Patents Assigned to Beijing Research Institute of Chemical Industry
  • Patent number: 9988505
    Abstract: A polyethylene composition comprising an ethylene/?-olefin copolymerized linear low density polyethylene, wherein the polyethylene composition has a Mw of from 100,000 g/mol to 200,000 g/mol, a Mw/Mn of from 4.0 to 9.0, a Mz/Mw of from 4.0 to 7.0, and a Mz+1/Mw of from 4.5 to 13.5, is provided. A film formed of the polyethylene composition is also provided.
    Type: Grant
    Filed: October 27, 2015
    Date of Patent: June 5, 2018
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum and Chemical Corporation
    Inventors: Dali Gao, Hongwei Shi, Shijun Zhang, Meifang Guo, Luqiang Yu, Jinliang Qiao, Ruxian Li, Yujing Tang, Jianjun Yin, Liangshi Wang, Honghong Huang, Qingquan Yang, Hao Zou, Jie Li, Liying Zhang, Hua Yin, Jianye Liu, Jingbo Shao, Mingfu Lyu, Liqiu Chu, Meng Xu, Hui Quan, Kai Xu, Mu Dong, Yun Lyu, Yihui Xu, Yaohui Xu, Peng Guo, Yiqing Bai
  • Patent number: 9951157
    Abstract: Spherical carriers for an olefin polymerization catalyst, catalyst components, catalysts, and preparation methods therefor are disclosed. The method for preparing the spherical carriers comprises the following steps: (1) reacting, in the presence of at least one polymeric dispersion stabilizer, a magnesium halide with an organic compound containing active hydrogen to form a complex solution; (2) reacting said complex solution with an alkylene oxide-type compound to directly precipitate solid particles; and (3) recovering the solid particles to obtain spherical carriers. When a catalyst prepared by using the present spherical carrier is used in propylene polymerization, said catalyst exhibits high polymerization activity and high stereo-directing ability.
    Type: Grant
    Filed: October 17, 2014
    Date of Patent: April 24, 2018
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Weili Li, Xianzhi Xia, Yuexiang Liu, Yongtai Ling, Jin Zhao, Jigui Zhang, Futang Gao, Ping Gao, Yang Tan, Renqi Peng, Zhihui Zhang, Jie Lin, Ruilin Duan, Changyou Ma
  • Patent number: 9944883
    Abstract: The present invention relates to the field of lubricant, and specifically provides a lubricant composition and its preparation method and use. The lubricant composition comprises a base oil and rubber particles having radiation crosslinked structure dispersed therein, wherein the base oil is continuous phase and the rubber particles are dispersed phase. The viscosity of the lubricant composition of the present invention can be effectively adjusted as temperature changes. As compared with the lubricant composition comprising chemically crosslinked rubber particles, it has a lower viscosity at low temperatures and a higher viscosity at high temperatures, and has a relatively high viscosity index, which can meet the application requirements at the temperature above 200° C. In addition, the lubricant composition of the present invention also has excellent antiwear and friction-reducing properties.
    Type: Grant
    Filed: April 19, 2016
    Date of Patent: April 17, 2018
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Xiaohong Zhang, Chuanlun Cai, Jinmei Lai, Jinliang Qiao, Zhihai Song, Guicun Qi, Binghai Li, Xiang Wang, Jianming Gao, Hongbin Zhang, Haibin Jiang, Gu He, Yue Ru
  • Patent number: 9834675
    Abstract: The present invention relates to a resin composition having an improved haze effect and light transmittance and a process for preparing the same. The resin composition comprises blended components: a) a matrix resin; and b) crosslinked copolymer microspheres; wherein the crosslinked copolymer microspheres are alternating copolymers formed from monomers having anhydride, amide and/or imide groups, with olefin monomers and/or furan and its derivatives and optionally crosslinked with a crosslinking agent; preferably, the resin composition has a haze of not less than 92%, and a light transmittance of not less than 55%, preferably a haze of not less than 92%, and a light transmittance of not less than 59%, and more preferably a haze of not less than 95%, and a light transmittance of not less than 59%. The resin composition is energy efficient in use, provides excellent light diffusing effect, and, at the same time reduces the material cost.
