Abstract: The invention relates to a method for separating by distillation a portion or the entirety of an azeptine derivative (III), which is selected from the group consisting of aminohexylidene imine, tetrahydroazepine, hexylhexahydroazepine and of aminohexylhexahydroazepine, out of a mixture (II) containing an azepine derivative (III) and an amine (I). The inventive method is characterized in that the distillation is carried out with a maximum bottom temperature of 150° C.
Abstract: The invention relates to a process for the preparation of an alkali metal catalyst by mixing an alkali metal with pulverulent, solid potassium carbonate as support, wherein the potassium carbonate has a specific surface area of at least 0.3 m2/g, and to the use thereof for the side-chain alkylation of alkylbenzenes.
Abstract: Expression vectors and yeast cells that contain a heterologous G protein-coupled receptor gene and a gene mutation that causes increased sensitivity to receptor activation or a gene mutation that permits transcriptional activation of pheromone-responsive genes without cell cycle arrest. Methods of making the yeast cells.
Type:
Grant
Filed:
November 25, 2002
Date of Patent:
December 12, 2006
Assignee:
BASF Aktiengesellschaft
Inventors:
Mark Henry Pausch, Bradley Alton Ozenberger, John Richard Hadcock, Laura Alicia Price, Eileen Marie Kajkowski, Donald Richard Kirsch, Deborah Tardy Chaleff
Abstract: Process for the preparation of ethylenamines, in particular diethylenetriamine (DETA), by continuous reaction of ethylenediamine (EDA) in the presence of a heterogeneous catalyst, where the reaction is carried out in a reaction column.
Type:
Application
Filed:
July 15, 2004
Publication date:
December 7, 2006
Applicant:
BASF Aktiengesellschaft
Inventors:
Matthias Frauenkron, Thomas Krug, Holger Evers, Johann-Peter Melder, Roderich Rottger, Markus Siegert, Till Gerlach, Jan Nouwen, Ellen Dahlhoff, Christian Miller
Abstract: Catalyst systems for preparing phthalic anhydride by means of gas-phase oxidation of o-xylene and/or naphthalene, and a process for preparing phthalic anhydride using the catalyst systems.
Type:
Application
Filed:
May 15, 2004
Publication date:
December 7, 2006
Applicant:
BASF AKTIENGESELLSCHAFT
Inventors:
Sebastian Storck, Jurgen Zuhike, Samuel Neto, Frank Rosowski
Abstract: Process for purifying and cooling a gas stream comprising a dialkyl ester A) of an aromatic dicarboxylic acid, which comprises treating the gas stream with an aliphatic dihydroxy compound B) at above the melting point of the dialkyl ester A) in a 1st stage and treating the gas stream with an aliphatic dihydroxy compound B) at above the melting point of the dihydroxy compound B) in at least one 2nd stage.
Type:
Application
Filed:
April 7, 2004
Publication date:
December 7, 2006
Applicant:
BASF AKTIENGESELLSCHAFT
Inventors:
Manfred Heckmann, Karl Holemann, Jan-Martin Loning, Thomas Heitz
Abstract: Emulsifier-free antifoams are obtainable by mixing a) from 80 to 99% by weight of at least one finely divided, virtually water-insoluble, inert solid with b) from 1 to 20% by weight of at least one hydrophobic, organic compound which has an antifoam action and is solid at room temperature in the absence of a solvent in a shear gradient such that the particle size of the compounds (b) which have an antifoam action is reduced to a mean particle size of from 0.5 to 15 ?m, emulsifier-free oil-in-water dispersions of mixtures of (a) and (b) are prepared by mixing the component (a) in an amount of from 80 to 99% by weight with the compounds of component (b) in an amount of from 1 to 20% by weight in the absence of emulsifiers in an extruder or kneader in a manner such that the mean particle size of the component (b) in the mixture is brought to 0.5 to 15 ?m, at up to 100° C.
Type:
Application
Filed:
August 27, 2004
Publication date:
December 7, 2006
Applicant:
BASF Aktiengesellschaft
Inventors:
Rainer Dyllick-Brenzinger, Markus Schmid, Jorg Wehrle, Klaus Lorenz, Stefan Bruhns, Michael Senge
Abstract: A synergistic herbicidal mixture comprising A) picolinafen; or one of its environmentally compatible salts; and B) a synergistically effective amount of at least a sulfonylurea of formula II, wherein the variables A, B, X and R1 to R3 have the meanings given in the specification; and, if desired, C) at least a safener. Compositions comprising these mixtures, processes for the preparation of these compositions and their use for controlling undesired plants.
