Abstract: Ionically crosslinked ethylene copolymers prepared by mixing a carboxyl-containing copolymer with an aqueous metal salt solution in the reaction zone of a twin-screw extruder and transferring the product to a devolatilization zone, and are used as adhesion promoters, injection molded articles or laminating films.
Type:
Grant
Filed:
June 14, 1989
Date of Patent:
March 26, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Norbert Hasenbein, Lothar Schlemmer, Thomas Muehlenbernd, Gernot Koehler
Abstract: A method for producing a granulated riboflavin product comprises making a specific mixture of riboflavin, binder and water, followed by homogenizing the mixture and thereafter spray-drying the homogenized mixture so that granules are produced. The mixture has a relatively high vitamin and binder content but is reduced to a relatively low viscosity (via homogenization) so that spray drying can be performed.
Type:
Grant
Filed:
May 23, 1990
Date of Patent:
March 19, 1991
Assignee:
BASF Corporation
Inventors:
Terence K. Kilbride, Jr., Rudolph E. Lisa
Abstract: Aqueous glyoxal solutions which contain organic acids are purified by means of a membrane cell comprising two or more compartments by passing the glyoxal solution through at least one of the cell compartments separated from the neighboring compartment(s) by anion exchange membranes and by passing the aqueous solution of a base through at least one of the neighboring compartments.
Type:
Grant
Filed:
December 11, 1989
Date of Patent:
March 19, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Michael Steiniger, Hartwig Voss, Leopold Hupfer
Abstract: Cyclohexenone derivatives of the formula ##STR1## where R.sup.1, R.sup.2 R.sup.3, R.sup.4 and R.sup.5 have the meanings given in the disclosure, and their use for controlling unwanted plant growth.
Type:
Grant
Filed:
April 18, 1988
Date of Patent:
March 19, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Michael Keil, Rainer Becker, Dieter Jahn, Norbert Goetz, Ulrich Schirmer, Bruno Wuerzer
Abstract: The preparation of 4-methylenetetrahydropyran (I) by reacting 3-methylenepentane-1,5-diol with a sulfohalide in the presence of an aqueous mineral base. Compound I serves as an intermediate in organic syntheses.
Type:
Grant
Filed:
July 3, 1990
Date of Patent:
March 19, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Thomas Kuekenhoehner, Wolfgang Spiegler, Norbert Goetz, Wolfgang Rohr
Abstract: A process for the pre-treatment of textile surfaces which impart soil release properties, comprising contacting a textile with a dispersion graft copolymer of:(a) a polyalkylene oxide which has a number average molecular weight of from 300 to 100,000, is based on ethylene oxide, propylene oxide and/or butylene oxide and may be capped at one end through etherification, esterification, amidation or reaction with a isocyanate, and(b) at least one vinyl ester derived from a saturated monocarboxylic acid containing 1 to 6 carbon atoms and/or a methyl or ethyl ester of acrylic or methacrylic acidin a weight ratio (a):(b) of from 1:0.2 to 1:10 in an aqueous liquor.
Type:
Grant
Filed:
October 5, 1989
Date of Patent:
March 19, 1991
Assignee:
BASF Corporation
Inventors:
Richard J. Holland, Alicia V. York, Ronald M. Ruppert
Abstract: Thiamine monophosphate is separated from a solution of thiamine phosphates containing thiamine monophosphate and cocarboxylase and having a pH of 2-7 by using a cation exchanger resin having a pK.sub.a of 1.0-4.5.
Type:
Grant
Filed:
February 21, 1990
Date of Patent:
March 12, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Walter Dobuler, Wolfgang Schul, Joachim Paust, Alfred Mitschker
Abstract: Sulfonamide derivatives of the formula I ##STR1## where R.sup.1 is a C.sub.1 -C.sub.4 -alkyl or phenyl group which may be substituted by halogen, trifluoromethyl or C.sub.1 -C.sub.4 -alkyl, R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, A is a group CHOR.sup.3 C.dbd.O, C.dbd.S or C.dbd.N--OR.sup.4, R.sup.3 is hydrogen, C.sub.1 -C.sub.4 -alkyl phenyl, benzyl or C.sub.1 -C.sub.4 -acyl, R.sup.4 is hydrogen or methyl, B may be methylene or ethylene in the m or p position or, of A is not carbonyl, may be methyleneoxy, the oxygen atom being bonded to the aromatic, and E is a carboxyl, phosphonic acid or sulfo radical, their physiologically acceptable salts, esters with C.sub.1 -C.sub.4 -alcohols or amides or the tetrazol-5-yl radical, their preparation and their use as drugs.
