Abstract: A process for preparing furan-2,5-dicarboxylic acid is disclosed. The process includes the following steps: preparing or providing a starting mixture including 5-(hydroxy-methyl)furfural (HMF), 5,5?-[oxy-bis(methylene)]bis-2-furfural (di-HMF), and water; subjecting said starting mixture to oxidation conditions in the presence of an oxygen-containing gas and a catalytically effective amount of a heterogeneous catalyst including one or more noble metals on a support so that both HMF and di-HMF react to give furane-2,5-dicarboxylic acid in a product mixture also including water and oxidation by-products. The use of a catalyst is also disclosed, the catalyst including one or more noble metals on a support as an heterogeneous oxidation catalyst for catalyzing in an aqueous starting mixture the reaction of both HMF and di-HMF to furane-2,5-dicarboxylic acid.
Type:
Grant
Filed:
July 1, 2016
Date of Patent:
August 20, 2019
Assignee:
BASF SE
Inventors:
Alvaro Gordillo, Holger Werhan, Richard Dehn, Benoit Blank, Joaquim Henrique Teles, Stephan A Schunk, Markus Piepenbrink, Rene Backes, Lei Zhang
Abstract: An electrochemical cell comprising (A) an anode comprising at least one anode active material, (B) a cathode comprising at least one cathode active material selected from mixed lithium transition metal oxides containing Mn and at least one second transition metal; lithium intercalating mixed oxides containing Ni, Al and at least one second transition metal; LiNiPO4; LiMnPO4; and LiCoPO4; (C) an electrolyte composition containing (i) at least one aprotic organic solvent; (ii) at least one lithium ion containing conducting salt; (iii) a compound of formula (I).
Type:
Application
Filed:
September 20, 2017
Publication date:
August 15, 2019
Applicant:
BASF SE
Inventors:
Manuel Alejandro MENDEZ AGUDELO, Johannes David HOECKER, Frederick Francois CHESNEAU, Kazuki YOSHIDA, Jinbum KIM
Abstract: The present invention relates to a process for generating a thin inorganic film on a substrate. In particular, the present invention relates to a process in which a compound of formula (I) is brought into a gaseous or an aerosol state and deposited from the gaseous or aerosol state onto a solid substrate: In the formula (I), R1, R2, R3, R4, and R5 are independently hydrogen, an alkyl group, an alkenyl group, an aryl group or a silyl group; p is 1, 2; M is Ni or Co; X is a ?-donating ligand which coordinates M; m is 1 or 2; and n is 0 to 3.
Type:
Application
Filed:
July 14, 2017
Publication date:
August 15, 2019
Applicant:
BASF SE
Inventors:
Carolin LIMBURG, Daniel LOEFFLER, Hagen WILMER, Marc WALTER, Matthias REINERS
Abstract: The present invention relates to novel uses of copolymers for removing and/or reducing the level of deposits in the fuel system and/or injection system of direct injection diesel and/or gasoline engines.
Abstract: The present invention relates to compositions comprising at least one thermoplastic polyurethane, at least one metal hydroxide, and at least one phosphorus-containing flame retardant, where the thermoplastic polyurethane is a thermoplastic polyurethane based on at least one diisocyanate and on at least one polycarbonatediol. The present invention further relates to the use of compositions of this type for producing cable sheathing.
Type:
Grant
Filed:
June 21, 2013
Date of Patent:
August 13, 2019
Assignee:
BASF SE
Inventors:
Oliver Steffen Henze, Oliver Muehren, Alfons Bertels, Sabine Conrad
Abstract: The present invention relates to a method of producing emulsion polymer particles having a core-shell structure wherein at least one polyalkylene oxide containing additive is used in the core, and also to their use in paints, paper coatings, foams, crop protection agents, liquid inks and cosmetic compositions.
Type:
Grant
Filed:
August 13, 2014
Date of Patent:
August 13, 2019
Assignee:
BASF SE
Inventors:
Daniel Kehrloesser, Joost Leswin, Daniel Specker, Konrad Roschmann, Matthias Gerst, Harm Wiese
Abstract: Disclosed herein is a latex paint containing i) a multistage carboxylated polymer latex binder, ii) a titanium dioxide pigment, and iii) a polymeric dispersant PD having a number average molecular weight, as determined by GPC, of at most 5500 Dalton. Also disclosed are methods for preparing the latex paint, and coatings containing the latex paint.
