Abstract: Water-absorbing, expanded, crosslinked polymers obtainable by(I) foaming a polymerizable aqueous mixture which comprises(a) monoethylenically unsaturated monomers which contain acidic groups and are at least 50 mol % neutralized,(b) with or without other monoethylenically unsaturated monomers,(c) crosslinkers,(d) initiators,(e) 0.1-20% by weight of at least one surfactant,(f) with or without at least one solubilizer and(g) with or without thickeners, foam stabilizers, polymerization regulators, fillers and/or cell nucleating agents,where the foaming takes place by dispersing fine bubbles of a gas which is inert to free radicals, and(II) polymerizing the foamed mixture to form an expanded hydrogel and adjusting the water content of the expanded polymer to 1-45% by weight, a process for their production and their use in hygiene articles employed to absorb body fluids and in dressing material for covering wounds.
Type:
Grant
Filed:
May 4, 1998
Date of Patent:
October 24, 2000
Assignee:
BASF Aktiengesellschaft
Inventors:
Hans-Joachim Hahnle, Manfred Walter, Jurgen Tropsch, Gunnar Schornick, Thomas Anstock
Abstract: Perylene-3,4-dicarboximides I ##STR1## (R.sup.1 is hydrogen; C.sub.1 -C.sub.8 -alkyl; C.sub.5 -C.sub.8 -cycloalkyl; substituted or unsubstituted phenyl or naphthyl;R.sup.2 independently at each occurrence is hydrogen; C.sub.1 -C.sub.18 -alkyl, substituted or unsubstituted aryloxy, arylthio, hetaryloxy or hetarylthio)are prepared by reacting the corresponding perylene-3,4,9,10-tetracarboxylic acid or its anhydride (II) with an amide IIIR.sup.3 --CO--NHR.sup.1 III(R.sup.3 : C.sub.1 -C.sub.4 -alkyl or --NR.sup.4 R.sup.5 where R.sup.4 and R.sup.5 independently are hydrogen or one of the R.sup.1 alkyls, cycloalkyls, phenyls or naphthyls and where if two or more of R.sup.1, R.sup.4 and R.sup.5 are other than hydrogen they are identical)under superatmospheric pressure in the presence of an inert diluent and a transition metal catalyst.
Type:
Grant
Filed:
December 7, 1998
Date of Patent:
October 24, 2000
Assignee:
BASF Aktiengesellschaft
Inventors:
Arno Boehm, Harald Arms, Willi Helfer, Georg Henning
Abstract: Fungicidal mixtures, comprisinga) an oxime ether of the formula I ##STR1## where the substituents have the following meanings: X is oxygen or amino (NH);Y is CH or N;Z is oxygen, sulfur, amino (NH) or C.sub.1 -C.sub.4 -alkylamino (N--C.sub.1 -C.sub.4 -alkyl);R' is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -haloalkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.3 -C.sub.6 -haloalkynyl, C.sub.3 -C.sub.6 -cycloalkylmethyl, or is benzyl which can be partially or fully halogenated and/or can have attached to it one to three of the following radicals: cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy and C.sub.1 -C.sub.4 -alkylthio and/orb) a carbamate of the formula II ##STR2## where T is CH or N, n is 0, 1 or 2 and R is halogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.
Type:
Grant
Filed:
October 22, 1998
Date of Patent:
October 24, 2000
Assignee:
BASF Aktiengesellschaft
Inventors:
Ruth Muller, Herbert Bayer, Hubert Sauter, Eberhard Ammermann, Gisela Lorenz, Siegfried Strathmann, Reinhold Saur, Klaus Schelberger, Joachim Leyendecker
Abstract: Methods of regulating gene expression in subjects using tetracycline-responsive fusion proteins are disclosed. In one embodiment, the method involves introducing into a cell the subject a nucleic acid molecule encoding a fusion protein which inhibits transcription, the fusion protein comprising a first polypeptide which binds to a tet operator sequence, operatively linked to a heterologous second polypeptide which inhibits transcription in eukaryotic cells; and modulating the concentration of a tetracycline, or analogue thereof, in the subject. The first polypeptide can binds to a tet operator sequence in the absence, but not the presence, of tetracycline. Alternatively, the first polypeptide can binds to a tet operator sequence in the presence, but not the absence, of tetracycline.
Abstract: Herbicidally active cyclohexenone oxime ether metal salts of formula I ##STR1## where R.sup.a, R.sup.b, R.sup.c, R.sup.d, R.sup.e, Alk and R.sup.f are as defined in the specification disclosure, having an improved shelf life and thermal stability and reduced water vapor uptake.
Abstract: The present invention relates to at least simply unsaturated polyolefins with a number mean molecular weight in the range of 400 to 1,500 dalton and a dispersibility of M.sub.W /M.sub.N <1.2, obtained through catalytic dimerization from at least simply unsaturated olefin-oligomers, as well as to the method for their production. The present invention further relates to derivatives of these polyolefins which can be obtained by functionalizing at least a double link of the polyolefin. The invention also relates to the use of polyolefins and/or functionalization products as additives for fuels or lubricants.
