Abstract: Polymeric compositions obtainable by free-radical polymerization of at least two different alkyl (meth)acrylates in the presence of at least one ethylene-vinyl ester copolymer, the alkyl (meth)acrylates used being a mixture comprising alkyl (meth)acrylates having linear C12- to C60-alkyl radicals and different alkyl (meth)acrylates having linear C1- to C11-alkyl radicals and/or branched C4- to C60-alkyl radicals and/or cyclic C5- to C20-alkyl radicals. The use of such polymeric compositions as pour point depressants for crude oils, mineral oils or mineral oil products.
Type:
Application
Filed:
December 17, 2013
Publication date:
June 19, 2014
Applicant:
BASF SE
Inventors:
Ivette Garcia Castro, Kai Gumlich, Stefan Frenzel, Maria Heuken, Rouven Konrad, Karin Neubecker
Abstract: The present invention relates to aqueous multistage polymer dispersions obtainable by free-radically initiated aqueous emulsion polymerization, having a soft phase and a hard phase, and a hard-to-soft stage ratio of 25% to 95% by weight to 75% to 5% by weight, the glass transition temperature (Tg) of the soft phase, as first stage, being ?30 to 0° C. and that of the hard phase, as second stage, being 20 to 60° C., comprising at least one monomer of the general formula I in which the variables have the following definitions: n=0 to 2, R1, R2, R3=independently of one another hydrogen or methyl group, X=O or NH, Y=H, alkali metal or NH4, to processes for preparing these aqueous polymer dispersions, and to the use thereof as binders in coatings, and also to coatings comprising the polymer dispersion of the invention.
Type:
Grant
Filed:
December 21, 2011
Date of Patent:
June 17, 2014
Assignee:
BASF SE
Inventors:
Sebastian Roller, Ekkehard Jahns, Hans-Juergen Denu
Abstract: The present invention relates to benzoxazinones of the general formula (I) wherein the variables are defined according to the description, processes and intermediates for preparing the benzoxazinones of the formula (I), compositions comprising them and their use as herbicides, i.e. for controlling harmful plants, and also a method for controlling unwanted vegetation which comprises allowing a herbicidal effective amount of at least one benzoxazinones of the formula (I) to act on plants, their seed and/or their habitat.
Type:
Grant
Filed:
June 11, 2010
Date of Patent:
June 17, 2014
Assignee:
BASF SE
Inventors:
Matthias Witschel, Trevor William Newton, Thomas Seitz, Helmut Walter, Bernd Sievernich, Anja Simon, Ricarda Niggeweg, Klaus Groβmann, Liliana Parra Rapado, Richard Roger Evans
Abstract: A process for producing granules containing one or more complexing agent salts of the general formula from an aqueous starting solution, containing the one or more complexing agent salts in a concentration of from 10 to 80% by weight, based on the total weight of the aqueous starting solution, in a jet apparatus.
Type:
Grant
Filed:
September 23, 2011
Date of Patent:
June 17, 2014
Assignee:
BASF SE
Inventors:
Stefan Blei, Michael Schoenherr, Franz Weber, Francois Becker
Abstract: Pigment compositions containing organic pigments with an outstanding migration-free property and an excellent rheology at high concentration, and derivatives thereof containing heterocyclic substituents. The pigment compositions contains (a) carbon black or an organic pigment containing a chromophore Q1 of the following formula, wherein Z1 and Z2 are O or N—, C· is a carbon atom with an electron in a p orbital, and n is an integer from 1 to 4; and (b) a compound containing a chromophore of the following formula (II), wherein Q2 is an m-valent residue of carbon black or of the chromophore Q1; G1 is preferably and R1, R2, R3, R4, R5, R6, and R8 are preferably all H; m is an integer from 1 to 4. The pigment compositions can be used as rheology modifiers, preferably for pigmented coating compositions.
Type:
Grant
Filed:
June 15, 2010
Date of Patent:
June 17, 2014
Assignee:
BASF SE
Inventors:
Céline Vairon, Marc Maurer, Ulrich Veith, Sascha Gysin
Abstract: The invention according to the present invention relates to the manufacture of paper and or boards and/or binding agents and a method and apparatus related to the same by providing for the defibrillation of cellulose fibers into a form in which the same can be subsequently sued to form the finished product directly or can be used to bind other materials together and then be formed into the finished product. The apparatus includes a twin screw conveyor through the material and liquid passes to be processed.
Type:
Grant
Filed:
November 5, 2010
Date of Patent:
June 17, 2014
Assignee:
BASF SE
Inventors:
Trevor W. R. Dean, Karnik Tarverdi, Robert Bramsteidl, Luca Achilli
Abstract: The present invention relates to an ethoxylated polyethylenimine polymer comprising (1) a polyethyleneimine backbone, (2) a polyoxyethylene chain wherein the polyoxyethylene chain has an average of 40 to 90 ethyleneoxide units per unit of NH in the polyethyleneimine backbone, (3) a quaternization degree of from 1% to less than 50%.
