Abstract: The present invention relates to a particularly economic overall method for producing menthol, specifically for producing optically active, essentially enantiomerically and diastereomerically pure L-menthol and racemic menthol, starting from the starting material citral which is available inexpensively on an industrial scale. The method comprises the following steps a.1) catalytic hydrogenation of neral and/or geranial to give citronellal, b.1) cyclization of citronellal to isopulegol in the presence of an acidic catalyst, c.1) purification of isopulegol by crystallization and d.1) catalytic hydrogenation of isopulegol to give menthol.
Type:
Application
Filed:
October 23, 2012
Publication date:
February 21, 2013
Applicant:
BASF SE
Inventors:
Gunnar Heydrich, Gabriele Gralla, Matthias Rauls, Joachim Schmidt-Leithoff, Klaus Ebel, Wolfgang Krause, Steffen Oehlenschläger, Christoph Jäkel, Marko Friedrich, Eike Johannes Bergner, Nawid Kashani-Shirazi, Rocco Paciello
Abstract: A process for preparing polyaryl ethers in which a polycondensation of the monomer building blocks is carried out using microwave irradiation leads to thermoplastic molding compositions having improved color properties.
Type:
Grant
Filed:
November 11, 2008
Date of Patent:
February 19, 2013
Assignee:
BASF SE
Inventors:
Martin Weber, Volker Warzelhan, Faissal-Ali El-Toufaili, Andreas Greiner, Heiner Stange, Seema Agrarwal
Abstract: A coating composition comprises a first copolymer and a second copolymer. The first copolymer has at least one linear polymer strand having a weight average molecular weight of at least 1,500 Daltons and functionality X with an equivalent weight of no more than 500. The second copolymer has at least one linear polymer strand having a weight average molecular weight of at least 1,500 Daltons and functionality X? with an equivalent weight of no more than 1,500. The coating composition is free of gloss flattening agents, yet still produces a cured film having a low gloss of less than 70 gloss units at an angle of incidence of 60°, as measured according to ASTM D 2457.
Type:
Grant
Filed:
August 10, 2011
Date of Patent:
February 19, 2013
Assignee:
BASF Corporation
Inventors:
William H. Merritt, Nicholas Caiozzo, Sergio Balatan, Walter H. Ohrbom, Gregory G. Menovcik
Abstract: The present invention relates to the use of sterically hindered amines comprising one or more groups of the general formula (I) to stabilize inanimate organic material, more particularly plastics or coating materials, where R1 and R2 each independently, alike or different, are H, C1-C20 alkyl, C3-C15 cycloalkyl, aryl, hetaryl or a heterocycle, R4, R5, R6, and R7 each independently, alike or different, are C1-C20 alkyl, or R4 and R6 or R5 and R7 together are a tetramethylene or pentamethylene group, and R3 is aryl or hetaryl. The invention further relates to methods of stabilizing inanimate organic material, especially plastics or coating materials. Additionally provided by the invention are selected sterically hindered amines comprising one or more groups of the general formula (I). Additionally provided by the invention are materials that comprise selected sterically hindered amines.
Type:
Grant
Filed:
August 14, 2009
Date of Patent:
February 19, 2013
Assignee:
BASF SE
Inventors:
Alban Glaser, Sylke Haremza, Simon Schambony
Abstract: The present invention relates to a process for separating at least one first material from a mixture comprising this at least one first material in an amount of from 0.001 to 1.
Abstract: The present invention relates to an agglomerate of at least one particle P which is hydrophobicized on the surface with at least one first surface-active substance and at least one magnetic particle MP which is hydrophobicized on the surface with at least one second surface-active substance, a process for producing it and also the use of these agglomerates.
