Abstract: In a process for preparing acrylic acid, a reaction gas which comprises a gaseous formaldehyde source and gaseous acetic acid and in which the partial pressure of the formaldehyde source, calculated as formaldehyde equivalents, is at least 85 mbar and in which the molar ratio of the acetic acid to the formaldehyde source, calculated as formaldehyde equivalents, is at least 1 is contacted with a solid condensation catalyst. The space-time yield can be enhanced significantly by increasing the partial pressure of the reactants. The space-time yield remains high even after prolonged process duration.

Abstract: The present invention pertains to the field of diagnostics for gonadal toxicity and toxicological assessments for risk stratification of chemical compounds. Specifically, it relates to a method for diagnosing gonadal toxicity. It also relates to a method for determining whether a compound is capable of inducing such gonadal toxicity in a subject and to a method of identifying a drug for treating gonadal toxicity. Furthermore, the present invention relates to a device and a kit for diagnosing gonadal toxicity.

Abstract: Process for preparing a vinylidenecarboxylic acid or ester thereof, wherein a reaction gas comprising gaseous formaldehyde, molecular oxygen and an alkycarboxylic acid or ester thereof is brought into contact with a solid catalyst whose active composition comprises a vanadium-phosphorus oxide having an average oxidation state of vanadium of from +4.40 to +5.0 to give a product gas comprising the vinylidenecarboxylic acid or ester thereof.

Abstract: The invention relates to a process for preparing aromatic amines by hydrogenation of corresponding nitroaromatics by means of hydrogen, and also an apparatus suitable for this purpose. In particular, the invention relates to a process for preparing toluenediamine (TDA) by hydrogenation of dinitrotoluene (DNT).

Abstract: The present invention relates to associative polyurethane thickeners which comprise hyperbranched polymers in polymerized-in form, to the preparation of these thickeners, and to the use thereof, particularly in cosmetic preparations.

Abstract: The present invention relates to a process for subsequent surface modification of finely structured structures formed from hard inorganic materials, and to the structures obtainable by this process as such.

Abstract: Disclosed is an improved method for reducing the static sensitivity of a heat sensitive coating composition while not deteriorating the dynamic sensitivity, wherein N-(p-toluenesulphonyl)-N?-(3-p-toluenesulphonyl-oxy-phenyl)urea having an X-ray powder pattern having Bragg angles (2?/CuK?) of 10.3, 11.1, 13.0, 13.3, 15.6, 17.1, 18.1, 18.4, 19.6, 20.0, 20.8, 21.3, 23.1, 25.0, 25.5, 26.4, 26.8, 27.5, 29.1, 32.8 is used as a colour developer.

Abstract: The invention relates to a thermoplastic molding composition containing at least one polyester, a compound of the formula (I) a mixture of compounds of the formula (II) and optionally additional compounds and additives. The invention further relates to the use of the thermoplastic molding composition for the producing fibers, foils and moldings. The invention further relates to fibers, foils and moldings containing the thermoplastic molding composition.

Abstract: A herbicidal composition comprising a) at least one 3-phenyluracils of formula I wherein the variables R1 to R7 are as defined in the specification; and b) at least one 3-sulfonylisoxazoline of formula II wherein the variables R8 and R9 are as defined in the specification; and c) optionally at least one safener III selected from the group as defined in the specification.

Abstract: A composition comprising at least one expandable styrene polymer component and at least one cyclohexanecarboxylic ester and also optionally further components can be processed to mechanically robust foam materials.

Abstract: Use of thermoplastic molding compositions comprising, as essential components, A) a polyester, B) from 20 to 200 mmol/kg of polyester A) of at least one compound of the general formula (I) where respectively independently at any position -A1- is —NR—, —O—, —S—, —CH=A4- where R is H or C1-6-alkyl, A4 is N or CH A2 is COOX or OX, where X is Li, Na, K, Rb, Cs, Mg/2, Ca/2, Sr/2, Ba/2, Al/3 A3 is C1-6-alkyl, C6-12-aryl, O7-13-alkaryl, C7-13-aralkyl, O—C1-6-alkyl, O—C6-12-aryl, O—C7-13-alkaryl, O—C7-13-aralkyl, COOX?, OX?, SX?, SO3X?, where X? is H or X, S—C1-6-alkyl, S—C6-12-aryl, NR2, halogen, NO2, n is an integer from 1 to 4, and m is an integer from 0 to 4?n, where m=1, if A3=NO2, with the proviso that the number of mmol is based on the group(s) COOX and OX and SX? where X??X, to the extent that these are present in the compound of the general formula (I), and also moreover C) from 0 to 230% by weight of further added substances, based on the weight of component A), for producing laser-transparent m

Abstract: The present invention relates to a method of supplementing the catalyst in continuous hydroformylation during ongoing operation.

