Abstract: The invention relates to a spider-silk-like polymer fiber in the technical field of chemical bionics, a preparation method therefor and the use thereof. The spider-silk-like polymer fiber comprises a matrix polymer and a particle additive dispersed therein, wherein the particles have an average particle size of 0.1-1000 microns, and the polymer fiber has a spider-silk-like microstructure comprising a fiber body and spaced spindle knot structural units on the fiber body, wherein the spindle knot structural units comprise the particles, and the radial height of the spindle knot structural units is greater than the diameter of the fiber body. The preparation method of the polymer fiber of the invention does not require greatly modifying the existing spinning processes, and the equipment does not need to be changed, the process is simple, and the cost is low.

Abstract: A method for preparing an aliphatic polyester resin powder includes the steps of a) heat dissolving a crystalline aliphatic polyester resin in an organic solvent to obtain an aliphatic polyester resin solution; b) cooling the aliphatic polyester resin solution to precipitate a solid, thereby obtaining a solid-liquid mixture; c) optionally adding an adjuvant to the solid-liquid mixture and mixing; and d) conducting solid-liquid separation and drying to obtain an aliphatic polyester resin powder suitable for selective laser sintering. The crystalline aliphatic polyester resin powder obtained has good antioxidant property, good powder flowability, moderate size, smooth surface, suitable bulk density, and suitable dispersibility and particle size distribution. The aliphatic polyester resin powder is particularly suitable for selective laser sintering method.

Abstract: The present invention relates to a polymer/filler/metal composite fiber, including a polymer fiber comprising a metal short fiber and a filler; the metal short fiber is distributed as a dispersed phase within the polymer fiber and distributed in parallel to the axis of the polymer fiber; the filler is dispersed within the polymer fiber and distributed between the metal short fibers; the filler does not melt at the processing temperature of the polymer; said metal is a low melting point metal and selected from at least one of single component metals and metal alloys, and has a melting point which ranges from 20 to 480° C., and, at the same time, which is lower than the processing temperature of the polymer; the metal short fiber and the polymer fiber have a volume ratio of from 0.01:100 to 20:100; the filler and the polymer have a weight ratio of from 0.1:100 to 30:100.

Abstract: Disclosed is a composite catalyst, comprising carbon in a continuous phase and Raney alloy particles in a dispersed phase. The Raney alloy particles are dispersed evenly or unevenly in the carbon in a continuous phase, and the carbon in a continuous phase is obtained by carbonizing at least one carbonizable organic substance. The catalyst has good particle strength, high catalytic activity, and good selectivity.

Abstract: The invention relates to a flame-retardant thermoplastic material, comprising thermoplastic base resin, a flame retardant, and an optional antioxidant, wherein the flame retardant comprises a complex of phosphine oxide and a transition metal salt. The invention also relates to flame-retardant thermoplastic expanded beads. A foam molding prepared from the flame-retardant thermoplastic expanded beads has good flame-retardant and antistatic properties, has excellent mechanical properties and is widely used.

Abstract: Disclosed is a catalyst component for olefin polymerization. The catalyst component comprises magnesium, titanium, halogen and an internal electron donor. The internal electron donor includes an imine compound with a ketone group as shown in Formula I. Disclosed further is a method of preparing the catalyst component, and a catalyst for olefin polymerization containing the catalyst component. When the catalyst is used in olefin polymerization reaction especially propene polymerization reaction, the catalyst has a high long-term activity and good hydrogen response, and the obtained polymer has characteristics of an adjustable isotactic index and a relatively wide molecular weight distribution.

Abstract: Disclosed is a composite catalyst, comprising carbon in a continuous phase and Raney alloy particles in a dispersed phase. The Raney alloy particles are dispersed evenly or unevenly in the carbon in a continuous phase, and the carbon in a continuous phase is obtained by carbonizing at least one carbonizable organic substance. The catalyst has good particle strength, high catalytic activity, and good selectivity.