Type:
Grant
Filed:
March 3, 2010
Date of Patent:
February 19, 2013
Assignees:
BASF SE, Siemens Aktiengesellschaft
Inventors:
Imme Domke, Hartmut Hibst, Alexej Michailovski, Norbert Mronga, Werner Hartmann, Wolfgang Krieglstein, Vladimir Danov
Abstract: The present invention relates to a process of the invention for separating at least one first material from a mixture comprising this at least one first material and at least one second material, which comprises the steps: (A) Contacting of at least one magnetic particle and at least one bifunctional molecule or an adduct of the two with the mixture comprising the at least one first material and at least one second material so that an adduct is formed from the at least one magnetic particle, the bifunctional compound of the general formula (I) and the at least one first material, (B) suspension of the adduct obtained in step (A) in a suitable suspension medium, (C) separation of the adduct present in the suspension from step (B) from the suspension by application of a magnetic field, (D) if appropriate, dissociation of the adduct separated off in step (C) in order to obtain the at least one first material. a corresponding adduct and the use of such an adduct for the separation of mixtures of materials.
Abstract: Provided herein are isolated laccase enzymes and nucleic acids encoding them. Also provided are mediators for laccase reactions. Also provided herein are methods for using laccases to oxidize lignins and other phenolic and aromatic compounds, such as for bio-bleaching and decolorization of wood pulp under high temperature and pH conditions to facilitate a substantial reduction in use of bleaching chemicals, as well as for treatment of fibers.
Type:
Grant
Filed:
August 31, 2007
Date of Patent:
February 19, 2013
Assignees:
Verenium Corporation, BASF SE
Inventors:
Janne S. Kerovuo, Sylke Haremza, Oliver Koch, Tilo Habicher, Dan Robertson, Grace DeSantis, Ryan McCann, Peter Luginbühl
Abstract: Metal complexes comprising at least one polycyclic aromatic ligand which is bonded to the central metal via two nitrogen atoms, an organic light-emitting diode comprising at least one inventive metal complex, a light-emitting layer comprising at least one inventive metal complex, an organic light-emitting diode comprising at least one inventive light-emitting layer, the use of the at least one inventive metal complex in organic light-emitting diodes, and a device selected from the group consisting of stationary visual display units such as visual display units of computers, televisions, visual display units in printers, kitchen appliances and advertising panels, illuminations, information panels and mobile visual display units such as visual display units in cellphones, laptops, digital cameras, vehicles, and destination displays on buses and trains, comprising at least one inventive organic light-emitting diode.
Type:
Grant
Filed:
June 9, 2009
Date of Patent:
February 19, 2013
Assignee:
BASF SE
Inventors:
Oliver Molt, Christian Lennartz, Evelyn Fuchs, Korinna Dormann, Nicolle Langer, Christian Schildknecht, Jens Rudolph, Gerhard Wagenblast, Soichi Watanabe
Abstract: The present invention relates to new high-functionality, highly branched or hyperbranched polylysines, to processes for preparing them, and to their use.
Type:
Grant
Filed:
May 6, 2010
Date of Patent:
February 19, 2013
Assignee:
BASF Aktiengesellschaft
Inventors:
Bernd Bruchmann, Harm-Anton Klok, Markus Thomas Scholl
Abstract: The use of polycyclic phenolic compounds which have up to 20 benzene rings per molecule and are obtainable by reacting a tetrahydrobenzoxazine I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals with one or more of the same or different phenols II where R7, R8, R9 and R10 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and/or with one or more of the same or different tetrahydrobenzoxazines I, with the proviso that at least one of the substituents has from 13 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, have in each case from 1 to 20 carbon atoms as stabilizers for stabilizing inanimate organic material against the action of light, oxygen and heat.
Type:
Grant
Filed:
January 28, 2011
Date of Patent:
February 19, 2013
Assignee:
BASF SE
Inventors:
Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
Abstract: Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitriles and conjugated dienes which form a ? complex with M1; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ?1; o is the number of ligands K, where o can be 0 or ?1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific tr
Type:
Grant
Filed:
October 14, 2010
Date of Patent:
February 19, 2013
Assignee:
BASF SE
Inventors:
Markus Bold, Christian Lennartz, Martina Prinz, Hans-Werner Schmidt, Mukundan Thelakkat, Markus Baete, Christian Neuber, Wolfgang Kowalsky, Christian Schildknecht, Hans-Hermann Johannes
Abstract: A non-cytotoxic chlorine dioxide composition and a mixed agent bleaching composition for tooth whitening are disclosed. Methods of use are also provided.
