Abstract: This invention, therefore, relates to the field of polyurethane coatings for use in automobile basecoat/clearcoat systems. In particular, this invention relates to water-dispersible polyurethane resins having polyether sidechains which may be utilized in basecoat compositions as principal resins or grind resins. These polyurethane resins may be laterally stabilized or terminally stabilized. The terminally stabilized resins of this invention are preferably employed as principal resins in basecoat compositions.
Type:
Grant
Filed:
December 22, 1988
Date of Patent:
August 7, 1990
Assignee:
BASF Corporation, Inmont Division
Inventors:
Thomas G. Savino, Thomas C. Balch, Alan L. Steinmetz, Sergio E. Balatin, Nicholas Caiozzo
Abstract: Metal-containing or metalfree, monosubstituted or disubstituted phthalocyanines I which have one or two of the following radicals R as substituents on their benzene rings: R=bromine, cyano, C.sub.1 -C.sub.3 -alkyl, n-butyl, i-butyl, C.sub.5 -C.sub.20 -alkyl, C.sub.5 -C.sub.10 -cycloalkyl, fluorinated C.sub.1 -C.sub.6 -alkyl, C.sub.6 -C.sub.20 -aryl, XR.sup.1, where X is oxygen, sulfur, selenium, tellurium or imino (NH) and R.sup.1 is C.sub.1 -C.sub.6 -alkyl, fluorinated C.sub.1 -C.sub.6 -alkyl or C.sub.6 -C.sub.20 -aryl, or Si(R.sup.2).sub.3, where R.sup.2 is C.sub.1 -C.sub.6 -alkyl, each and every substituted benzene ring being substituted by only one R radical, are useful in Laser-optical recording materials.
Type:
Grant
Filed:
February 24, 1989
Date of Patent:
August 7, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Bernhard Albert, Harald Kuppelmaier, Gerhard Wagenblast
Abstract: Guanidiniumdodecylbenzene sulfonates of the formula ##STR1## where R is the group --H, --CH.sub.3 or ##STR2## and X is 1, 2, 3 or 4, and fungicides containing these compounds.
Abstract: Azetidine derivatives of the formula I ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.3 -alkyl, A is --XR.sup.3 or --N(R.sup.5)--OR.sup.4, X is oxygen or sulfur, R.sup.3 is C.sub.1 -C.sub.20 -alkyl, C.sub.1 -C.sub.20 -haloalkyl, C.sub.3 -C.sub.18 -alkenyl, C.sub.3 - or C.sub.4 -alkynyl, bridged C.sub.3 -C.sub.12 -cycloalkyl or C.sub.4 -C.sub.12 -alkylcycloalkyl, the cycloalkyl radicals or alkylcycloalkyl radicals being unsubstituted or substituted by C.sub.1 -C.sub.5 -alkyl or cyclohexyl, R.sup.4 is C.sub.1 -C.sub.20 -alkyl, C.sub.1 -C.sub.12 -haloalkyl, C.sub.1 -C.sub.6 -cyanoalkyl, C.sub.1 -C.sub.12 -alkoxyalkyl, C.sub.3 -C.sub.18 -alkenyl, C.sub.3 -C.sub.18 -haloalkenyl, C.sub.3 - or C.sub.4 -alkynyl, C.sub.3 -C.sub.12 -cycloalkyl or C.sub.4 -C.sub.12 -cycloalkylalkyl, C.sub.3 -C.sub.16 -alkoxycarbonylalkyl or unsubstituted or substituted C.sub.7 -C.sub.20 -aralkyl and R.sup.5 is hydrogen or C.sub.1 -C.sub.3 -alkyl, and agents and methods for regulating plant growth.
Type:
Grant
Filed:
July 7, 1989
Date of Patent:
July 31, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Costin Rentzea, Wilhelm Rademacher, Johann Jung, Albrecht Harreus
Abstract: A mixture of a substance having thrombolytic activity and of an antithrombotic substance which is suitable for controlling vascular disorders caused by thrombosis is described.
Type:
Grant
Filed:
February 13, 1989
Date of Patent:
July 31, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Volker Eschenfelder, Bernhard Schmied, Klaus Ruebsamen
Abstract: Pigmentary Opal Sulfate is made by combining triphenylpararosaniline (Opal Blue) with a dilute acid. The pigmentary Opal Sulfate is a substitute for Alkali Blue. The most preferred process for producing the pigmentary Opal Sulfate involves drowning a solution of Opal Blue in a highly agitated solution of dilute sulfuric acid.