Abstract: The present invention refers to a flame retardant comprising a complex formed by phosphine oxide and transition metal salt, wherein has good flame retardant property. The present invention also refers to a composite flame retardant and flame retardant antistatic composition. The present invention also further refers to a flame resistant method, which adds the abovementioned flame retardant, composite flame retardant or flame retardant antistatic composition into the material, so that said material has flame retardance or flame retardance and antistatic, and has excellent mechanical properties.

Abstract: The invention discloses a process for preparing high-performance propylene polymers, the process utilizing a high activity, highly stereoselective Ziegler-Natta catalyst and two or more stages of polymerization carried out under different hydrogen concentrations to prepare propylene polymers having broad molecular weight distribution, wherein non-uniformness of isotacticity of molecular chains of the final propylene polymers is improved by adjusting or controlling stereoselectivity of catalytic active sites under different hydrogen concentrations, namely, making the low molecular weight fraction of the polymers having a higher isotacticity and making the high molecular weight fraction of the polymers having a lower isotacticity, thereby overcoming the drawbacks of the propylene polymers having broad molecular weight distribution known in the art. The resulting final polymers have excellent combined properties, in particular, remarkably improved mechanical properties.

Abstract: A polyester composition includes a first polyester selected from one or more of aliphatic-aromatic copolyesters, which is a copolymer comprising repeating units A as shown in formula (I) and repeating units B as shown in formula (II), in which m is an integer of 2 to 10 and n is an integer of 2 to 8; p is an integer of 2 to 10; and m, n and p are the same or different from each other. Optionally, the polyester composition has a second polyester. The polyester composition includes at least two polyesters. The polyester composition can be used in shape memory materials, 3D print wires, heat shrinkable sleeves, functional layers, medical limb immobilization braces, heat shrinkable thin films, nonwoven fabrics, elastic fibers, etc.

Abstract: A polyester composition includes polybutylene terephthalate and an aliphatic-aromatic copolyester. Based on the total weight of the polybutylene terephthalate and the aliphatic-aromatic copolyester, the content of the polybutylene terephthalate is from 50 to 99% by weight, and the content of the aliphatic-aromatic copolyester is from 1 to 50% by weight. Further, a method for preparing such a polyester composition and a toughened composite material prepared therefrom. The polyester composition has an elongation at break of up to 230% or more, and an improved toughness without substantial loss of strength.

Abstract: Disclosed herein are a polypropylene with narrow molecular weight distribution and a process for preparing the same in a reactor using a Ziegler-Natta catalyst.

Abstract: A magnesium halide adduct represented by the formula (I): MgX2.mROH.nE.pH2O, in which X is chlorine, bromine, a C1-C12 alkoxy, a C3-C10 cycloalkoxy or a C6-C10 aryloxy, with the proviso that at least one X is chlorine or bromine; R is a C1-C12 alkyl, a C3-C10 cycloalkyl or a C6-C10 aryl; E is an o-alkoxybenzoate compound represented by the formula (II): in which R1 and R2 groups are independently a C1-C12 linear or branched alkyl, a C3-C10 cycloalkyl, a C6-C10 aryl, a C7-C10 alkaryl or an C7-C10 aralkyl, the R1 and R2 groups are identical to or different from the R group; m is in a range of from 1.0 to 5.0; n is in a range of from 0.001 to 0.5; and p is in a range of from 0 to 0.8, is disclosed. A catalyst component useful in olefin polymerization, which comprises a reaction product of (1) the magnesium halide adduct, (2) a titanium compound, and optionally (3) an electron donor compound, is also disclosed.

Abstract: A heat transfer tube includes a twisted baffle arranged in an inner wall of the tube. The twisted baffle extends spirally along an axial direction of the heat transfer tube. The twisted baffle is provided with a non-through gap extending along an axial direction of the heat transfer tube from an end to the other end of the twisted baffle. A cracking furnace uses the heat transfer tube. The heat transfer tube and cracking furnace have good heat transfer effects and small pressure loss.

