Abstract: A masterbatch comprising pigment and demolding agent is provided. The demolding agent is selected from the group comprising low molecular weight polyolefin oils, low molecular weight polyolefin waxes, montan waxes and aliphatic or aromatic carboxylic acid esters of fatty acids and/or fatty alcohols, wherein the pigment content of the masterbatch is from 3 to 70 wt. %, based on the total weight of the masterbatch. The masterbatch is suitable for preparation of a polymer composition having improved pigment dispersion.
Type:
Grant
Filed:
December 20, 2011
Date of Patent:
June 16, 2015
Assignee:
BAYER MATERIALSCIENCE AG
Inventors:
Andreas Seidel, Hans-Jurgen Thiem, Reiner Rudolf, Joerg Reichenauer, Thomas Eckel
Abstract: The present invention relates to a process for the production of carbon nanotubes by decomposition of hydrocarbons on a heterogeneous catalyst in a fluidized bed reactor, wherein the reactor can be operated batchwise or continuously, and in the case of continuous operation discharge can take place with sifting or without sifting.
Type:
Grant
Filed:
April 13, 2007
Date of Patent:
June 9, 2015
Assignee:
Bayer Materialscience AG
Inventors:
Sigurd Buchholz, Maziar Kakhi, Volker Michele, Leslaw Mleczko, Christian Münnich, Reiner Rudolf, Aurel Wolf
Abstract: A conveying device for a mixture of free-flowing finely divided solid materials, in particular for powdered and/or granular (mixed) material, especially polymer granules with a liquid includes a telescopic pipe which is vertically arranged and can be flexibly fitted for conveying a mixture of preferably polymer granules with a liquid, for example for flushing a contaminated conveying device.
Type:
Grant
Filed:
March 26, 2012
Date of Patent:
June 9, 2015
Assignee:
Bayer MaterialScience AG
Inventors:
Herbert Ungerechts, Hans-Jörg Frank, Markus Hagedorn
Abstract: Isocyanates are produced by reacting a primary amine with phosgene in the gas phase. In this process, the amine is vaporized and then superheated prior to introduction into the reactor. The amine is superheated to a temperature at least 10° C. above dew point before entry into the reactor. A pressure difference between the vaporizer and entry into the reactor of from 1 to 500 mbar is maintained.
Type:
Grant
Filed:
July 6, 2010
Date of Patent:
June 9, 2015
Assignee:
Bayer MaterialScience AG
Inventors:
Rainer Bruns, Wolfgang Lorenz, Andreas Karl Rausch
Abstract: The present invention relates to a multilayer structure comprising A) a functional film comprising a VIS/IR-reflecting metal layer on a carrier film, wherein the carrier film can be in single-layer form or in the form of a UV- and/or UV/VIS-reflecting multi-ply layer, and at least one adhesive layer, and optionally at least one scratch-resistant layer, B) a functional layer comprising a layer of metal nitrides, metal oxides or semimetal oxides, mixed oxides or metals, wherein the layer can additionally have a coating, C) optionally a carrier film, D) optionally an adhesive layer, E) a substrate layer. By means of such a multilayer structure it is possible, in the adhesive bonding of thin functional films by means of a PSA (“pressure sensitive adhesive”) to thermoplastics such as, for example, polycarbonate, largely to avoid blistering of the adhesively bonded film in the case of outside use (in a changing climate).
Abstract: [Problem] To increase adhesive strength between an aqueous base coat layer and a clear coat layer in a coating method by a two-coat one-bake system where an aqueous base coat paint is coated, then a clear coat paint is coated, and these two coated films are simultaneously hardened, in comparison with the conventional method. [Solution] Provided is a coating method using a specific hardener in a clear coat paint. Namely, the hardener is characterized in that (1) it includes a reaction product of (i) a derivative of 1,6-hexamethylene diisocyanate including a trimer and virtually not including a diisocyanate monomer, and (ii) a compound having both an active hydrogen and a hydrophilic group; and (2) viscosity at 23° C. is not more than 1,000 mPa·s. The compound having both an active hydrogen and a hydrophilic group herein is a compound having an active hydrogen-containing group and a sulfo group represented by formula (I), and preferably the sulfo group in a hardener is neutralized with a tertiary amine.
