Abstract: A process for rectificatively separating an acrylic acid-containing liquid, by withdrawing an acrylic acid-rich stream from the rectification column above the feed point and polymerization-inhibiting the upper section of the rectification column by means of diacrylic acid.
Type:
Application
Filed:
September 14, 2004
Publication date:
April 14, 2005
Applicant:
BASF Aktiengesellschaft
Inventors:
Frank Hofer, Volker Schliephake, Klaus Muller-Engel
Abstract: Hydrophilic composite material comprising components A and B, and optionally C, where A is a substance which readily swells with water, B is a substance which forms a porous structure or has a predetermined porous structure, and in whose pores A is present, and C is a binder.
Type:
Application
Filed:
January 30, 2003
Publication date:
April 14, 2005
Applicant:
Basf Aktiengesellschaft
Inventors:
Harald Keller, Ekkehard Jahns, Thomas Frechen, Wolfgang Schrepp
Abstract: The present invention relates to a process for preparing polyoxyalkylene glycol of high purity and having a low color number from the corresponding alkylene glycol and a starter in the presence of a basic catalyst, wherein a reducing agent is present in the polymerization.
Abstract: Method for improving plant growth by application of a mixture M comprising a component a) of a1) 20 to 96% by weight of sulfur, a2) 4 to 80% by weight of a complexing agent and, if appropriate, one or more crop protectants b) and/or additives c).
Type:
Application
Filed:
July 31, 2002
Publication date:
April 14, 2005
Applicant:
BASF AKTIENGESELLSCHAFT
Inventors:
Jorn Tidow, Herbert Scholz, Adolf Parg, Reinhold Stadler, Karl-Heinrich Schneider, Reinhardt Hahndel, Gerhard Pompejus, Francesc Forcades
Abstract: Disclosed is a method for making nongelled functional addition polymers from linear unsaturated anhydrides. The method subjects a linear unsaturated anhydride compound, an active hydrogen compound, and an epoxide compound to reaction conditions such that each of the following three reactions occur: (i) polymerization of polymerizable C?C bonds, (ii) ring opening of an anhydride functional group of the linear unsaturated anhydride compound by the active hydrogen compound to create an acid functional group, and (iii) reaction of the acid functional group resulting from the anhydride ring opening with the epoxide compound. At the time of reaction (iii), the acid functional group resulting from the anhydride ring opening may be selected from an ethylenically unsaturated monomer, a polymer, or both. In one embodiment, the method does not include the physical removal of any acid functional monomers or polymerization products. Also disclosed are a curable coating composition and a coated substrate.
Type:
Application
Filed:
October 1, 2004
Publication date:
April 14, 2005
Applicant:
BASF Corporation
Inventors:
Walter Ohrbom, Donald Campbell, Donald St. Aubin, Swaminathan Ramesh, Paul Harris, Ulrike Rockrath
Abstract: The present invention relates to compositions based on a homogeneous, aqueous phase comprising at least one active ingredient from the class of the quaternized compounds, ethylene oxide/propylene oxide block copolymers and ammonium nitrate. Further active ingredients can be incorporated. The homogeneous phase is stabilized by ammonium nitrate. The use of the compositions as bioregulators is described.
Type:
Grant
Filed:
December 5, 2001
Date of Patent:
April 12, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Reiner Kober, Wilhelm Rademacher, Hans-Michael Fricke
Abstract: Thermoplastic molding compositions comprising, as substantive components, A) from 5% by weight to (99.99% by weight minus 1 ppb), based on components A) to D), of a polyoxymethylene homo- or copolymer, B) from 1 ppb to 1% by weight, based on the molding composition made from A) to D), of at least one polyethyleneimine homo- or copolymer, C) from 0.01 to 15% by weight of carbon black, and D) from 0 to 80% by weight of other additives, where the total of percentages by weight of components A) to D) is always 100%.
Abstract: A process for preparing a polymer, which comprises a) reacting a mixture (I) containing 6-aminocapronitrile and water in the presence of a catalyst to obtain a mixture (II) containing caprolactam, ammonia, water, high boilers and low boilers, then b) removing ammonia from mixture (II) to obtain a mixture (III) containing caprolactam, water, high boilers and low boilers, then c) removing all or some of the water from mixture (III) to obtain a mixture (IV) containing caprolactam, high boilers and low boilers and then d) feeding mixture (IV) to a polymerization reaction, and also the polymer obtainable by this process, the use of the polymer for producing fibers, sheetlike structures and moldings, and also fibers, sheetlike structures and moldings obtainable using such a polymer.