    Type: Grant
    Filed: April 8, 2016
    Date of Patent: December 5, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Jinliang Qiao, Yue Ru, Xiaohong Zhang, Wantai Yang, Guicun Qi, Chuanlun Cai, Jinmei Lai, Binghai Li, Xiang Wang, Zhihai Song, Jianming Gao, Hongbin Zhang, Haibin Jiang, Gu He
  • Patent number: 9822196
    Abstract: The present disclosure discloses a catalyst composition for olefin polymerization, comprising the following components: a): a solid catalyst component containing magnesium, titanium, halogens, and at least one internal electron donor having a lone pair of electrons; b): an aluminum alkyl compound; and c): an external electron donor containing a first external electron donor C1, which is a malonate compound. In the present disclosure, a catalyst composition having an external electron donor that contains a malonate compound is used in olefin polymerization, in particular propene polymerization, and can significantly improve catalytic activity and hydrogen response of the catalyst and expand molecular weight distribution of polymers, which facilitates development of different polymers.
    Type: Grant
    Filed: September 28, 2014
    Date of Patent: November 21, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Changxiu Li, Mingzhi Gao, Haitao Liu, Jing Ma, Jianhua Chen, Xianzhong Li, Xiaoxia Cai, Jixing Ma, Jun Wang, Jianjun Hu
  • Patent number: 9751965
    Abstract: Disclosed herein is a polymerization method of propylene, which can prepare a propylene homopolymer with both high fluidity and high rigidity as well as a propylene/?-define copolymer having both high fluidity and a good rigidity-toughness balance by, for example, control of polymerization steps and elevation of polymerization temperature, while the catalyst still maintains a relatively high polymerization activity.
    Type: Grant
    Filed: October 30, 2013
    Date of Patent: September 5, 2017
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Luqiang Yu, Zhichao Yang, Jiangbo Chen, Jianxin Zhang, Yafeng Du, Qinyu Tong, Kang Sun, Yang Liu, Jie Zou, Lusheng Wang, Zengyue Dai, Zhong Tan
  • Patent number: 9751960
    Abstract: The present disclosure provides a solid catalyst component for olefin polymerization, comprising magnesium, titanium, a halogen, and an electron donor, wherein the electron donor is at least one selected from the group consisting of diol diester compounds as shown in Formula (I). The catalyst according to the present disclosure has significantly improved polymerization activity, hydrogen response, and stereoselectivity. According to the present disclosure, when the catalyst system containing a diol diester compound as shown in Formula (I) of the present disclosure is used in olefin polymerization, the catalyst shows good comprehensive performance, including high catalytic activity. In particular, in the presence of highly concentrated hydrogen, the catalyst has an improved hydrogen response and/or isotacticity of the polymers obtained can be significantly improved.
    Type: Grant
    Filed: May 21, 2014
    Date of Patent: September 5, 2017
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Changxiu Li, Mingzhi Gao, Haitao Liu, Jianhua Chen, Jing Ma, Jixing Ma, Xiaoxia Cai, Jun Wang, Xiaofan Zhang, Jianjun Hu
  • Patent number: 9643172
    Abstract: A metal loaded catalyst comprises a support and main active metal components and optional auxiliary active metal components, wherein the main active metal components are elementary substances and obtained by ionizing radiation reducing precursors of main active metal components. The catalyst can be widely used in the catalytic reactions of petrochemistry industry with high activity and selectivity. The catalyst can be used directly without being reduced preliminarily by hydrogen.
    Type: Grant
    Filed: October 16, 2015
    Date of Patent: May 9, 2017
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry
    Inventors: Wei Dai, Jing Peng, Haibo Yu, Hui Peng, Genshuan Wei, Maolin Zhai, Zuwang Mao, Yi Le, Wei Mu, Haijiang Liu, Yunxian Zhu
  • Publication number: 20170101486
    Abstract: A magnesium halide adduct represented by the formula (I): MgX2.mROH.nE.pH2O, in which X is chlorine, bromine, a C1-C12 alkoxy, a C3-C10 cycloalkoxy or a C6-C10 aryloxy, with the proviso that at least one X is chlorine or bromine; R is a C1-C12 alkyl, a C3-C10 cycloalkyl or a C6-C10 aryl; E is an o-alkoxybenzoate compound represented by the formula (II): in which R1 and R2 groups are independently a C1-C12 linear or branched alkyl, a C3-C10 cycloalkyl, a C6-C10 aryl, a C7-C10 alkaryl or an C7-C10 aralkyl, the R1 and R2 groups are identical to or different from the R group; m is in a range of from 1.0 to 5.0; n is in a range of from 0.001to 0.5; and p is in a range of from 0 to 0.8, is disclosed. A catalyst component useful in olefin polymerization, which comprises a reaction product of (1) the magnesium halide adduct, (2) a titanium compound, and optionally (3) an electron donor compound, is also disclosed.