Type:
Application
Filed:
October 6, 2017
Publication date:
August 8, 2019
Applicant:
BASF SE
Inventors:
Immanuel WILLERICH, Volodymyr BOYKO, Bernd RECK, Jules MIKHAEL, Joost LESWIN, Mary THOMSON, Markus RUECKEL, Martin Robert SCHEUBLE
Abstract: What are described are compounds having two or more exovinylene cyclocarbonate units, wherein the exovinylene cyclocarbonate units are bonded to one another via at least one organic, siloxane-free connecting group which is not bonded directly to the exovinylene double bonds, excluding connecting groups formed by polymerization of (meth)acrylic monomers. The connecting group preferably has at least one acetal group. Also described are a process for preparing the compounds, two-component binders comprising the compounds, and uses of the compounds.
Abstract: Process for hydrogenating toluenediamine (TDA) tar containing TDA and high boilers relative to TDA, including the step of contacting the toluenediamine tar with a heterogeneous hydrogenation catalyst comprising at least one metal selected from the group consisting of Ni, Co, Ru, Pd, Pt on at least one catalyst support selected from the group consisting of carbon, TiO2 and ZrO2, and with hydrogen under hydrogenating conditions.
Type:
Application
Filed:
October 9, 2017
Publication date:
August 8, 2019
Applicant:
BASF SE
Inventors:
Armin LANGE DE OLIVEIRA, Ines LOTTENBURGER, Christian BECHTOLD, Thomas HEIDEMANN
Abstract: The invention relates to a method for producing seals made of polyurethane, in which (a) aliphatic polyisocyanate, (b) compounds containing at least two isocyanate-reactive groups, (c) catalysts, (d) antioxidants and/or light stabilizers, and, optionally, (e) blowing agents, and (f) auxiliary agents and/or additives are mixed to form a reaction mixture, and the reaction mixture is allowed to complete the reaction to form polyurethane. The seal made of polyurethane has a Shore A hardness of less than 90 and a density of at least 850 g/L. The polymeric compounds having groups reactive toward isocyanate include b1) polyetherols having a functionality of 2 to 4 and a hydroxyl number of 20 to 100 mg KOH/g, b2) hydrophobic polyols having an OH number of less than 180 mg KOH/g and a functionality of greater than 2 to 3, and b3) chain extenders.
Type:
Grant
Filed:
July 29, 2015
Date of Patent:
August 6, 2019
Assignee:
BASF SE
Inventors:
Stefan Bokern, Pierre Coppens, Patrick Bolze, Thomas Mathieu, Carola Melloh
Abstract: A reverse-phase suspension polymerization process for the manufacture of polymer beads comprising forming aqueous monomer beads comprising an aqueous solution of water-soluble ethylenically unsaturated monomer or monomer blend and polymerizing the monomer or monomer blend, to form polymer beads while suspended in a non-aqueous liquid, and recovering polymer beads, in which the process comprises providing in a vessel (1) a volume (2) of non-aqueous liquid wherein the volume of non-aqueous liquid extends between at least one polymer bead discharge point (3) and at least one monomer feed point (4), feeding the aqueous monomer or monomer blend through orifices (5) into, or onto, the non-aqueous liquid to form aqueous monomer beads, allowing the aqueous monomer beads to flow towards the polymer bead discharge point initiating polymerization of the aqueous monomer beads to form polymerizing beads, wherein the polymerizing beads form polymer beads when they reach the polymer bead discharge point, removing a suspensi
Type:
Grant
Filed:
July 29, 2014
Date of Patent:
August 6, 2019
Assignee:
BASF SE
Inventors:
Pascal Hesse, Aleksandra Jelicic, Gabriela Eugenia Fonseca Zepeda, Robert Haschick, Shankara Narayanan Keelapandal Ramamoorthy, Gareth Ian Naylor, John Scott Barratt, Oliver Soetje, Marcel Lievre, Florian Rainau, Mark Lebkuecher
Abstract: A proppant includes a particle present in an amount of from 90 to 99.5 percent by weight and a polymeric coating disposed about the particle and present in an amount of from 0.5 to 10 percent by weight, based on the total weight of the proppant. The polymeric coating includes the reaction product of an acrylate copolymer and an isocyanate. The acrylate copolymer includes styrene units and has a hydroxyl number of from 20 to 500 mg KOH/g. A method of forming the proppant includes the steps of combining the acrylate copolymer and the isocyanate to react and form the polymeric coating and coating the particle with the polymeric coating to form the proppant.