Type:
Grant
Filed:
July 27, 1999
Date of Patent:
October 17, 2000
Assignee:
BASF Aktiengesellschaft
Inventors:
Hans Peter Rath, Irene Trotsch-Schaller, Dietmar Posselt, Bernhard Geissler, Johann-Peter Melder, Joachim Rosch
Abstract: Malonic ester derivatives of the formula I ##STR1## where the variables have the meaning explained in the description, as photostable UV filters in cosmetic and pharmaceutical preparations for protecting the human skin or human hair from the sun's rays, alone or together with compounds absorbing in the UV region and known for cosmetic and pharmaceutical preparations.
Abstract: A cosmetic or pharmaceutical composition which comprises at least one polymer or copolymer which is obtainable by free-radical emulsion or suspension polymerization in the presence of at least one chain-transfer reagent, has a glass transition temperature above -35.degree. C. and a content of organic volatile constituents .ltoreq.0.5% by weight, and is at least 20% by weight composed of a (meth)acrylic ester.
Type:
Grant
Filed:
June 26, 1997
Date of Patent:
October 17, 2000
Assignee:
BASF Aktiengesellschaft
Inventors:
Volker Schehlmann, Christian Schade, Axel Sanner, Karin Sperling, Hans-Ulrich Wekel
Abstract: The invention relates to the use of reactive prepolymeric organic compounds, containing structural units having at least one readily abstractable hydrogen with a bond energy of not more than 397 kJ/-mol and having at least one ethylenic double bond, for crosslinking, with or without free-radical initiators, by means of heat, high-energy radiation or heat and high-energy radiation.
Type:
Grant
Filed:
September 30, 1998
Date of Patent:
October 17, 2000
Assignee:
BASF Aktiengesellschaft
Inventors:
Rainer Blum, Thomas Loerzer, Gunther Hegemann, Gunther Baumgarten
Abstract: The present invention relates to films coated with two or more coats, whereinA the surface of a plastic film having a thickness of from 10 to 500 .mu.m is coated if desired with a filler composition,B the surface of the plastic film, or the filler coat, is overcoated with at least one pigmented paint coat,C the pigmented paint coat is coated if desired with a transparent plastic film.
Abstract: Linear, alternating .alpha.-olefin-CO copolymers are obtainable by polymerization of a monomer mixture comprisinga) carbon monoxide,b) 1-alkenes which are functionalized by a covalently bonded crown ether unit or cryptand unit A containing at least 5 heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur and/or selenium in the polyheteroatom framework, and, if desired,c) C.sub.2 -C.sub.24 -1-alkenes.
Type:
Grant
Filed:
September 29, 1999
Date of Patent:
October 17, 2000
Assignee:
BASF Aktiengesellschaft
Inventors:
Michael Geprags, Joachim Queisser, Bernhard Rieger, Martin Moller, Adnan S. Abu-Surrah, Harm-Anton Klok, Peter Eibeck, Markus Schmid
Abstract: Fungicidal mixtures, comprising a) a carbamate of the formula I ##STR1## where T is CH or N, n is 0, 1 or 2 and R is halogen, C.sub.1 --C.sub.4 --alkyl or C.sub.1 --C.sub.4 --haloalkyl, it being possible for the radicals R to be different when n is 2, and/orb) an oxime ether of the formula II ##STR2## where X is oxygen or amino (NH);Y is CH or N;Z is oxygen, sulfur, amino (NH) or C.sub.1 --C.sub.4 --alkylamino (N--C.sub.1 --C.sub.4 --alkyl);R' is C.sub.1 --C.sub.6 --alkyl, C.sub.1 --C.sub.6 --haloalkyl, C.sub.3 --C.sub.6 --alkenyl, C.sub.2 --C.sub.6 --haloalkenyl, C.sub.3 --C.sub.6 --alkynyl, C.sub.3 --C.sub.6 --haloalkynyl, (C.sub.3 --C.sub.6 --cycloalkyl)methyl, or is benzyl which may be partially or fully halogenated and/or carry one to three of the following radicals: cyano, C.sub.1 --C.sub.4 --alkyl, C.sub.1 --C.sub.4 --haloalkyl, C.sub.1 --C.sub.4 --alkoxy, C.sub.1 --C.sub.4 --haloalkoxy and C.sub.1 --C.sub.