Abstract: The present invention relates to a process for preparing 4-isopropylcyclohexylmethanol (IPCHM) from para-cymene. The process for preparing 4-isopropylcyclohexylmethanol (IPCHM) comprises an electrochemical process for preparing a mixture of 4-isopropylbenzaldehyde dimethyl acetal and 4-(1-alkoxy-1-methylethyl)benzaldehyde dimethyl acetal, and intermediates passed through in the process, a hydrolysis step to form the corresponding benzaldehydes and a hydrogenation of this mixture to form 4-isopropylcyclohexylmethanol (IPCHM).

Abstract: The invention relates to an aqueous solution of acrylic acid polymers, obtainable by polymerization of acrylic acid in feed mode with peroxodisulfate as initiator in the presence of hypophosphite in water as solvent, wherein (i) water and optionally one or more ethylenically unsaturated comonomers are initially charged, and (ii) acrylic acid in acidic, unneutralized form, optionally one or more ethylenically unsaturated comonomers, aqueous peroxodisulfate solution and aqueous hypophosphite solution are added continuously, and (iii) a base is added on completion of the acrylic acid feed to the aqueous solution, wherein the comonomer content does not exceed 30% by weight, based on total monomer content.

Abstract: The present patent application describes a method of regenerating a ruthenium catalyst for the hydrogenation of benzene, which comprises flushing the catalyst with inert gas in a regeneration step until the original activity or part of the original activity has been attained.

Abstract: A process for producing rigid polyurethane foams, in which a mixture of one or more high-functionality polyether alcohols having functionalities of from 3.5 to 5.5 and a hydroxyl number of from 350 to 550 mg KOH/g, one or more polyether alcohols based on aliphatic and/or aromatic amines and having functionalities of from 3 to 4 and a hydroxyl number of from 150 to 800 mg KOH/g, an OH-comprising fatty acid ester and, if appropriate, one or more low molecular weight chain extenders and/or crosslinkers having functionalities of from 2 to 3 and a molecular weight Mw of <400 g/mol is used as polyol component, is described. The rigid polyurethane foams obtained have a good surface quality.

Abstract: The present invention relates to quick-drying two-component polyurethane coating compositions, to processes for preparing them, and to their use.

Abstract: Copolymer compositions and methods for making these compositions are described. The copolymers include a vinyl aromatic monomer; a second monomer, and a biobased monomer. The second monomer is selected from the group consisting of butadiene, alkyl acrylates, alkyl methacrylates, and mixtures thereof. Examples of biobased monomers useful in the compositions include isobornyl acrylate, isobornyl methacrylate, tetrahydrofurfuryl acrylate, tetrahydrofurfuryl methacrylate, lauryl acrylate, lauryl methacrylate, and mixtures thereof. The compositions described herein can be used for binder or coating compositions and can include coating pigments, mineral fillers, and other additives.

Abstract: The invention relates to a process for producing a water-absorbing material by coating water-absorbing polymer particles with a film-forming polyurethane and silica, heat treating the coated particles and coating the heat-treated particles with pyrogenic hydrophilic silica. The invention further relates to the water-absorbing material obtainable according to the process of the invention. The water-absorbing material has improved wicking ability (FHA) and core shell saline flow conductivity (CS-SFC).

Abstract: The present invention provides aqueous dispersions comprising a pigment (B) at least partially enveloped by polyurethane (A) and further comprising at least one polymerization inhibitor (C), said polyurethane (A) being obtainable by reaction of (a) 15% to 70% by weight of di- or polyisocyanate comprising on average from 1 to 10 allophanate groups and on average from 1 to 10 C—C double bonds per molecule, and optionally (b) 0% to 60% by weight of further di- or polyisocyanate, with (c) 5% to 50% by weight of compound having at least two isocyanate-reactive groups, weight % ages being based on total polyurethane (A).