Abstract: The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.
Type:
Grant
Filed:
March 25, 2003
Date of Patent:
February 15, 2005
Assignee:
BASF Corporation
Inventors:
Donald H. Campbell, Walter H. Ohrbom, Joseph Borst, Michael A. Gessner, Donald L. St. Aubin, Marvin L. Green, Bruce E. Oermann
Abstract: A heat-curable composition comprising (I) at least one constituent whose molecule comprises on average (A) at least one functional group containing at least one bond which may be activated by means of heat and/or actinic radiation, and/or (B) at least one reactive functional group which is able to undergo thermal crosslinking reactions with groups of its own kind and/or with complementary reactive functional groups, with the proviso that there are always groups (A) and (B) in the composition; said constituent excluding the polyurethane dispersion synthesized from aliphatic polyisocyanates, compounds containing isocyanate-reactive functional groups and containing bonds that may be activated with actinic radiation, low molecular mass aliphatic compounds containing isocyanate-reactive functional groups, compounds containing isocyanate-reactive functional groups and dispersing functional groups, neutralizing agents for the dispersing functional groups, blocking agents for isocyanate groups, and/or compounds c
Abstract: A 7-(R)-Aminotriazolopyrimidines of formula I where the substituents and index are as defined below: R1 is hydrogen or methyl; R2 is methyl; R3 is C2-C10-alkyl, C1-C4-alkoxymethyl, C3-C10-cycloalkyl; Y is halogen, cyano, C1-C4-alkyl or C1-C4-alkoxy; where * is a center of chirality in the R configuration, processes for their preparation, compositions comprising them and their use for controlling harmful fungi.
Type:
Grant
Filed:
November 9, 2001
Date of Patent:
February 15, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Jordi Tormo i Blasco, Klaus Ditrich, Hubert Sauter, Oliver Cullmann, Markus Gewehr, Wassilios Grammenos, Bernd Müller, Thomas Grote, Andreas Gypser, Joachim Rheinheimer, Ingo Rose, Peter Schäfer, Frank Schieweck, Eberhard Ammermann, Siegfried Strathmann, Gisela Lorenz, Reinhard Stierl
Abstract: A gas distributor for an apparatus for making the gas stream fed into the interior of the apparatus via an inlet whose hydraulic diameter is smaller than the hydraulic diameter of the apparatus uniform, wherein the gas distributor has a perforated curved surface which has a concave side and a convex side which is shaped so that its edge is matched to the interior wall of the apparatus in the region of the inlet where the concave side of the surface of the gas distributor faces the inlet and can be fitted in a fully enclosing manner to the interior wall of the apparatus, is proposed.
Abstract: Process for the preparation of a crystalline solid comprising at least one zeolitic material, in which the solid is crystallized from at least one precursor compound and the reaction discharge of the crystallization is fed directly to a drying stage.
Type:
Application
Filed:
August 30, 2004
Publication date:
February 10, 2005
Applicant:
BASF Akiengesellschaft
Inventors:
Ulrich Mueller, Friedrich Hill, Norbert Rieber
Abstract: A stabilizer composition is described and comprises a 2-cyano-3,3-diarylacrylate, a sterically hindered monomeric amine, a sterically hindered phenol and, where appropriate, a chromane derivative and/or an organic phosphite and/or phosphonite. The stabilizer composition is particularly suitable for stabilizing thermoplastic polyurethane with respect to light, oxygen, and heat.
Abstract: Process for operating a continuous heterogeneously catalyzed gas phase partial oxidation of at least one organic compound using compressed air as the oxygen source which is filtered before its compression.
Type:
Application
Filed:
August 6, 2004
Publication date:
February 10, 2005
Applicant:
BASF Aktiengesellschaft
Inventors:
Volker Schliephake, Ulrich Hammon, Rolf-Dieter Becher, Klaus Muller-Engel
Abstract: A luminescent flexographic printing ink for printing control marks comprises a combination of a light-scattering pigment and an optical brightener and is not opaque. The luminescent flexographic printing ink is used for printing control marks and bar codes and for the production of decorative papers, wood laminates and floor panels.