Type:
Grant
Filed:
October 22, 1998
Date of Patent:
October 17, 2000
Assignee:
BASF Aktiengesellschaft
Inventors:
Bernd Muller, Hubert Sauter, Eberhard Ammermann, Gisela Lorenz, Siegfried Strathmann, Klaus Schelberger, Maria Scherer, Dietrich Mappes, Joachim Leyendecker, Herbert Bayer, Ruth Muller
Abstract: 2-(3-Pyrazolyloxymethylene)nitrobenzene [sic] derivatives of the formula I ##STR1## where the substituents and indices have the meanings given in the description,are prepared by bromination of an o-nitrotoluene of the formula II ##STR2## and subsequent reaction with a 3-hydroxypyrazole of the formula IV ##STR3##
Type:
Grant
Filed:
January 27, 2000
Date of Patent:
October 17, 2000
Assignee:
BASF Aktiengesellschaft
Inventors:
Horst Wingert, Norbert Gotz, Michael Keil, Ralf Klintz, Uwe Josef Vogelbacher, Josef Wahl
Abstract: The invention provides for a process for preparing pulverulent polymers by drying aqueous polymer dispersions in the presence of copolymers based on ethylenically unsaturated C.sub.3 -C.sub.6 carboxylic acids and their hydroxyalkyl esters as assistants;polymer powders obtainable by this process;aqueous polymer dispersions obtainable by free-radical aqueous emulsion polymerization of ethylenically unsaturated monomers in the presence of the novel copolymers, and the powders obtainable therefrom, anda polymeric binder as well as and mineral building materials which comprise the novel polymer powders.
Type:
Grant
Filed:
February 12, 1998
Date of Patent:
October 17, 2000
Assignee:
BASF Aktiengesellschaft
Inventors:
Joachim Pakusch, Maximilian Angel, Peter Claassen, Andree Dragon
Abstract: An insoluble, only slight swellable, polymer having modified amino groups, which contain units of the formulae: ##STR1## or both (I) and (II), wherein R.sup.1, R.sup.2, R.sup.3 and Me are as defined herein.
Type:
Grant
Filed:
March 11, 1999
Date of Patent:
October 17, 2000
Assignee:
BASF Aktiengesellschaft
Inventors:
Jens Utecht, Martin Rubenacker, Claudia Nilz, Rainer Rahm
Abstract: Substituted benzyl bromides of the formula I ##STR1## where at least one substituent R.sup.1-5 is an electron-attracting group such as fluorine, chlorine, bromine, C.sub.1 -C.sub.4 -alkoxycarbonyl, cyano or nitro, and the other substituents R.sup.1-5 are hydrogen or methyl,are prepared by bromination of substituted toluenes of the formula II ##STR2## with a brominating agent at from 20 to 95.degree. C.
Type:
Grant
Filed:
January 11, 2000
Date of Patent:
October 17, 2000
Assignee:
BASF Aktiengesellschaft
Inventors:
Horst Wingert, Norbert Gotz, Michael Keil, Bernd Muller
Abstract: A process for obtaining glycols of low aldehyde content in which the plant used to obtain the glycol(s) is surface-treated, in whole or in part, with at least one reductive phosphorus compound.
Abstract: A carpet yarn is a plurality of fibers spun from a multiconstituent polymer alloy composed of 60 wt. % or more of nylon 6; up to about 37 wt. % of a stereoregular polyolefin having a melt flow index of from about 2 to about 100; and 3-37 wt. % of a polyolefin that is at least partially modified by one or more type of polar monomer. Upon steam heatsetting at about 124.degree. C., the yarn shrinks less than about 20%.
Abstract: The present invention relates to a process for the production of lenticular tablets by melt calendering in which molding rolls with depressions in the shape of segments of an ellipsoid are used. The process according to the invention affords tablets which are easily deflashed and in which the tablet residue to be abraded when there is a displacement between the upper and lower half of the tablet is small.
Type:
Grant
Filed:
June 20, 1997
Date of Patent:
October 17, 2000
Assignee:
BASF Aktiengesellschaft
Inventors:
Joerg Rosenberg, Werner Maier, Jorg Breitenbach
Abstract: In a process for preparing carbonyl compounds of the formula ##STR1## where R.sup.1 is a hydrogen atom or an alkyl radical having from 1 to 3 carbon atoms, R.sup.2 is a hydrogen atom or a radical of the formula ##STR2## where R.sup.3 is a hydrogen atom or together with R.sup.4 is an oxygen atom, R.sup.4 is the radical OR.sup.6 or together with R.sup.3 is an oxygen atom, R.sup.5 is a hydrogen atom, an alkyl radical having from 1 to 8 carbon atoms or a cyclohexyl or cyclopentyl radical and R.sup.6 is an alkyl radical having from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula --CH.sub.2 --CHO or --CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CHO, by gas-phase oxidation of methanol or alcohols of the formula ##STR3## where R.sup.1 and R.sup.5 are as defined above and R.sup.7 is a hydrogen atom or a radical OR.sup.8 and R.sup.8 is a hydrogen atom, an alkyl radical having from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical for the formula --CH.sub.2 --CH.sub.
Type:
Grant
Filed:
June 16, 1999
Date of Patent:
October 17, 2000
Assignee:
BASF Aktiengesellschaft
Inventors:
Thomas Fetzer, Dirk Demuth, Heinz Rutter, Helmuth Menig, Peter Resch, Wilhelm Ruppel, Harro Wache