Abstract: Expandable-polystyrene beads suitable for use in making impervious containers are made from a recipe including styrene, free-radical initiator and polyvinyl pyrrolidone, and this practice includes a step of washing the beads in a warm aqueous solution to which an alkoxylated nonionic surfactant having 70-90 percent of its molecular weight accounted for by oxyethylene units is added in an amount effective to cause the washing to remove contaminating grafted polyvinyl pyrrolidone from the surface of the beads and cause them to become expandable into impervious product containers.
Type:
Grant
Filed:
July 21, 1978
Date of Patent:
November 13, 1979
Assignee:
BASF Wyandotte Corporation
Inventors:
Pauls Davis, Herbert H. Gahmig, Irving R. Schmolka
Abstract: The production of .beta.-haloalkylaminosulfonyl halides by the reaction of an aziridine with a sulfuryl halide, and the new .beta.-haloalkylaminosulfonyl halides. The new compounds which can be prepared by the process of the invention are valuable starting materials for the manufacture of plant protection agents, dyes and pharmaceutical substances.
Abstract: An improved process for the manufacture of 2-methyl-2-hepten-6-one by reacting an alkyl acetoacetate with 2-methyl-3-buten-2-ol in the presence of an organic aluminum compound such as aluminum trialcoholate, aluminum triacetoacetate, aluminum alkylacetoacetate or aluminum triaryloxylate. 2-Methyl-2-hepten-6-one is an intermediate for the manufacture of vitamins.
Type:
Grant
Filed:
November 3, 1977
Date of Patent:
November 6, 1979
Assignee:
BASF Aktiengesellschaft
Inventors:
Heinrich Pasedach, Rudolf Mohr, Axel Nissen
Abstract: A process for welding membranes of fluorinated polymers which contain groups with exchangeable H-ions. To carry out the process, the polymer in at least one of the membranes to be welded together must be in the H-form.
Abstract: A new valuable fungicide based on N-tridecyl-2,6-dimethylmorpholine as the active ingredient, the said ingredient being in the form of microcapsules of which the wall consists of a polymer while the core contains the active ingredient.
Type:
Grant
Filed:
February 21, 1978
Date of Patent:
October 23, 1979
Assignee:
BASF Aktiengesellschaft
Inventors:
Karl Kuchner, Josef B. Pawliczek, Ernst-Heinrich Pommer, Dietrich Schlotterbeck, Wolfgang Sliwka, August Wigger
Abstract: Thermoplastic nylons are stabilized with copper compounds and synergistic halides by incorporation of from 0.1 to 10% of a concentrate of nylon, copper bromide or iodide and calcium bromide, zinc bromide or magnesium bromide. The stabilized nylons may be thermoplastically processed to give semimanufactures or films.
Type:
Grant
Filed:
September 14, 1977
Date of Patent:
October 23, 1979
Assignee:
BASF Aktiengsellschaft
Inventors:
Claus Cordes, Peter Horn, Hans-Peter Weiss, Herbert Gutsche
Abstract: Unsaturated polyester molding compositions which contain ethylenically unsaturated polyesters, copolymerizable ethylenically unsaturated monomeric compounds and a polyalkylene ether copolymer have improved shelf life, can be cured with little shrinkage and after curing give a smooth surface with high gloss.
Type:
Grant
Filed:
November 30, 1977
Date of Patent:
October 23, 1979
Assignee:
BASF Aktiengesellschaft
Inventors:
Richard Hoene, Anton Hesse, Kurt Demmler, Horst Lawonn
Abstract: Halobenzenes are manufactured by (a) a one-vessel reaction of anilines with halogenating agents to give haloanilines, followed by reaction of the mixture thus obtained with alkanols and nitrosylating agents in the presence of water and acid at not less than 35.degree. C. or (b) the corresponding reaction of a haloaniline which has been manufactured in the above manner or by some other method and has been isolated from its reaction mixture. The products are starting materials for the manufacture of drugs, dyes and pesticides.
Type:
Grant
Filed:
November 15, 1977
Date of Patent:
October 23, 1979
Assignee:
BASF Aktiengesellschaft
Inventors:
Horst Scheuermann, Ulrich Jersak, Helmut Gorth
Abstract: Benzaldehydes are reacted with cyanoacetaldehyde, for which reaction the cyanoacetaldehyde can be produced from isoxazole in a basic medium. The reaction gives .alpha.-cyanocinnamaldehydes, the hydrogenation of which gives the corresponding dihydrocinnamyl compounds, which can be converted to 2,4-diaminopyrimidines by reaction with guanidine, using various methods.
Abstract: A process for the manufacture of fire protection materials, in which an aqueous alkali metal silicate solution is dried to a water content of from 6 to 40% and the resulting powder is thermoplastically molded to form sheets, tapes or strips. These can be fitted into openings and passages of building units; in the event of a fire they eliminate water and form a stable, heat-insulating foam.
Type:
Grant
Filed:
July 13, 1977
Date of Patent:
October 23, 1979
Assignee:
BASF Aktiengesellschaft
Inventors:
Arndt C. Caesar, Ludwig Zuern, Rudi Weindel
Abstract: Cathodic electrocoating binders based on polycondensation products which contain amino groups and which are, at least partially, in the form of their ammonium salts or quaternary ammonium salts.The polycondensation products containing amino groups are obtained by adduct formation of p-hydroxyacetophenone with polymers containing epoxide groups, followed by reaction of these adducts with formaldehyde and a secondary amine.The electrocoating binders of the invention may be used for coating metallic substrates and give coatings which are particularly corrosion-resistant and adhere particularly firmly.