Type:
Application
Filed:
March 12, 2004
Publication date:
December 7, 2006
Applicant:
BASF AKTIENGESELLSCHAFT
Inventors:
Cyrill Zagar, Adam Burnhams, Peter Dombo, Andreas Landes, Bernd Sievernich, Herve Vantieghem
Abstract: Process for working up a bottom stream comprising high boilers and ionic liquid from an extractive rectification in which the ionic liquid is used as entrainer, which comprises feeding the bottom stream to an evaporation stage which is operated at a pressure of less than 500 mbar or to a stripper which is operated by means of inert gas or steam, and the major part of the high boiler present is separated off in vapor form from the ionic liquid.
Type:
Application
Filed:
July 15, 2004
Publication date:
December 7, 2006
Applicant:
BASF Aktiengesellschaft
Inventors:
York Beste, Hartmut Shoenmakers, Wolfgang Arlt, Matthias Seiler, Carsten Jork
Abstract: Tert-alkylphenoxy-substituted polycyclic compounds of the general formula I where P is a conjugated polycyclic radical which is stable to bases and nucleophiles, optionally bears aryl substituents and contains no group from the group consisting of —CO—NH—CO—, —COOH and —CO—O—CO—; R is C1–C8-alkyl, whose carbon chain may be interrupted by one or more groups selected from the group consisting of —O—, —S—, —NR1—, —CO— and/or —SO2— and which may be monosubstituted or polysubstituted by C1–C6-alkoxy or by a 5- to 7-membered heterocyclic radical which is attached via a nitrogen atom and may contain further heteroatoms and be aromatic; C5–C8-cycloalkyl whose carbon chain may be interrupted by one or more groups selected from the group consisting of —O—, —S—, —NR1—, —CO— and/or —SO2— and which may be monosubstituted or polysubstituted by C1–C6-alkyl; R1 is hydrogen or C1–C6-alkyl; Hal is chlorine and/or bromine; m is from 0 to 15; n is from 1 to 16, subject to the proviso that the sum m+n is ?16, are prepared a
Type:
Grant
Filed:
March 20, 2002
Date of Patent:
December 5, 2006
Assignee:
BASF Aktiengesellschaft
Inventors:
Arno Boehm, Willi Helfer, Georg Beck, Matthias Krieger, Peter Erk
Abstract: The present invention relates to polymer mixtures comprising hydrogel forming polymers capable of absorbing aqueous fluids, having different pH values and each being preparable by polymerization of olefinically unsaturated carboxylic acids or derivatives thereof, their preparation, use and hygiene articles containing same. More particularly, the invention relates to 2-component polymer mixtures comprising polymers having a pH range from acidic to neutral.
Abstract: The invention relates to a process for preparing N-phosphono-methylglycine by reacting a hexahydrotriazine compound with a triacyl phosphite in an organic solvent, hydrolyzing the resulting phosphono compound after prior extraction into an aqueous phase and separation from the organic phase. The process avoids decomposition of the organic solvent during hydrolysis.
Type:
Grant
Filed:
June 21, 2002
Date of Patent:
December 5, 2006
Assignee:
BASF Aktiengesellschaft
Inventors:
Christian Wulff, Stefan Orsten, Alfred Oftring, Peter Zehner
Abstract: An acrylic composition is formed by reacting a functionalized, chain-stopping monomer, a first compound, and a highly-branched, polyfunctional core molecule. The first compound includes vinyl functionality and at least one other functionality that is different from the vinyl functionality, such as epoxy functionality. The first compound, specifically the vinyl functionality of the first compound, reacts with the monomer to form a functionalized intermediate, and the core molecule reacts with this functionalized intermediate to form the acrylic composition.
Abstract: The invention relates to a method for producing dialdehydes and/or ethylenically unsaturated monoaldehydes by reacting at least one compound with at least two ethylenically unsaturated double bonds with carbon monoxide and hydrogen in the presence of a hydroformylating catalyst with at least one complex of a metal of subgroup VIII. The subgroup comprises at least pnicogen chelate ligands.
Type:
Grant
Filed:
September 12, 2003
Date of Patent:
December 5, 2006
Assignee:
BASF Aktiengesellschaft
Inventors:
Martin Volland, Wolfgang Ahlers, Klaus Ebel, Rocco Paciello, Michael Röper, Thomas Mackewitz, Volker Böhm, Xavier Sava, Oliver Löber, Oliver Bey, Jürgen Stephan, Frank Haese
Abstract: Lactones are prepared by catalytic carbonylation of oxiranes using a catalyst system comprising a) at least one carbonylation catalyst A comprising uncharged or anionic transition metal complexes of metals of groups 5 to 11 of the Periodic Table of the Elements and b) at least one chiral Lewis acid B, with the exception of [(salph)Al(THF)2][Co(CO)4], as catalyst.
