Abstract: The present invention relates to a process for the continuous preparation of diaryl carbonates from phosgene and at least one monohydroxy compound (monophenol) in the presence of catalysts, and also the use thereof for preparing polycarbonates. The hydrogen chloride formed in the reaction is converted by electrochemical oxidation into chlorine, with the chlorine being recirculated to the preparation of phosgene. In particular, the process comprises utilization of the hydrogen chloride formed for the process for preparing diphenyl carbonate (DPC process).

Abstract: The present invention relates to a process for producing a polyurethane foam, where the blowing agent used is present in the supercritical or near-critical state. A reaction mixture is introduced into a closed mould, where the closed mould has been set up in such a way that its interior volume and/or the pressure prevailing in its interior can be altered after the introduction of the mixture by external influence. Through the selection of the surfactant it is possible to obtain microemulsions of the blowing agent in the polyol phase. The invention further relates to a nanocellular polyurethane foam obtainable by the process of the invention.

Abstract: The invention relates to a process for the preparation of a polyurethane polymer, comprising the step of reaction of A) polyester polyols with secondary hydroxyl end groups, which are obtainable from the reaction of a polyester comprising carboxyl end groups with an epoxide of the general formula (1): wherein R1 represents an alkyl radical or an aryl radical and wherein the polyester comprising carboxyl end groups has an acid number of from ?25 mg of KOH/g to ?400 mg of KOH/g and a hydroxyl number of ?5 mg of KOH/g, with B) polyisocyanates which are chosen from the group comprising toluoylene-diisocyanate, diphenylmethane-diisocyanate, polymeric diphenylmethane-diisocyanate, xylylene-diisocyanate, naphthylene-diisocyanate, hexamethylene-diisocyanate, diisocyanatodicyclohexylmethane and/or isophorone-diisocyanate. The invention furthermore relates to polyurethane polymers prepared by such a process.

Abstract: The invention relates to (co)polycarbonate compositions and molding compositions which feature improved optical properties, good flowability, and high heat resistance.

Abstract: The invention relates to a continuous method for producing, by using microparticles, thermoplastics provided with reinforcement fibres. The production methods relate to such composite materials, which contain the reinforcement fibres in a parallel (or predominantly parallel) arrangement in the thermoplastic matrix.

Abstract: The invention relates to a method of selecting photoinitiator systems comprising at least one sensitizer and at least one coinitiator, for photopolymer formulations for producing holographic media.

Abstract: The invention relates to polyisocyanate polyaddition products and to the use of specific catalysts for their preparation, and to their use, in particular for the coating sector.

Abstract: The invention relates to a method for producing organic diisocyanates by reacting the corresponding diamines with phosgene in inert solvents. High-melting diamines from the series of 1,5-naphthalenediamine, tetralindiamine, 1,4-phenylenediamine, durenediamine, and o-tolidinediamine are used as diamines. According to the invention, a suspension of the diamines in inert solvents is produced, wherein dynamic mixing units, selected from dispersion disks and rotor-stator systems, are used, and the obtained suspension is phosgenated.

Abstract: The invention relates to a method for producing compounds containing isocyanate and silane groups by reacting at least A) one monomeric diisocyanate containing aliphatically, cycloaliphatically, araliphatically and/or aromatically bonded isocyanate groups with B) a mercaptosilane, characterised in that component A) is reacted with component B) in an equivalent ratio of isocyanate groups to mercapto groups of at least 06:01 to at most 40:1. Furthermore, the invention relates to the products which can be obtained using the method according to the invention, and to a composition containing compounds that contain isocyanate and silane groups. Moreover, the invention relates to the use of the products which can be obtained using the method according to the invention and the composition according to the invention as starting components in the production of silane group-containing polyurethanes, cross-linkable binders, varnish, and raw materials for sealants or adhesives.

Abstract: The invention relates to polyisocyanate polyaddition products and to the use of specific catalysts for their preparation, and to their use, in particular for the coating sector.

Abstract: The invention relates to a reaction system for producing PUR and PIR hard foam materials, comprising the following components: A) a compound which is reactive towards isocyanates; B1) a surfactant component; C) a propellant in a supercritical or near-critical state; D) a polyisocyanate; and E) a layer silicate. The invention further relates to a reaction system for producing PUR and PIR hard foam materials, comprising the following components: B2) a surfactant component with functional groups which are reactive towards isocyanates; C) a propellant in a supercritical or near-critical state; D) a polyisocyanate; and E) a layer silicate. The invention further relates to a method for producing PUR and PIR hard foam materials and to PUR and PIR hard foam materials which can be obtained from the aforementioned reaction systems.

Abstract: The invention relates to polycarbonate-based or copolycarbonate-based security documents and/or documents of value which contain at least one hologram integrated in the card body, and to a method for producing such security documents and/or documents of value.

Abstract: The present invention relates to a security document and/or document of value with a hologram in a visually changeable window as a novel security element, and also to a method for producing the same.

Abstract: The invention relates to a sandwich composite element (100) and a method for producing a sandwich composite element (100) having a first outer layer (10) and a second outer layer (11), wherein a polyurethane foam core body (12) is arranged between the first outer layer (10) and the second outer layer (11). According to the invention, a subjacent outer layer (13, 14) for mechanically stiffening the composite element (100) is arranged between the foam core body (12) and at least one of the outer layers (10, 11).

Abstract: The present invention relates to a method for producing linear and/or cyclic carbonate esters, involving the step of reacting an epoxide with carbon dioxide in the presence of a catalyser. The invention further relates to the use of special catalysers for reacting epoxides with carbon dioxide, special catalysers and special reaction products. The catalyser comprises a complex of a metal M or M-A with a ligand L, the metal M being present in an oxidation state of >=0, A standing for halide, carboxylate, phenolate, sulfonate, phosphonate, alkyl, alkoxy or amido, and the ligand L having the subsequent structure (Ia) or (Ib), wherein one or both of the OH groups shown in (Ia) and/or (Ib) can also be deprotonated.

Abstract: The invention relates to processes for preparing metal(IV) compounds which are suitable especially as catalysts for preparation of polyesters, polyurethanes and polysiloxanes, and to the use of the metal compounds for preparation of polyesters, polyurethanes or polysiloxanes.

Abstract: The invention relates to layer structures for ID cards on which information can be written by laser engraving and which have an additional layer that is applied to the card body after the laser engraving and restricts or completely prevents subsequent writing on the card by means of laser engraving, and consequently prevents falsification of the identifying information contained, and relates to a method for blocking the laser engraving writability of layer structures on which information can be written by laser engraving.

Abstract: Composition and process for low temperature curing of polyuretdione-polyol compositions in which the polyuretdione is prepared from a polyisocyanate with isocyanate groups and a polyol containing primary hydroxyl groups. The catalyst for the composition and process is an amine catalyst containing the group —N?C—N—, being aprotic, having a pKa greater than 20 and upon addition to the liquid coating composition causing a phase-change of the coating composition from liquid to solid at 25° C. and 1 atm. within one week.

Abstract: The present invention provides a coated plastics film with a zinc tin oxide coating which has improved absorption property, in particular in the blue spectral range from 380 to 430 nm, the zinc tin oxide coating itself and a process for the production thereof, and an electronic device comprising a corresponding coated plastics film.

Abstract: Aromatic amines are produced by adiabatic hydrogenation of nitroaromatic compounds in the gas phase on one or more fixed catalysts. The nitroaromatic reactant is passed over the catalyst under pressure and at elevated temperature with hydrogen, water, optionally nitrogen and substantially in the absence of the aromatic amine produced from the nitroaromatic.