Type:
Grant
Filed:
May 6, 2002
Date of Patent:
February 8, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Herbert Hirschmann, Guido Schweizer, Jörg Pohé
Abstract: A hydrophilic or hydrophobic polyurethane having at least one olefinically unsaturated group selected from the group consisting of pendant olefinically unsaturated groups, terminal olefinically unsaturated groups, and mixtures thereo wherein the pendant olefinically unsaturated groups are sele consisting of pendant olefinically unsaturated groups which are attached to a cycloaliphatic group which represents a link in the polymer main chain and pendant olefinically unsaturated groups which are present as a double bond in a cycloolefinic group which constitutes a link in the polymer main chain, and the terminal olefinically unsaturated groups are selected from the group consisting of terminal olefinically unsaturated groups which are attached to a cycloaliphatic group which forms an endgroup of the polymer main chain and terminal olefinically unsaturated groups which are present as a double bond in a cycloolefinic structure which forms en endgroup of the polymer main chain.
Abstract: In paper coating slips containing, as a binder, a copolymer which is obtainable by free radical polymerization of ethylenically unsaturated compounds, at least one of the ethylenically unsaturated compounds is a polymer having at least one copolymerizable ethylenically unsaturated group, a number average molecular weight of from 500 to 50000 g/mol and at least one carboxyl group (referred to below as ethylenically unsaturated polymer for short).
Type:
Grant
Filed:
March 27, 2001
Date of Patent:
February 8, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Volker Schädler, David Christie, Roland Ettl
Abstract: Coating composition comprising (a1) radiation curable component that polymerizes upon exposure to actinic radiation comprising at least two functional groups comprising at least one bond that is activatable upon exposure to actinic radiation, optionally, at least one isocyanate-reactive functional group, and optionally, at least one hydroxyl-reactive functional group; (a2) thermally curable binder component that polymerizes upon exposure to heat comprising at least two functional groups that are reactive with functional groups of component (a3), wherein at least 5% by weight based on a nonvolatile weight of component (a2) is component (X) that is a polymer with at least two functional groups (a21), a Tg of less than 0° C., and an equivalent weight of greater than 225; (a3) thermally curable crosslinking component comprising at least two functional groups that are reactive with functional groups of (a2); and (a4) optionally, at least one reactive diluent.
Type:
Grant
Filed:
June 4, 2003
Date of Patent:
February 8, 2005
Assignee:
BASF Corporation
Inventors:
Thomas C. Balch, Lyle A. Caillouette, Karl R. Gust
Abstract: Aqueous primary dispersions and coating materials comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core-shell particles having a diameter?500 nm preparable by controlled free-radical microemulsion or miniemulsion polymerization of A) at least one olefinically unsaturated monomer and B) at least one olefinically unsaturated monomer which is different than the olefinically unsaturated monomer (A) and has the general formula I: R1R2C?CR3R4 (I), in which the radicals R1, R2, R3 and R4 independently of one another are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R1, R2, R3 and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals; and also their use.
Type:
Grant
Filed:
November 8, 2000
Date of Patent:
February 8, 2005
Assignee:
BASF Coatings AG
Inventors:
Maximilian Bendix, Wolfgang Bremser, David Christie
Abstract: (Meth)acrylic acid is purified by crystallization by a process in which the (meth)acrylic acid is purified by a combination of at least two different dynamic crystallization processes, in particular a suspension crystallization and a layer crystallization.
Type:
Grant
Filed:
January 24, 2001
Date of Patent:
February 8, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Emile De Decker, Erik Bastiaensen, Dieter Baumann, Bernd Eck, Jörg Heilek
Abstract: Catalyst systems for the copolymerization of carbon monoxide and ?-olefinically unsaturated compounds contain, as essential components, a) a metal complex of the formula (I) ?where R1 to R4 are each linear or branched C2- to C28-alkyl, C3- to C14-cycloalkyl or alkylaryl where the alkyl moiety is of 1 to 28 carbon atoms and the aryl moiety is of 6 to 15 carbon atoms, each of which is substituted by at least one polar protic or ionic functional group based on elements of groups IVA to VIA of the Periodic Table of Elements, and b) if required, one or more Lewis or protic acids or a mixture of Lewis and protic acids.
Type:
Grant
Filed:
October 24, 2003
Date of Patent:
February 8, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Joachim Queisser, Michael Slany, Michael Geprägs, Ekkehard Lindner, Markus Schmid, Joachim Wald, Peter Wegner
Abstract: The novel compounds of formula I: wherein R, A, X1, X2, X3, Z and m have the meaning given in claim 1, and the agronomically acceptable salts or N-oxides thereof, and herbicidal compositions containing such compounds as active ingredients.