    Type: Application
    Filed: October 13, 2016
    Publication date: April 13, 2017
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Xianzhi XIA, Yuexiang LIU, Jigui ZHANG, Xinsheng WANG, Ping GAO, Suzhen QIAO, Maoping YIN, Weili LI, Tianyi ZHANG, Renqi PENG, Ying CHEN, Zhihui ZHANG
  • Publication number: 20170073441
    Abstract: The present invention provides a catalyst component for olefin polymerization, obtained by a reaction of magnesium, titanium, halogen and an internal electron donor, the internal electron donor comprising an imine compound as shown in Formula Z. The present invention also provides a preparation method of the catalyst component, and a catalyst for olefin polymerization containing the same. When the catalyst of the present invention is used for olefin polymerization reaction, the catalyst has a high activity, and a slow rate of activity decay, and the obtained polymer has a high isotacticity index, and a wide molecular weight distribution.
    Type: Application
    Filed: April 24, 2015
    Publication date: March 16, 2017
    Applicants: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroteum & Chemical Corporation
    Inventors: Mingzhi GAO, Jun WANG, Haitao LIU, Jing MA, Jianhua CHEN, Jixing MA, Xiaoxia CAI, Changxiu LI, Jianjun HU, Xiaofan ZHANG, Xianzhong LI, Zhihui ZHANG, Ruilin DUAN, Linna YANG, Changyou MA
  • Patent number: 9593185
    Abstract: The present disclosure provides a suspension of a solid catalyst component used in propylene polymerization and a method for preparing the same. The suspension includes the solid catalyst component and a liquid medium containing propylene and an alkane, and is preferably prepared by mixing the solid catalyst component and the alkane to obtain a mixed slurry, which is further mixed with liquid propylene. Using of a proper liquid dispersing agent at a proper proportion and amount enables the solid catalyst component to be more homogeneously dispersed, thus preventing the phenomenon of agglomeration in the polymerization process without using a large amount of the dispersing agent or any additional mixer. The present disclosure further provides a method of propylene polymerization, including feeding the suspension into a reaction system of propylene polymerization, wherein propylene polymerization is initiated under polymerization conditions.
    Type: Grant
    Filed: December 5, 2014
    Date of Patent: March 14, 2017
    Assignees: China Petroleum & Chemical Corporation, Sinopec Catalyst Co., Ltd., Beijing Research Institute Of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Jinlai Qin, Haixiang Cui, Xiaodong Wang, Mingzhi Gao, Cuiling Xiao, Yanju Sun, Liang Pan, Xin Chen, Ziqiang Wang
  • Patent number: 9592491
    Abstract: The present disclosure discloses an ?-alumina carrier, comprising the elements of lanthanum and silicon both dispersed in the interior and on the surface of the carrier. The mass ratio of the element of lanthanum to the element of silicon is in the range from 0.1:1 to 20:1. The inventors of the present disclosure have made extensive researches into the field of the silver catalyst and alumina carrier thereof, and added the elements of lanthanum and silicon (i.e., bulk phase addition) in preparing the alumina carrier used in the silver catalyst. The carrier thus obtained contains the elements of silicon and lanthanum both in the interior and on the surface thereof, and has improved specific surface area and strength. The silver catalyst prepared with the carrier can react in a low reaction temperature (has a high reaction activity) and has a high selectivity in producing ethylene oxide through oxidation of ethylene.