Type:
Grant
Filed:
April 30, 2001
Date of Patent:
April 12, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Frank Ohlbach, Helmut Winterling, Andreas Ansmann, Rolf-Hartmuth Fischer, Johann-Peter Melder, Stefan Maixner, Peter Bassler, Hermann Luyken
Abstract: In a process for preparing polytetrahydrofuran having terminal OH groups (PTHF) from the corresponding polytetramethylene ether having acyloxy end groups by transesterification with alcohols in the presence of a sodium-containing catalyst followed by passing the alcoholic PTHF solution in the presence of a catalytic amount of water directly through at least one ion exchanger to remove the sodium ions, the removal of the sodium ions is carried out in a fully continuous ion exchange unit which comprises: a plurality of ion exchange cells (Z) which are arranged on a rotary platform and are each provided with a distribution element and a collection element and a central valve (V) having a stator disk (S) and a rotor disk (R) via which the introduction and discharge of all liquid streams into or out of the ion exchange unit occurs, and feed and discharge lines from each ion exchange cell (Z) to the central valve (V).
Type:
Grant
Filed:
August 20, 2002
Date of Patent:
April 12, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Jürgen Ciprian, Wulfrich Friedemann Beer, Volkmar Menger
Abstract: Proposals are made for a process for preparing polymer solutions and/or polymer dispersions by free-radical addition polymerization and for the use of the polymers prepared, particularly as gas hydrate inhibitors.
Type:
Grant
Filed:
March 6, 2001
Date of Patent:
April 12, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Maximilian Angel, Stefan Stein, Karin Neubecker
Abstract: The present invention relates to a novel, heterogeneous catalyst which is suitable, in particular, for olefin metathesis. This catalyst is immobilized on an inorganic support and contains at least one active rhenium compound containing at least one carbene group and, if desired, further functional groups. The rhenium compound is bonded to the material used as support by a chemical bond.
Type:
Grant
Filed:
September 14, 2001
Date of Patent:
April 12, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Jean-Marie Basset, Mathieu Chabanas, Christophe Coperet
Abstract: Polymers of a poly(meth)acrylic acid main chain in which, based on the main chain, 0 to 30% by weight of the (meth)acrylic acid basic building blocks may be replaced by maleic acid (anhydride) basic building blocks, fumaric acid basic building blocks or mixtures thereof and 0 to 10% by weight of the (meth)acrylic acid basic building blocks may be replaced by other copolymerizable ethylenic basic building blocks, and C1-30-alkylpoly-C2-4-alkylene glycols, bonded to the main chain via ester groups, having an average molecular weight of from 250 to 10 000 as side chains, where, based on the polymer, 1 to 19% by weight of the main chain and 81 to 99% by weight of the side chains are present and this ratio and the average molecular weight of the side chains are chosen such that free carboxyl groups are present in the polymer, are used as controllable dispersants for detergents or cleaners or constituents thereof.
Type:
Grant
Filed:
June 6, 2001
Date of Patent:
April 12, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter Neumann, Werner Bertleff, Matthias Kroner, Bernard Mohr
Abstract: Positionally isomeric diethyloctanediol dicarbamates and diethyloctanediol diallophanates, processes for preparing them, and their use as synthesis building blocks and constituents of adhesives, sealing compounds, and coating materials.
Type:
Grant
Filed:
January 24, 2001
Date of Patent:
April 12, 2005
Assignee:
BASF Coatings AG
Inventors:
Heinz-Peter Rink, Jochem Henkelmann, Werner-Alfons Jung, Paul J. Harris, Swaminathan Ramesh
Abstract: Rylene derivatives of the general formula I where the variables have the following meanings: R is hydrogen or substituted or unsubstituted C1-C30-alkyl, aryl or hetaryl; R1 is hydrogen or bromine; R2 is hydrogen or C1-C6-alkyl; R3 is hydrogen, C1-C18-alkyl or substituted or unsubstituted aryl or hetaryl; and n is 2 or 3.