Type:
Grant
Filed:
July 31, 2003
Date of Patent:
December 5, 2006
Assignee:
BASF Aktiengesellschaft
Inventors:
Gerrit Luinstra, Bernhard Rieger, Markus Allmendinger
Abstract: The present invention relates to a catalyst composition for the oxychlorination of ethylene, comprising a mixture of metal salts on a support, where said metal salts are applied to the support in such ratios that the catalyst composition comprises a) from 3 to 12% by weight of copper as copper salt, b) from 0 to 3% by weight of an alkaline earth metal as alkaline earth metal salt, c) from 0 to 3% by weight of an alkaline metal as alkaline metal salt, d) from 0.001 to 0.1% by weight, preferably from 0.005 to 0.05% by weight, of at least one metal selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium and platinum, and/or from 0.0001 to 0.1% by weight, preferably from 0.001 to 0.05% by weight, of gold, as corresponding metal salt or tetrachloroauric acid, where all percentages by weight are based on the total weight of the catalyst including support material.
Abstract: A molding composition is described and comprises a mixture of interpenetrating polymers. A first phase comprises a crosslinked isobutene polymer, and a second phase encompasses a reinforcing polymer comprising (meth)acrylic and/or vinylaromatic units. The first phase is the reaction product of an isobutene polymer having an average of at least 1.4 functional groups in the molecule and of a crosslinking agent having an average of at least two functional groups in the molecule, the functionality of these being complementary to that of the functional groups of the isobutene polymer. The molding composition is particularly suitable for the roofing of buildings, or as impact-modified polystyrene or polymethyl methacrylate.
Type:
Application
Filed:
August 19, 2004
Publication date:
November 30, 2006
Applicant:
Basf Aktiengesellschaft
Inventors:
Domonique Teyssie, Cedric Vancaeyzeele, Judith Laskar, Odile Fichet, Sylvie Boileau, Richard Blackborow, Hans Rath, Arno Lange, Gabriele Lang, Helmut Mach, Margit Hiller
Abstract: A process for obtaining oligomers of polytetrahydrofuran or of tetrahydrofuran copolymers from a methanolic crude product which contains polytetrahydrofuran or tetrahydrofuran copolymers and is obtained in the transesterification of the mono- and/or diesters of polytetrahydrofuran or tetrahydrofuran copolymers with methanol, which comprises a) removing the majority of the methanol from the crude product in a first distillation stage, b) separating the resulting bottom product by distillation into a top fraction comprising the oligomers of polytetrahydrofuran or of tetrahydrofuran copolymers, and polytetrahydrofuran or tetrahydrofuran copolymer, c) condensing the oligomers of polytetrahydrofuran or of tetrahydrofuran copolymers out of the top fraction from stage b).
Type:
Application
Filed:
June 19, 2004
Publication date:
November 30, 2006
Applicant:
BASF Aktiengesellschaft
Inventors:
Volkmar Menger, Michael Schwarztrauber, Martin Haubner, Klaus-Peter Pfaff
Abstract: Isolated nucleic acid molecules, designated RRP nucleic acid molecules, which encode novel RRP proteins from Corynebacterium glutamicum are described. The invention also provides antisense nucleic acid molecules, recombinant expression vectors containing RRP nucleic acid molecules, and host cells into which the expression vectors have been introduced. The invention still further provides isolated RRP proteins, mutated RRP proteins, fusion proteins, antigenic peptides and methods for the improvement of production of a desired compound from C. glutamicum based on genetic engineering of RRP genes in this organism.
Type:
Application
Filed:
March 7, 2006
Publication date:
November 30, 2006
Applicant:
BASF Aktiengesellschaft
Inventors:
Markus Pompejus, Burkhard Kroger, Hartwig Schroder, Oskar Zelder, Gregor Haberhauer
Abstract: The invention relates to N?-substituted N-acylamidine transition metal complexes of the general formula (I), wherein M represents a transition metal, selected from the group of metals including Ni, Cu, Ru, Rh, Pd, Os, Ir and Pt, X represents Cl, Br, triflate, methane sulfonate or p-toluol sulfonate, m is 0, 1 or 2, n is 1, 2 or 3 and the radicals have the following meanings: R1, R2 is a straight-chain or branched, cyclic hydrocarbon group with 1 to 20 carbon atoms which can be mono or poly-unsaturated, an aromatic group with 3 to 6 chain members, which is linked directly or via a C1 to C6 alkyl or C2 to C6 alkylene group, whereby the mentioned groups can carry one or more substituents. Ar represents C6 to C10 aryl or hetaryl with 5 to 10 ring members, whereby the mentioned groups can be substituted by C1 to C6 alkyl, C1 to C4 halogenalkyl, NR10R11, COOR6, Si(R7)3Si(R7)2R8, OR3 and/or halogen.
Type:
Grant
Filed:
November 28, 2003
Date of Patent:
November 28, 2006
Assignee:
BASF Aktiengesellschaft
Inventors:
Jan Kurt Eberhardt, Ernst-Ulrich Würthwein