Abstract: The present invention provides a catalyst component for olefin polymerization, obtained by a reaction of magnesium, titanium, halogen and an internal electron donor, the internal electron donor comprising an imine compound as shown in Formula Z. The present invention also provides a preparation method of the catalyst component, and a catalyst for olefin polymerization containing the same. When the catalyst of the present invention is used for olefin polymerization reaction, the catalyst has a high activity, and a slow rate of activity decay, and the obtained polymer has a high isotacticity index, and a wide molecular weight distribution.

Abstract: The present invention discloses a catalyst component for propene polymerization, comprising titanium, magnesium, halogen, and internal electron donor A, wherein said internal electron donor A is selected from the compounds as shown in Formula I, in Formula I, R is selected from hydrogen, hydroxyl, and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen, hydroxyl, and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C6-C30 heteroaryl, C7-C30 alkylaryl and C7-C30 arylalkyl; R1 and R2 may be identical to or different from each other, and are selected from hydrogen and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C7-C30 alkylaryl and C7-C30 arylalkyl. According to the present invention, by using the compound as shown in Formula I as internal electron donor compound for propene polymerization, the catalyst has a higher activity, and a slow rate of delay of activity.

Abstract: The present invention provides a preparation method of a catalyst component for olefin polymerization, comprising firstly dissolving an anhydrous magnesium halide into a mixed solvent which comprises an oxygen-containing organic titanium compound, an organic epoxy compound, a hydroxy-containing compound, and an inert solvent, and does not comprise a phosphate compound, so as to form a magnesium halide solution; then mixing the magnesium halide solution with a halogen-containing compound to precipitate a solid, so as to obtain the catalyst component, wherein the halogen-containing compound comprises at least one selected from a group consisting of halogen and titanium-containing compounds, halogenated organic hydrocarbon compounds, acyl halide compounds, halogen and phosphorus-containing compounds, halogen and boron-containing compounds, halogenated organic aluminum compounds, and halogen and silicon-containing compounds.

Abstract: A catalyst component (A) for olefin polymerization is prepared by contacting a solid component (a) containing magnesium, titanium, halogen and an internal electron donor compound with an organosilicon compound (b), wherein the organosilicon compound (b) is one or more selected from a Si—H functional group containing chainlike polysiloxane (b1) represented by formula (Ix), a cyclic polysiloxane (b2) represented by formula (Iy) and a Si—H functional group containing organosilicon compound (b3) represented by formula (Iz). In addition, a process for preparing the catalyst component and the corresponding catalyst is described. The catalyst component and its catalyst have high catalytic activity, good hydrogen response, and good stereospecificity, the catalyst can release its activity more evenly, and the obtained polymer has significantly increased bulk density. The definitions of R1 to R10, n and z in the formulae (Ix), (ly) and (Iz) are as described in the specification.

Abstract: A magnesium halide solution is disclosed. The magnesium halide solution comprises a magnesium halide, an oxygen-containing organic titanium compound, a hydroxyl-containing compound, and an organic solvent. The magnesium halide solution further comprises an organic heterocyclic compound. The organic solvent is a hydrocarbon and/or a halogenated hydrocarbon. The organic heterocyclic compound is at least one selected from a group consisting of a sulphur-containing organic heterocyclic compound, a nitrogen-containing organic heterocyclic compound, and an organic epoxy compound. The magnesium halide solution has a good stability, and can be used for preparing a catalyst for olefin polymerization and copolymerization reactions. The raw material of the magnesium halide solution is cheap and easy to be obtained. The preparing method is easy to be performed and is environment-friendly.

Abstract: A complex nanofiltration membrane comprising a substrate and a separating layer, wherein the separating layer is an oxidant-treated, crosslinked network structure formed from a hydroxyl-containing polymer, a thiol-containing silane coupling agent and a crosslinking agent, is disclosed. Also disclosed are a process for preparing the complex nanofiltration membrane and use of the complex nanofiltration membrane in water treatment.