    Type: Grant
    Filed: October 28, 2014
    Date of Patent: March 14, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Xianfeng Li, Jinbing Li, Xinxin Sun, Jianshe Chen, Shuyuan Cao, Lixin Gao, Hui Wang, Rujun Liang, Qian Xue, Zhixiang Zhang
  • Publication number: 20170058060
    Abstract: A magnesium halide solution is disclosed. The magnesium halide solution comprises a magnesium halide, an oxygen-containing organic titanium compound, a hydroxyl-containing compound, and an organic solvent. The magnesium halide solution further comprises an organic heterocyclic compound. The organic solvent is a hydrocarbon and/or a halogenated hydrocarbon. The organic heterocyclic compound is at least one selected from a group consisting of a sulphur-containing organic heterocyclic compound, a nitrogen-containing organic heterocyclic compound, and an organic epoxy compound. The magnesium halide solution has a good stability, and can be used for preparing a catalyst for olefin polymerization and copolymerization reactions. The raw material of the magnesium halide solution is cheap and easy to be obtained. The preparing method is easy to be performed and is environment-friendly.
    Type: Application
    Filed: April 29, 2015
    Publication date: March 2, 2017
    Applicants: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Shibo WANG, Junling ZHOU, Dongbing LIU, Lei ZHANG, Xinping LV, Bingquan MAO, Zhenjie LIU, Xin ZHOU, Changli ZHANG, Baoquan XING
  • Publication number: 20170051086
    Abstract: The present invention provides a preparation method of a catalyst component for olefin polymerization, comprising firstly dissolving an anhydrous magnesium halide into a mixed solvent which comprises an oxygen-containing organic titanium compound, an organic epoxy compound, a hydroxy-containing compound, and an inert solvent, and does not comprise a phosphate compound, so as to form a magnesium halide solution; then mixing the magnesium halide solution with a halogen-containing compound to precipitate a solid, so as to obtain the catalyst component, wherein the halogen-containing compound comprises at least one selected from a group consisting of halogen and titanium-containing compounds, halogenated organic hydrocarbon compounds, acyl halide compounds, halogen and phosphorus-containing compounds, halogen and boron-containing compounds, halogenated organic aluminium compounds, and halogen and silicon-containing compounds.
    Type: Application
    Filed: April 29, 2015
    Publication date: February 23, 2017
    Applicants: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Shibo WANG, Junling ZHOU, Dongbing LIU, Lei ZHANG, Xinping LV, Bingquan MAO, Zhenjie LIU, Xin ZHOU, Changli ZHANG, Baoquan Xing
  • Publication number: 20170044280
    Abstract: The present invention discloses a catalyst component for propene polymerization, comprising titanium, magnesium, halogen, and internal electron donor A, wherein said internal electron donor A is selected from the compounds as shown in Formula I, in Formula I, R is selected from hydrogen, hydroxyl, and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen, hydroxyl, and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C6-C30 heteroaryl, C7-C30 alkylaryl and C7-C30 arylalkyl; R1 and R2 may be identical to or different from each other, and are selected from hydrogen and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C7-C30 alkylaryl and C7-C30 arylalkyl. According to the present invention, by using the compound as shown in Formula I as internal electron donor compound for propene polymerization, the catalyst has a higher activity, and a slow rate of delay of activity.
    Type: Application
    Filed: April 24, 2015
    Publication date: February 16, 2017
    Applicants: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry China Petroleum & Chemical Corporation
    Inventors: Jun WANG, Mingzhi GAO, Haitao LIU, Jing MA, Jianhua CHEN, Xiaoxia CAI, Jixing MA, Changxiu LI, Jianjun HU, Xiaofan ZHANG, Xianzhong LI, Zhihui ZHANG, Ruilin DUAN, Linna YANG, Changyou MA
  • Patent number: 9505677
    Abstract: The present disclosure provides a steam cracking process, comprising heating a liquid feed stock in a convection section of a cracking furnace and subsequently conveying the material to a radiant section of the cracking furnace for cracking reaction therein, wherein a monoolefin-containing stream is conveyed to the cracking furnace for cracking reaction through at least one of modes A to C.
