curing agent and as adhesion promoter and which comprises at least two components (M1) and (M2), which are different from one another and have in each case independently of one another free and/or blocked isocyanate groups, and which optionally comprises a further component (M3) different from (M1) and (M2); component (M1) comprises at least one aliphatic polyisocyanate, and component (M2) comprises at least one aliphatic polyisocyanate having polyether units, wherein the relative weight ratio of (M1) and (M2) in (M) to one another is in a range from 25:1 to 3:1, based in each case on the solids content of (M1) and (M2), and at least one of the components (M1), (M2), and optionally (M3) present in (M) has hydrolyzable silane groups, to a use of (M) as curing agent and adhesion promoter in a coating composition, to such a coating composition, and to methods for at least partly coating a substrate with a surfacer coat and for at least partly co
Abstract: The present invention relates to an aqueous coating composition comprising at least one binder (A) comprising at least one polymeric resin (A1), at least one pigment (B), and an aqueous dispersion of at least one thickener (C), where (C) is obtainable by a method comprising at least the steps (1), (2), (3), and (4), namely preparing a dispersion or solution of at least one polyurethane as a polymeric resin (C2) in at least one organic solvent (step (1)), preparing a mixture of the dispersion or solution obtained by step (1) and of a melt or solution of at least one polyamide as at least one polymeric resin (C1) having an acid number in a range from 1 to 200 mg of KOH per g of (C1) (step (2)), adding water to the mixture obtained by step (2) (step (3)), and removing the organic solvent from the mixture obtained by step (3), to give the aqueous dispersion of (C) (step (4)), to the use thereof for at least partly coating an optionally coated substrate with a basecoat film, to a coating method of this kind, and t