Type:
Grant
Filed:
July 14, 2009
Date of Patent:
February 19, 2013
Assignee:
BASF Corporation
Inventors:
Barry Keven Speronello, Frank S. Castellana, Linda Hratko
Abstract: This invention encompasses novel amphiphilic block copolymers comprising polysiloxane blocks and polycationic blocks. The polycationic blocks are formed from diallyldialkylammonium derivatives. The formed block copolymers are particularly useful for treating or conditioning keratinous substances such as hair or skin.
Type:
Grant
Filed:
July 2, 2010
Date of Patent:
February 19, 2013
Assignee:
BASF SE
Inventors:
Balint Koroskenyi, Manuel Gamez-Garcia, Jianwen Mao
Abstract: Processes for obtaining aromatic hydrocarbons from a hydrocarbon mixture a1. Mixture a1 is extractively distilled with extractive solvent a2 producing mixture bl comprising solvent a2, aromatic hydrocarbons and high boilers, and nonaromatic hydrocarbon mixture b2. Mixture b1 is distilled to aromatic hydrocarbon c1 and solvent comprising high boilers c2. Substream dl is removed from c2 and c2 is recycled to extractive distillation. Substream d1 is extracted with water producing aqueous phase e1 and organic phase e2. Aqueous phase e1 is distilled and purified solvent a2 is recovered and recycled into extractive distillation of mixture b1. Substream e2? is removed from organic phase e2 and recycled into extractive distillation of mixture b1. The amount of organic phase e2? is such that when d1 comprising solvent, high boilers, water and circulated stream e2? is dispersed, aqueous extract phase e1, forms a disperse phase and organic phase e2 a continuous phase.
Abstract: A process for preparing polyoxymethylene homopolymers or copolymers (7) by homopolymerization or copolymerization of trioxane, starting from methanol (1), in which methanol (1) is oxidized in a first reactor in a first production plant (A) to give an aqueous formaldehyde-comprising stream (2) which is fed to a second production plant (B) in which pure trioxane (6) is obtained and removal of low boilers (5) by distillation is carried out and the pure trioxane (6) is fed to a third production plant (C) in which it is homopolymerized or copolymerized to form polyoxymethylene homopolymers or copolymers (7), wherein the low boiler stream (5) from the low boiler removal column (K 2) is recycled to the feed stream into the first reactor in the first production plant (A), is proposed.
Type:
Grant
Filed:
December 11, 2008
Date of Patent:
February 19, 2013
Assignee:
BASF SE
Inventors:
Markus Siegert, Tobias Kortekamp, Eckhard Stroefer, Christoph Sigwart, Neven Lang
Abstract: A polymer mixture in solid or aqueous form includes a content of from 5 to 95% by weight of a first polymer and a content of from 5 to 95% by weight of a second polymer. The first polymer is a water-soluble or water-dispersible polymer having a weight-average molecular weight of 1000 to 20 000 g/mol. The second polymer is a water-soluble or water-dispersible polymer having a weight-average molecular weight of 1000 to 50 000 g/mol. The polymer mixture can inhibit precipitation and sedimentation of calcium salts and magnesium salts in water-bearing systems.
Type:
Application
Filed:
August 8, 2012
Publication date:
February 14, 2013
Applicant:
BASF SE
Inventors:
Jürgen DETERING, Torben Gädt, Stephan Nied, Andreas Kempter, Bolette Urtel, Jessica Neumann
Abstract: The present invention provides saflufenacil-tolerant plants. The present invention also provides methods for controlling the growth of weeds by applying saflufenacil to which the saflufenacil-tolerant plants of the invention are tolerant. Plants of the invention express a cytochrome P450 polypeptide, the expression of which confers, to the plants, tolerance to the saflufenacil.