Type:
Grant
Filed:
March 11, 2014
Date of Patent:
August 6, 2019
Assignee:
BASF SE
Inventors:
Shawn Fitzgerald, Christopher M. Tanguay, Timothy D. Klots
Abstract: A process for preparing isosorbide di(meth)acrylate by transesterifying alkyl (meth)acrylate with isosorbide, comprising the steps of: (i) reacting alkyl (meth)acrylate with isosorbide in the presence of a catalyst comprising titanium(IV) or zirconium(IV) and a stabilizer in the presence of an azeotroping agent which forms an azeotrope with the alcohol bound in the alkyl (meth)acrylate, (ii) continuously distilling off the azeotrope of azeotroping agent and alcohol, wherein steps (i) and (ii) are conducted simultaneously until the isosorbide has been essentially fully converted, (iii) adding water to the product mixture which comprises isosorbide (meth)acrylate and is obtained in steps (i) and (ii) and removing the hydrolyzate of the catalyst comprising titanium(IV) or zirconium(IV), (iv) distilling unconverted alkyl (meth)acrylate and azeotroping agent out of the product mixture, (v) distilling off water from the product mixture, wherein step (iv) can also be conducted before step (iii) and steps (iv) and
Type:
Grant
Filed:
February 26, 2016
Date of Patent:
August 6, 2019
Assignee:
BASF SE
Inventors:
Andrea Misske, Friederike Fleischhaker, Christoph Fleckenstein, Martin Kaller, Ritesh Nair, Ulrik Stengel, Mathieu Blanchot
Abstract: The present invention relates to a precursor (1) for production of a high-temperature superconductor (HTS) in ribbon form, comprising a metallic substrate (10) in ribbon form having a first ribbon side (11) and a second ribbon side (12), wherein, on the first ribbon side (11), (a) the substrate (10) has a defined texture as template for crystallographically aligned growth of a buffer layer or an HTS layer and (b) an exposed surface of the substrate (10) is present or one or more layers (20,30) are present that are selected from the group consisting of: buffer precursor layer, pyrolyzed buffer precursor layer, buffer layer, HTS precursor layer, pyrolyzed HTS buffer precursor layer and pyrolyzed and further consolidated HTS buffer precursor layer, and, on the second ribbon side (12), at least one ceramic barrier layer (40) that protects the substrate (10) against oxidation or a precursor which is converted to such a layer during the HTS crystallization annealing or the pyrolysis is present, wherein, when one or
Type:
Grant
Filed:
July 23, 2015
Date of Patent:
August 6, 2019
Assignee:
BASF SE
Inventors:
Brygida Wojtyniak, Viktor Weimann, Michael Baecker, Martina Falter
Abstract: This invention relates to a continuous process for making a polymer polyol, the polymer polyol produced according to the said process and its applications.
Type:
Grant
Filed:
April 20, 2015
Date of Patent:
August 6, 2019
Assignee:
BASF SE
Inventors:
Christian Koenig, Dejan Petrovic, Achim Loeffler, Andreas Bauder, Daniel Freidank, Dirk Opfermann, Isa Alexandra Queiroz Da Fonseca, Caroline Mages-Sauter, Chuan Long Fu, Shu Kui Wang
Abstract: The invention relates to the use of specific quaternized nitrogen compounds which are also subjected to specific transesterification or amidation, as a fuel and lubricant additive or kerosene additive, such as in particular as a detergent additive, for decreasing or preventing deposits in the injection systems of direct-injection diesel engines, in particular in common rail injection systems, for decreasing the fuel consumption of direct-injection diesel engines, in particular of diesel engines having common rail injection systems, and for minimizing the power loss in direct-injection diesel engines, in particular in diesel engines having common rail injection systems. The invention further relates to the use as an additive for petrol, in particular for operation of DISI engines.
Type:
Grant
Filed:
September 19, 2014
Date of Patent:
August 6, 2019
Assignee:
BASF SE
Inventors:
Markus Hansch, Harald Boehnke, Wolfgang Grabarse, Ludwig Voelkel, Maxim Peretolchin
Abstract: The present invention relates to a disposable hygiene article comprising a melt-spun elastic fiber, in particular a diaper. Furthermore, the present invention relates to a process for preparing a disposable hygiene article comprising the steps of providing a melt-spun elastic fiber and applying the melt-spun elastic fiber to a disposable hygiene article or a part which is used to prepare the disposable hygiene article; as well as the use of a melt-spun elastic fiber in a preparation process for preparing a disposable hygiene article.