Type:
Grant
Filed:
May 9, 2013
Date of Patent:
June 17, 2014
Assignee:
BASF SE
Inventors:
Rainer Dobrawa, Sophia Ebert, Stefano Scialla, Frank Hulskotter, Gloria Di Capua, Patrick Delplancke, Marc Evers
Abstract: The present invention relates to a process for the continuous production of polymer mixtures comprising: a) from 10 to 80% by weight of a biodegradable polyester (Q) composed of aliphatic or aliphatic and aromatic dicarboxylic acids and of aliphatic dihydroxy compounds, and b) from 20 to 90% by weight of one or more polymers (T) selected from the group consisting of: polylactic acid, polycaprolactone, polypropylene carbonate, polyglycolide, aliphatic polyester, cellulose acetate, and polyhydroxyalkanoate, where i) a mixture composed of the aliphatic dihydroxy compounds, of the aliphatic and aromatic dicarboxylic acids and, if appropriate, of further comonomers (component C) is mixed, without addition of any catalyst, to give a paste or, as an alternative, the liquid esters of the dicarboxylic acids are fed into the system, as also are the dihydroxy compound and, if appropriate, further comonomers, without addition of any catalyst, and in a first stage this mixture, together with the entire amount or with a
Type:
Grant
Filed:
October 12, 2010
Date of Patent:
June 17, 2014
Assignee:
BASF SE
Inventors:
Robert Loos, Uwe Witt, Motonori Yamamoto, Günther Mair, Andreas Garbe
Abstract: The present invention relates to powder compositions whose particles comprise at least one inorganic pigment, wherein at least one biodegradable polyester polymer and/or polyalkylene carbonate polymer is arranged on the pigment surface, a process for producing these powder compositions and use thereof in the production of paper, card and board.
Abstract: A synergistic herbicidal mixture comprising A) picolinafen; or one of its environmentally compatible salts; and B) a synergistically effective amount of at least a sulfonylurea of formula II wherein the variables A, B, X and R1 to R3 have the meanings given in the specification; and, if desired, C) at least a safener. Compositions comprising these mixtures, processes for the preparation of these compositions and their use for controlling undesired plants.
Type:
Grant
Filed:
August 2, 2012
Date of Patent:
June 17, 2014
Assignee:
BASF Aktiengesellschaft
Inventors:
Cyrill Zagar, Adam F. Burnhams, Peter Dombo, Andreas Landes, Bernd Sievernich, Herve R. Vantieghem
Abstract: The invention relates to a process for the production of paper, card and board, including the steps of draining a filler-containing paper stock, having a certain fibrous concentration and containing at least one water-soluble amphoteric copolymer, with sheet formation in a wire section, then pressing the paper in a press section, diluting the paper stock to a fibrous concentration in the range from 5 to 15 g/l, draining the diluted paper stock to form a sheet, and then pressing the sheet in the press section to a solids content G(x) wt % or greater, such that G(x) computes according to: G(x)=48+(x?15)·0.4, where x is the numerical value of a filler content of the dry paper, card or board (in wt %), and G(x) is a numerical value of the minimal solids content (in wt %) to which the sheet is pressed.
Abstract: A process for mineral oil production, in which an aqueous formulation comprising at least one water-soluble, hydrophobically associating copolymer (A) and at least one nonionic and/or anionic surfactant (B) is injected through at least one injection borehole into a mineral oil deposit, and crude oil is withdrawn from the deposit through at least one production borehole, wherein the water-soluble, hydrophobically associating copolymer comprises at least acrylamide or derivatives thereof, a monomer having anionic groups and a monomer which can bring about the association of the copolymer, and aqueous formulation, which is suitable for execution of the process.
Type:
Grant
Filed:
November 23, 2011
Date of Patent:
June 17, 2014
Assignee:
BASF SE
Inventors:
Roland Reichenbach-Klinke, Björn Langlotz
Abstract: The present invention relates to a novel method of in vitro assay of the molecules of the extracellular matrix synthesized by cells in culture and uses thereof in the form of a kit for in vitro measurement and/or for a method of screening of cosmetic and/or pharmaceutical ingredients.
Type:
Application
Filed:
June 18, 2012
Publication date:
June 12, 2014
Applicant:
BASF Beauty Care Solutions France S.A.S.
Abstract: The present invention relates to N-thio-anthranilamide compounds and the stereoisomers, salts, tautomers and N-oxides thereof and to compositions comprising the same. The invention also relates to the use of the N-thio-anthranilamide compounds or of the compositions comprising such compounds for combating invertebrate pests. Furthermore, the invention relates to methods of applying such compounds.