Abstract: A conveying device for free-flowing fine-particle solids, in particular for powdery and/or granular (mixed) material, especially plastic granulate, includes a vertically arranged and flexibly mountable telescopic pipe for the conveyance of, preferably, polymer granulates, for example in a plant for the filling of polymer granulates.
Type:
Grant
Filed:
March 23, 2012
Date of Patent:
May 26, 2015
Assignee:
Bayer MaterialScience AG
Inventors:
Herbert Ungerechts, Hans-Joerg Frank, Dieter Scholten, Markus Hagedorn
Abstract: The invention relates to a method for treating wastewater containing nitroaromatics and nitrohydroxyaromatics, as for example arises in the production of nitroaromatics or in the production of nitrohydroxyaromatics, by a two-stage method consisting of pre-reduction and wet oxidation.
Abstract: The invention provides a process for preparing diaryl carbonates from dialkyl carbonates and aromatic hydroxyl compounds using at least two reaction columns, a process section for recovering the dialkyl carbonate used in the reaction and for removing the alcohol of reaction, one or more process steps for removing the by-products obtained in the process which have a boiling point between that of the dialkyl carbonate and that of the alkyl aryl carbonate formed during the preparation of the diaryl carbonate, and a process step for further purification of the diaryl carbonate obtained from the reaction columns.
Type:
Grant
Filed:
June 12, 2009
Date of Patent:
May 26, 2015
Assignee:
Bayer MaterialScience AG
Inventors:
Andre Düx, Guenter Olf, Kaspar Hallenberger, Georg Ronge, Ricarda Leiberich, Johan Vanden Eynde, Wim Wuytack, Pieter Ooms, Johann Rechner
Abstract: The invention relates to low-viscosity, low-monomer aqueous polymer dispersions based on polychloroprene, and a process for the preparation thereof and the use thereof as a contact adhesive.
Type:
Grant
Filed:
August 19, 2008
Date of Patent:
May 26, 2015
Assignee:
Bayer MaterialScience AG
Inventors:
Dirk Achten, Peter Kueker, Juergen Kempkes, Bianka Lorenz, Peter Reichert, Winfried Jeske, Jose Colinas-Martinez
Abstract: The present invention provides a method for producing flame-retardant polyurethane foams, the resulting flame-retardant polyurethane foams having particularly low densities.
Type:
Application
Filed:
May 17, 2013
Publication date:
May 21, 2015
Applicant:
BAYER MATERIALSCIENCE AG
Inventors:
Sven Meyer-Ahrens, Stefan Lindner, Bert Klesczewski
Abstract: The present invention relates to impact-modified polylactic acid/polycarbonate compositions, containing A) 48 to 90 parts by weight, based in each case on the sum of the parts by weight of components A+B+C+D, of aromatic polycarbonate, B) 1 to 40 parts by weight, based in each case on the sum of the parts by weight of components A+B+C+D, of polylactic acid, C) 0.5 to 15 parts by weight, based in each case on the sum of the parts by weight of components A+B+C+D, of graft polymer, D) 2 to 25 parts by weight, based in each case on the sum of the parts by weight of components A+B+C+D, of a salt of a phosphinic acid and optionally additional components such as vinyl polymers and additives, which are distinguished by an optimum combination of high heat resistance, good flame retardance and excellent mechanical properties, to the use of the polycarbonate compositions for the production of mouldings and the mouldings themselves.
Abstract: The invention relates to radiation curable coating systems on the basis of aqueous polyurethane dispersions, to a method for the production thereof, to the use of the coating systems as paints and/or adhesives, and to objects and substrates provided with said paints and/or adhesives.
Type:
Grant
Filed:
January 30, 2010
Date of Patent:
May 19, 2015
Assignee:
Bayer MaterialScience AG
Inventors:
Stefan Sommer, Harald Blum, Jürgen Lippemeier, Miguel Fernandez
Abstract: The present invention relates to a process for producing polyether polyols having primary hydroxyl end groups, comprising the steps of reacting a starter compound containing active hydrogen atoms with an epoxide under double metal cyanide catalysis, reacting the resulting product with a cyclic carboxylic anhydride and reacting this resulting product with ethylene oxide in the presence of a catalyst containing at least one nitrogen atom per molecule, excluding non-cyclic, identically substituted tertiary amines. The invention further relates to polyether polyols obtainable by this process, compositions containing said polyols and polyurethane polymers based on said polyols.
Abstract: Isocyanates are produced in the gas phase and by-products such as ammonium halides are selectively separated from the gas phase by desublimation.