Type:
Grant
Filed:
May 26, 1989
Date of Patent:
March 12, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Bernhard Schmied, Hand D. Lehmann, Verena Baldinger, Klaus Ruebsamen
Abstract: The use of diphenyl ether derivatives of the general formula I ##STR1## where A is a radical ##STR2## where R.sup.1 is hydrogen, an alkali metal or alkaline earth metal ion, substituted or unsubstituted ammonium, alkyl of from 1 to 4 carbon atoms or alkoxycarbonylalkyl of a total of 1 to 6 carbon atoms and R.sup.2 is alkyl of from 1 to 4 carbon atoms, for the desiccation and abscission of plant organs.
Type:
Grant
Filed:
December 18, 1989
Date of Patent:
March 12, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Klaus Grossmann, Helmut Walter, Bruno Wuerzer
Abstract: A method and apparatus are disclosed for wrapping a cover yarn onto an elastic core yarn utilizing a "producer" package directly. The disclosed apparatus eliminates the conventional rewinding step used by garment material manufacturers.
Abstract: Transition metal complexes of the general formula I[A].sup.x- [Q].sup.+.sub.x Iwhere Q is one equivalent of a cation, x is from 0 to 2 and A is a transition metal complex of the general formula ##STR1## where n is from 1 to 3, M is positively charged cobalt, rhodium, iridium or ruthenium, the ligands B are phosphonic, arsonic, phosphinic and/or arsinic acid ligands which are esterified with identical or different alcohols, one or more of these alcohol components carrying a functional group, L is ##STR2## the radicals R.sup.5 are identical or different radicals from the group consisting of C.sub.1 -C.sub.4 -alkyl and phenyl, p is an integer from 0 to 6, q is an integer from 0 to 5, and R.sup.1 is fluorine, chlorine, bromine, iodine, cyanide, isocyanide, cyanate, isocyanate, thiocyanate, isothiocyanate, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.
Type:
Grant
Filed:
June 2, 1989
Date of Patent:
March 12, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Werner Bertleff, Dieter Koeffer, Wolfgang Klaeui, Choong-Eui Song
Abstract: Efflorescence phenomena on mineral substrates are prevented by coating the surface of the mineral substrates with aqueous polyacrylate dispersions and drying the coating, if necessary at elevated temperatures, by a process in which a mixture of(A) a dispersion of a copolymer of(a) (meth)acrylates of alkanols which are of 3 to 20 carbon atoms and have a tertiary CH group,(b) styrene, .alpha.-methylstyrene, methyl methacrylate, tert-butyl (meth)acrylate and/or (meth)acrylonitrile and(c) mono- and/or dicarboxylic acids of 3 to 5 carbon atoms and/or or their amides which may be substituted at the N atom by alkyl, and(B) an aromatic ketoneis used for the coating, and the coating is exposed to ultraviolet light.
Type:
Grant
Filed:
August 8, 1989
Date of Patent:
March 12, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Gerd Rehmer, Manfred Schwartz, Bernhard Dotzauer
Abstract: CO.sub.2 and, if necessary, H.sub.2 S are removed from a gas which contains CO.sub.2 and may contain H.sub.2 S with an absorption liquid by a process in which the gas which contains CO.sub.2 and may contain H.sub.2 S is treated in an absorption zone with the absorption liquid, the treated gas is removed from the absorption zone, the absorption liquid which is obtained from the absorption zone and is laden with CO.sub.2 and may be laden with H.sub.2 S is then regenerated in that the said absorption liquid is let down in one or more let-down stages and a let-down gas is taken off at the top of the first let-down stage or, in the case of a plurality of let-down stages, at the top of one or more of the first to penultimate let-down stages, and the partially regenerated absorption liquid obtained from the last let-down stage is, if required, fed to a stripping zone for further regeneration, one or more acid gas streams which contain the CO.sub.2 and may contain H.sub.
Abstract: Sulfonamides of the general formula I ##STR1## where A, n, R.sup.1, R.sup.2, R.sup.3, W, X, Y and Z have the meanings given in the disclosure and claims, salts and N-oxides thereof, and their use as herbicidal agents.