    Type: Grant
    Filed: October 28, 2013
    Date of Patent: November 29, 2016
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Guoqing Wang, Lijun Zhang, Yonggang Zhang, Junjie Liu, Zhiguo Du, Xianfeng Zhou, Wei Li, Cong Zhou
  • Patent number: 9499569
    Abstract: A magnesium halide adduct represented by the formula (I): MgX2.mROH.nE.pH2O, in which X is chlorine, bromine, a C1-C12 alkoxy, a C3-C10 cycloalkoxy or a C6-C10 aryloxy, with the proviso that at least one X is chlorine or bromine; R is a C1-C12 alkyl, a C3-C10 cycloalkyl or a C6-C10 aryl; E is an o-alkoxybenzoate compound represented by the formula (II): in which R1 and R2 groups are independently a C1-C12 linear or branched alkyl, a C3-C10 cycloalkyl, a C6-C10 aryl, a C7-C10 alkaryl or an C7-C10 aralkyl, the R1 and R2 groups are identical to or different from the R group; m is in a range of from 1.0 to 5.0; n is in a range of from 0.001 to 0.5; and p is in a range of from 0 to 0.8, is disclosed. A catalyst component useful in olefin polymerization, which comprises a reaction product of (1) the magnesium halide adduct, (2) a titanium compound, and optionally (3) an electron donor compound, is also disclosed.
    Type: Grant
    Filed: July 15, 2009
    Date of Patent: November 22, 2016
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Xianzhi Xia, Yuexiang Liu, Jigui Zhang, Xinsheng Wang, Ping Gao, Suzhen Qiao, Maoping Yin, Weili Li, Tianyi Zhang, Renqi Peng, Ying Chen, Zhihui Zhang
  • Patent number: 9453122
    Abstract: A rubber composition, preparation method and vulcanized rubber thereof are provided. The rubber composition comprises uncrosslinked rubber and rubber particles having crosslinked structure dispersed therein, wherein the rubber particles having crosslinked structure are synthetic rubber particles and/or natural rubber particles with an average particle size of 20 to 500 nm and a gel content of 60% by weight or higher, and the uncrosslinked rubber is styrene-butadiene rubber, and wherein the weight ratio of the rubber particles having crosslinked structure to the uncrosslinked rubber is 1:99-20:80.
    Type: Grant
    Filed: October 26, 2012
    Date of Patent: September 27, 2016
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Jinliang Qiao, Yuexin Cong, Xiaohong Zhang, Ying Li, Jianming Gao, Qianmin Zhang, Zhihai Song, Yanling Sun, Meifang Guo, Peijun Song, Chuanlun Cai, Guoxun Zhao, Hongwei Shi, Guicun Qi, Jinmei Lai, Hongbin Zhang, Ya Wang, Binghai Li, Xiang Wang
  • Patent number: 9424959
    Abstract: The invention provides a conductive full vulcanized thermoplastic elastomer and its preparation method, and relates to the technical field of full vulcanized thermoplastic elastomer. The full vulcanized thermoplastic elastomer is obtained by melt-blending components including rubber particles having crosslinking structure with mean particle diameter of 0.02 to 1 ?m, carbon nanotubes as conductive fillers and thermoplastic plastics once, wherein the weight ratio of the rubber particles and the thermoplastic plastics is from 30:70 to 75:25 and the content of conductive fillers is from 0.3 to 10 weight parts based on the total weight of rubber particles and thermoplastic plastics of 100 weight parts. The resulting conductive full vulcanized thermoplastic elastomers have low content of conductive fillers and excellent combination performances.
    Type: Grant
    Filed: March 2, 2012
    Date of Patent: August 23, 2016
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry China Petroleum & Chemical Corporation
    Inventors: Xiaohong Zhang, Jinliang Qiao, Guicun Qi, Zhihai Song, Chuanlun Cai, Ya Wang, Jianming Gao, Hongbin Zhang, Jinmei Lai, Binghai Li, Haosheng Wang, Yilei Zhu
  • Patent number: 9376513
    Abstract: Disclosed is a solid catalyst component for olefin polymerization. The catalyst component comprises a dialkoxy magnesium carrier, a titanium compound, and a product from an internal electron donor reacting in an inert solvent. The internal electron donor compound comprises a 2,3-di-non-linear-alkyl-2-cyano succinic acid diester compound as presented in formula I.
    Type: Grant
    Filed: January 19, 2012
    Date of Patent: June 28, 2016
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Zhong Tan, Lunjia Xie, Xiudong Xu, Yu Tian, Qilong Zhou, Zaixing Feng, Li'an Yan, Siyuan Zhao, Jinhua Yu, Zhufang Sun, Fengkui Li, Shanshan Yin, Weiwei Song