Type:
Grant
Filed:
February 14, 2002
Date of Patent:
April 12, 2005
Assignees:
BASF Aktiengesellschaft, Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.
Inventors:
Matthias Krieger, Arno Böhm, Erik Reuther, Klaus Müllen
Abstract: The use of an aqueous polymer dispersion comprising dispersed particles of at least one polymer A1 obtainable by free-radical emulsion polymerization in the presence of a polymer A2 synthesized from from 50 to 99.5% by weight of at least one ethylenically unsaturated monocarboxylic and/or dicarboxylic acid, from 0.5 to 50% by weight of at least one ethylenically unsaturated compound selected from the esters of ethylenically unsaturated monocarboxylic acids and the monoesters and diesters of ethylenically unsaturated dicarboxylic acids with an amine containing at least one hydroxyl group, up to 20% by weight of at least one further monomer as a binder for producing filter materials.
Abstract: The present invention relates to a process for preparing dye-comprising aqueous polymer dispersions by free-radical aqueous emulsion polymerization of ethylenically unsaturated monomers in the presence of free-radical initiators, in which at least some of the monomers are employed in the form of an oil-in-water emulsion E1 whose disperse phase comprises at least one oil-soluble dye, wherein the disperse phase of E1 is formed essentially of dye-comprising monomer droplets having a diameter<500 nm. The present invention also relates to perylene dyes of the formula III as set forth in claim 35. The present invention relates in addition to dye-comprising formulations which comprise the dye-comprising polymers of the invention and to pigmented formulations which comprise a polymer of the invention comprising optical brightener.
Type:
Application
Filed:
July 30, 2003
Publication date:
April 7, 2005
Applicant:
BASF Aktiengesellschaf
Inventors:
Klemens Mathauer, Arno Bohm, Walter Machtle, Peter Rossmanith, Sabine Kielhorn-Bayer, Klaus Mullen, Ulrike Rohr, Friedrich-Wilhelm Raulfs, Ulrike Schlosser, Wolfgang Schrof, Harutyun Hanciogullari, Karl Siemensmeyer, Paul Delavier, Rudiger Sens, Torsten Freund, Takahiro Ikeda, Takanori Wakebe
Abstract: Polyisobutenylphenols are prepared by alkylating an aromatic hydroxy compound with substantially monoethylenically unsaturated and substantially homopolymeric polyisobutenes in the presence of a Lewis acid alkylation catalyst by a process in which an ether is additionally used as a cocatalyst, the ether having a molecular weight of at least 102 g/mol in the case of BF3 as the Lewis acid.
Abstract: In a process for preparing an ester of an unsaturated carboxylic acid by reacting an ester of the unsaturated carboxylic acid and a C1-C4-alkanol with an alcohol R3OH, where R3 is a C4-C20-alkyl radical, a C5-C7-cycloalkyl radical, a phenyl-C1-C4-alkyl radical or a C2-C12-alkyl radical substituted by at least one NR5R5 group or by from 1 to 3 hydroxyl groups or C1-C4-alkoxyl groups or interrupted by one or more oxygen atoms, where the radicals R5 are, independently of one another, C1-C6-alkyl or together with the nitrogen atom form a 5- to 7-membered heterocyclic ring which may contain a further nitrogen or oxygen atom, in the presence of a transesterification catalyst, the transesterification catalyst used is at least one metal alkanolate containing at least one OR1 group, where R1 is a 2,2,6,6-tetraalkyl-1-oxylpiperidin-4-yl radical.
Abstract: Countercurrent stripping pipe for removing volatile organic constituents from reaction products, having a column pipe (201) composed of a plurality of pipe sections (201a-d), in which trays (202) are arranged, connections (205, 208) for supplying and removing the reaction products and connections (206, 207) for supplying and removing at least one stripping agent in countercurrent to the reaction products. In accordance with the invention, a plurality of successive trays (202) in each case are joined to one another and form at least two inserts (211a-c) which can be removed from the column pipe (201).
Type:
Grant
Filed:
October 12, 1999
Date of Patent:
April 5, 2005
Assignee:
BASF Aktiengesellschaft
Inventors:
Wolfgang Hübinger, Günter Staufer, Peter Keller