Type:
Grant
Filed:
July 12, 1989
Date of Patent:
March 12, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Thomas Saupe, Gerhard Klebe, Ulrich Schirmer, Gerhard Paul, Reiner Kober, Bruno Wuerzer, Rainer Berghaus, Norbert Meyer, Karl-Otto Westphalen
Abstract: Olefinically unsaturated carboxylic esters having a terminal ester group and of the general formulae Ia and IbR.sup.1 --CH.sub.2 --CH.dbd.CH--(CH.sub.2).sub.r--1 --COOR.sup.2 (Ia)R.sup.1 --CH.dbd.CH--(CH.sub.2).sub.r --COOR.sup.2 (Ib)and, if desired, further double bond isomers, where R.sup.1 is hydrogen or an organic radical, R.sup.2 is C.sub.1 -C.sub.8 -alkyl and r is from 1 to 20, are prepared by a process in which an .alpha.-substituted .alpha.,.omega.-(n-alkylenedicarboxylic ester) of the general formula II ##STR1## where R.sup.1 and R.sup.2 and r have the abovementioned meanings and R.sup.3 is C.sub.1 -C.sub.8 -alkyl, is converted over an acidic heterogeneous catalyst at from 150.degree. to 800.degree. C. and under from 0.01 to 50 bar.
Type:
Grant
Filed:
April 14, 1989
Date of Patent:
March 12, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Franz Merger, Hans Horler, Wolfgang Hoelderich, Tom Witzel
Abstract: Novel zinc salts, lead salts and/or calcium salts of carboxylic acids of the general formula ##STR1## where A is a radical of the formula ##STR2## Y is --CO-- or --SO.sub.2 --, X.sup.1 is C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy or halogen, X.sup.2 is hydrogen, C.sub.1 -C.sub.8 -alkyl or halogen, X.sup.3 is hydrogen, nitro or halogen, m and n are each 1 or 2, and X.sup.1 may furthermore be hydrogen if A is a radical of the formula (III) or X.sup.3 is nitro or m is 2, in particular the basic salts of (I), are suitable as corrosion inhibitors for coating systems.
Abstract: Ascorbic acid 2-phosphate is prepared by reacting ascorbic acid or an ascorbic acid derivative with POCl.sub.3 in the presence of a tertiary amine in a suitable aqueous solvent at from -10.degree. to 25.degree. C. while maintaining a pH of about 8-13.5 with KOH during the entire phosphorylation reaction and then isolating the ascorbic acid 2-phosphate, by a process in which an aqueous solution of a magnesium compound is added to the reaction mixture obtained in the phosphorylation, without prior treatment with an ion exchanger, until the formation of crystalline KMg PO.sub.4 is complete, the KMgPO.sub.4 which is crystallized out is separated off, the resulting filtrate is evaporated down at a pH of from 6 to 11 and/or from 0.
Type:
Grant
Filed:
March 1, 1990
Date of Patent:
March 12, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Walter Dobler, Joachim Paust, Roland Betz
Abstract: Sulfonamides of the general formula I ##STR1## where A, n, R.sup.1, R.sup.2, R.sup.3, W, X, Y and Z have the meanings given in the disclosure and claims, salts and N-oxides thereof, and their use as herbicidal agents.
Type:
Grant
Filed:
July 12, 1989
Date of Patent:
March 12, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Thomas Saupe, Gerhard Klebe, Ulrich Schirmer, Gerhard Paul, Reiner Kober, Bruno Wuerzer, Rainer Berghaus, Norbert Meyer, Karl-Otto Westphalen
Abstract: Dyes are transferred from a carrier by sublimation/vaporization to plastic-coated papers by a process in which the dyes used are of the general formula (I) ##STR1## where A is D--N.dbd.N-- or ##STR2## R.sup.1 and R.sup.2 are each hydrogen, alkyl, alkoxy, alkylthio or halogen and R.sup.1 and R together may furthermore form a 5-membered or 6-membered heterocyclic ring, and R and R' independently of one another are each hydrogen, phenyl which is unsubstituted or substituted by methyl or methoxy, or C.sub.5 - or C.sub.6 -cycloalkyl or C.sub.1 -C.sub.6 -alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.2 -C.sub.5 -alkanoyloxy, C.sub.1 -C.sub.4 -alkoxycarbonyloxy, C.sub.1 -C.sub.4 -alkoxy-C.sub.2 -or C.sub.3 -alkoxycarbonyloxy, hydroxyl, cyano, halogen, phenyl or C.sub.5 - or C.sub.
Type:
Grant
Filed:
July 24, 1989
Date of Patent:
March 12, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Bernhard Albert, Karl-Heinz Etzbach, Ruediger Sens