Type:
Grant
Filed:
December 28, 1987
Date of Patent:
July 31, 1990
Assignee:
BASF Corporation
Inventors:
Anand S. G. Sharangpani, Floyd G. Spence, Brian D. Teunis
Abstract: The invention relates to aqueous electrocoating baths for cathodic paint deposition which contain, as cathodically depositable binders, modified epoxide-amine adducts and are prepared by reacting, in the presence of basic amine catalysts,(1)(A) polyepoxides with(B) compounds which contain, per molecule, one or more, preferably 2, hydroxyl groups bonded to aromatic and/or (cyclo)aliphatic molecular fragments, to form epoxide group-containing intermediates, and(2) by subsequently reacting these intermediates, if appropriate, with further conventional modifiers and finally with(C) primary and/or secondary (poly)amines or their salts and/or salts of tertiary amines, the resultant reaction products being neutralized with acids, if appropriate, dispersed in an aqueous medium and these dispersions further processed by well-known methods to form electrocoating baths.
Abstract: N-hydroxypyrazoles of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 may be identical or different and are each hydrogen, alkyl, halogen or aryl, or R.sup.1 and R.sup.2 or R.sup.2 and R.sup.3 together with the carbon atoms carrying these radicals form an aromatic or nonaromatic ring of 5 or 6 carbon atoms are prepared by a process in which(A) a pyrazole of the general formula II ##STR2## is converted in a conventional manner with an alkali metal hydroxide, alkali metal hydride or alkali metal carbonate into one of its metal salts of the general formula III ##STR3## where ME.sym. is a cation of an alkali metal, and (B) the resulting metal salt of the general formula III is reacted with dibenzoyl peroxide in an inert organic solvent or in a 2-phase system, in the presence or absence of a phase transfer catalyst.
Type:
Grant
Filed:
June 16, 1989
Date of Patent:
July 31, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Ulf Baus, Wolfgang Reuther, Rolf Fikentscher
Abstract: N-hydroxypyrazoles of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 may be identical or different and are each hydrogen or halogen, are prepared by a process in which a pyrazole of the general formula II ##STR2## where R.sup.1, R.sup.2 and R.sup.3 have the meanings stated for formula I, is reacted with an aliphatic or aromatic peroxocarboxylic acid, preferably in the presence of from 0 to 15 moles of an alkali metal hydroxide, alkaline earth metal hydroxide, alkali meteal carbonate or alkaline earth metal carbonate in such a way that the reaction temperature is from -5.degree. C. to 60.degree.C.The reaction can be carried out in water as a solvent or in a 2-phase system consisting of water and an inert organic solvent which is poorly miscible with water, in the presence or absence of a suitable phase transfer catalyst. The peroxocarboxylic acid can be prepared in the reaction mixture before the reaction from H.sub.2 O.sub.
Abstract: Dispersions of crosslinked polymer micro-particles in aqueous media, a process for the preparation of these dispersions, and coating compositions containing these dispersions.The invention relates to dispersions of crosslinked polymer micro-particles in aqueous media, which have been prepared:(1) by dispersing a mixture of the components (A) and (B) in an aqueous medium, the component (A) being composed of one or more polyester-polyols containing at least 2 hydroxyl groups, and the component (B) being composed of one or more polyisocyanate compounds, and the component (A) having available a number of ionic groups, preferably carboxylate groups, sufficient to form a stable dispersion, and at least one part of the components (A) and/or (B) containing more than 2 hydroxyl or isocyanate, respectively, groups per molecule and(2) by subsequently heating the dispersion thus obtained to a temperature sufficiently high for the components (A) and (B) to react to form crosslinked polymer micro-particles.
Type:
Grant
Filed:
August 26, 1988
Date of Patent:
July 31, 1990
Assignee:
BASF Lacke & Farben Aktiengesellschaft
Inventors:
Hans-Dieter Hille, Horst Muller, Arnold Dobbelstein
Abstract: A liquid crystalline copolymer contains a comonomer to which a radical ##STR1## is bonded, where X is a chemical bond, O or NR.sup.1, Y is a chemical bond or --CO--, R.sup.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl and A is a linear or branched C.sub.2 -C.sub.20 -alkylene group which may be interrupted by --O-- or ##STR2## The liquid crystalline copolymers have very good lightfastness, high dichroism and a high absorption.
Abstract: Novel (p-phenoxyphenoxy)-methyl-five-membered heeroaromatic radicals of the formula ##STR1## where the substituents have the following meanings: R.sup.1, R.sup.2, R.sup.3 hydrogen, halogen, C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.3 -C.sub.10 -cycloalkyl, nitro or cyano,R.sup.4 hydrogen or C.sub.1 -C.sub.4 -alkyl, and a five-membered heteroaromatic ring, and their use for combating pests.