Abstract: New phosphoric acid derivatives, a process for their manufacture by reaction of cyclopropylmethyl halides with salts of phosphoric acid derivatives, and pesticides containing these new phosphoric acid derivatives as active ingredients.
Type:
Grant
Filed:
March 20, 1978
Date of Patent:
October 16, 1979
Assignee:
BASF Aktiengesellschaft
Inventors:
Hans Theobald, Heinrich Adolphi, Karl Eicken
Abstract: Process for the manufacture of .alpha.-naphthol by hydrolyzing .alpha.-naphthyl esters of aliphatic carboxylic acids in a distillation column by means of steam in counter-current at a particular temperature, and in a certain ratio, in the presence of organic sulfonic acids. The .alpha.-naphthol obtainable by the process of the invention is a valuable starting material for the manufacture of dyes, drugs and insecticides, e.g. .alpha.-naphthyl N-methylcarbamate.
Abstract: Process for the manufacture of .alpha.-naphthol by hydrolyzing .alpha.-naphthyl esters of aliphatic carboxylic acids in a distillation column by means of steam in counter-current at a particular temperature, and in a certain ratio, in the presence of naphtholsulfonic acids and/or sulfonic acids of naphthyl esters. The .alpha.-naphthol obtainable by the process of the invention is a valuable starting material for the manufacture of dyes, drugs and insecticides, e.g. .alpha.-naphthyl N-methylcarbamate.
Type:
Grant
Filed:
February 10, 1978
Date of Patent:
October 16, 1979
Assignee:
BASF Aktiengesellschaft
Inventors:
Ludwig Schuster, Eckhard Hickmann, Klaus Halbritter
Abstract: A process for the manufacture of butanedicarboxylic acid esters, wherein(a) an aqueous cobalt salt solution is treated, at from 50.degree. to 200.degree. C. and under a pressure of from 50 to 500 bars, with excess carbon monoxide and hydrogen in the presence of active charcoal laden with cobalt carbonyl,(b) the resulting aqueous solution of cobalt carbonyl hydride is extracted with butadiene or with a hydrocarbon mixture containing butadiene and the aqueous phase is separated off,(c) the butadiene, or butadiene-hydrocarbon mixture, containing cobalt carbonyl hydride, cobalt carbonyl and butenyl-cobalt tricarbonyl is reacted with carbon monoxide and an excess of an alkanol of 1 to 4 carbon atoms in the presence of from 0.5 to 2 moles, per mole of butadiene, of a tertiary nitrogen base having a pK.sub.a of from 3 to 11, at from 80.degree. to 150.degree. C.
Type:
Grant
Filed:
March 3, 1978
Date of Patent:
October 16, 1979
Assignee:
BASF Aktiengesellschaft
Inventors:
Rudolf Kummer, Heinz-Walter Schneider, Rolf Platz, Peter Magnussen, Franz-Josef Weiss
Abstract: A process for the manufacture of butanedicarboxylic acid esters, wherein(a) an aqueous cobalt salt solution is treated with carbon monoxide and hydrogen in the presence of active charcoal,(b) the resulting aqueous solution is extracted with butadiene or with a hydrocarbon mixture containing butadiene,(c) the butadiene, or butadiene/hydrocarbon mixture, containing cobalt carbonyl hydride, cobalt carbonyl and butenyl-cobalt tricarbonyl, is reacted with carbon monoxide and an excess of an alkanol of 1 to 4 carbon atoms in the presence of a tertiary nitrogen base,(d) the tertiary nitrogen bases contained in the resulting reaction mixture are removed from the latter to the extent of leaving from 0.1 to 0.
Type:
Grant
Filed:
September 8, 1978
Date of Patent:
October 2, 1979
Assignee:
BASF Aktiengesellschaft
Inventors:
Rudolf Kummer, Heinz-Walter Schneider, Franz-Josef Weiss
Abstract: A process for the continuous high pressure polymerization of ethylene in a polymerization system which comprises a polymerization zone (A), a high pressure product isolation zone (B), a throttling and control system (C), a low pressure product isolation zone (D), a second throttling and control system (E) and a discharge extruder (F), and wherein, according to the invention, the level of the ethylene polymer in the high pressure product isolation zone (B) and in the low pressure product isolation zone (D) is varied periodically. The process gives an ethylene polymer of improved homogeneity, which when used to manufacture films does not tend to form specks or fisheyes.
Abstract: A process for the manufacture of olefin polymers by polymerizing .alpha.-monoolefins at relatively low temperatures and relatively low olefin pressures by means of a catalyst obtained from a silicate carrier (component a), an aluminum compound (component b) and a chromium compound (component c). The catalyst is obtained by (1) in a first stage, initially (1.1) charging a particular silicate carrier (component a) with (1.2) a mixture of (1.2.1) an aluminum salt or a mixture of an aluminum salt with up to 80 mole%, based on the salt mixture, of a nickel-II salt (component b) and (1.2.2) a chromium compound (component c), this compound being chromium trioxide or a compound which is converted to chromium trioxide under the conditions of stage (2), by treatment with a solution of the mixture (1.2), and (2), in a second stage then maintaining the product, obtained from stage (1), for a certain time at a high temperature in an anhydrous oxygen-containing gas stream.
Type:
Grant
Filed:
April 28, 1978
Date of Patent:
October 2, 1979
Assignee:
BASF Aktiengesellschaft
Inventors:
Wolfgang Gruber, Hans Frielingsdorf, Robert Bachl, Guenther Schweier