Type:
Application
Filed:
August 10, 2012
Publication date:
June 12, 2014
Applicant:
BASF SE
Inventors:
Prashant Deshmukh, Karsten Körber, Joachim Dickhaut, Henricus Maria Martinus Bastiaans, Markus Kordes, Florian Kaiser, Arun Narine, Nina Gertrud Bandur, Gemma Veitch, Deborah L. Culbertson, Paul Neese, Koshi Gunjima
Abstract: The present invention relates to a process for preparing an N-substituted 1H-pyrazole-5-carbonylchloride compound of the formula (I) in which R1 is hydrogen, halogen, cyano, C1-C6-alkyl, C1-C6-fluoroalkyl, C3-C8-cycloalkyl, C3-C8-fluorocycloalkyl, C2-C6-alkenyl, C2-C6-fluoroalkenyl, C1-C6-alkoxy, C1-C6-fluoroalkoxy, C1-C4-fluoroalkoxy-C1-C4-alkyl, phenyl and the like; each R2 is independently selected from halogen, C1-C6-alkyl, C1-C6-fluoroalkyl, C3-C8-cycloalkyl, C3-C8-fluorocycloalkyl, C2-C6-alkenyl, C2-C6-fluoroalkenyl, C1-C6-alkoxy, phenyl and the like; r is 0, 1, 2, 3 or 4; comprising the steps of i) deprotonating a compound of the formula (II) in which the variables R1, R2 and r are each as defined above, with a base selected from lithium-organic base having a carbon or nitrogen bound lithium or with a magnesium-organic base having a carbon bound magnesium; and ii) subjecting the product obtained in step (i) to a chlorocarbonylation by reacting it with a reagent selected from the group c
Type:
Application
Filed:
August 10, 2012
Publication date:
June 12, 2014
Applicant:
BASF SE
Inventors:
Karsten Körber, Prashant Deshmukh, Florian Kaiser, Michael Rack, Timo Frassetto, Gemma Veitch, Markus Kordes
Abstract: The invention relates to a process for the oxidative dehydrogenation of n-butenes to butadiene, which comprises at least two production steps (i) and at least one regeneration step (ii), in which (i) in one production step, a starting gas mixture comprising n-butenes is mixed with an oxygen-comprising gas and brought into contact with a multimetal oxide catalyst which comprises at least molybdenum and a further metal and is arranged in a fixed catalyst bed in a fixed-bed reactor, and (ii) in a regeneration step, the multimetal oxide catalyst is regenerated by passing an oxygen-comprising regeneration gas mixture over the fixed catalyst bed and burning off the carbon deposited on the catalyst, where a regeneration step (ii) is carried out between two production steps (i), wherein the at least two production steps (i) are carried out at a temperature of at least 350° C. and the at least one regeneration step (ii) is carried out at a temperature which is not more than 50° C.
Type:
Application
Filed:
December 5, 2013
Publication date:
June 12, 2014
Applicant:
BASF SE
Inventors:
Philipp Grüne, Wolfgang Rüttinger, Christian Walsdorff
Abstract: Disclosed are compounds of formula (1) or formula (2). The compounds are useful for the dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, and preferably hair, more preferably human hair. (1) (2).
Type:
Application
Filed:
May 2, 2012
Publication date:
June 12, 2014
Applicant:
BASF SE
Inventors:
Sophie Marquais-Bienewald, Christian Cremer, Beate Frohling
Abstract: In a method of preparing polyalkyleneimines from alkyleneimines in the presence of a liquid solvent, and a catalyst, the preparing is effected semi-discontinuously in one reaction container. The preparing is optionally effected in the presence of further additives. Polyalkyleneimines obtained by such methods and formulations thereof likewise form part of the subject matter of the invention, especially those having a low proportion of chloride-containing compounds. Such polyalkyleneimines have uses in the field of medical technology, printing media, wastewater treatment, surface treatment, cosmetics, laundry detergents, biotechnology, packaging, electronics, paper, building construction chemistry, textiles, chromatography, ion exchangers, oil industry, ceramics, glass, membrane technology, catalysts, electroplating, biocides or wood protection.
Type:
Application
Filed:
December 9, 2013
Publication date:
June 12, 2014
Applicant:
BASF SE
Inventors:
Stephan HUEFFER, Andreas KRAMER, Frank DIETSCHE
Abstract: The invention relates to a catalyst which comprises a catalytically active multimetal oxide which comprises molybdenum and at least one further metal has the general formula (I) Mo12BiaMnbCocFedX1eX2fOx??(I), where the variables have the following meanings: X1=Si and/or Al; X2=Li, Na, K, Cs and/or Rb; a=0.2 to 1; b=0 to 2; c=2 to 10; d=0.5 to 10; e=0 to 10; f=0 to 0.5; and x=is a number determined by the valence and abundance of the elements other than oxygen in (I).
Type:
Application
Filed:
December 5, 2013
Publication date:
June 12, 2014
Applicant:
BASF SE
Inventors:
Wolfgang Rüttinger, Christian Walsdorff, Philipp Grüne
Abstract: The present invention relates to a continuous process for preparing racemic or optically active menthol in pure or enriched form by distillatively separating menthol from substance mixtures which comprise essentially menthol and diastereomers thereof. This distillative separation is performed in a dividing wall column with 50 to 300 theoretical plates and one or more side draw points at an absolute operating pressure of 5 to 500 mbar.