Abstract: The present invention relates to a multilayer oxygen-consuming electrode having a side facing the oxygen-containing gas and a side facing the alkaline electrolyte, wherein the electrode includes at least one support, and at least two layers comprising a catalyst and a hydrophobic material, wherein the outermost layer facing the gas side has a lower proportion of catalyst than the outermost layer facing the electrolyte side and wherein the proportion of hydrophobic material is not more than 8% by weight based on the total amount of the catalyst and the hydrophobic material.

Abstract: The invention concerns aqueous secondary polymer dispersions based on special acrylate building blocks, a process for their production and their use as binders for the production of blister-free coatings.

Abstract: The invention relates to radiation curable coating systems on the basis of aqueous polyurethane dispersions, to a method for the production thereof, to the use of the coating systems as paints and/or adhesives, and to objects and substrates provided with said paints and/or adhesives.

Abstract: The invention is directed to a process for preparing aromatic carbamates which comprises the reaction of an aromatic amine with an organic carbonate in the presence of a catalyst characterized in that Zn4O(OAc)6 is used as catalyst.

Abstract: The present invention relates to radiation-curable coating compositions based on tin-free aqueous polyurethane dispersions based on polyurethane acrylates (i), characterized in that the polyurethane acrylate (i) comprises as builder components A) one or more compounds with at least one group which is reactive towards isocyanate and at least one unsaturated group which can undergo free radical polymerization, B) one or more compounds which differ from A) and have at least one group which is reactive towards isocyanate, C) one or more compounds with at least one group which is reactive towards isocyanate and additionally at least one group having a hydrophilizing action, D) one or more organic polyisocyanates, which are reacted in the presence of F) bismuth(III) salt(s) and G) an acid having a pKa of <2.5, and a process for the preparation thereof, the use of the coating compositions as lacquers and/or adhesives, and objects and substrates provided with these lacquers and/or adhesives.

Abstract: The present invention relates to an improved process of ozonolysis of carbon nanotubes assisted by water vapour. The improved methodology provides an eco-friendly, cheaper, practical and efficient approach to functionalize carbon nanotubes with oxygen-containing moieties for further chemical functionalization and composite dispersion.

Abstract: An aqueous polymer dispersion that includes a) a polyurethane dispersion having an average particle size of 60 to 350 nm and b) an aqueous silicon dioxide dispersion having a particle diameter of the SiO2 particles of 20 to 400 nm. The dispersion is prepared by mixing the polyurethane dispersion (a) with the silicon dioxide dispersion (b). The aqueous polymer dispersion can be used in adhesive compositions, which can be used to bond substrates together, especially substrates that are structural components of shoes.

Abstract: The invention relates to a process for isocyanate modification which includes reacting a) at least one organic isocyanate having an NCO functionality greater than or equal to 1, b) a catalyst comprising at least one phosphonium salt comprising at least one cycloalkyl substituent bonded directly to a P atom of a phosphonium cation, c) optionally a solvent, and d) optionally additives. The present invention also relates to a catalyst for isocyanate modification comprising at least one phosphonium salt comprising at least one cycloalkyl substituent bonded directly to a P atom of a phosphonium cation.

Abstract: A polyol emulsion of castor oil and monoepoxides is combined with methylenediphenyl diisocyanate (MDI) and cement to produce a polymer cement.

Abstract: Aromatic amines are produced by catalytic hydrogenation of aromatic nitro compounds. The reaction mixture generated by this hydrogenation is then worked up by distillation in a manner which makes it possible to substantially free the amine of water with increased energy efficiency. Water free of amine and low boilers and the low boiling materials are also obtained.

Abstract: The invention relates to polycarbonates that comprise defect structures and cyclic oligomers and have improved properties. The invention also relates to molded articles and extrudates made from said polycarbonates.

Abstract: The invention relates to carbon nanotubes comprising hydroxy groups, wherein the surface thereof comprises hydroxy alkyl ester groups covalently bound thereon, chosen from the group according to the general formula (1) and/or the general formula (2), wherein (CNT) stands for the surface of the carbon nanotube and R1 and R2 are independently from each other hydrocarbon, an alkyl radical or an aryl radical. The invention further relates to a method for the production thereof by means of reaction of carbon acid groups of the carbon nanotubes with an epoxy, furthermore a polyurethane polymer, wherein said carbon nanotubes are covalently bound, a method for producing a polymer of said kind and use of the carbon nanotubes for producing polymers.

Abstract: A process is described for producing polycarbonate and utilizing at least some of the process waste water by concentrating the sodium chloride-containing waste water phases for the electrolysis using osmotic membrane distillation, if appropriate with simultaneous dilution of the sodium hydroxide solution obtained from the electrolysis for the polycarbonate production process.

Abstract: The present invention relates to a process for preparing low-viscosity reaction products of polyisocyanates containing activated, ethylenically unsaturated groups which react, with polymerization, on exposure to actinic radiation.

Abstract: The present invention relates to an oxygen-consuming electrode comprising at least one support structure having a surface and a gas diffusion coating having a catalytically active component disposed on the surface. The coating contains at least one fluorine-containing polymer, a silver compound, selected from the group consisting of silver particles, reducible silver compounds, and mixtures thereof, and a hydrophilic caustic alkali-resistant filler which is electrically nonconductive or has a poor electrical conductivity and has an average particle diameter from 5 to 200 ?m.

Abstract: The invention relates to (co)polycarbonate compositions and molding compositions which feature improved optical properties, good flowability, and high heat resistance.

Abstract: Printable compositions comprising: (a) 5 to 40 parts by weight of silver nanoparticles having a maximum effective diameter of 150 nm, as determined by laser correlation spectroscopy; (b) 50 to 99.5 parts by weight of water; (c) 0.01 to 15 parts by weight of a dispersing agent; (d) 0.5 to 5 parts by weight of a film former; and (g) 30 to 70 parts by weight of metal particles having a maximum effective diameter of 10 ?m, as determined by laser correlation spectroscopy; wherein the printable composition has a viscosity of at least 1 Pa·s; processes for producing electrically conductive coatings using such compositions and electrically conductive coatings prepared thereby.

Abstract: The present invention relates to a UV-crosslinkable composition comprising a) unmodified, protonated silica nanoparticles; b) urethane acrylate; c) polar solvent; and d) UV initiator system, wherein the amount by weight of unmodified, protonated silica nanoparticles exceeds the content of urethane acrylate and is at least 50.1 wt. %, based on the dry weight of the coating, to the use of the composition in the coating of substrates, and to substrates coated with such formulations.

Abstract: An impact modified thermoplastic molding composition comprising aromatic polycarbonate and/or polyester carbonate and a rubber-modified graft polymer prepared by the bulk, solution or bulk-suspension polymerization process is disclosed. The composition that is characterized by its low content of lithium ions and its content of sodium and/or potassium ions exceeding a minimum level features improved hydrolytic resistance.

Abstract: The invention relates to the use of heterocycles containing trivalent phosphorus as a ring member as catalysts for isocyanate modification and to a process for preparing polyisocyanates of the trimer type.