Type:
Grant
Filed:
April 20, 1988
Date of Patent:
July 24, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Hans Theobald, Christoph Kuenast, Peter Hofmeister, Hans-Juergen Neubauer, Thomas Kuekenhoehner, Wolfgang Krieg, Joachim Leyendecker, Uwe Kardorff
Abstract: Aqueous polyester dispersions are prepared by(a) condensing an aromatic dicarboxylic acid or ester with at least one diol to give a prepolymer having an acid number of from 2 to 8,(b) reacting the prepolymer with at least one molecular weight enhancer compound, e.g. trimellitic anhydride to give a polyester having an acid number of from 40 to 60, and(c) dispersing the polyester in an aqueous medium to form an aqueous dispersion by adding an aqueous mixture of ammonia and an amine in a molar ratio of from 10:1 to 1:10 to a melt of the polyester which has a temperature within the range from 150.degree. to 230.degree. C.,and are used as sizes for sizing filament warp yarns.
Abstract: Phenylethanols of the formula ##STR1## where R is hydrogen, alkyl of from 1 to 4 carbon atoms, alkoxy of from 1 to 4 carbon atoms, fluorine, trifluoromethyl or trifluoromethoxy, are prepared by reacting epoxides of the formula ##STR2## where R is as defined above, in the presence of hydrogen over zeolites and/or phosphates, doped with hydrogenating metal as catalysts, preferably over zeolites of the pentasil type.
Type:
Grant
Filed:
January 13, 1989
Date of Patent:
July 24, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Wolfgang Hoelderich, Norbert Goetz, Leopold Hupfer
Abstract: Organic halogen compounds in which one or more halogen atoms are covalently bonded to the carbon are subjected to reductive dehalogenation by reaction with a hydrocarbon in the presence of carbon at elevated temperatures with formation of a hydrogen halide, by a process in which the dehalogenation is carried out in the presence of iron powder or an iron compound as a cocatalyst, at from 100.degree. to 450.degree. C.
Type:
Grant
Filed:
May 2, 1988
Date of Patent:
July 24, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Toni Dockner, Manfred Sauerwald, Herbert Krug, Matthias Irgang
Abstract: An improved multifilamentary fibrous material is formed having solid particles of a matrix-forming thermosetting resin substantially uniformly dispersed among adjoining filaments in the absence of fusion bonding. The thermosetting resin particles initially are dispersed in an aqueous medium containing an effective amount of a dissolved polymeric binding agent and the viscosity of the medium subsequently is substantially increased to at least 50,000 cps. to form a gelled impregnation bath having a plastic flow characteristic with shear-thinning behavior wherein the thermosetting resin particles are substantially uniformly suspended. The resulting impregnation bath is caused to flow between the adjoining filaments of the multifilamentary fibrous material with a concomitant viscosity reduction which aids in the incorporation of the resin particles. The concentration of the aqueous medium in the product is controlled to yield a uniform, handleable, drapable, tacky, and highly stable product.
Type:
Grant
Filed:
October 25, 1989
Date of Patent:
July 24, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Robert Dyksterhouse, Joel A. Dyksterhouse, Alan C. Handermann, Edward D. Western
Abstract: Thermoplastic molding materials based on polyphenylene ethers and nylons are prepared in an extruder by a continuous process in which a modified polyphenylene ether is prepared in a first zone of the extruder and is then mixed with nylons and, if required, further additives in one or more further zones.
Type:
Grant
Filed:
May 8, 1989
Date of Patent:
July 24, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Christof Taubitz, Hermann Gausepohl, Erhard Seiler, Klaus Boehlke, Lothar Schlemmer
Abstract: Agents for reducing transpiration in plants and/or avoiding impairment to plants caused by heat and dry stress, comprising a synergistic mixture containing at least one acetylene compound of the formula I ##STR1## where the substituents have the following meanings R.sup.1 CH.sub.2 OH, COOH, CH.sub.2 OR.sup.4, COOR.sup.4 or CHXY,OR.sup.2 andY OR.sup.3 or X and Y together are C.sub.2 -C.sub.5 -alkylenedioxy which is unsubstituted or mono-, di- or trisubstituted by C.sub.1 -C.sub.4 -alkyl, or are a doubly bonded oxygen atom,R.sup.2, R.sup.3 C.sub.1 -C.sub.8 -alkyl andR.sup.4 C.sub.1 -C.sub.8 -alkyl, C.sub.2 -C.sub.8 -alkoxyalkyl, C.sub.2 -C.sub.4 -haloalkyl, phenyl or C.sub.7 -C.sub.16 -phenylalkyl,and at least one phenylbenzylurea of the general formula II ##STR2## where the substituents have the following meanings R.sup.5 hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, phenyl or C.sub.7 -C.sub.16 -phenylalkyl andR.sup.6 -R.sup.
Type:
Grant
Filed:
February 6, 1989
Date of Patent:
July 24, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Guenter Schulz, Juergen Schubert, Hubert Sauter, Klaus Grosmann, Johann Jung