Type:
Grant
Filed:
May 26, 2009
Date of Patent:
May 12, 2015
Assignee:
Bayer MaterialScience AG
Inventors:
Sven Michael Hansen, Ralf Schneider, Bernd Schwethelm, Rolf Schiefer, Jürgen Dreher
Abstract: A mixing silo for free-flowing finely divided solid materials, in particular for powdered, fibrous and/or granular mixed material, especially polymer granules, specifically suited for mixing polymer granules, having an excellent mixing quality and at the same time a simplified and improved suitability for washing out in order to avoid cross contamination. The mixing silo may be used for homogenizing possibly inhomogeneous polymer granule batches in the form of a stream of product from a process producing polymer granules.
Type:
Grant
Filed:
March 8, 2012
Date of Patent:
May 12, 2015
Assignee:
Bayer MaterialScience AG
Inventors:
Herbert Ungerechts, Hans-Jörg Frank, Christoph Schwemler, Reiner Horl, Hans-Jürgen Thiem, Markus Hagedorn
Abstract: The present invention relates to a polymer composition including a transparent thermoplastic plastic, an inorganic infrared absorber, also referred to as IR absorber hereinbelow, optionally an inorganic nano-scale pigment, and the combination of at least one organic coloring agent of a specific structure, and to the preparation and use of the polymer compositions according to the invention and to products produced therefrom.
Type:
Grant
Filed:
December 15, 2011
Date of Patent:
May 12, 2015
Assignee:
Bayer MaterialScience AG
Inventors:
Alexander Meyer, Joerg Reichenauer, Andrea Scagnelli, Vincenzo Taravella
Abstract: The present invention relates to a method for working up distillation, residues from isocyanate production in which monomeric isocyanate present in distillation residues is recovered by means of a spray-dry method and the overall yield of monomeric isocyanate is thus significantly increased.
Type:
Grant
Filed:
July 9, 2013
Date of Patent:
May 12, 2015
Assignee:
Bayer MaterialScience AG
Inventors:
Friedhelm Steffens, Tim Loddenkemper, Rainer Bellinghausen, Hartwig Kempkes
Abstract: Process for producing a polyurethane foam and polyurethane foam obtainable therefrom A process for producing a polyurethane foam with bimodal cell size distribution, comprising the following steps: providing a mixture in a mixing head, where the mixture comprises: A) a component reactive towards isocyanates; B) a surfactant component; C) a blowing agent component selected from the group consisting of linear, branched or cyclic C1- to C6-alkanes, linear, branched or cyclic C1- to C6-fluoroalkanes, N2, O2, argon and/or CO2, where blowing agent component C) is present in the supercritical or near-critical state; D) a polyisocyanate component; discharging the mixture comprising components A), B), C), and D) from the mixing head where, during the discharge of the mixture, the pressure prevailing in the mixture is lowered to atmospheric pressure.
Type:
Grant
Filed:
November 3, 2010
Date of Patent:
May 5, 2015
Assignee:
Bayer MaterialScience AG
Inventors:
Stefan Lindner, Wolfgang Friederichs, Reinhard Strey, Thomas Sottmann, Elena Khazova, Lorenz Kramer, Verena Dahl, Agnes Chalbi
Abstract: Aromatic isocyanates are produced by reacting one or more aromatic primary amines with phosgene in the gas phase. The phosgene and primary aromatic amine(s) are reacted at a temperature above the boiling temperature of the amine(s) in a reactor having a reaction space which is essentially rotationally symmetric to the direction of flow. The flow fate, averaged over the cross-section, of the reaction mixture along the axis of the essentially rotationally symmetric reaction space in the section of the reaction space in which the conversion of the amine groups into isocyanate groups is between 4 and 80% is not more than 8 m/sec. The flow rate averaged over the cross-section of the reaction mixture along the axis of the essentially rotationally symmetric reaction space in the section of the reaction space in which the conversion of the amine groups into isocyanate groups is 4 to 80% is always below the flow rate averaged over the cross-section at the start of this section.
Type:
Grant
Filed:
December 7, 2009
Date of Patent:
May 5, 2015
Assignee:
Bayer MaterialScience AG
Inventors:
Klaus Biskup, Rainer Bruns, Wolfgang Lorenz, Fritz Pohl, Friedhelm Steffens, Volker Michele