Type:
Grant
Filed:
March 21, 2002
Date of Patent:
February 8, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Stefan Scheiblich, Thomas Maier, Helmut Siegfried Baltruschat, Thomas Hoellmueller
Abstract: In a process for preparing essentially unbranched oligomers of alkenes having from 4 to 6 carbon atoms starting from the alkenes or a hydrocarbon stream comprising such alkenes over a nickel-containing heterogeneous catalyst in an adiabatically operated reactor at from 20 to 300° C. and pressures of from 1 to 100 bar, a first substream of the output from the reactor is worked up to isolate the oligomers and the second substream is recirculated together with fresh alkene or a fresh hydrocarbon stream comprising such alkenes to the reactor.
Type:
Grant
Filed:
March 22, 2001
Date of Patent:
February 8, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Ralf Schulz, Thomas Heidemann, Peter Schwab, Peter Zehner
Abstract: COS is selectively removed with respect to CO2 from a hydrocarbonaceous fluid stream which contains CO2 and COS. Examples of the fluid stream include a gas stream, for example natural gas, synthesis gas from heavy oil or heavy residues or refinery gas, or from liquid or liquefied hydrocarbons, for example LPG (Liquefied Petroleum Gas) or NGL (Natural Gas Liquids). The process is carried out by (1) intimately contacting the fluid stream in an absorption or extraction zone with a scrubbing liquor consisting of an aqueous amine solution containing from 1.5 to 5 mol/l of an aliphatic alkanolamine having of from 2 to 12 carbon atoms and from 0.8 to 1.7 mol/l of at least one activator selected from the group consisting of piperazine, methyl piperazine and morpholine, (2) removing the COS essentially completely from the fluid stream, and (3) separating the substantially COS-decontaminated fluid stream and the COS-loaded scrubbing liquor and discharging them from the absorption or extraction zone.
Type:
Grant
Filed:
October 4, 2000
Date of Patent:
February 8, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Rupert Wagner, Randolf Hugo, Thomas S. Holst
Abstract: A process is provided for the distillative separation of pentene nitrile isomers which have a relative volatility alpha ranging from 1.0 to 1.3 in the pressure range from 1 to 500 kPa, wherein the distillation is carried out in the presence of a liquid diluent which forms with the pentene nitrile isomers, under the same pressure conditions, azeotropes whose relative volatility alpha is higher than that of the pentene nitrile isomers to be separated.
Type:
Grant
Filed:
September 25, 2001
Date of Patent:
February 8, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Tim Jungkamp, Dagmar Pascale Kunsmann-Keitel, Robert Baumann, Peter Bassler, Wolfgang Siegel
Abstract: Homo- and copolymers of isobutene are prepared by continuous cationic polymerization of isobutene or mixtures of isobutene with ethylenically unsaturated comonomers in the presence of an initiator system comprising: i) a Lewis acid selected from covalent metal-halogen compounds and covalent semimetal-halogen compounds and ii) at least one aprotic organic compound I having at least one functional group FG which forms a carbocation or a cationic complex with the Lewis acid under polymerization conditions in an organic solvent inert with respect to the Lewis acid, by a process in which the polymerization is carried out in a tubular flow-through reactor which has a plurality of curves having an alternating direction of curvature.
Type:
Grant
Filed:
May 24, 2002
Date of Patent:
February 8, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Stephan Hüffer, Hans Peter Rath, Gabriele Lang, Jens Kremeskötter, Elmar Stöckelmann
Abstract: Methods and apparatus are provided for dispensing chemical material, and in particular, granular, agricultural material, from a moving device driven over terrain to be treated with the material. A metering system for dispersing the material includes on apertured metering disk positioned above a rotatable impeller. The apertured disk meters material from a product container, by gravity feed, onto the impeller below at a rate proportional to the linear speed at which the apparatus is driven to dispense material at a uniform density over the terrain. The metering disk is a component of a product container which is removably mounted to the device. The impeller rotates at a constant speed to disperse the deposited material at a uniform distance from the apparatus, and the position on which the material is deposited on the impeller is adjustable.